SOLUTION & COLLIGATIVE PROPERTIES

Preface

As you have gone through the theory part that consists of given fundamental
principles, definitions, concepts involved and solved problems. After going through
theory part it becomes necessary to solve the unsolved problems based on the
concepts given. To solve this purpose we are providing exercise part that
comprises of various exercises based on the theory. By solving various kinds
of problems you can check your grasp on the topic and can determine whether
you have been able to find optimum depth in relevant topic or not.

Students are advised to solve the questions of exercises (Levels # 1, 2, 3, 4)

in the same sequence or as directed by the faculty members, religiously and
very carefully.

Level # 3 is not for foundation course students, it will be discussed in fresher

or target courses.

Total No.of questions in Solution & Colligative Properties are -

Level # 1 ....................................................................................... 67
Level # 2 ........................................ ........................................... 71
Level # 3 ........................................ ........................................... 20
Level # 4 ........................................ ........................................... 39

Total No. of questions .............................................................. 197

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 Q.10 5.85 g of NaCl are dissolved in 90 g of
Questions Different concentration terms of water. The mole fraction of NaCl is -
based on
a solution (A) 0.1 (B) 0.01
(C) 0.2 (D) 0.0196
Q.1 The molarity of a glucose solution containing
Q.11 The molality of 15% (wt./vol.) solution of
36 g of glucose per 400 mL of the solution is-
H 2 SO 4 of density 1.1 g/cm 3 is
(A) 1.0 (B) 0.5 (C) 2.0 (D) 0.05
approximately-
Q.2 A molal solution is one that contains one (A) 1.2 (B) 1.4 (C) 1.8 (D) 1.6
mole of a solute in -
Q.12 10 mL of concentrated H 2 SO 4 (18M) is
(A) 1000gm of the solution
diluted to one litre. The approximate strength
(B) 1000c.c. of the solution
of the dilute acid is-
(C) 1000c.c of the solvent
(A) 18 M (B) 180 M
(D) 1000gm of the solvent
(C) 0.18 M (D) 1.8 M
Q.3 Molarity of a solution relates the-
Q.13 2.3 g of C2H5OH (mol. wt. 46) are dissolved
(A) Moles of solute and solvent
in 500 mL of water. The molarity of the
(B) Moles of solute and mass of solution
solution is -
(C) Volume of solute and volume of solvent
(A) 0.01 (B) 0.1 (C) 0.05 (D) 2.0
(D) Volume of solution and moles of solute
Q.14 The number of moles present in 2 litre of 0.5
Q.4 The units of mole fraction of a compound in
M NaOH is-
solution are-
(A) 2 (B) 1 (C) 0.1 (D) 0.5
(A) mol kg –1 (B) mol litre –1
(C) g litre–1 (D) None of these Q.15 3.0 molal NaOH solution has a density of
1.110 g/ml. The molarity of the solution is-
Q.5 Which of the following is correct-
wt. (A) 2.9732 (B) 3.05
(A) mole = molarity x Vin = (C) 3.64 (D) 3.0504
mol. wt.
(B) milli mole = molarity x Vin mL Q.16 A solution contains one mole of alcohol and
wt.
= x 1000 four moles of water. What are the mole
mol. wt. fractions of water and alcohol-
(C) Moles and millimoles of reactants react
(A) 1/4, 4/1 (B) 4/1, 1/4
according to stoichiometric ratio of
(C) 4/5, 1/5 (D) 1/5, 4/5
balanced chemical equation
(D) All Q.17 The mole fraction of NaCl in a solution
containing 1 mole of NaCl in 1000 g of water
Q.6 The hardness of water is usually expressed
is -
in-
(A) 0.0177 (B) 0.001
(A) ppm (B) g/litre
(C) 0.5 (D) 0.244
(C) Mol/litre (D) None
Q.18 In the aqueous solution of sulphuric acid the
Q.7 Density of water is 1g/mL. The concentration
mole fraction of water is 0.85. The molality of
of water in mol/litre is-
the solution is-
(A) 1000 (B) 18 (C) 0.018 (D) 55.5
(A) 8.9 m (B) 0.19 m
Q.8 How many grams of NaOH will be needed to (C) 9.8 m (D) 15 m
prepare 250 mL of 0.1 M solution -
Q.19 1000 gram aqueous solution of CaCO 3
(A) 1 g (B) 10 g (C) 4 g (D) 6 g
contains 10 gram of carbonate. Concentration
Q.9 How many grams of glucose should be of solution is-
dissolved to make one litre solution of 10%(w/v) (A) 10 ppm (B) 100 ppm
glucose- (C) 1000 ppm (D) 10,000 ppm
(A) 10 g (B) 180 g (C) 100 g (D) 1.8 g
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Q.20 Equal volumes of 0.1 M AgNO3 and 0.2 M Q.28 The relative lowering in vapour pressure is-
NaCl are mixed. The concentration of NO3– 1
ions in the mixture will be- (A)  Xsolute (B) 
X solute
(A) 0.1 M (B) 0.05 M (C) = Xsolute (D)  m
(C) 0.2 M (D) 0.15 M
Q.29 The boiling point of C6H6 , CH3OH , C6H5NH2
Q.21 H2O2 solution used for hair bleaching is sold and C6H5NO2 are 800C , 650C , 1840C and
as a solution of approximately 5.0 g H2O2 2120C respectively. Which will show highest
per 100 mL of the solution. The molecular vapour pressure at room temperature-
weight of H2O2 is 34. The molarity of this (A) C6H6 (B) CH3OH
solution is approximately- (C) C6H5NH2 (D) C6H5NO2
(A) 3.0 (B) 1.5 (C) 0.15 (D) 4.0 Q.30 An aqueous solution of methanol in water
has vapour pressure –
Q.22 All of the water in a 0.20 M solution of NaCl
(A) Equal to that of water
was evaporated and 0.150 mol of NaCl was
(B) Equal to that of methanol
obtained. What was the original volume of
(C) More than that of water
the sample ? (D) Less than that of water
(A) 30 mL (B) 333 mL
(C) 750 mL (D) 1000 mL Q.31 When a substance is dissolved in a solvent,
the vapour pressure of solvent decreases. This
Q.23 25 mL of 3.0 M HNO3 are mixed with 75 mL brings -
of 4.0M HNO3. If the volumes are additive, (A) An increase in b.pt. of the solution
the molarity of the final mixture would be - (B) A decrease in b.pt of a solution
(A) 3.25 M (B) 4.0 M (C) An increase in f.pt of the solvent
(C) 3.75 M (D) 3.50 M (D) none
Q.24 10 gram of glucose are dissolved in 150 gram Q.32 Boiling point of water is defined as the
of water. The mass % of glucose is- temperature at which –
(A) 5% (B) 6.25% (A) Vapour pressure of water becomes equal
(C) 93.75% (D) 15% to that of atmospheric pressure
(B) Bubbles are formed
Q.25 If 100 ml of 1.0 M NaOH solution is diluted (C) Steam comes out
to 1.0 L, the resulting solution contains- (D) None of the above
(A) 1 mole of NaOH
(B) 0.1 mole of NaOH Questions Raoult’s laws-ideal & Non-ideal
(C) 10.0 mole of NaOH based on solution
(D) 0.05 mole of NaOH Q.33 A solution of sulphuric acid in water
exhibits -
Questions Vapour pressure & Relative (A) Negative deviations from Raoult’s law
based on lowering in vapour pressure (B) Positive deviations from Raoult’s law
(C) Ideal properties
Q.26 If P0 and Ps are the vapour pressures of the (D) The applicability of Henry’s law
solvent and solution respectively and n1 and
Q.34 Binary liquid mixtures which exhibit positive
n2 are the mole fractions of the solvent and deviations from Raoult’s law boil at .....
solute respectively, then- temperature than the expected b.pt -
(A) Ps = P0n1 (B) Ps = P0n2 (A) Lower (B) Higher
(C) P0 = Psn2 (D) Ps = P0 (n1/n2) (C) Same (D) Can’t be said
Q.27 Vapour pressure of a solvent containing Q.35 Which of the following is not correct for ideal
nonvolatile solute is - solution -
(A) More than the vapour pressure of a solvent (A) Raoult's law is obeyed for entire
(B) Less than the vapour pressure of solvent concentration range and temperatures
(C) Equal to the vapour pressure of solvent (B) Smix = 0
(D) None of these (C) Vmix = 0
(D) Hmix = 0

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Q.36 Which one of the following liquid-pairs shows Q.44 Azeotropic mixture of water and HCl boils at
a positive deviation from Raoult's law- 381.5 K. By distilling the mixture it is possible
(A) Acetone-chloroform to obtain-
(B) Benzene-methanol (A) Pure HCl only
(C) Water-Hydrochloric acid (B) Pure water only
(D) Water-nitric acid (C) Neither HCl nor water
(D) Both water and HCl in pure state
Q.37 Which of the following conditions is not
correct for ideal solution-
(A) no change in volume on mixing Questions
Elevation in B.P. & depression in F.P.
based on
(B) no change in enthalpy on mixing
(C) it obey's Raoult's law Q.45 Which of the following is not a colligative
(D) Ionisation of solute should occurs to a property -
small extent (A) T f (B)  (C) T b (D) Kb
Q.38 When a crystal of the solute is introduced Q.46 Solute when dissolved in water -
into a super saturated solution of the solute- (A) Increases the vapour pressure of water
(A) The solute dissolves (B) Decreases the boiling point of water
(B) The excess solute crystallises out (C) Decreases the freezing point of water
(C) The solution becomes unsaturated (D) All of the above
(D) The solution remains super saturated Q.47 The elevation of boiling point method is used
Q.39 An ideal solution is that which- for the determination of molecular weight of -
(A) Shows positive deviation from Raoult's (A) Non-volatile and soluble solute
law (B) Non-volatile and insoluble solute
(B) Shows negative deviation from Raoult's (C) Volatile and soluble solute
law (D) Volatile and insoluble solute
(C) Has no connection with Raoult's law Q.48 Which statement is correct for the boiling
(D) Obeys Raoult's law point of solvent containing a dissolved solid
Q.40 Which does not influence the solubility of a substance-
solid in a liquid solvent- (A) Boiling point of the liquid is depressed
(A) Nature of solute (B) Boiling point of the liquid is elevated
(B) Nature of solvent (C) There is no effect on the boiling point
(C) Temperature (D) The change depends upon the polarity of
(D) Pressure the liquid
Q.41 When one mole of non-volatile solute is Q.49 In cold countries, ethylene glycol is added
dissolved in three moles of solvent, the vapour to water in the radiators of cars during
pressure of the solution relative to the vapour winters. It results in -
pressure of the pure solvent is - (A) Lowering in boiling point
1 1 3 (B) Reducing viscosity
(A) (B) (C) (D) 1 (C) Reducing specific heat
3 4 4
(D) Lowering in freezing point
Q.42 Solutions distilled without change in
composition at a temperature are called- Q.50 The molal elevation/depression constant
(A) Amorphous depends upon-
(B) Azeotropic mixture (A) Nature of solvent (B) Nature of solute
(C) Ideal solution (C) Temperature (D) H solution
(D) Super saturated solution Q.51 An example of colligative property is-
Q.43 Which pair shows a contraction in volume on (A) Freezing point
mixing along with evolution of heat- (B) Boiling point
(A) CHCl3 + C6H6 (B) H2O + HCl (C) Vapour pressure
(C) H2O + HNO3 (D) All (D) Osmotic pressure

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Questions Q.59 The correct relationship between the boiling
based on Osmotic Pressure points of very dilute solutions of AlCl3 ( t1)
and CaCl 2 (t 2 ), having the same molar
Q.52 The passing of particles through
concentration is-
semipermeable membrane is called -
(A) t1 = t2 (B) t1 > t2
(A) Osmosis (B) Electrodialysis
(C) t2 > t1 (D) t2  t1
(C) Electrophoresis (D) Electroplating
Q.60 0.5 M solution of urea is isotonic with-
Q.53 In the case of osmosis, solvent molecules
(A) 0.5 M NaCl solution
move from-
(B) 0.5 M sugar solution
(A) Higher vapour pressure to lower vapour
(C) 0.5 M BaCl2 solution
pressure
(D) 0.5 M solution benzoic acid in benzene
(B) Higher concentration to lower
concentration Q.61 Which salt may show the same value of Vant
(C) Lower vapour pressure to higher vapour Hoff factor (i) as that of K4Fe(CN)6 in very
pressure dilute solution state-
(D) Higher osmotic pressure to lower osmotic (A) Al2(SO4)3 (B) NaCl
pressure (C) Al(NO3)3 (D) Na2SO4

Q.54 If mole fraction of the solvent in a solution Q.62 Which compound corresponds Vant Hoff
decreases then- factor (i) to be equal to 2 in dilute solution-
(A) Vapour pressure of solution increases (A) K2SO4 (B) NaHSO4
(B) b.pt decreases (C) Sugar (D) MgSO4
(C) Osmotic pressure increases Q.63 In which of the following , the Vant Hoff factor
(D) All are correct (i) is equal to one-
Q.55 Two solutions have different osmotic (A) NaCl (B) KNO3
pressures. The solution of higher osmotic (C) Urea (D) All
pressure is called- Q.64 The Vant Hoff factor (i) for a dilute aqueous
(A) Isotonic solution solution of glucose is-
(B) Hypotonic solution (A) zero (B) 1.0
(C) Isotopic solution (C) 1.5 (D) 2.0
(D) Hypertonic solution
Q.65 Vant Hoff factor (i) -
Q.56 According to Boyle-Vant Hoff law for (A) Is less than one in case of dissociation
solutions, the osmotic pressure of a dilute (B) Is more than one in case of association
solution is - normal molecular mass
(A) Inversely proportional to its volume (C) i = observed molecular mass
(B) Directly proportional to its volume
observed molecular mass
(C) Equal to its volume (D) i = normal molecular mass
(D) None of the above
Q.57 Which solution will show maximum elevation Q.66 In case of electrolyte which dissociates in
in b.pt - solution the Vant Hoff's Factor -
(A) 0.1 M KCl (B) 0.1 M BaCl2 (A) > unity (B) < Unity
(C) 0.1 M FeCl3 (D) 0.1 M Fe2(SO4)3 (C) = Unity (D) can be > or < 1
Q.67 Which one of the following salts would have
Questions Colligative properties of
the same value of the Vant Hoff factor (i) as
based on electrolytes, Vant Hoff’s Factor that of K3 [Fe(CN)6].
Q.58 W hich of the following 0.1 M aqueous (A) NaCl (B) Na2SO4
solutions will have the lowest freezing point - (C) Al2(SO4)3 (D) Al(NO3)3
(A) Potassium sulphate(B) Sodium chloride
(C) Urea (D) Glucose

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Q.1 Select correct statement - Q.8 Consider following solutions -
(A) b.p. of 1 molal NaCl solution is twice I : 1 M aq. glucose
that of 1 molal sucrose solution II. : 1 M aq. sodium chloride
(B) b.p. elevation of 1 molal glucose solution III. : 1 M benzoic acid in benzene
is half of the 1 molal KCl solution IV. : 1 M ammonium phosphate
(C) b.p. is a colligative property Select incorrect statement -
(D) All of the above (A) all are isotonic solutions
(B) III is hypotonic of I, II, IV
Q.2 Total vapour pressure of mixture of 1 mol
(C) I, II, IV are hypertonic of III
volatile component A(pºA = 100 mmHg) and
(D) IV is hypertonic of I, II, III
3 mol of volatile component B (pºB = 60
mmHg) is 75 mm. For such case - Q.9 The relationship between osmotic pressure
(A) there is positive deviation from Raoult's at 273 K when 10 g glucose (P1) 10 g urea
law (P2) and 10 g sucrose (P3) are dissolved in
(B) boiling point has been lowered 250 ml of water is -
(C) force of attraction between A and B is (A) P1 > P2 > P3 (B) P3 > P1 > P2
smaller than that between A and A or (C) P2 > P1 > P3 (D) P2 > P3 > P1
between B and B Q.10 The osmotic pressure of a solution of benzoic
(D) All the above statements are correct acid dissolved in benzene is less than
Q.3 At a given temperature, total vapour pressure expected because -
in Torr of a mixture of volatile components A (A) Benzoic acid is an organic solute
and B is given by (B) Benzene is a non-polar solvent
P = 120 – 75 XB (C) Benzoic acid dissociates in benzene
hence, vapour pressure of pure A and B (D) Benzoic acid gets associated in benzene
respectively (in Torr) are - Q.11 Assuming each salt to be completely
(A) 120, 75 (B) 120, 195 dissociated which of the following will have
(C) 120, 45 (D) 75, 45 highest osmotic pressure-
Q.4 Van't Hoff factors of aqueous solutions of X, (A) Decimolar Al2(SO4)3
Y, Z are 1.8, 0.8 and 2.5. Hence their - (B) Decimolar BaCl2
(A) b.p. : Y < X < Z (C) Decimolar Na2SO4
(B) f.p. : Z < X < Y (D) A solution obtained by mixing equal
(C) osmotic pressure : X = Y = Z volumes of (B) and (C) and filtering
(D) v.p. : Y < X < Z Q.12 Which one of the following pairs of solution
Q.5 Decimolar solution of potassium ferricyanide, can we expect to be isotonic at the same
K3[Fe(CN)6] has osmotic pressure of 3.94 temperature-
atm at 27ºC. Hence percent ionisation of the (A) 0.1 M urea and 0.1 M NaCl
solute is - (B) 0.1 M urea and 0.2 M MgCl2
(A) 10% (B) 20% (C) 30% (D) 40% (C) 0.1 M NaCl and 0.1M Na2SO4
(D) 0.1 M Ca(NO3)2 and 0.1 M Na2SO4
Q.6 An aqueous solution of urea containing 18 g
urea in 1500 cm 3 of solution has a density of Q.13 For a solution containing non-volatile solute,
1.052 g/cm 3. If the molecular weight of urea the relative lowering of vapour pressure is
is 60, then the molality of solution is- 0.2. If the solution contains 5 moles in all,
(A) 0.2 (B) 0.192 (C) 0.064 (D) 1.2 which of the following are true ?
I. Mole fraction of solute in the solution is 0.2
Q.7 2.56 g of sulphur in 100 g of CS2 has depression
II. No. of moles of solute in the solution is 0.2
in f.p. of 0.010º, Kf = 0.1º (molal)–1. Hence,
III. No. of moles of solvent in the solution is 4
atomicity of sulphur is -
IV. Mole fraction of solvent is 0.2 -
(A) 2 (B) 4 (C) 6 (D) 8
(A) I, IV (B) II, III (C) I, III (D) II, IV

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Q.14 A complex containing K+, Pt (IV) and Cl– is Q.24 A molal solution is one that contains one
100% ionised giving i = 3. Thus, complex is - mole of a solute in-
(A) K2 [PtCl4] (B) K2[PtCl6] (A) 1000 gram of the solvent
(C) K3[PtCl5] (D) K[PtCl3] (B) One litre of the solvent
(C) One litre of the solution
Q.15 If pKa = – log Ka = 4, and Ka = C2 then van't
(D) 22.4 litres of the solution
Hoff factor for weak monobasic acid when
C = 0.01 M is - Q.25 One among the following is an incorrect
(A) 0.01 (B) 1.02 (C) 1.10 (D) 1.20 statement-
(A) Molality of a solution is dependent on the
Q.16 pH of 1M HA (weak acid) is 2. Hence van't
temperature
Hoff factor is -
(B) Molarity of a solution is dependent on the
(A) 1.2 (B) 1.02 (C) 1.1 (D) 1.01
temperature
Q.17 In which case van't Hoff factor is maximum ? (C) Normality of 0.5 M aqueous solution of
(A) KCl, 50% ionised H2C2O4.2H2O is 1 N
(B) K2SO4 40% ionised (D) Molality of a solution relates moles of
(C) FeCl3, 30% ionised solute and mass of solvent
(D) SnCl4, 20% ionised
Q.26 Molality of the solution is-
Q.18 If 18 gram of glucose (C 6H 12O 6) is present (A) The number of moles of the solute
in 1000 gram of an aqueous solution of dissolved per kilogram of solvent
glucose it is said to be- (B) The number of gram mole of the solute
(A) 39.2 gram (B) 1.1 molal dissolved per ml of the solution
(C) 0.5 molal (D) 0.1 molal (C) The number of grams of the solute
Q.19 What is the molarity of H2SO4 solution that dissolved per kilogram of solvent
has a density of 1.84 gm/cc at 350C and (D) The number of moles of the solute
contains 98% by weight - dissolved per litre of the solution
(A) 4.18 M (B) 8.14 M Q.27 An azeotropic solution of two liquids has
(C) 18.4 M (D) 18 M boiling point lower than either when it -
Q.20 In order to prepare 100 cm 3 of 0.250 M (A) shows a negative deviation from Raoult's
barium chloride solution the amount of law
BaCl2.2H 2O required will be- (B) shows a positive deviation from Raoult's
(A) 0.250 moles law
(B) 0.0025 moles (C) shows no deviation from Raoult's law
(C) 2.5 moles (D) is saturated
(D) 6.1 gram of BaCl2.2H2O Q.28 A molar solution represents a solution of
Q.21 25 mL of 3 M HCl were added to 75 mL of molarity equal to–
0.05 M HCl. The molarity of HCl in the (A) 1 (B) 2
resulting solution is approximately- (C) 3 (D) None
(A) 0.055 M (B) 0.35 M Q.29 1000 g aqueous solution of CaCO3 contains
(C) 0.787 M (D) 3.05 M 10 g of calcium carbonate. Concentration of
Q.22 0.2 mole of HCl and 0.1 mole of CaCl2 were solution is-
dissolved in water to have 500 ml of solution, (A) 10 ppm (B) 100 ppm
the molarity of Cl¯ ions is- (C) 1000 ppm (D) 10000 ppm
(A) 0.04 M (B) 0.8 M (C) 0.4 M (D) 0.08 M Q.30 The osmotic pressure of 10%(w/v) aqueous
Q.23 When 5.0 gram of BaCl2 is dissolved in water solution of urea (1) is related to that of
to have 10 6 gram of solution. The 10%(w/v) aqueous solution of glucose (2)
concentration of solution is - as -
(A) 2.5 ppm (B) 5 ppm (A) 1 = 2 (B) 1 > 2
(C) 5M (D) 5 gm L –1 (C) 1 < 2 (D) 1 = 1 – 2

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Q.31 Cryoscopic constant of a liquid is - Q.38 The freezing point of 1 molal NaCl solution
(A) Decrease in freezing point when 1 gram assuming NaCl to be 100% dissociated in
of solute is dissolved per kg of the solvent water is-
(B) Decrease in the freezing point when 1 (A) – 1.86 0C (B) – 3.720C
mole of solute is dissolved per kg of the 0
(C) + 1.86 C (D) + 3.72 0C
solvent
Q.39 The molar freezing point constant for water is
(C) Is the elevation for 1 molar solution
1.86 0C/mole. If 342 gm of cane sugar
(D) Is a factor used for calculation of elevation
(C12H22O11) is dissolved in 1000 gram of
in boiling point
water, the solution will freeze at-
Q.32 If the vapour pressure of solutions of two (A) – 1.86 0C (B) 1.86 0C
liquids are less than those expected from 0
(C) – 3.92 C (D) 2.420C
ideal solution they are said to have-
Q.40 100 ml of liquid A and 25 ml of liquid B is
(A) Negative deviation from ideal behaviour
mixed to give a solution which does not obey
(B) Positive deviations from ideal behaviour
Raoult's law. The volume of the solution -
(C) Ideal behaviour
(A) will be 125 ml
(D) Positive deviation for lower conc. and
(B) can be > or < than 125 ml
negative deviations for higher
(C) can be greater than, equal to or less than
concentration
125 ml
Q.33 A solution of benzoic acid dissolved in (D) will be less than 125 ml
benzene will show a molecular mass closer
Q.41 A binary solution of ethanol and n-heptane is
to -
an example of -
(A) 122 (B) 244 (C) 61 (D) 366
(A) Ideal solution
Q.34 The osmotic pressure of the solution having (B) Non ideal solution with +ve deviation
concentration 0.05 M . (C) Non ideal solution with – ve deviation
(A) Increases with increase in temperature (D) Un predictable behaviour
(B) Does not change with change in
Q.42 H2O and perchloric acid (b.p. 383 K ) form
temperature
constant boiling mixture at 71.6% of perchloric
(C) Decreases with increase in temperature
acid. The boiling point of the solution at this
(D) Initially decreases and then increases with
composition is -
rise in temperature
(A) > 373 but < 383 K (B) < 373 K
Q.35 Pure benzene freezes at 5.450C at a certain (C) > than 383 K (D) = 373 K
place but a 0.374 m solution of tetra
Q.43 10 gram of solute with molecular mass 100
chloroethane in benzene freezes at 3.550C.
gram mol-1 is dissolved in 100 gram solvent
The Kf for benzene is -
to show 0.3 0C elevation in boiling point. The
(A) 5.08 K. kg mol –1 (B) 508 K kg mol –1
value of molal ebullioscopic constant will be-
(C) 0.508 K kg mol –1 (D) 50.8 0C kg mol –1
(A) 10 (B) 3
Q.36 At certain Hill-station pure water boils at (C) 0.3 (D) Unpredictable
99.7250C. If Kb for water is 0.5130C kg mol –1.
Q.44 If the observed and theoretical molecular
The boiling point of 0.69 m solution of urea
mass of NaCl is found to be 31.80 and 58.50,
will be-
then the degree of dissociation of NaCl is-
(A) 100.079 0C (B) 1030C
0
(A) 83.96% (B) 8.39%
(C) 100.359 C (D) Un predictable
(C) 90% (D) 100%
Q.37 The freezing point of a 0.05 molal solution
Q.45 When mango is placed in dilute aqueous
of a non-electrolyte in water is -
solution of hydrochloride acid, it -
(Kf = 1.860C/mol) -
(A) Shrinks (B) Swells
(A) – 1.86 0C (B) – 0.93 0C
(C) Bursts (D) Nothing happens
(C) – 0.0930C (D) 0.930C

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Q.46 In certain solvent, phenol dimerizes to the Q.54 A 0.01 M solution of glucose in water freezes
extent of 60%. Its observed molecular mass at – 0.0186 0C. A 0.01 M solution of KCl in
in that solvent should be- water is freezes at temperature-
(A) > 94 (B) = 94 (A) higher than – 0.01860C
(C) < 94 (D) Unpredictable (B) 00C
Q.47 Two liquids A and B form an ideal solution. At (C) 0.0186 0C
300 K the vapour pressure of a solution of 1 (D) lower than -0.0186 0C
mole of A and x moles of B is 550 mm. If the Q.55 The osmotic pressure of 0.2 molar solution
vapour pressures of pure A and B are 400 of urea at 300 K
mm and 600 mm respectively, then x is - (R = 0.082 litre atm mol –1 K –1) is -
(A) 1 (B) 2 (C) 3 (D) 4
(A) 4.92 atm (B) 1 atm
Q.48 Equal volume of 1M urea and 1M glucose (C) 0.25 atm (D) 27 atm
are mixed. The mixture will have-
Q.56 A liquid is in equilibrium with its vapour at its
(A) Same osmotic pressure
boiling point. On the average the molecules
(B) Lower osmotic pressure
(C) Higher osmotic pressure in the two phase have equal-
(D) None of these (A) Inter-molecular forces
(B) Potential energy
Q.49 For dilute solution Raoult's law states that- (C) Total energy
(A) The lowering of vapour pressure is equal (D) Kinetic energy
to the mole fraction of the solute
(B) The relative lowering of vapour pressure Q.57 The hard shell of an egg is dissolved in acetic
is equal to the mole fraction of the solute acid and then egg was subsequently placed
(C) The relative lowering of vapour pressure in saturated solution of NaCl
is proportional to the amount of solute in (A) The egg will shrink
solution (B) The egg will become harder
(D) The vapour pressure of the solution is (C) The egg will swell
equal to the mole fraction of the solvent (D) No change in the size of egg
Q.50 An azeotropic solution of two liquids has Q.58 All form ideal solutions except -
boiling point lower than either of them when it- (A) C2H5Br and C2H5I
(A) Shows a negative deviation from Raoult's (B) C6H5Cl and C6H5Br
law (C) C6H6 and C6H5.CH3
(B) Shows no deviation from Raoult's law (D) C2H5I and C2H5OH
(C) Shows positive deviation from Raoult's
law Q.59 The substance A when dissolved in solvent
(D) Is saturated B shows the molecular mass corresponding
to A3. The vant Hoff's factor will be-
Q.51 The molal elevation constant is the ratio of
(A) 1 (B) 2 (C) 3 (D) 1/3
the elevation in BP to-
(A) Molarity Q.60 Which statement is incorrect about osmotic
(B) Molality pressure (), volume (V) and temperature (T)-
(C) Mole fraction of solute 1
(D) Mole fraction of solvent (A)   if T is constant
V
Q.52 The osmotic pressure of solution increases if- (B)   T if V is constant
(A) Temperature is decreased (C)   V if T is the constant
(B) Solution constant is increased (D)  V is constant if T is constant
(C) Number of solute molecules are increased Q.61 The osmotic pressure of a solution is given
(D) Volume is increased by the relation -
Q.53 A 5% solution of can sugar is isotonic with RT CT
(A)  = (B)  =
0.877 % of X. The molecular weight of C R
substance X is - RC 
(A) 58.98 (B) 119.96 (C)  = (D) = RT
T C
(C) 95.58 (D) 126.98
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Q.62 Blood cells retain their normal shapes in Q.68 The osmotic pressure of equimolar solutions
solutions which are- of urea, BaCl2 and AlCl3 will be in the order-
(A) isotonic to blood (A) AlCl3 > BaCl2 > Urea
(B) hypotonic to blood (B) BaCl2 > AlCl3 > Urea
(C) hypertonic to blood (C) Urea > BaCl2 > AlCl3
(D) all of these (D) BaCl2 > Urea > AlCl3
Q.63 The osmotic pressure of a dilute solution is Q.69 Which of the following is a colligative property-
given by- (A) Change in free energy
(A) P = P0X (B) V = nRT (B) Dipole moment
P P0  P (C) Heat of vaporisation
(C) P = P0N2 (D) = (D) Osmotic pressure
P0 P0

Q.64 Osmotic pressure of a solution increases by- Q.70 Which of the following statements is correct
(A) Decreasing the temperature for the boiling point of solvent containing a
(B) Increasing the volume dissolved solid substance-
(C) Increasing the number of molecules of (A) Boiling point of the liquid is depressed
the solute (B) Boiling point of the liquid is elevated
(D) None of the above (C) There is no effect on the boiling point
Q.65 The solution having same osmotic pressure (D) The change depends upon the polarity of
are called- the liquid
(A) Equivalent solutions
(B) Ideal solutions Q.71 The vapour pressures of pure A and B at
(C) Equimolar solutions given temperature are 108 and 36 bar
(D) Isotonic solutions respectively what is the mole fraction of B in
the vapour phase of the solution containing
Q.66 A property which depends primarily on the equimolar mixture of A and B -
number of molecules of a system and not on (A) 0.25 (B) 0.5
their nature is known to be- (C) 0.75 (D) 0.66
(A) Constitutive (B) Additive
(C) Colligative (D) None of the above
Q.67 The values of observed and theoretical
molecular masses of certain electrolyte XY
are 65.4 and 114.45 respectively. The
electrolyte XY in the solution has dissociation
to the extent of -
(A) 75% (B) 80%
(C) 50% (D) 90%

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PASSAGE BASED QUESTIONS STATEMENT TYPE QUESTION

Passage Each of the questions given below consists

of Statement – I and Statement – II. Use the
Vapour pressure of a solvent is the pressure following Key to choose the appropriate
exerted by vapours when they are in equilibrium answer.
with its solvent at that temperature. The vapour (A) If both Statement- I and Statement- II are
pressure of solvent is dependent on nature of true, and Statement - II is the correct
solvent, temperature, addition of non-volatile explanation of Statement– I.
solute as well as nature of solute to dissociate (B) If both Statement - I and Statement - II are
or associate. The vapour pressure of a mixture true but Statement - II is not the correct
obtained by mixing two volatile liquids is given explanation of Statement – I.
by PM = Pº A . XA + Pº B . XB where PºA and PºB (C) If Statement - I is true but Statement - II is
are vapour pressures of pure components A false.
and B and XA, XB are their mole fraction in (D) If Statement - I is false but Statement - II is
mixture. For solute-solvent system, the relation true.
becomes PM = Pº A . XA where B is non-volatile
solute. Q.4 Statement - I. Addition of a non-volatile solute
causes a depression in vapour pressure.
Statement - II. Vapour pressure of a solution
Q.1 The vapour pressure of benzene and its solution
is directly proportional to mole fraction of solvent.
with a non-electrolyte are 640 and 600 mm
respectively. The molality of the solution is -
Q.5 Statement - I. 0.02 m solutions of urea and
(A) 0.80 (B) 0.86 sucrose will freeze at same temperature.
(C) 0.90 (D) 0.95 Statement - II. Freezing point of a solution
is inversely proportional to the concentration
of solution.
Q.2 A mixture of two volatile liquids A and B for
1 and 3 moles respectivley has a V.P. of 300 Q.6 Statement - I. For isotonic solutions C1 = C2
mm at 27ºC. If one mole of A is further added Statement - II. For isotonic solutions 1 = 2
to this solution, the vapour pressure becomes
290 mm at 27ºC. The vapour pressure of pure Q.7 Statement - I. Benzene-toluene mixture forms
A is - ideal solution at low concentrations.
Statement - II. Components with structural
(A) 250 mm (B) 316 mm similarity forms ideal solution in general.
(C) 220 mm (D) 270 mm
Q.8 Statement - I. Dissolution of sulphuric acid
in water gives a solution which shows negative
Q.3 The amount of solute (mol. wt. 60) required deviation.
to dissolve in 180 g of water to reduce the Statement - II. The solutions which have
vapour pressure to 4/5 of the pure water - same vapour pressure at a given temperature
(A) 120 g (B) 150 g are called isotonic solutions.

(C) 200 g (D) 60 g Q.9 Statement - I. Greater the molal depression

constant of the solvent used less is the
freezing point of the solution.
Statement - II. Depression in freezing point
depends upon the nature of the solvent.

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Q.10 Statement - I. Vant Hoff factor for electrolytes
TRUE/FALSE
is always geater than unity.
Statement - II. The no. of particles increases State whether the following statements are
in solution due to electrolytic dissociation. True or False :

Q.11 Statement - I. The vapour pressure of 0.1 M Q.14 the value of SMix for ideal solution is = 0.
sugar solution is more than that of 0.1 M
potassium chloride solution. Q.15 If pressure greater than osmotic pressure is
Statement - II. Lowering of vapour pressure applied on solution which has been separated
is directly proportional to the no. of species from pure solvent by semi-permeable
present in the solution. membarane reverse osmosis will occur.

Q.12 Statement - I. Blood cells are isotonic with

Q.16 A 10% aqueous solution of NaCl is isotonic
0.16 M NaCl solution.
with 10% aqueous solution of glucose.
Statement - II. Cell wall of blood cells acts
as semi-permeable membrane.
Q.17 Osmotic pressure is directly proportional to
Q.13 Statement - I. Molarity of the solution changes temperature.
with temperature.
Statement - II. Molarity is a colligative Q.18 All solutions containing 1 g of non-volatile
property. solutes will have same freezing point.

COLUMN MATCHING

Match the following columns :

Q.19 Column I Column II

A. Ideal solution P. Solute-solvent interactions are weaker
than solute-solute
B. Solutions showing positive deviations Q. Solute-solvent interactions are similar
to solute-solute
C. Solutions showing negative deviations R. Solute-solvent interactions are stronger
than solute-solute interactions

Q.20 Column I Column II

A. Hmix = 0 P. Isotonic solutions
B. T f/molality Q. Mole fraction of solute
C. (n – 1)  + 1 R. Ideal solution
D. 1 = 2 S. Van’t Hoff factor for electrolyte
E. P/Pº T. Molal depression constant

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 Q.7 25 ml of a solution of barium hydroxide required
SECTION - A 35 ml on titration with a 0.1 molar solution of
Q.1 Which of the following concentration factor is hydrochloric acid. Molarity of barium hydroxide
affected by change in temperature ? solution was – [AIEEE-2003]
[AIEEE-2002] (A) 0.28 (B) 0.35 (C) 0.07 (D) 0.14
(A) Molarity (B) Molality
Q.8 Which one of the following aqueous solutions
(C) Mol fraction (D) Weight fraction
will exhibit highest boiling point ?[AIEEE-2004]
Q.2 For an aqueous solution, freezing point is – (A) 0.01 M Na2SO4 (B) 0.01 M KNO3
0.186ºC . Elevation of the boiling point of the (C) 0.015 M urea (D) 0.015 M glucose
same solution is Q.9 To neutralise completely 20 mL of 0.1 M
(Kƒ = 1.86º mol–1 kg) and Kb = 0.512º mol–1 kg) aqueous solution of phosphorous acid (H3PO3),
[AIEEE-2002] the volume of 0.1 M aqueous KOH solution
(A) 0.186º (B) 100.0512º required is - [AIEEE-2004]
(C) 1.86º (D) 5.12º (A) 10 mL (B) 20 mL (C) 40 mL (D) 60 mL
Q.3 In a mixture of A and B, components show Q.10 Which of the following liquid pairs shows a
negative deviation when – [AIEEE-2002] positive deviation from Raoult’s law ?
(A) A – B interaction is stronger than A – A and [AIEEE-2004]
B – B interaction (A) Water - hydrochloric acid
(B) A – B interaction is weaker than A – A and (B) Benzene - methanol
B – B interaction (C) Water - nitric acid
(C) Vmix > 0, Smix > 0 (D) Acetone - chloroform
(D) Vmix = 0, Smix > 0 Q.11 Which one of the following statement is FALSE ?
Q.4 A pressure cooker reduces cooking time for food [AIEEE-2004]
because – [AIEEE-2003] (A) Raoult’s law states that the vapour pressure
(A) The higher pressure inside the cooker of a component over a solution is
crushes the food material proportional to its mole fraction
(B) Cooking involves chemical changes helped (B) The osmotic pressure () of a solution is
by a rise in temperature given by the equation  = MRT where M is
the molarity of the solution
(C) Heat is more evenly distributed in the
(C) The correct order of osmotic pressure for
cooking space
0.01 M aqueous solution of each compound
(D) Boiling point of water involved in cooking is
is BaCl2 > KCl >CH3COOH > sucrose.
increased
(D) Two sucrose solutions of same molality
Q.5 If liquids A and B form an ideal solution – prepared in different solvents will have the
[AIEEE-2003] same freezing point depression.
(A) The free energy of mixing is zero Q.12 If  is the degree of dissociation of Na2SO4, the
(B) The free energy as well as the entropy of vant Hoff's factor (i) used for calculating the
mixing are each zero molecular mass is – [AIEEE-2005]
(C) The enthalpy of mixing is zero (A) 1 –  (B) 1 + 
(D) The entropy of mixing is zero (C) 1 – 2 (D) 1 + 2
Q.6 In a 0.2 molal aqueous solution of a weak acid Q.13 Benzene and toluene form nearly ideal
HX the degree of ionization is 0.3 . Taking kƒ for solutions. At 20ºC, the vapour pressure of
water as 1.85, the freezing point of the solution benzene is 75 torr and that of toluene is 22 torr.
will be nearest to – [AIEEE-2003] The partial vapour pressure of benzene at 20ºC
(A) –0.260ºC (B) + 0.480ºC for a solution containing 78 g of benzene and
(C) –0.480ºC (D) –0.360ºC 46 g of toluene in torr is – [AIEEE-2005]
(A) 25 (B) 50 (C) 53.5 (D) 37.5

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Q.14 Two solutions of a substance (non electrolyte) Q.22 At 80º C , the vapour pressure of pure liquid ‘A’
are mixed in the following manner. 480 ml of 1.5 is 520 mm Hg and that of pure liquid ‘B’ is 1000
M first solution + 520 mL of 1.2 M second mm Hg. If a mixture solution of ‘A’ and ‘B’ boils
solution. What is the molarity of the final mixture ? at 80º C and 1 atm pressure, the amount of ‘A’
[AIEEE-2005] in the mixture is (1 atm = 760 mm Hg)
(A) 1.50 M (B) 1.20 M [AIEEE 2008]
(C) 2.70 M (D)1.344 M (A) 34 mol percent (B) 48 mol percent
(C) 50 mol percent (D) 52 mol percent
Q.15 Equimolal solutions in the same solvent have –
[AIEEE-2005] Q.23 A binary liquid solution is prepared by mixing n-
(A) Same freezing point but different boiling point heptane and ethanol. Which one of the following
(B) Same boling point but different freezing point statements is correct regarding the behaviour
(C) Different boiling and different freezing point of the solution ? [AIEEE 2009]
(D) Same boiling and same freezing points (A) The solution is non-ideal, showing +ve
deviation form Raoult’s Law
Q.16 18 g of glucose (C6H12O6) is added to 178.2 g
(B) The solution is non-ideal, showing –ve
of water. The vapour pressure of water for this
deviation from Raoult’s Law
aqueous solution at 100º C is - [AIEEE 2006] (C) n-heptane shows +ve deviation while
(A) 7.60 Torr (B) 76.00 Torr ethanol shows – ve deviation from
(C) 752.40 Torr (D) 759.00 Torr Raoult’s Law
Q.17 Density of a 2.05 M solution of acetic acid in (D) The solution formed is an ideal solution
water is 1.02 g/mL. The molality of the solution Q.24 Two liquids X and Y form an ideal solution At
is - [AIEEE 2006] 300 K, vapour pressure of the solution contain-
(A) 3.28 mol kg–1 (B) 2.28 mol kg–1 ing 1 mol of X and 3 mol of Y is 550 mmHg. At
(C) 0.44 mol kg–1 (D) 1.14 mol kg–1 the same temperature, if 1 mol of Y is further
Q.18 A mixture of ethyl alcohol and propyl alcohol added to this solution, vapour pressure of the
has a vapour pressure of 290 mm at 300 K. solution increases by 10 mmHg. Vapour pres-
The vapour pressure of propyl alcohol is 200 sure (in mmHg) of X and Y in their pure states
mm. If the mole fraction of ethyl alcohol is will be, respectively - [AIEEE 2009]
(A) 300 and 400 (B) 400 and 600
0.6, its vapour pressure (in mm) at the same
(C) 500 and 600 (D) 200 and 300
temperature will be - [AIEEE 2007]
(A) 350 (B) 300 (C) 700 (D) 360
SECTION - B
Q.19 A 5.25% solution of a substance is isotonic Q.1 When mercuric iodide is added to the aqueous
with a 1.5% solution of urea (molar mass = solution of potassium iodide, the - [IIT-1987]
60 g mol–1) in the same solvent. If the (A) freezing point is raised
densities of both the solutions are assumed (B) freezing point is lowered
to be equal to 1.0 gcm –3, molar mass of the (C) freezing point does not change
substance will be - [AIEEE 2007] (D) boiling point does not change
(A) 90.0g mol –1 (B) 115.0g mol–1
–1 Q.2 A sugar syrup of weight 214.2 grams contains
(C) 105.0g mol (D) 210.0 g mol–1
34.2 grams of sugar. The molal concentration is -
Q.20 The density (in g mL–1) of a 3.60 M sulphuric [IIT-1988]
acid solution that is 29% H2SO4 (Molar mass = (A) 0.55 (B) 5.5 (C) 55 (D) 0.1
98 g mol– 1 ) by mass will be - [AIEEE 2007] Q.3 The vapour pressure of benzene at a certain
(A) 1.64 (B) 1.88 (C) 1.22 (D) 1.45 temp. is 640 mm Hg. A non-volatile-non-
Q.21 The vapour pressure of water at 20º C is 17.5 electrolyte and weighing 2.175 g is added to
mm Hg. If 18g of glucose (C6H12O6) is added to 39.0 g of benzene. The vapour pressure of the
178.2 g of water at 20° C, the vapour pressure solution is 600 mm Hg. What is the molecular
of the resulting solution will be - [AIEEE 2008] weight of the solid substance ? [IIT-1990]
(A) 15.750 mm Hg (B) 16.500 mm Hg (A) 6.96 (B) 65.3
(C) 17.325 mm Hg (D) 17.675 mm Hg (C) 63.8 (D) none of these

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Q.4 The vapour pressure of solution containing 5 g of Q.10 The van’t Hoff factor for 0.1 M Ba (NO3)2 solution
non-electrolyte in 90g of water at a particular is 2.74. The degree of dissociation is - [IIT-1999]
temperature is 2985 Nm–2. The vapour pressure (A) 91.3% (B) 87 %
of pure water at that temperature is 3000 Nm–2. (C) 100 % (D) 74 %
The molecular weight of the solute is - [IIT-1993]
Q.11 The normality of 0.3 M phosphorous acid
(A) 180 (B) 90 (C) 270 (D) 200
(H3PO3) is - [IIT- 1999]
Q.5 Increasing the temperature of an aqueous (A) 0.1 (B) 0.9
solution will cause - [IIT-1993] (C) 0.3 (D) 0.6
(A) decrease in molality
(B) decrease in molarity Q.12 Aqueous solutions of 0.004 M Na2SO4 and 0.01
(C) decrease in mole fraction M Glucose are isotonic. The degree of
(D) decrease in % (w/w) dissociation of Na2SO4 is - [IIT-2004]
Q.6 The molecular weight of benzoic acid in benzene (A) 25% (B) 60%
as determined by depressing in freezing point (C) 75% (D) 85%
method corresponds to - [IIT-1996] Q.13 13.44 gm of CuCl2 is dissolved in 1 kg of water.
(A) ionization of benzoic acid Determine the elevation in boiling point of the
(B) dimerization of benzoic acid solution.
(C) trimerization of benzoic acid Kb = 0.5 Kg mol–1 wt of CuCl2 = 134.1.[IIT-2005]
(D) solvation of benzoic acid
(A) 0.16 (B) 0.052
Q.7 Azeotropes are [IIT-1996] (C) 0.1 (D) 0.5
(A) liquid mixtures which distil unchanged in
Q.14 When 20 g of naphthoic acid (C11H8O 2) is
composition
dissolved in 50g of benzene (Kf = 1.72 K kg
(B) liquids which can mix with each other in all
mol-1), a freezing point depression of 2K is
proportions
observed. The van’t Hoff factor (i) is - [IIT-2007]
(C) solids which form solid solutions of definite
composition (A) 0.5 (B) 1
(D) gases which can be separated (C) 2 (D) 3
Q.15 The Henry’s law constant for the solubility of N2
Q.8 0.2 molal acid HX is 20% ionised in solution gas in water at 298 K is 1.0 × 105 atm. The
Kf = 1.86 K molality–1. The freezing point of the mole fraction of N2 in air is 0.8. The number of
solution is - [IIT-1997] moles of N2 from air dissolved in 10 moles of
(A) – 0.45 (B) – 0.90 water at 298 K and 5 atm pressure is -[IIT-2009]
(C) – 0.30 (D) –0.53 (A) 4.0 × 10–4 (B) 4.0 × 10–5
Q.9 In the depression of freezing point experiment, (C) 5.0 × 10 –4
(D) 4.0 × 10–6
it is found that the [IIT-1999]
(A) Vapour pressure of the solution is less than
that of pure solvent
(B) Vapour pressure of the solution is more than
that of pure solvent
(C) only solute molecules solidify at the freezing
point.
(D) only solvent molecules solidify at the
freezing point.

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Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. B D D D D A D A C D D C B B A C A C D B
Q.No. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. B C C B B A B C B C A A A A B B D B D D
Q.No. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. B B D C D C A B D A D A A C D A D A B B
Q.No. 61 62 63 64 65 66 67
Ans. A D C B C A D

Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. B D C A,B B B D A C D A D C B C D C D C D
Q.No. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. C B B A A A B A D B B A B A A A C B A B
Q.No. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. B C C A B A C A B C B C A D A D A D D C
Q.No. 61 62 63 64 65 66 67 68 69 70 71
Ans. D A B C D C A A D B A

Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
Ans. B A B A B D A C A A D B C FALSE TRUE FALSE TRUE FALSE
Q.No. 19 20

Ans. A-Q; B-P; C-R A - R; B - T; C- S ; D- P ; E - Q

Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24
Ans. A B A D C C C A C B D D B D C C B A D C C C A C

Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. A A B D B B A A D B D C A A A

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