Carbon and Its Compounds
Carbon and Its Compounds
Learning Objectives
Students will be able to know about Study Plan
covalent bonding in carbon compounds. Maximum Time = 3:30 Hrs
the concept of homologous series.
Maximum Questions = 64
Nomenclature of carbon compounds containing functional groups.
List of Topics
Difference between saturated and unsaturated hydrocarbons.
Topic-1: Carbon and its Properties,
Chemical properties of carbon compounds.
Homologous Series and IUPAC Names
Chemical properties of carbon compounds (combustion, oxidation, addition, and �����������������������������������������������������������
substitution reaction). Topic-2 : Ethanol, Ethanoic acid, Soaps, and
Properties and uses of Ethanol and Ethanoic acid.
Detergents������������������������������������������
Soaps and detergents.
TOPIC-1 C arbon and its Properties, Homologous Series and IUPAC Names
Concepts Covered:
Covalent bonding in carbon compounds Versatile nature of carbon Homologous series Nomenclature of carbon
compounds containing functional groups Difference between saturated and unsaturated hydrocarbons Chemical
properties of carbon compounds.
Lewis dot structures reflect the electronic structures of the elements, including how the electrons are paired. In
Lewis dot structures each dot represents an electron. A pair of dots between chemical symbols for atoms represents
a bond.
Example-1
(i) H2
H–CºC–H
CBSE Question Bank Chapterwise & Topicwise, SCIENCE, Class-X
On the basis of structures, hydrocarbons can be: IUPAC name of hydrocarbon consists of two parts. It
(i) Straight chain hydrocarbons: Propane, butane, etc. involves:
(ii) Branched chain hydrocarbon: Iso-butane, iso-pentane, (i) Word root: Number of carbons in the longest carbon
etc. chain.
(iii) Cyclic hydrocarbons: Cyclohexane C6H12, benzene Number of carbon atoms Word root (Greek name)
C6H6, etc.
1 Meth
Cyclic or Closed Chain Hydrocarbons: These are the
2 Eth
hydrocarbons which have carbon-carbon closed chain. 3 Prop
They are classified as: 4 But
(i) Alicyclic hydrocarbons: These are the hydrocarbons 5 Pent
which do not have benzene ring in their structures. 6 Hex
(ii) Aromatic hydrocarbons: The hydrocarbons which 7 Hept
have benzene ring in their structures. When hydrogen 8 Oct
bonded to carbon of benzene is substituted with 9 Non
halogens, radicals, or other functional groups, the 10 Dec
derivatives are called aromatic compounds.
(ii) Suffix: It depends on the type of carbon-carbon bond.
Benzene: It is an aromatic hydrocarbon which has the
For a single bond suffix is – ane; for double bond, suffix
molecular formula C6H6. It has alternating carbon -
is – ene; and for triple bond suffix is – yne.
carbon single and double bonds.
Types of Formulae for Writing Hydrocarbons:
(i) Molecular formula: It involves the actual number of
each type of atom present in the compound.
(ii) Structural formula: The actual arrangement of atoms
is written in structural formula.
(iii) Condensed formula: It is the shortened form of the
structural formula.
In hydrocarbon chain, one or more hydrogen atom
is replaced by other atoms in accordance with their
Benzene can also be represented as: valencies. These are heteroatoms.
These heteroatoms or group of atoms which make
carbon compounds reactive and decides its properties
are called functional groups.
Some important functional groups in carbon compounds are:
Heteroatoms Functional group Formula of functional group Prefix/suffix
Cl/Br Halo (Chloro/Bromo) — Cl, — Br, — I Chloro/Bromo/Iodo
Oxygen 1. Alcohol — OH — ol
2. Aldehyde — CHO — al
3. Ketone — one
6. A carbon compound 'A' having a melting point Ans. (a) Functional group: Aldehyde ½
156 K and a boiling point 351 K, having a molecular (b) General formula : CnH2nO ½
formula C2H6O is soluble in water in all proportions.
(c) It forms the part of the homologous series of the
(a) Identify 'A' and draw its electron dot structure.
aldehydes as these compounds differ from each
(b) Give the molecular formula of any two homologous
other by –CH2 unit. 1
of 'A'. Ap [SQP 2021-22]
Structure of 4th member of this series is:
Concept Applied Lewis dot structure
Answering Tip
1
Understand the basic concepts involved in (b)
drawing the dot structure. Make sure that you Ionic compounds Covalent compounds
have made dots for all the shared bonds.
They have high melting They have low melting
7. Describe an experiment that can confirm the and boiling points. and boiling points.
presence of carbon in a compound. With a valency
of 4, how is carbon able to attain noble gas They are formed by the They are formed by
configuration in its compounds? C [SQP 2020-21] transfer of electrons sharing of electrons
between the combining between the combining
Ans. - Burn the compound in the air/oxygen; Gas atoms. atoms.
evolved turns lime water milky 1 1+1
- By sharing its four valence electrons with other 3. “Two different forms of carbon–diamond and
elements. [Marking Scheme SQP, 2020-21] 1 graphite–have different structure and very different
8. Organic compounds belonging to different physical properties even though their chemical
homologous series can be isomers. For example, properties are the same.” Explain why.
propanal and propanone are isomers. A [Outside Delhi Term-2, 2022]
Can an alkane and an alcohol be isomers? Why or Concept Applied Allotropes of Carbon
why not? K [CFPQ]
Ans. Diamond and graphite are allotropes of carbon.
Short Answer Type Questions-II (3 marks each) Allotropes are different forms of an element having
1. Consider the following organic compounds: different physical properties. The element-carbon-
occurs in various forms in nature with different
physical properties but nearly same chemical
(i) (ii)
properties. Diamond is a giant molecule of carbon
atoms in which each carbon atom is bonded to four
(a) Name the functional group present in these other carbon atoms forming a rigid three dimensional
compounds. structure, which is responsible for its hardness.
(b) Write the general formula for the compounds of Graphite crystal consists of layers of carbon atoms
this functional group. in which each carbon atom is bonded to three other
(c) State the relationship between these compounds carbon atoms in the same plane in a hexagonal array.
and draw the structure of any other compound Graphite structure is formed by hexagonal array
having similar functional group. being placed in layer one above the other. 3
F [Delhi, Term-2, 2022]
CBSE Question Bank Chapterwise & Topicwise, SCIENCE, Class-X
4. What is a homologous series of carbon compounds? (ii) They have the same functional group.
Give an example and list its three characteristics.
(iii) The difference in the molecular mass of the two
U [Outside Delhi, Set- 1, 2019]
successive member in 14 u.
Ans. A series of compounds in which the same (iv) The difference in the molecular formula of two
functional group substitutes for hydrogen in a
carbon chain is called a homologous series.1 successive member is of CH2 unit.
Example: Alkane/Alkene/Alkyne/Alcohol½ (v) They have similar chemical properties.
Characteristics: (Any three points) ½ × 3
(i) They have the same general formula. [Marking Scheme, OD, 2019]
5. Shown below are the structural formulae of four carbon compounds.
CH3 – C – CH3 CH3 – CH – CH3 CH3 – CH2 – C – OH CH3 – OH
|| | ||
O OH O
p Q R S
(a) Two of these compounds are more likely to have similar chemical properties. Identify these two compounds.
Give a reason for your answer.
(b) Identify which of these compounds are likely to have the same boiling point. Justify your answer.
K [CFPQ]
Concept Applied Carbon Compounds
6. Give reasons why carbon can neither form C4+ cations nor C4– anions, but forms covalent compounds. Also,
state why covalent compounds are bad conductors of electricity and have low melting and boiling points?
U [Outside Delhi Set-1, 2022]
Carbon and its Compounds
7. Two carbon compounds X and Y have the molecular Structural formula:
formula C4H8 and C5H12 respectively. Which one
of these is most likely to show addition reaction?
Justify your answer. Also, give the chemical
equation to explain the process of addition reaction
in this case. U [Delhi 31/1/1 2017]
(c) C is an alcohol.
Concept Applied Saturated and unsaturated Conc. H2SO4 acts as a dehydrating agent and
hydrocarbon. removes a water molecule from ethanol.
Hot conc.H SO
C 2 H 5OH →
2 4
C 2 H 4 +H 2O
Ans. C4H8; it is an unsaturated hydrocarbon due to the (d) CH3COOH+C2H5OH
conc H 2 SO4
→
presence of a double bond. 1+1 CH3COOC2H5 + H2O
Ni//Pd
C4H8 + H2 → C4 H10 ½ Catalyst Major product is an ester and it is used to make
½ Equation (or any other) ½ + ½ perfumes/flavouring agents. ½
[Marking Scheme, Delhi, 2017] [Marking Scheme, SQP, 2020-21]
2. Write the chemical formula and name of the
Commonly Made Error compound which is the active ingredient of all
alcoholic drinks. List its two uses. Write the chemical
Generally students get confused between equation and the name of the product formed when
saturated and unsaturated compounds and this compound reacts with: (i) sodium metal (ii) hot
their molecular formula. concentrated sulphuric acid.
U [Delhi, Set- 1, 2019]
Answering Tip
Ans. • C2H5OH, Ethanol/Ethyl alcohol
Be clear with basic concepts of saturated and • Good solvent; used in medicines (Any other)
unsaturated compounds, their molecular (i) 2C2H5OH + 2 Na ¾® 2C2H5ONa + H2
formulae. Also, remember how saturated and Sodium ethoxide
unsaturated compounds react differently. Hot Conc. H 2 SO4
(ii) C2H5OH → CH2=CH2+ H2O
443 K
Ethene
Long Answer Type Questions (5 marks each)
[Marking Scheme, Delhi, 2019] 1+1+1+ ½ + 1 + ½
1. The formulae of four organic compounds are given
below: 3. What is methane? Draw its electron dot structure.
A B C D Name the type of bonds formed in this compound.
Why are such compounds: (i) poor conductors of
C2H4 CH3COOH C2H5OH C 2H 6 electricity and (ii) have low melting and boiling
(a) W hich one of these compounds A, B, C, or D is a points? What happens when this compound burns
saturated hydrocarbon? in oxygen? F [Delhi, Set- 1, 2019]
(b) Identify the organic acid and give its structural
Concept Applied Lewis Dot structure
formula.
(c) Which of the above compounds when heated at Ans. • CH4/Simplest hydrocarbon
443K in the presence of concentrated H2SO4 forms
ethene as the major product? What is the role played
by concentrated H2SO4 in this reaction? Also, write
the chemical equation involved.
(d) Give a chemical equation when B and C react with
each other in presence of concentrated H2SO4.
Name the major product formed and mention one
of its important uses. U+A [SQP, 2020-21]
4. Why are certain compounds called hydrocarbons? Write the general formula for homologous series of alkanes,
alkenes, and alkynes and also draw the structure of the first member of each series. Write the name of the
reaction that converts alkenes into alkanes and also write a chemical equation to show the necessary conditions
for the reaction to occur. U [OD Set-1 2017, 2019]
5. Carry out the following conversions stating the (d) 2Na + 2CH3COOH → 2CH3COONa + H2
condition (s) for each: (Q) (R)
(i) Ethanol to Ethene (e) Dehydration of ethanol occurs /
(ii) Ethene to Ethane conc. H SO
C2H5OH 2 4
→ C2H4 + H 2O
(iii) Ethane to Chloroethane
(iv) Ethanol to Ethanoic acid (P)
(v) Ethanoic acid to Ethyl ethanoate 7. An organic compound ‘X’ is liquid at room
[Outside Delhi Set-1, 2023] temperature. It is also a very good solvent and has the
molecular formula C2H6O. Upon oxidation ‘X’ gives
Concept Applied Carbon Reactions ‘Y’. ‘Y’ releases a gas ‘W’ with brisk effervescence
6. An organic compound ‘P’ is a constituent of wines. on reacting with NaHCO3. X reacts with Y in the
‘P’ on reacting with acidified K2Cr2O7 forms another presence of conc. H2SO4 to give another compound
compound ‘Q’. When a piece of sodium is added to ‘Z’ which has a pleasant smell. 'Z'.
‘Q’, a gas ‘R’ evolves which burns with a pop sound (a) Give the chemical name and chemical formula of
when a burning matchstick is brought near it. 'Y'.
(a) Give the chemical name of compound 'P'. (b) How will you test for the gas ‘W’?
(b) Mention another use of the compound ‘P’ apart
(c) Depict the formation 'Y' and 'Z' using chemical
from the use mentioned in the question.
(c) Illustrate with the help of chemical equation the equations.
conversion of ‘P’ into ‘Q’. (d) Name the reaction of formation of ‘Z’.
(d) Give a balanced equation to depict the reaction of Q (e) Give any one use of ‘Z’? [APQ 2023-24]
with sodium. Ans. (a) Ethanoic acid Y = CH3COOH
(e) What happens when ‘P’ is heated with conc. H2SO4 (b) The gas evolved ‘W’ turns the lime water milky
at 443 K? Write its chemical equation. [APQ 2023-24] Acid. K Cr O
Ans. (a) P = Ethanol (c) C2H5OH 2 2 7
→ CH3COOH
(b) Industrial solvent/ingredient of cough syrup/ (X) (Y)
homeopathic medicine/lab reagent - any one or any C2H5OH + CH3COOH → CH3COOC2H5 + H2O
other (X) (Y) (Z)
acidified K Cr O
(c) C2H5OH
2 2 7
→ CH3COOH (d) Esterification Reaction
(P) (Q) (e) Any one use: use-perfumes/cosmetics;
Carbon and its Compounds
Ans. Ethanoic acid reacts with NaOH to give sodium salt Ans. (a) By dissolving 5 g of KMnO4 in 100 mL of water/
and water but C2H5OH does not show this reaction. By dissolving 5 g of KMnO4 in water to make a final
1 volume of 100 mL.
Ethanoic acid reacts with NaHCO3 (Sodium (b) As an oxidising agent 1
Bicarbonate) or Na2CO3 (Sodium Carbonate) and Purple colour persists ½+½
gives sodium salt of ethanoic acid, water, and Alkaline KMnO4
(c) CH3CH2OH → CH3COOH 1
carbon dioxide. [Marking Scheme, 2019] 1 heat
7. When ethanol reacts with ethanoic acid in the C2H6O in the presence of an acid, a sweet smelling
presence of conc. H2SO4, a substance with a fruity compound ‘C’ is formed.
smell is produced. Answer the following: (1) Identify ‘B’ and ‘C’.
(i) State the class of compounds to which the fruity (2) State the role of acid in this reaction.
smelling compounds belong. Write the chemical (3) Write chemical equation for the reaction involved.
equation for the reaction and write the chemical [Set-1 OD., 2023]
name of the product formed. Ans (a) (i) A = Ethanoic acid (CH3COOH)
(ii) State the role of conc. H2SO4. CH3COOH + NaOH → CH3COONa + H2O
U [Term-2, Set-1, 2, 2016] (ii) (1) B = Ethanol CH3CH2OH,
Ans. (i) Esters. ½ C = Ester (Ethyl ethanoate CH3COOC2H5)
Chemical Equation: (2) Acid acts as a catalyst and increases the reaction rate.
O (3) CH3COOH + CH3CH2OH
—
—
H SO
CH3 — C — OH + CH3CH2OH
2 4
→ CH3COOCH2CH3 + H2O
Conc. H2SO4
2. (i) Name the compound formed when ethanol is
O heated at 443K in the presence of conc. H2SO4 and
draw its electron dot structure. State the role of
—
—
6. Soaps and detergents are two types of salts. State micelles in which carbon chain of the molecules
the difference between the two. Write the mecha- dissolves in the oil while the ionic end dissolves
nism of the cleansing action of soaps. Why do in water and faces outside. The micelles thus help
soaps not form lather (foam) with hard water? in dissolving the dirt in water. (Note: 1 mark to
Mention any two problems that arise due to the use be awarded if only labelled diagram of micelle is
of detergents instead of soaps. given)
U [Delhi Set-I 2017] Ca2+ and Mg2+ present in hard water form
insoluble substance (scum) with soap.
Concept Applied Cleansing Action of soap
Two problems:
Ans. (i) Soaps are the sodium or potassium salts of (a) Non-biodegradable
long chain carboxylic acids while detergents are (b) Water pollution/soil pollution
the ammonium or sulphonate salts of long chain
carboxylic acids. (Note: 1 mark to be awarded for any one of the
(ii) The dirt is oily in nature and when soap is added problems.) [Marking Scheme, Delhi 2017]
to water, its molecules form structures called 2+1+1+2
Carbon and its Compounds
(b)
Is this true about carbon compounds? Yes or
No
(i) They are good conductors of No
electricity.
(ii) They exist in either saturated or un- Yes
saturated form.
(iii) They have lower boiling points Yes
than ionic compounds.
2
[D] Case Based Subjective Questions OR
1. Read the given passage and answer the questions (b) Carbon, due to strong C–C bond. 1+1
that follow: 2. Given below is a four-carbon skeleton of a
hydrocarbon compound.
The pictures show the bonds formed by the C
sharing of electrons by the atoms of four different |
molecules. [SAS] C —C
|
C
(a) Fill in the hydrogen atoms/bonds to form:
(i) a saturated hydrocarbon
(ii) an unsaturated hydrocarbon
(b) If the four-carbon skeleton is of a straight chained
(a) Out of these molecules–Hydrogen, carbon, nitrogen alkene, draw the structures of all the possible
and oxygen—which has the strongest bond between compounds.
its atoms? What is this type of bond between atoms OR
known as? 2 If the four-carbon skeleton is of a straight chained
alkyne:
(b) Which of these statements is true about carbon
(i) How many carbon atoms may NOT be bonded to
compounds? Write ‘Yes’ or ‘No’ for the correct
any hydrogen atoms?
response. [SAS] (ii) How many hydrogen atoms will there be in the
Is this true about carbon Yes or No compound? [APQ 2023-24]
compounds? CH2
||
(i) They are good conductors of Ans. (a) (i) H3C —C
electricity. |
CH3
(ii) They exist in either saturated
or unsaturated form. CH2
||
(iii) They have lower boiling (ii) H3C —C
points than ionic compounds. |
CH3
2
OR (b) CH3CH2CH2CH3 CH3CHCH3
(b) Which element exhibits the property of catenation Butane |
to the maximum extent and why? CH3
2-Methylpropane
Ans. (a) Carbon can gain four electrons and form C4–
OR
anion or lose four electrons to form the C4+ cation.
(b) (i) 1 or 2 carbon atoms
It forms four covalent bonds by sharing its valence
(ii) six hydrogens
electrons with other atoms. 1
H2
This type of bond between atoms is known as
covalent bond covalent. Carbon compounds are H3C—C—C ºº CH
or
those where there is a carbon–carbon bond.1
H3C—C ºº C—CH3
LATQs
4. (a)
(ii) Ethanoic acid: CH3COOH 1
Soaps Detergents
l Composition: Ammonium or 1
Sodium or Potassium Sulphonate salts of
salts of long chain fatty long chain carboxylic
(b) As oxygen is added to ethanol acids/carboxylic acids. acids.
Oxidising agent : Alkaline KMnO4 ½
Acidified K2Cr2O7 ½ l Cleansing action in Does not form scum. 1
[Marking Scheme, 2020-21] hard water: Forms
scum.
3. (a) CH3CH2OH½
(b) Carbon dioxide/ CO2 ½ (b) l Hydrogen gas is evolved
(c) Carbon dioxide and water/ CO2 and H2O ½+½ l Behaves like an acid. ½+½
CH3CH2OH + 3O2 → 2CO2 + 3H2O 1
(c) H H
5. (i) CH3COOC2H5 + NaOH → CH3 COONa H C H
+ C2H5OH H C C H
(c) H H
H C C H
H C H H C H
H C C H
H H 1
H C C H
C H (d) Ethanal / Acetaldehyde 1
H
[Marking Scheme, 2020]
H H 1
REFLECTION
1. Have you understood the properties of carbon and the concept of homologous series?
2. Can you write the IUPAC name of various carbon compounds?
3. Can you now answer the questions related to chemical properties of carbon compounds?
4. Can you distinguish between soaps and detergents on the basis of their composition and cleansing
action in hard water?
ARTIFICIAL INTELLIGENCE
AI CONCEPTS
PARAMETERS DESCRIPTION
INTEGRATED
Chapter Covered Chapter 4: Carbon and its Compounds
Name of the Book Science, Class 10, NCERT
Subject and Artificial Bonding in Carbon- The Covalent Bond, Properties of Data Acquisition
Intelligence Carbon Compounds, Electron Dot Structure, Allotropes of Data Exploration
Integrated Carbon. Auto draw
Learning Students will be able to:
Objectives • Understand the nature of bonding in carbon.
• Explain why carbon forms a covalent bond.
• Draw electron dot structures of various molecules.
• Enlist various allotropes of carbon, their structure, and
uses.
Time Required 2 periods of 35-40 minutes each.
Classroom Flexible seating arrangement.
Arrangement
Material Required Laptop/desktop or smart mobile phone with internet
connection, notebook, pens, white board, etc.
Pre-Preparation Students will be asked to make a list of ten items that they
Activities have used/consumed since morning. They will group the
items as follows:
Items made up of metals-
Items made up of glass-
Others-
After they divide the items, they will write which item may
contain carbon in some form.
Previous Knowledge Students must be aware about atomic number and atomic
mass, concept of valence electron, and valency.
CBSE Question Bank Chapterwise & Topicwise, SCIENCE, Class-X
Methodology •
Students will be divided into groups of 4-5. Data acquisition
•
They will be asked to collect the data of melting and Data Exploration
boiling points of at least 10 carbon compound sand
arrange the data in the ascending order.
•
Students will plot a line graph for melting point as well
as boiling point.
•
Students will be able to explain the forces of attraction Autodraw
among different carbon compounds based on the
plotted graph.
•
Next, students will watch a video to understand the
nature of bonding in carbon.
Learning Outcomes By the end of the class the students will be able to:
• Enlist properties of carbon compounds.
• Explain why carbon forms a covalent bond.
• iii) Diagrammatically depict the properties of various
allotropes of carbon.
Follow up Activities Students will be assessed on the basis of their learning
with the help of AI-based app, KAHOOT.
Reflections Students will learn the basics of AI with the help of apps.
They will be asked to find out about the apps that can be
used as an alternative to the above-mentioned app.