SAFETY DATA SHEET Page:1/7

MSDS No.:MFP-0423
Product Name: TNP40/TNP41/TNP42/TNP43/TNP44/TNP46,
IUP18/IUP19/IUP20/IUP21
Prepared Date:3-Jul-2013
Revised Date: 1-May-2015
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product Name: TNP40/TNP41/TNP42/TNP43/TNP44/TNP46, IUP18/IUP19/IUP20/IUP21

used for: 4750, 4050, 4020, 3320
Supplier Identification:
Konica Minolta Business Solutions U.S.A., Inc.
100 Williams Drive, Ramsey, New Jersey 07446, U.S.A.
Telephone: 201-825-4000
Emergency Telephone No.
CHEMTREC
Telephone: 1-800-424-9300

2. HAZARDS IDENTIFICATION
Regulation (EC) No 1272/2008
Classification: Not classified as dangerous.

Hazard Communication Standard (USA)

Classification: Not classified as dangerous.

LABEL ELEMENTS
Precautionary pictograms: ---
Signal word: ---
Hazard Statement: ---
Precautionary Statements: ---

Other Hazards
Dust explosion (like most finely divided organic powders).
 SAFETY DATA SHEET Page:2/7
MSDS No.:MFP-0423
Product Name: TNP40/TNP41/TNP42/TNP43/TNP44/TNP46,
IUP18/IUP19/IUP20/IUP21
Prepared Date:3-Jul-2013
Revised Date: 1-May-2015
3. COMPOSITION / INFORMATION ON INGREDIENTS
Substance [ ] Preparation [ X ]

Major Ingredients:
[Generic Name] [CAS No.] [%]
Polyester resin +++ 75-85
Iron oxide 1317-61-9 3-7
Carbon black 1333-86-4 3-7
Amorphous silica(mofified) +++ 1-3
Polymer wax +++ 1-5
Titanium dioxide 13463-67-7 0.1-1
+++: Supplier’s confidential information

Hazardous Ingredients:
Chemical Name: Carbon black
CAS No.: 1333-86-4
EINECS-No.: 215-609-9 REACH Registration number: 01-2119384822-32-XXXX
NTP(USA): Not listed IARC Monographs: Group 2B
California Proposition 65(USA): Listed
Symbol(EC): Not listed H code(EC): Not listed
DFG-MAK(GER): III 3B
Chemical Name: Titanium dioxide
CAS No.: 13463-67-7 EINECS-No.: 236-675-5
NTP(USA): Not listed IARC Monographs: Group 2B
Symbol(EC): Not listed H code(EC): Not listed

4. FIRST-AID MEASURES
Ingestion: Wash out mouth with water. Drink one or two glasses of water. If symptoms occur, get medical
attention.
Inhalation: Move victim to fresh air immediately. If symptoms occur, get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for 15 minutes. If symptoms occur, get medical
attention.
Skin Contact: Wash with water and mild soap.

5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: CO2, water spray, foam and dry chemical
Extinguishing Media to Avoid: Full water jet
Fire and Explosion Hazards: If dispersed in air, like most finely divided organic powders, may form an explosive
mixture.
Protection of Firefighters: Use self-contained breathing apparatus(SCBA).
 SAFETY DATA SHEET Page:3/7
MSDS No.:MFP-0423
Product Name: TNP40/TNP41/TNP42/TNP43/TNP44/TNP46,
IUP18/IUP19/IUP20/IUP21
Prepared Date:3-Jul-2013
Revised Date: 1-May-2015
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions: None
Environmental Precautions: None
Methods for Cleaning Up: Wear personal protective equipment(See Section 8). Vacuum or sweep material
and place in a bag and hold for waste disposal. Use vacuum equipped with High
Efficiency Particulate Air(HEPA) filter. Vacuum should be electrically bonded and
grounded to dispel static electricity. To avoid dust generation, do not sweep dry.

7. HANDLING AND STORAGE

Handling
Technical Measures: None
Precautions: Do not breathe dust. Avoid contact with eyes.
Safe Handling Advice: Try not to disperse the particulates.
Storage
Technical Measures: None
Storage Conditions: Keep container closed. Store in a cool and dry place. Keep out of reach of children.
Incompatible Products: None
Packaging Materials: Bottles or Cartridge designated by Konica Minolta.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Measures
Ventilation: None required with intended use.
Control Parameters (As total dust)
ACGIH-TLV (USA): 10mg/m3 (Inhalable particles), 3.0 mg/m3 (Respirable particles)
OSHA-PEL (USA): 15mg/m3 (Total dusts), 5.0 mg/m3 (Respirable fraction)
DFG-MAK (GER): 4mg/m3 (Inhalable fraction), 1.5mg/m3 (Respirable fraction)
Worksafe-TWA (Austl.): 10mg/m3
Control Parameters (As Ingredients: Carbon black)
ACGIH-TLV (USA): 3mg/m3
OSHA Z-Table (USA): 3.5mg/m3
Worksafe-TWA (Austl.): 3mg/m3
Control Parameters (As Ingredients: Titanium dioxide)
ACGIH-TLV(USA): 10mg/m3
OSHA Z-Tables(USA): 15mg/m3
Worksafe-TWA(Austl): 10mg/m3
Personal Protective Equipment
Not required under normal conditions. For use other than in normal operating procedures (such as in the
event of large spill), goggles and respirators may be required.
Hygiene Measures: Wash hands after handling.
 SAFETY DATA SHEET Page:4/7
MSDS No.:MFP-0423
Product Name: TNP40/TNP41/TNP42/TNP43/TNP44/TNP46,
IUP18/IUP19/IUP20/IUP21
Prepared Date:3-Jul-2013
Revised Date: 1-May-2015
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical State: Solid Color: Black
Form: Powder (mean dia. is um by volume)
Odor: Faint odor
PH Not applicable
Boiling Point(°C): Not applicable
Melting Point(°C)/[F]: Around /[] (Softening Point)
Flash Point(°C): Not applicable
Auto-Ignition Temperature(°C): No data available
Upper/ lower flammability or explosive limits No data available
Explosion Properties: No data available
Evaporation rate: No data available
Vapor Pressure: Not applicable
Vapor density: Not applicable
Specific Gravity: Not determined
Solubility: Insoluble in water.
Partition Coefficient, n-Octanol/Water: Not applicable
Decomposition temperature: Not applicable

10. STABILITY AND REACTIVITY

Reactivity: None.
Stability: Stable except above 200C(392F).
Hazardous Reactions: Dust explosion, like most finely divided organic powders.
Conditions to avoid: Electric discharge, throwing into fire.
Materials to Avoid: Oxidizing materials.
Hazardous Decomposition Products: CO, CO2, NOx and smoke.
Hazardous Polymerization: Will not occur.
 SAFETY DATA SHEET Page:5/7
MSDS No.:MFP-0423
Product Name: TNP40/TNP41/TNP42/TNP43/TNP44/TNP46,
IUP18/IUP19/IUP20/IUP21
Prepared Date:3-Jul-2013
Revised Date: 1-May-2015
11. TOXICOLOGICAL INFORMATION
Acute Toxicity:
Ingestion(oral), LD50(mg/kg): >5000(Rat)
Dermal, LD50(mg/kg): No data available
Inhalation, LC50(mg/l): No data available
Eye irritation: No data available
Skin irritation: No data available
Skin sensitizer: No data available
Local Effects: see Chronic Toxicity or Long term Toxicity
Chronic Toxicity or Long Term Toxicity:
In a two-year inhalation study of chronic toxicity and carcinogenicity using a typical toner in rats, there
were no lung changes at all in the lowest exposure level (1mg/m3), the most relevant level to potential
human exposures. A minimal to mild degree of fibrosis was noted in 22% of the animals at the middle
exposure level (4mg/m3), and a mild to moderate degree of fibrosis was observed in 92% of the rats at
the highest exposure level(16mg/m3). The lung changes observed in the higher exposure groups are
interpreted in terms of "lung overloading", a series of generic responses to the presence of large
quantities of respirable, insoluble and relatively benign dusts retained for extended time periods in the
lungs. Lung tumor frequency was unchanged among rats exposed to toner at the three exposure
levels, and for air-only control rats.
Carcinogenicity
The IARC reevaluated carbon black as a Group 2B carcinogen (possible human carcinogen). This
evaluation is given to Carbon Black for which there is inadequate human evidence, but sufficient animal
evidence. The latter is based upon the development of lung tumors in rats receiving chronic inhalation
exposures to free carbon black at levels that induce particle overload of the lung.
Studies performed in animal models other than rats have not demonstrated an association between
carbon black and lung tumors. Moreover, a two-year cancer bioassay using a typical toner preparation
containing carbon black demonstrated no association between toner exposure and tumor development in
rats.
The IARC reevaluated titanium dioxide as a Group 2B carcinogen (possible human carcinogen). In
animal chronic inhalation studies, the tumor formulation observed in only rats with animal chronic
inhalation study are attributed to “lung overloading”, a generic response to excessive amounts of any dust
retained in the lungs for a prolonged interval. Use of this product, as intended, dose not result in inhalation
of excessive dust. Epidemiological study to date have not revealed any evidence of the relation between
exposure to titanium dioxide and diseases of the respiratory tract beyond general effects of dust.
Mutagenicity: Negative(AMES test)
Teratogenicity: No data available
(*= Based on data for other Konica Minolta Products with similar ingredients)

12. ECOLOGICAL INFORMATION

No data are available on the adverse effects of this material on the environment.
Ecotoxicity: No data available
Mobility: No data available
Persistence and degradability: No data available
Bioaccumulative potential: No data available
 SAFETY DATA SHEET Page:6/7
MSDS No.:MFP-0423
Product Name: TNP40/TNP41/TNP42/TNP43/TNP44/TNP46,
IUP18/IUP19/IUP20/IUP21
Prepared Date:3-Jul-2013
Revised Date: 1-May-2015
13. DISPOSAL CONSIDERATION
When disposing of the waste or recovered material, consult federal, state and/or local regulations for the proper
disposal method.

14. TRANSPORT INFORMATION

Information on Code and Classifications According to International Regulations
UN Classification: None
Further information: Not a dangerous good under IATA or IMDG.
Hazchem code (Austl.): None

15. REGULATORY INFORMATION

US Information
TSCA (Toxic Substances Control Act):
All chemical substances in this product comply with all applicable rules or order under TSCA.
California Proposition 65:
Ingredient carbon black subject to California Proposition 65 is bound in polymer-matrices so that
warnings are not required.
CERCLA(Comprehensive Environmental Response Compensation and Liability Act)：
None.
SARA Title III (Superfund Amendments and Reauthorization Act) 302 Extreme Hazardous Substance：
None.
311/312 Hazard Categories：
None.
313 Reportable Ingredients：
None.
EU Information
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
・Regulation (EC) No 2037/2000 of the European Parliament and of the Council on Substances That
Deplete the Ozone Layer: Not applicable
・Regulation (EC) No 850/2004 of the European Parliament and of the Council on Persistent Organic
Pollutants and Amending Directive 79/117/EEC (POPs): Not applicable
・Regulation (EU) No 649/2012 of the European Parliament and of the Council on Concerning the Export
and Import of Dangerous Chemicals (PIC): Not applicable
・Directive 2012/18/EU of the European Parliament and of the Council on the Control of Major-Accident
Hazards Involving Dangerous Substances, Amending and Subsequently Repealing Council Directive
96/82/EC, (Seveso III): Not applicable
・Regulation (EC) No 1907/2006 of the European Parliament and of the Council:
- Annex XIV- List of Substances Subject To Authorization: Not applicable
- Annex XVII- Restrictions on the Manufacture, Placing on the Market and Use of Certain
Dangerous Substances, Preparations and Articles: Not applicable

For this product a chemical safety assessment was not carried out.

Canada Information
WHMIS (Canada): This product is NOT subject to the controlled products regulations.
 SAFETY DATA SHEET Page:7/7
MSDS No.:MFP-0423
Product Name: TNP40/TNP41/TNP42/TNP43/TNP44/TNP46,
IUP18/IUP19/IUP20/IUP21
Prepared Date:3-Jul-2013
Revised Date: 1-May-2015
16. OTHER INFORMATION
HMIS Rating: The National Paint and Coating Association (USA): Health: 1 Flammability: 1 Reactivity: 0
Explanation of term: IARC 2B means "possible human carcinogen".
Abbreviations:
ACGIH-TWA: Threshold Limit Value of American Conference of Government Industrial Hygienists
CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act
DFG-MAK: Maximale Arbeitsplatz-Konzentration by Deutsche Forschuugsgemeinschaft
DGR: Dangerous Goods Regulations
EINECS: European Inventory of Existing Commercial Chemical Substances
H-Code: Hazard Code
HMIS: Hazardous Materials Identification System
IARC: International Agency for Research on Cancer
IATA: International Air Transport Association
IMDG: International Maritime Dangerous Goods Code
NTP: National Toxicology Program
OEL: Occupational exposure limit
OSHA: Occupational Safety and Health Administration
PBT: Persistent, Bioaccumulative and Toxic
SARA: Superfund Amendments and Reauthorization Act
TSCA: Toxic Substances Control Act
vPvB: very Persistent and very Bioaccumulative
WHMIS: Workplace Hazardous Materials Information System
Revision Information: Regular revision on revised date.
Literature References:
ANSI Z400.1-1993
ISO 11014-1
Commission Directive 91/155/EEC
IARC(2010): IARC monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans,
Vol. 93, Carbon Black, Titanium Dioxide, and Talc, Lyon, pp. 43-191

H.Muhle, B.Bellmann, O.Creutzenberg, C.Dasenbrock, H.Ernst, R.Kilpper, J.C.MacKenzie, P.Morrow,

U.Mohr, S.Takenaka, and R.Mermelstein(1991)
Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats. Fundamental and Applied
Toxicology 17, pp.280-299.
NIOSH CURRENT INTELLIGENCE BULLETIN :Evaluation of Health Hazard and Recommendation
for Occupational Exposure to Titanium Dioxide :DRAFT
Restrictions:
The above information is believed to be accurate and represents the best information currently available to
Our Corporation. However, Our Corporation makes no warranty with respect to such information, and Our
Corporation assumes no liability resulting from its use. Users should make their own investigation to
determine the suitability of the information for their particular purposes.