Sec 5
Sec 5
CEMENT
CLASS A
Intended for use from surface to 6,000 feet when special properties are not
required. May be tailored with additives to meet special requirements beyond
basic performance. It is a Portland cement similar to the ordinary construction
Type I, ASTM C 150.
CLASS B
Intended for use from surface to 6,000 feet when conditions require moderate to
high sulfate-resistance. Available in both moderate (similar to ASTM C 150,
Type II) and high sulfate-resistance types.
CLASS C
Intended for use from surface to 6,000 feet when conditions required high early
strength. Available in ordinary and moderate (similar to ASTMC 150, Type III)
and high sulfate-resistance types.
CLASS G
Intended for use from surface to 8,000 feet as a basic cement, as manufactured,
or can be used with accelerators and retarders to cover a wide range of well
depths and temperatures. No additions other than calcium sulfate or water, or
both, shall be interground or blended with the clinker during manufacture of Class
G Cement. Available in moderate and high sulfate-resistance types.
CLASS H
Intended for use from surface to 8,000 feet as a basic cement, as manufactured,
or can be used with accelerators and retarders to cover a range of well depths
and temperatures. No additions other than calcium sulfate or water, or both,
shall be interground or blended with the clinker during manufacture of Class H
cement. Available only in moderate sulfate-resistance type.
5-1
PHYSICAL PROPERTIES of CEMENTS and ADDITIVES
5-2
PHYSICAL PROPERTIES of CEMENTS and ADDITIVES
5-3
ABSOLUTE VOLUME NaCl (DISSOLVED)
% NaCI Gal/Lb
2% .0371
3% .03745
4% .0378
5% .0381
6% .0384
7% .0387
8% .0390
9% .0392
10% .0394
11% .03965
12% .0399
13% .0401
14% .0403
15% .0405
16% .0407
17% .04095
18% .0412
19% .0414
20% .0416
21% .0418
22% .0420
23% .0422
24% .0424
25% .0426
26% .0428
27% .0429
28% .0430
29% .04315
30% .0433
31% .04345
32% .0436
33% .04375
34% .0439
35% .0440
36% .0441
37% .0442
5-4
SALT* CEMENT
Sodium chloride, added to the mixing water or to the dry cement mix, reduces the damage to
fresh water-sensitive formations by cement filtrate. In addition, the use of salt provides a
better degree of bonding to water-sensitive shales. For cementing through salt beds, a salt-
saturated cement slurry is recommended. Salt causes cements to expand after setting–the
higher the concentration of salt, (up to saturation) the more the expansion. The amount of
salt used is expressed as “% by weight of fresh water.”
Salt added to mixing water for Salt Slurry Density of Salt Water
% Lbs of NaCl/gal Lbs of NaCl/cu ft Lb/gal Lb/cu ft
0 8.34 62.4
3 .25 1.87 8.50 63.6
5 .41 3.14 8.60 64.3
10 .83 6.21 8.89 66.5
15 1.25 9.35 9.10 68.1
16 1.33 9.95 9.18 68.7
18 1.50 11.22 9.27 69.3
20 1.67 12.49 9.36 70.0
25 2.09 15.63 9.56 71.5
(saturated) 37.2 3.10 23.19 10.08 75.4
* The terms "Salt", "Sodium Chloride" and "NaCl" are used interchangeably.
SLURRY PROPERTIES of API CEMENTS with SALT
Cement Salt % by Density Mix Water Yield
Class wt of water lb/gal lb/cu ft % gal/sk cu ft/sk
0 15.7 117.2 46 5.18 1.17
11 15.8 118.4 46 5.18 1.20
15 15.9 119.0 46 5.18 1.21
A, H * 18 16.0 119.3 46 5.18 1.22
20 16.0 119.5 46 5.18 1.22
25 16.1 120.1 46 5.18 1.23
(saturated) 37.2 16.2 121.4 46 5.18 1.26
0 14.8 111.0 56 6.31 1.32
11 15.0 112.4 56 6.31 1.35
15 15.1 113.1 56 6.31 1.37
C 18 15.2 113.5 56 6.31 1.38
20 15.2 113.7 56 6.31 1.38
25 15.3 114.4 56 6.31 1.40
(saturated) 37.2 15.5 115.9 56 6.31 1.43
0 16.5 123.5 38 4.28 1.05
11 16.6 124.5 38 4.28 1.07
15 16.7 124.9 38 4.28 1.08
H* 18 16.7 125.2 38 4.28 1.09
20 16.8 125.4 38 4.28 1.09
25 16.8 125.8 38 4.28 1.10
(saturated) 37.2 17.0 126.9 38 4.28 1.13
0 15.9 118.7 44 4.96 1.14
11 16.0 119.8 44 4.96 1.17
15 16.1 120.3 44 4.96 1.18
G 18 16.1 120.7 44 4.96 1.18
20 16.2 120.9 44 4.96 1.19
25 16.2 121.4 44 4.96 1.20
(saturated) 37.2 16.4 122.6 44 4.96 1.23
*See note on p. 5-8 concerning densities of Class H cement.
5-5
CALCULATION OF SLURRY PROPERTIES
Working from a known or design density, and the absolute volume factors (ppg 5-2 thru
5-4) of the materials used, mixing water and yield can be calculated for any slurry. Two
examples are shown on this and the following page.
ABSOLUTE VOLUME
Slurry Calculation Work Sheet
(Basic Slurry Design)
5-6
ABSOLUTE VOLUME
Slurry Calculation Work Sheet
(Basic Slurry Design)
5-7
SLURRY PROPERTIES OF NEAT API CEMENTS FRESH WATER RATIOS
The density and yield of neat API cement slurries depend only on the amount of mixing
water used. If too much mixing water is used, the slurry will be thin and have excessive free
water, or else completely separate into water and solids. If too little mixing water is used,
the slurry will be too thick to pump. The “normal” amount of mixing water for each slurry is
shown in bold face type. This usually corresponds to the official API recommendations.
5-8
API CLASS G CEMENT WITH SEA WATER
5-9
CEMENTS WITH BENTONITE (Gel)
Bentonite percentages are by weight of cement
5-10
FLY ASH CEMENT BLEND 15:85:8 with SALT & CLASS A CEMENT
MIXED WITH FRESH WATER
Density Mix Water Yield Salt, % by Wt
Lb/gal % Gal/sk Cu Ft/sk of Water
12.7 104 11.3 2.06 3.0
12.4 115 12.56 2.23 5.0
12.2 124 13.52 2.35 3.0
5-11
SODIUM METASILICATE SLURRIES
BJ Services’ Sodium Metasilicate cement systems are low density, high yield,
economical slurries that have relatively high strength. These properties can be varied,
depending on the amount of Sodium Metasilicate additive used and the amount of
mixing water. Sodium Metasilicate is usually used with the unretarded cements, API
Classes A, C, G and H.
5-12
SODIUM SILICATE L
Relatively High Strength: Higher than other “filler” slurries having the
same density.
5-13
TRINITY LITE-WATE (TLW)*
WITH VARIOUS FRESH WATER RATIOS
Density Mix Water Yield
Lb/gal % Gal/sk Cu Ft/sk
14.2 54.6 4.92 1.09
13.5 67.0 6.02 1.24
13.0 78.0 7.02 1.37
12.5 91.5 8.24 1.54
12.0 109.0 9.81 1.75
*This manufactured light weight cement is manufactured by Texas Industries and marketed
by Trinity as TLW.
5-14
LW-6 LITE-SET CEMENTING SYSTEMS
LW-7-2, LW-7-4
BJ Services’ LW-7-2 and LW-7-4 are products consisting primarily of unicellular silicate
microspheres with an average density of 0.37—0.38 gm/cc. Like LW-6, LW-7-2 and LW-
7-4 lower the slurry density due to their own lower density. By placing extra solid
material in the slurry, as opposed to extra water, the cement crystal structure can build
up around the particles resulting in a stronger set product. As opposed to LW-6,
however, LW-7-2 and LW-7-4 are silicate in nature instead of pozzolanic. This in turn
leads to higher compressive strength as the materials react with cement.
5-15
WEIGHTED SLURRIES
A weighted cement slurry is one that is made heavier by the addition of a weighting
agent. BJ Services reccommends two additives, (Hematite and W-10*), to increase
slurry density. The table indicates the amount of Hematite needed to attain the desired
slurry density. The chart shows the percent of W-10 needed to obtain a desired cement
density. As with many other additives, it is recommended that specific tests be conducted
when weighting materials are to be used under critical cementing conditions.
* W-10 is Manganese oxide
Hematite W-10
Cement Density 100
Class Lb/gal % Lb/sk
90
15.8 0 0
G 17.0 19.3 18.2 80
17.5 28.6 26.9 70
% W-10 BWOC
18.0 38.5 36.2
60
G 18.5 48.9 46.0
19.0 60.1 56.5 50
G 19.5 71.9 67.6 40
20.0 84.6 79.5
30
16.5 0 0
H 17.0 7.7 7.2 20
17.5 15.9 15.0 10
18.0 24.7 23.2 0
H 18.5 34.0 32.0
16 17 18 19 20 21
19.0 43.9 41.3
H 19.5 54.4 51.2 Cement Density, Lb/gal
20.0 65.7 61.8
5-16
KOL-SEAL
Kol-Seal is a low-density additive that can provide lost circulation control and excellent
scouring action. It can be used as an extender to provide a light-weight, high-yield slurry
with higher compressive strengths than slurries of the same weight using Gilsonite.
These water-based systems are designed to reduce the permeability of thief zones.
When brine or cement slurries accelerated with calcium chloride contact Flow-Guard,
they will gel and create impermeable skin damage to the zone.
5-17
“P” TANK BULK CEMENT CAPACITIES
PLEASE NOTE:
Some tanks vary ± 2.5% of table volumes due to difference in vent systems.
5-18