27-04-2025

1803CJA101001250001 JM

PART-1 : PHYSICS

SECTION-I

1) Dimensional formula of coefficient of viscosity (η) in equation F = 6πηrv where F is force, r is

radius and v is velocity :-

(A) MLT–1
(B) ML–1T–1
(C) ML–1T
(D) M–1L–1T–1

2) When an object moves at high velocity in a fluid the drag force on it is given by , where v
is the object’s velocity and A is area. What sort of quantity is k?

(A) Dimensionless constant

(B) Acceleration
(C) Mass
(D) Density

3)

For a hypothetical model, total energy of an electron is given as :

Total energy
where r = distance of electron, F = force on electron, v = speed of electron, t = time.

Choose CORRECT dimensional formulae of .

(A) [M–1L–2T–1]
(B) [ML–1T–3]
(C) [M–1L–3T–1]
(D) [ML–3T1]

4) If unit of length and time is doubled, the numerical value of g (acceleration due to gravity) will be

(A) doubled
(B) halved
(C) four times
(D) same

5) The velocity is v of a particle and time is t. If , where a, b and c are constants.

Then dimensions of a, b and c are respectively:–

(A) LT–2, L and T

(B) L2, T and LT2
(C) LT2, LT and L
(D) L, LT and T2

6) The speed of a wave produced in water is given by υ = λa gb ρc. Where λ, g and ρ are wavelength
of wave, acceleration due to gravity and density of water respectively. The values of a, b and c
respectively, are :

(A)

(B) 1, 1, 0
(C) 1, –1, 0

(D)

7) Boltzman’s constant ‘k’ has dimensions of - [Use :E = 1.5 kT, E → Energy ; T → Temperature]

0
(A) M L2T–2K–1
(B) M1L2T–2K–1
0
(C) M L2T–2
(D) M1L2T–2

8) Find value of cos(480°)

(A)

(B)

(C)

(D)

9) If area (A), velocity (v), and density (ρ) are base units, then the dimensional formula of force can
be represented as :-

(A) Avρ
(B) Av2ρ
(C) Avρ2
(D) A2vρ

10) The force is given in terms of time t and displacement x by the equation F = A cos Bx + C sin Dt

The dimensional formula of is :

 0
(A) [M L T–1]
(B) [M L2 T–3]
(C) [M1 L1 T–2]
(D) [M2 L2 T–3]

11) In a system of units, unit of mass is 10 kg, unit of length is 5m and unit of time is 1sec what will
be unit of force ?

(A) 25 N
(B) 50 N
(C) 0.5 N
(D) 2500 N

12)

In a new system; unit of mass, length and time is 2kg, 2m and 4sec respectively. Calculate the unit of
work in new system.

(A) 50 J
(B) 5 J
(C) 0.5 J
(D) 0.05 J

13) Match List-I with List-II.

List-I List-II
A. Coefficient of viscosity I. [M L2T–2]
B. Surface Tension II. [M L2T–1]
C. Angular momentum III. [M L–1T–1]
0
D. Rotational kinetic energy IV. [M L T–2]
(A) A–II, B–I, C–IV, D–III
(B) A–I, B–II, C–III, D–IV
(C) A–III, B–IV, C–II, D–I
(D) A–IV, B–III, C–II, D–I

14) If the potential energy U of the particle is given by where x is the distance from the
initial position. The dimensional formula of k is :-

(A) [M1L2T–2]
0
(B) [M1L T–2]
(C) [M1L1T–2]
(D) [M1L4T–2]
15) If then find the angle between and .

(A) 90°
(B) 120°
(C) 45°
(D) 60°

16) Which vector diagram represents the greatest magnitude of displacement for an object?

(A)

(B)

(C)

(D)
17) In the given figure

(A) Angle between is 110°

(B) Angle between is 110°
(C) Angle between is 60°
(D) Angle between is 120°

18) The vector sum of the forces of 10 N and 6 N can be

(A) 2 N
(B) 8 N
(C) 18 N
(D) 20 N

19) Three vectors and bear the following relations. and

. Angle between vectors...........

0
(A) and is 30
0
(B) and is 60
(C) and is 30o
(D) and is 60o

20) Two vectors have magnitudes 2 & 1 respectively. If the angle between is 60°, then

which of the following vectors may be equal to .

(A)

(B)

(C)

(D)

SECTION-II
1) What is value of expression
2(sin 15° + sin 75°)2 ?

2) In a new system of units, the unit of mass is 100 g, unit of length is 4m and unit of time is 2 sec. If

the numerical value of 10 J in this system is α, fill the value of .

3) If velocity (V), force (F) and time (T) are taken to be fundamental quantities. If the dimensional
formula of energy (Q) is represented by the Q = kVxFyTz. Then fill the value of (x + y + z) in OMR
sheet

4) The maximum and minimum magnitudes of the resultant of two forces are 7 N and 1 N
respectively. The magnitude of resultant force when act perpendicular to each other is (in N).

5) If and , then is equal to

PART-2 : CHEMISTRY

SECTION-I

1) Find the group of orbitals in which atleast one common nodal plane is present :

(A) 2px , 3dxy , 4dyz

(B) 2py , 3dxy , 4dyz
(C) 2pz , 3dxy , 4dyz
(D) 4dx –y , 5dz
2 2 2

2) Which of the following species are isotopic as well as isoelectronic

(A) 40Ca+2, 40Ar

(B) 39K+, 40K+
(C) 24Mg+2, 25Mg
(D) 23Na, 24Na+

3) m = –1 is not possible for

(A) 3px orbital

(B) 4dx 2
– y2 orbital
(C) 2s orbital
(D) 4f orbital

4) The number of orbitals having (n + ℓ) < 5 is :

(A) 9
(B) 8
(C) 4
(D) 10

5) For an electron present in which of the following orbital for which (n + l + m + s) value is
maximum. Consider maximum possible value for ‘m’ and minimum possible value of ms (where ever
applicable).

(A) 3p
(B) 5p
(C) 4d
(D) 5s

6) If the nitrogen atom had electronic configuration 1s7, it would have energy lower than that of
normal ground state configuration 1s2 2s2 2p3, because the electrons would be closer to the nucleus.
Yet 1s7 is not observed because it violates :–

(A) Aufbau's principle

(B) Hund's rule
(C) Pauli’s exclusion principle
(D) None of the above

7)

Match the list:

List- I List- II
(Set of quantum (Maximum
number) Possible value)

(P) n = 4, ℓ = 2, m = –1 (1) one electron

(Q) n = 3, ℓ = 1 (2) six electrons

(R) n = 5, ℓ = 0, s = (3) two electrons

(S) n = 2, ℓ = 2 (4) ten electrons

(5) zero electron

The CORRECT option is

(A) P → 3 ; Q → 2 ; R → 1 ; S → 4
(B) P → 2 ; Q → 3 ; R → 1 ; S → 4
(C) P → 3 ; Q → 2 ; R → 1 ; S → 5
(D) P → 3 ; Q → 2 ; R → 4 ; S → 5

8) Which of the following arrangements shows the correct order of decreasing paramagnetism?

(A) N > Al > O > Ca

(B) N > O > Al > Ca
(C) O > N > Al > Ca
(D) O > N > Ca > Al

9) Which of the following orbital does not exist?

(A) 5g
(B) 4f
(C) 5h
(D) 6h

10) If m = magnetic quantum number and = azimuthal quantum number, then relation between
given value of & total possible values of m is -

(A) m = +2
2
(B) m = 2 +1

(C)

(D) = 2m + 1

11) Consider the hypothetical situation where the azimuthal quantum number ( ) takes values 0, 1,
2, ...... (n + 1), where n is the principal quantum number. In the element with atomic number (z =
36) the last electron enter in which subshell ? (Rule for filling of electron are fixed).

(A) 3f
(B) 4p
(C) 2d
(D) 3g

12)

Electronic configuration

has violated :
(A) Hund's rule
(B) Pauli's principle
(C) Aufbau principle
(D) (n + l) rule

13) Choose the correct option having all the elements with d10 electronic configuration from the
following:

(A) 27Co, 28Ni, 26Fe, 24Cr

(B) 29Cu, 30Zn, 48Cd, 47Ag
(C) 46Pd, 28Ni, 26Fe, 24Cr
(D) 28Ni, 24Cr, 26Fe, 29Cu
14) The orbital with maximum energy is :-

(A) 3d
(B) 5p
(C) 4s
(D) 6d

15) In Palladium (Atomic no.–46), number of electron having (ℓ = 2) will be -

(A) 20
(B) 18
(C) 16
(D) 22

16) An element have electronic configuration as 1s2, 2s2, 2p6, 3s2,3p6, 4s2, 3d7. Incorrect statement
regarding element is -

(A) Element must be Co

(B) Element belongs to group no. ‘9’ according to the long form periodic table
(C) Maximum no. of electrons in element having m = +1 are 6

(D)
Element have spin magnetic moment B.M.

17)

Consider the following set of quantum number n = 3, |m| = 1. It represents how many orbitals ?

(A) 2
(B) 1
(C) 4
(D) 9

18) Which of the following is CORRECT set up quantum number(s) for the last electron enters in
'Fe'.
n ℓ m s

(1) 4 0 0

(2) 3 1 0

(3) 3 2 –1

(4) 3 2 –3

(A) 1
(B) 2
(C) 3
(D) 4

19) The zero probability of finding the electron in dx –y orbital

2 2

(A) Two opposite sides of the nucleus along x-axis

(B) In the nucleus
(C) Same on all the sides around the nucleus
(D) None of these

20) What is the number of unpaired electrons in the element (Z = 24) in its lowest energy states ?

(A) 1
(B) 5
(C) 4
(D) 6

SECTION-II

1) Total number of orbitals that are to be filled completely before entering into the 6s subshell for
filling of electrons (Add the digits till you get a single digit integer)

2) Count the number of electrons of 'Zn' which are present in orbitals which has only one nodal
plane.

3) Total number of degeneracies possible in 4th exited state of Li+2 ion

4) Find total number of maximum orbitals in 'Sc' atom, for which |m| ≤ 1 and contains at least one
electron. [At. No. of Sc (z = 21)]

5) How many unpaired electrons are present in Co3+ ion ?

PART-3 : MATHEMATICS

SECTION-I

1) If m2 – n2 = 7, where m, n ∊ Z, then number of ordered pairs (m, n) is

(A) 1
(B) 2
(C) 3
(D) 4
2) Number of positive integral solutions of the equation

(A) 4
(B) 6
(C) 8
(D) 10

3)

(A) 1
(B) 3
(C) –1
(D) 0

4) If ax = b, by = c, cz = a, then value of xyz is

(A) 0
(B) 1
(C) 2
(D) 3

5) The value of + + , (where x > 0) is

(A) 0
(B) 1
(C) 2
(D) 3

6) If then x =

(A) 1
(B) 3
(C) 4
(D) 0

7)

If , then vale of x is :
(A)

(B)

(C)

(D)

8) If x + y = 8 and x2 + y2 = 10, then value of x3 + y3 is

(A) 117
(B) –136
(C) 124
(D) –138

9) The expression is simplifed to

(A) a3
(B) a2
(C) a
(D) a4

10) The value of 8 terms is

(A) 2
(B) –2
(C)
(D)

11) If then x equal to

(A) –2
(B) 4
(C) –6
(D) –4

12) If a + b = –3 and ab = –2, then find a3 + b3.

(A) 5
(B) –5
(C) 45
(D) –45
13) The value of

is

(A) 0
(B) –1
(C) 1
(D) None of these

14)

(A) 3
(B) 6
(C) 5
(D) 4

15)

If a = x + , then x3 + x–3 =

(A) a3 + 3a
(B) a3 – 3a
(C) a3 + 3
(D) a3 – 3

16) If p(x) = x(x – 1)(x – 2)(x – 3), then find the remainder when p(x) is divided by (x + 1).

(A) 12
(B) –12
(C) 24
(D) –24

17) If where a and b are natural number then a + b = .....

(A) 4
(B) 6
(C) 8
(D) 10

18) The factor of the polynomial x3 + 3x2 + 4x + 12 is

(A) x + 3
(B) x – 3
(C) x + 2
(D) x – 2

19) If 3(x–y) = 27 & 3(x+y) = 243, then x equals :-

(A) 0
(B) 2
(C) 4
(D) 6

20) The polynomials P(x) = kx3 + 3x2 – 3 and Q(x) = 2x3 – 5x + k, when divided by (x – 4) leave the
same remainder. Then the value of k is

(A) 2
(B) 1
(C) 0
(D) –1

SECTION-II

1)

The value of (4 + 1)(42 + 1)(44 + 1)(48 + 1) + where λ ∈ then find the value of 'λ' is equal
to :

2) The value of

,
where x = 2 and ℓ = 2, m = 2, n = 3 is

3) If , then

4)

Number of ordered pair (x, y), x, y ∈ N satisfying the equation

5) If P(x) is a cubic polynomial such that P(1) = 1; P(2) = 2; P(3) = 3 with leading coefficient 3 then
find the value of P(4).
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B D D A A A B B B B B C C B A A B B A B

SECTION-II

Q. 21 22 23 24 25
A. 3 5 3 5 1

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B B C D C C C B C C C A B D A D C 3 B D

SECTION-II

Q. 46 47 48 49 50
A. 9 12 25 11 4

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D B A B B C B B D A D D A C B C C A C B

SECTION-II

Q. 71 72 73 74 75
A. 32 1 2 4 22
 SOLUTIONS

PART-1 : PHYSICS

1) = ML–1T–1

2)

3) [A] = [MT–2]
[B] = [LT–1]
[C] = [L3T–3]

5) Use dimesion analysis method

7)

E = 1.5 KT [energy] = [ML2T–2]

[ML2T–2] = [K] [K]
[ML2T–2K–1] = [K] = boltzman's constant

8) cos(480°) = cos (360°+120°)

= cos 120°
= cos(90 + 30)
= –sin (30)

11) In new system,

Force unit = 50 kgm/s2 = 50 N

12)

n1U1 = n2U2
1M1 = 2kg
1L1 = 2m
1T1 = 4S

So 0.5 J is unit of work in new system.

13)

16) use & Displacement = Change in position = final position-

initial position

19)

(Angle between )
Angle between = 60° and angle between

21)

22)

[Energy] = ML2T–2
In new system
 1 unit of energy =

= =

Now = 1 unit of energy in new system

1J = 10 J = unit = 25 unit

23) [Q] = [k][V]x[F]y[T]z

ML2T–2 = 1 × LxT–x Tz
M1L2T–2 = MyL(x + y)T(–x – 2y + z)
y = 1, x + y = 2, –x – 2y + z = –2
y = 1, x = 1 & z = 1
∴ (x + y + z) = 3

24)

Let forces be and then according to question F1 + F2 = 7 and F1 – F2= 1

⇒ F1 = 4 N & F2 = 3 N
When and act orthoganally then magnitude of resultant force

25) &

PART-2 : CHEMISTRY

26)

Types of orbital Nodal Plane

2py xz
3dxy xz, yz
4dyz xy, xz
∴ xz is common plane among given orbital.

27)

Isotope :
 Isoelectronic : Same 90 : of electrons
39 +
K = 18 electrons
40 +
K = 18 electrons

28)

For s-orbital : m = 0
∴ m = –1 is not possible

29)

Ans.: (4)

30) n l m s n+ℓ+m+s

3P 3 1 1 4.5

5P 5 1 1 6.5

4d 4 2 2 7.5

5s 5 0 0 4.5
So answer is 4d which have maximum value of (n + ℓ + m + s)

31) Ans. (3)

According to Pauli's exclusion rule each orbital can hold maximum two electrons.

32)

(P) : 4d : m = –1 i.e. one orbital.

1 orbital contains maximum 2

(Q) : 3p : = 6e–s

(R) : 5s : m = –1/2 = 1 e–.

(S) : 2d → does not exist

33)

No. of Unpaired electrons

N : sp3 3
4
O : 2p 2
Al : 3p1 1
2
Ca : 4s 0
∴ Order N > O > Al > Ca

34)
 n ℓ
5g 5 4
4f 4 3
5h 5 5
6h 6 5
X do not exist as n and ℓ can not be equal.

35)

m = –ℓ to +ℓ
∴ m = 2ℓ + 1

or

36)

ℓ = 0 to (n + 1)
∴ for n = 1, ℓ = 0, 1, 2
i.e. 1s, 1p, 1d
For n = 2, ℓ = 0, 1, 2, 3
i.e. 2s, 2p, 2d, 2f
Now arrange in increasing order of energy.
Caufbau's Principal
1s2 < 1p6 < 2s2 < 1d10 < 2p6 < 3s2 < 2d8.
∴ Last e– filled in 2d.

37)

Hund's Rule : e– remain unpaired and in parallel spin.

38) [Cr] = [Ar]4s1 3d5

[Cd] = [Kr]5s24d10
[Cu] = [Ar]4s13d10
[Ag] = [Kr]5s14d10
[Zn] = [Ar]4s23d10

39) According (n + l) Rule

(n + l) → maximum → energy maximum
3d → 3 + 2 = 5
5p → 5 + 1 = 6
4s → 4 + 0 = 4
6d → 6 + 2 = 8 → maximum energy

40) 46Pd = 1s2 2s2 2p6 3s2 3p6 4s2

Here
for ℓ = 2 (d – orbital)

41)

Since it has 27e–

∴ Given element is 'Co'.
and it belongs to Gr 9 in long form of Periodic Table.

∴ No. of e– in m = +1
= 2 in 2p6
= 2 in 3p6
= 2 in 3d–
6 e–s
(D) µ =
Co.4s2 3d7
n=3
∴µ= B.M.

Not µ =

42)

n = 3, m = –1, +1

Total = (4) Orbitals

43) 26Fe : 4s2 3d6

Last e– enters in 3d subshell.
∴ n = 3, l = 2, m= –1

44)

Zero probability of finding e– in dx2–y2 is in Nucleus and two nodal planes in b/w axis x and y.

45) 24Cr : 4s1 3ds

Unpaired electrons = 6
 46)

No. of orbital to be filled according to Aufbau's Principle.

= 27
∴2+7=9

47) 30Zn : 1s22s22p63s24s23d10

P-orbital has only 1 nodal plane.
∴ 6 + 6 = 12e–

48) 4th excited state i.e. in 5th shell

5s 5g 5ƒ 5d 5p
1 + 9 + 7 + 5 + 3 = 25

49) 21Sc :

50) 27Co: 4s2 3d7

0
Co+3 : 4s 3d6

∴
Unpaired electrons : 4

PART-3 : MATHEMATICS

51) (m + n)(m – n) = 7 ´ 1 = (–7) ´ (–1)

m+n=7
m–n=1
or
m+n=1
m–n=7
⇒ m = 4, n = 3 or m = 4, n = +3
m + n = –7
m – n = –1
or
m + n = –1
m – n = –7
⇒ m = –4, n = –3 or m = –4, n = +3

52) ⇒

x 36 20 12 8 6 5
 y 9 10 12 16 24 40
Since x and y ar positive integers
⇒ y ≥ y – 8 must divisible by 32
y – 8 = 1, 2, 4, 8, 16, 32

55)

58)

x+y=8 ...(1)
x2 + y2 = 10 ...(2)
2
(1) – (2) ⇒ xy = 27
x3 + y3 = (x + y)(x2 + y2 – xy)
= 8(10 – 27)

= –136

59)

⇒ a2 . a2 ⇒ a4

63)

⇒0

64)

= 51

68)

Let p(x) = x3 + 3x2 + 4x + 12 be the given polynomial. By factor theorem, (x – a) is a factor of a

polynomial p(x) iff p(a) = 0. Therefore, in order to prove that x + 3 is a factor of p(x), it is
sufficient to show that p(–3) = 0. Now,
p(x) = x3 + 3x2 + 4x + 12
⇒ p(–3) = – 27 + 27 – 12 + 12 = 0
Hence, (x + 3) is a factor of p(x) = x3 + 3x2 + 4x + 12.

70) P(4) = 64k + 48 – 3 = 64k + 45

Q(4) = 128 – 20 + k = k + 108
Given P(4) = Q(4)
∴ 64k + 45 = k + 108
⇒ 63k = 63 ⇒ k = 1

72)