04-05-2025

2401CJA101001250001 JM

PHYSICS

SECTION - I

1) Consider three physical quantities A, B and C. Operations A + B and B – C are valid with these
physical quantities. Which of the following conclusions you can't make?

(A) The operation A ± C is also valid.

(B) If dimension of any of the three is known, dimension of other two can be predicted.
(C) If dimension of product of any two of them is known, dimension of all of them can be predicted.
(D) If dimension of quotient of any two of them is known, dimension of all of them can be predicted.

2) The dimensional formula of k in the equation: Work Done = . Here ‘ ’ is pure constant and x
is distance, is

0
(A) [M1L T–2]
0
(B) [M L1T–1]
(C) [M1L1T–2]
0
(D) [M1L T–1]

3) A gas bubble formed from an explosion under water oscillates with a period proportional to PadbEc,
where P is the static pressure, d is the density of water and E is the energy of explosion. Then, a, b, c
are respectively,

(A) 1, 1, 1

(B)
, ,

(C)
, ,

(D) , ,

4) Which of the following quantities cannot enter into the list of fundamental quantities in any
system of units ?

(A) Mass, time and acceleration

(B) Length, volume and linear momentum
(C) Mass, velocity and time
(D) Length, force and time
5) If where F : force, r : distance, v : velocity and C & k are constants then dimension
of C is :-

(A) Dimensionless
(B) MLT–2
(C) ML2T–3
(D) ML2T–4

6) Value of one unit of momentum in SI system is equal to x unit in CGS system. Value of x is
[Momentum = mass × Velocity]

(A) 1
(B) 10–5
(C) 105
(D) 103

7)

Write the dimensions of in the relation , where P is the pressure, x is the distance and t
is the time,

0
(A) M–1L T–2
0
(B) ML T–2
0
(C) ML T2
(D) MLT–2

8)

If , then

(A) Dimensions of A and B must be same

(B) Dimensions of A and B cannot be same
(C) Dimensions of D and B must be same
(D) Dimensions of AD and y must be same

9) Due to some unknown interaction, force F experienced by a particle is given by the following

equation. Where A is positive constant and r distance of the particle from origin of a
coordinate system. Dimensions of constant A are

(A) ML2T–2
(B) ML3T–2
(C) ML4T–2
 0 0
(D) ML T

10) The dimensional formula of strain is :

(A) M1L1T–1
0 0 0
(B) M L T
(C) M1L2T–2
(D) M–1L2T2

11) The bottom of an electric pole of height 20m is situated at a distance of from you due
30° north of east. The magnitude of the position vector of a bulb situated on the top of the pole
relative to you is

(A) 30 m
(B) 50 m
(C)
(D)

12) Sum of two unit vectors is a unit vector. What is magnitude of their vector difference.

(A)
(B)

(C)

(D)

13) If and A = B + C, then the angle between and is :-

(A) 0

(B)

(C) π

(D)

14) Which vector diagram represents the greatest magnitude of displacement for an object ?

(A)

(B)
(C)

(D)

15) Personnel at an air post control tower track a UFO. At 11:02 am it was located at position A and

at 11:12 am was located at position B. Displacement vector UFO is :

(A)
(B)
(C)
(D)

16) Three forces act on a stationary particle and particle does not move. If the forces are
, and then the value of (a + b + c) will be

(A) 0
(B) 9
(C) –9
(D) Can't be determined

17) Correct statement, considering figure is :-

(A)
(B)
(C)
(D)
18) Unit vector of is :

(A)

(B)

(C)

(D)

19) What is the magnitude of projection of on yz plane ?

(A)
(B) 10
(C) 6
(D) 8

20) The three vectors OA, OB and OC have the same magnitude R. Then the sum of these vectors

have magnitude–

(A) R
(B)
(C) 3R
(D)

SECTION - II

1) The maximum and minimum magnitudes of the resultant of two forces are 35 N and 5 N
respectively. Find the magnitude of resultant force when they act perpendicular to each other.

2) If and , then is equal to

3) A particle moves along a path ABCD as shown in the figure. Then the magnitude of net
displacement of the particle from position A to D is , find the value of n.

4) In a certain system of units, 1 unit of time is 5 sec, 1 unit of mass is 20 kg and 1 unit of length is
10 m. In this system, one unit of power will correspond to_____watts.

5) The radius R, of the fireball produced by an atomic bomb explosion may be assumed to depend on
the density 'ρ' of the atmosphere, the time 't' elapsed since the explosion and the energy 'E' released
by the bomb. Deduce the formula for R by dimensional method. If your answer is

where k is dimensionless constant. Fill the value of .

CHEMISTRY

SECTION - I

1)

The total number of orbitals associated with the principal quantum number 5 is

(A) 25
(B) 5
(C) 20
(D) 10

2)

Which of the following has the maximum number of unpaired electrons?

(A) Fe+3
(B) Ti+3
(C) V+3
(D) Fe+2

3) The maximum probability of finding electron in the dxy orbital is -

(A) Along the x axis

(B) Along the y axis
(C) At an angle of 45° from the x and y axis
(D) At an angle of 90° from the x and y axis
4) When 4d orbital is complete, the entering electrons goes in to -

(A) 5f
(B) 5s
(C) 5p
(D) 6d Orbital

5)

Which orbital is non directional :

(A) s
(B) p
(C) d
(D) All

6)

In a multi-electron atom, which of the following orbitals described by the three quantum members
will have the same energy in the absence of magnetic and electric fields ?
(1) n = 1, = 0, m = 0 (2) n = 2, = 0, m = 0
(3) n = 2, = 1, m = 1 (4) n = 3, = 2, m = 1
(5) n = 3, = 2, m = 0

(A) (4) and (5)

(B) (3) and (4)
(C) (2) and (3)
(D) (1) and (2)

7) Which of the following orbital does not exist according to quantum theory?

(A) 5g
(B) 4f
(C) 5h
(D) 6h

8) How many unpaired electrons are present in the ground state of chromium (Z = 24)?

(A) 1
(B) 5
(C) 6
(D) 0

9) Which of the following combination only isoelectronic series :

(A) N3–, O2–, Cl–, Ne

(B) F–, Ar, S2–, Cl–
(C) P3–, S2–, Cl–, Ar
(D) N3–, F–, O2–, Ar

10) Correct set of quantum number is

(A)
n = 2, ℓ = 2, m = –1, s =

(B)
n = 3, ℓ = 2, m = –2, s =

(C)
n = 3, ℓ = 2, m = ,s=
(D) n = 3, ℓ = 1, m = –1, s = 0

11) Incorrect set of isoelectronic species.

(A) Sc+3, Ca+2, Cl–, Ar

3– 2– –
(B) PO4 , SO4 , ClO4
– 2– 3–
(C) NO3 , CO3 , BO3
(D) CO2, NO2, N2O

12) The species having same number of electrons in valence and penultimate shell -

(A) Ca
(B) Ar
(C) V+3
(D) Fe3+

13) In the following electronic configuration, some rules have been violated.

(I) Hund's rule

(II) Pauli's exclusion principle
(III) Aufbau principle

(A) I and II
(B) I and III
(C) II and III
(D) I, II and III

14) The quantum number of four electrons are given below:

I. n = 4, l = 2, ml = –2, ms = –1/2
II. n = 3, l = 2, ml = 1, ms = +1/2
III. n = 4, l =1, ml = 0, ms = +1/2
IV. n = 3, l = 1, ml = 1, ms =–1/2
The correct order of their increasing energies will be

(A) IV < II < III <I

(B) IV < III < II <I
(C) I < III < II <IV
(D) I < II < III <IV

15) Which of the following is not an isodiapher of 6C12

14
(A) 7N
16
(B) 8O
40
(C) 20Ca
19
(D) 9F

16) The spin only magnetic moment (µs) for Ni2+ will be :

(A) B.M
(B) B.M
(C) B.M
(D) 2 B.M

17) The number of electrons in Ca having minimum value of is.

(Consider only non-zero values of ℓ and m)

(A) 6
(B) 3
(C) 4
(D) None of these

18) Which quantum number will determine the shape of the orbital

(A) Principal quantum number

(B) Azimuthal quantum number
(C) Magnetic quantum number
(D) Spin quantum number

19) For an electron present in which of the following orbital for which (n + l + m + s) value is
maximum. Consider maximum possible value for ‘m’ and minimum possible value of ms (where ever
applicable).

(A) 3p
(B) 5p
(C) 4d
(D) 5s
20) Choose the correct option for the quantum numbers of the last electron of K+.

(A) 4, 0, 0, +1/2
(B) 3, 1, –1, –1/2

(C)
4, 1, 0, –

(D)
3, 0, 1,

SECTION - II

1) The number of given orbitals which have electron density along the axis is _________________

2) Find maximum number of electrons in ‘Al’ in which . [At. no. of Al = 13]

3) Total no. of exchange pair possible in 3d8 electronic configuration is ____.

4) The total number of electrons having quantum number n = 4, |mℓ| = 1, ms =

5) Sum of ' ' for 5p orbital

MATHEMATICS

SECTION - I

1) If A = {1, 3, 5, 7, 11, 13, 15, 17, 19, 21}

B = {2, 4, 6, ....., 22}
U is universal set, then A' ∪ ((A ∪ B) ∩ B') is -

(A) U
(B) A'
(C) A ∩ B
(D) A

2) Sets A and B have 4 and 9 elements each. What can be the minimum number of elements in A ∪ B
?

(A) 4
(B) 13
(C) 5
(D) 9
3) If A = {2, 4} and B = {1, 2, 5}, then (A ∪ B) × (A ∩ B) is

(A) {(2,1), (2,2), (2,4), (2,5)}

(B) {(1,2), (2,2), (2,4), (5,2)}
(C) {(1,2), (2,2), (4,2), (5,2)}
(D) None of these

4) If A = [1, 8), B = [3, 10], C = [2, 9) then interval A ∩ B ∩ C is

(A) [3, 8)
(B) [3, 10]
(C) [2, 8)
(D) [3, 9)

5)

The shaded region in the figure represents

(A) A ∩ (B ∪ C)
(B) A ∪ (B ∩ C)
(C) A ∩ (B – C)
(D) A – (B ∪ C)

6) For two sets A and B if n(A) = 7, n(B) = 13 and n(A ∩ B) = 5, then the incorrect statement is

(A) n(A ∪ B) = 15
(B) n(A – B) = 6
(C) n(A × B) = 91
(D) n{(A ∪ B) × (A ∩ B)} = 75

7) In a certain town 25% families own a cell phone, 15% families own a scooter and 65% families
own neither a cell phone nor a scooter. If 1500 families own both a cell phone and a scooter, then
the total number of families in the town who own cell phone only

(A) 7000
(B) 8000
(C) 6000
(D) 5000

8) If n(A) = 20, n(P(B)) = 225 and n(A ∪ B) = 35 then n(A ∩ B) is (where n(X) represent number of
elements in set X and P(X) represents power set of X)

(A) 10
(B) 20
(C) 5
(D) 15

9) If A = {ϕ, {ϕ}}, then the power set of A is

(A) {ϕ, {ϕ}, {ϕ, {ϕ}}}

(B) {ϕ, {ϕ}, {{ϕ}}, A}
(C) {ϕ, {{ϕ}}, {A}}
(D) {{ϕ}, {{ϕ}}}

10) Out of the members of three athletic teams in a school 21 are in the cricket team, 26 are in the
hockey team and 29 are in the football team. Among them, 14 play hockey and cricket, 15 play
hockey and football, and 12 play football and cricket. Eight play all the three games. Find the total
number of members in the three athletic teams.

(A) 41
(B) 42
(C) 43
(D) 44

11) The shaded region in given figure is-

(A)
(B)
(C)
(D)

12) Two finite sets have m and n elements. The number of subsets of the first set is 112 more than
that of the second set. The values of m and n are, respectively.

(A) 3, 7
(B) 7, 4
(C) 4, 4
(D) 7, 7
13) The value of is

(A) a integer
(B) an irrational number
(C) a rational number which is not integer
(D) none of these

14) The value of

,
(where x > 0) is

(A) 0
(B) 1
(C) 2
(D) 3

15) If , , then value of x3 + y3 + z3 – 2xyz is :

(A)
(B)
(C)
(D)

16) The expression simplifies to

(A) 4
(B)
(C)
(D) 6

17) is equal to

(A)
(B)
(C) 3
(D) –3

18) If 376a456b is divisible by 15 then greatest value of 'a' out of all possible values is ('a' and 'b' are
one digit number)

(A) 2
(B) 8
(C) 5
(D) 9

19) If x100 is divided by x2 – 3x + 2 then the remainder is ax – b then value of a – b is

(A) 2100 – 1
(B) –1
(C) 1
(D) 2100

20) ,
then n(A) :

(A) 1
(B) 2
(C) 3
(D) 0

SECTION - II

1) p(x) is a polynomial of degree 5 with leading coefficient unity such that p(1) = 1, p(2) = 4, p(3) =
9, p(4) = 16, p(5) = 25 then p(–1) is equal to :

2) If x & y are positive integers, such that & x ≥ y, then the number of ordered pairs of (x,
y) is

3) Let P(x) be a polynomial such that when P(x) is divided by (x – 3), then the remainder is 5 and
when P(x) is divided by (x – 5), then the remainder is 3. If r(x) is the remainder when P(x) is divided

by (x – 3) (x – 5) then is equal to

4) If , then total number of possible ordered pair of positive integer (x, y) is -

5) If A = {5, 10}, B = (5, 10), C = (5, 10], D = [5, 10), E = [5, 10], then how many of the following
statements are incorrect ?
(i) n(A) + n(B) = 6 (ii) B = {6,7,8,9}
(iii) C = {6,7,8,9,10} (iv) n(C) + n(D) + n(E) = 16
 ANSWER KEYS

PHYSICS

SECTION - I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D A C B D C B D B B D B C A D C C D B D

SECTION - II

Q. 21 22 23 24 25
A. 25.00 1.00 7.00 16.00 5.00

CHEMISTRY

SECTION - I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A A C C A A C C C B D B C A D A C B C B

SECTION - II

Q. 46 47 48 49 50
A. 5.00 9.00 13.00 6.00 6.00

MATHEMATICS

SECTION - I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A D C A D B C A B C C B A B A B C D C A

SECTION - II

Q. 71 72 73 74 75
A. -719.00 2.00 3.50 6.00 4.00
 SOLUTIONS

PHYSICS

1)

[A] = [B] = [C],

2)

= [MT–2]

3)

Let
Writing dimensions on both sides.
0 0
[M L T] = [ML–1T–2]a [ML–3]b [ML2T–2]c
0 0
⇒ [M L T]=Ma+b+cL–a–3b+2cT–2a–2c
Thus a+b+c=0, –a–3b +2c =0, –2a–2c=1

On solving these equations, we get ,b= and c =

4)

In (B) volume = L3
length = L

as volume is completely derival from length, it is a derived quantity

5) Ans. (4)

[C] = [M1L2T–4]

6) (1000) ×100 = x
∴ x = 105

7)

Here, ‘a’ hasd the same dimensions as t2

a = [T2],
= [M–1T4]

Now,

11) Distance of bulb

=
=

12)

A=B=C=1

13) and A = B + C

⇒ θ=π

14) use &

Displacement = Change in position = final position- initial position

15)

Displacement = final position – initial position

16) For a particle remains at rest, the net force will be zero.
∴
∴ a = –8, b = –1 and c = 0
∴ (a + b + c) = (–8 – 1 + 0) = –9

18)
 R = 2a cos

19)

Length of projection on yz plane is

=
0
24) 1 s1 = 5 s
1 kg10 = 20 kg
0
1 m1 = 10 m
1 W = 1 kg m2 s–3
1 W' = 1 kg10 m12 s1–3

1 W' = kg m2 s–3
1 W' = 16 W

CHEMISTRY

26)

Total number of orbital = n2

52 = 25

30)

Refer to notes

35)

For an electron

40)

For isodiaphers; A1 =2Z1, A2-2Z2

41) The number of unparied electrons in Ni+2 = 2

µs = B.M
42) Here we need minimum value of
Electronic configvration of Ca
Ca = 1s2 2s2 2p6 3s2 3p6 4s2
n= 1 2 2 3 3 4
ℓ= 0 0 1 0 1 0
only Non zero value of ℓ

⇒ Now for minimum value for

n. should be minimum, so selected shell = 2
⇒ Total electrons for selected values of
(n, , mℓ) = 4 electron of 2 p

43)

(A) Principal quantum number = energy and size

(B) Azimuthal quantum number = Shape
(C) magnetic quantum number = orientation
(D) Spin quantum number = not applied for orbital

44) n l m s n+ℓ+m+s

3P 3 1 1 4.5

5P 5 1 1 6.5

4d 4 2 2 7.5

5s 5 0 0 4.5
So answer is 4d which have maximum value of (n + ℓ + m + s)

45) last electron of K⊕ enters into 3P subshell

So for 3P subshell → n ℓ m s

3 1 –1/1/0 + /
So according to given options answer is (B)

47) Al13
 × m can be 0 if either
l = 0 or m = 0 or × m = 0
Total = 9

48)

Exchange pair for +1/2e (5e–) =

Exchange pair of –1/2e (3e–) =

Formula n = No. of e–1

MATHEMATICS

51) (A ∪ B) ∩ B' = A
⇒ A' ∪ ((A ∪ B) ∩ B') = A' ∪ A = U

52) Do Your Self

53) A ∪ B = {1, 2, 4, 5}
A ∩ B = {2}
(A ∪ B) × (A ∩ B) = {(1,2), (2,2), (4,2), (5,2)}

54)

55) Shaded region contain element of A not in B and not in C hence it is

A – (A ∩ B) – (A ∩ C) + (A ∩ B ∩ C)

56)

n(A) = 7; n(B) = 13
n(A – B) = n(A) – n(A ∩ B) = 7 – 5 = 2
n(A ∪ B) = n(A) + n(B) – n(A ∩ B)
= 7 + 13 – 5 = 75
 n(A × B) = n(A) × n(B) = 7 × 13 = 91

n{(A ∪ B) × (A ∩ B)} = 15 × 5 = 75

57)

Let the total population of town be x

x = 30,000

Total number of families who own cell phone only =

58) Given n(P(B)) = 225

⇒ B has 25 elements
i.e. n(B) = 25
Now n(A ∪ B) = n(A) + n(B) – n(A ∩ B)
⇒ n(A ∩ B) = 20 + 25 – 35 = 10

59)

A = {ϕ, {ϕ}}
P(A) = {ϕ,{ϕ}, {{ϕ}}, A}

60) Let C, H, F denote the sets of members who are on the cricket team, hockey team and

football team respectively. Then we are given n(C) = 21, n(H) = 26,
n(F) = 29
n(H ∩ C) = 14, n(H ∩ F) = 15, n(F ∩ C) = 12
n(C ∩ H ∩ F) = 8
n(C ∪ H ∪ F) = n(C) + (H) + n(F) – n(C ∩ H) – n(H ∩ F) – n(F ∩ C) + n(C ∩ H ∩ F)
Hence, n(C ∪ H ∪ F) = (21 + 26 + 29) – (14 + 15 + 12) + 8 = 43

61)
 63)

64)

65)

x+y+z=0
∴ x3 + y3 + z3 = 3xyz
x3 + y3 + z3 – 2xyz = xyz
∴ x3 + y3 + z3 – 2xyz

66)

67)

68) N = 376a456b

for divisiblity by 5 b
case I b = 0
For divisible by 3
31 + a
a = {2, 5, 8}
case II b = 5
For divisible by 3
36 + a
a = {0, 3, 6, 9}
Greatest value of a is 9

69)

f(x) = x100 = (x2 – 3x + 2) · Q(x) + (ax – b)

f(x) = (x – 2) (x – 1) · Q(x) + (ax – b)
f(1) = a – b
a – b = 1100 = 1

72)

∵
⇒ 7x + 7y = xy
⇒ xy – 7x – 7y = 0
⇒ xy – 7x – 7y + 49 = 49
⇒ (x – 7)(y – 7) = 49

73) P(x) = (x – 3) (x – 5) Q(x) + ax + b

P(3) = 3a + b = 5 ...(1)
P(5) = 5a + b = 3 ...(2)
from (1) & (2)
a = –1, b = 8
r(x) = –x + 8

r(1) = 7 ⇒

74)

4y + 5x = xy
xy – 5x – 4y = 0
(x – 4) (y – 5) = 20
Now 20 can be split in following ways
1 × 20 ⇒ (x, y) = (5, 25)
20 × 1 ⇒ (x, y) = (24, 6)
4 × 5 ⇒ (x, y) = (8, 10)
5 × 4 ⇒ (x, y) = (9, 9)
10 × 2 ⇒ (x, y) = (14, 7)
2 × 10 ⇒ (x, y) = (6, 15)
Hence, total number of possible ordered pair of positive integer (x, y) is 6.

75)

A={5, 10}, B=(5, 10), c =(5, 10]

D=[5, 10), E=[5, 10]
n(A)=2
In B there is infinite number of elements.
Same is true for C, D and E.
So all four are incorrect.