LESSON-2 11.

Radius of Bohr’s orbit of hydrogen atom is-

Structure of atom (A) 0.241 A0 (B) 0.48 A0 (C) 0.529 A0 (D) 1.06 A0
1. The charge to mass ratio of electron is- 12. Energy associated with third Bohr orbit of
(A) 1.6022 x 10-19 C Kg-1 (B) 1.925 x 1012 C Kg-1 hydrogen is-
(C) 1.758 x 1011 C Kg-1 (D) 1.869 x 1013 C Kg-1 (A) -2.18 x 10-18 J (B) -0.342 x 10-19 J
2. The ratio of mass of an electron to that of the (C) – 0.726 x 10-18 J (D) -2.42 x 10-19 J
mass of hydrogen atom is- 13. Which of the following transition in hydrogen
(A) 1:3871 (B) 1:1837 (C) 1:1296 (D) 1:3781 atom will give rise to the least energetic
3. Isotones have- photon-
(A) Same number of protons (A) n=6 to n= 5 (B) n=5 to n= 3
(B)Same number of electrons (C) n=6 to n=1 (D) n=5 to n= 4
(C) Same number of neutrons 14. Wavelength associated with an electron
(D) None of the above moving with velocity of 1010 ms-1 is-
4. Which among the following is wrongly (A) 6.62 x 10-10 m (B) 7.27 x 10-14 m
matched- (C) 3.69 x 10-12 m (D) 4.92 x 10-11 m
(A) UV rays- Ozone layer absorbs 15. Possible values of magnetic quantum number
(B) Visible radiations – 400 - 750 nm wavelength for p- orbital are-
(C) IR radiations- Microwave oven (A) 0 (B) -1,0,+1 (C) -2,-1,0,+1,+2 (D) None
(D) Microwaves- Heating effect 16. The notation of orbital with n=5 & l=3 is
5. Correct sequence of frequency of the (A) 2p (B) 5s (C) 5f (D) 3d
electromagnetic radiations in electromagnetic 17. Shape of an orbital is given by-
spectrum is- (A) Principal quantum number
(A) X- rays> UV rays>Micro waves> Radio waves (B) Spin quantum number
(B) X- rays< UV rays<Micro waves< Radio waves (C) Magnetic quantum number
(C) Micro waves> Radio waves> X- rays> UV rays (D) Azimuthal quantum number
(D) UV rays>Micro waves> Radio waves> X- rays 18. Orientation of orbital is given by-
6. Kinetic energy of photoelectron depends upon- (A) Principal quantum number
(A)Intensity of striking light (B) Spin quantum number
(B) Number of photons striking (C) Magnetic quantum number
(C) Number of photoelectrons ejected (D) Azimuthal quantum number
(D) Frequency of striking light 19. For n= 4 , which one of the following values of
7. The value of n1 for Paschen series of hydrogen l is not possible-
spectrum is- (A) 1 (B) 2 (C) 3 (D) 4
(A) 1 (B) 2 (C) 3 (D) 4 20. Which among the following is wrongly
8. Observe the following and predict the correctly matched-
matched set- (A) s- orbital- Spherical shape
(P) Balmer series- (W) Far IR region (B) p- orbital- Double dumbbell shape
(Q) Lyman series - (X) IR region (C) f- Orbital- Complex shape
(R) Pfund series- (Y) UV region (D) All the above
(S) Brackett Series- (Z) Visible region 21. Number of electrons present in 3 d orbital of
(A) P-W, Q-Y, R-Z, S- X (B) P-Z, Q-Y, R-W, S-X Cu+ is-
(C) P-W, Q-Y, R-X, S- Z (D) P-Y, Q-Z, R-W, S-X (A) 5 (B) 10 (C) 2 (D) 4
9. Bohr’s theory is not applicable to- 22. The maximum number of electrons occupy in
(A) He+ (B) Li2+ (C) Be+ (D) H dx2-y2 orbital is-
10. Number of spectral lines can be seen when (A) 5 (B) 1 (C) 10 (D) 2
electron jump from n2= 5 to n1 = 1 :- 23. The number of unpaired electrons present in
(A) 5 (B) 2 (C) 3 (D) 4 Mg atom is-
(A) 0 (B) 2 (C) 1 (D) 12 (A) Energy is released (B) Energy is absorbed
24. The correct sequence of energy of orbitals of (C) No change in energy (D) It radiates energy
multi electron species is- 36. Which transition of Li2+ is associated with
(A) 4p < 3d < 4s (B) 4s < 3d < 4p same energy change as n= 6 to n= 4 transition
(C) 4s < 4p < 3d (D) 3d< 4s < 4p in He+
25. The maximum number of unpaired electrons (A) n=3 to n= 1 (B) n=8 to n= 6
present in px orbital is- (C) n= 9 to n= 6 (D) n=2 to n= 1
(A) 0 (B) 2 (C) 1 (D) 3 37. Zeeman effect refers to the-
26. The ion which is isoelectronic with CO is- (A) Splitting of spectral lines in magnetic field.
(A) CN- (B) N2+ (C) O2- (D) N2- (B) Splitting of spectral lines in electric field.
27. Which of the following has maximum number (C) Emission of electrons from metal by striking
of unpaired ‘d’ electrons- of light.
(A) N3+ (B) Fe2+ (C) Zn+ (D) Cu+ (D) Random scattering of α- particles by gold foil.
28. The frequency of a wave is 6 x 1015 s-1 . Its 38. Assuming velocity to be same , the
wave number would be- wavelength associated with which of the
(A) 105 cm-1 (B) 2 X 107 m-1 (C) 2 X 107 cm-1 (D)All particles would be maximum-
29. The number of photons of light of wavelength (A) Electron(B) Proton (C) Neutron (D) α-particle
7000 A0 equivalent to 1 J are 39. If the uncertainty in the position of electron is
(A) -3.52 x 10-18 (B) 3.52 x 1018 zero, the uncertainty in its momentum would
(C) 50000 (D) 1000000 be-
30. The threshold energy is given as E0 and (A) Zero (B) Greater then h/4π
radiation of energy ‘ E’ falls on metal, then the (C) Less then h/4π (D) Infinite
K.E. is given by- 40. If kinetic energy of a proton is increased by
(A) (E-E0)/2 (B) (E-E0) (C) (E0-E) (D) E/E0 nine times, the de-Broglie wavelength
31. If the threshold wavelength (λ0 ) for ejection associated with it would become-
of electron from metal is 330 nm, ten work (A) 3 times(B) 9 times(C) 1/3 times(D) 1/9 times
function for the photoelectric emission is- 41. The de-Broglie wavelength of an electron
(A) 6 x 10-10 J (B) 1.2 x 10-18 J travelling with 10% of velocity of light is
(C) 3 x 10-19 J (D) 6 x 10-19 J equal to-
32. According to Bohr’s theory angular (A) 242.4 pm(B) 24.2 pm(C) 2.42 pm(D)0.242 pm
momentum of an electron in 6th orbit is- 42. The wavelength associated with a ball of 200g
(A) 2.5 h/π (B) 6 h/π (C) 3 h/π (D) 2.5 π / h and moving with a speed with 5 m/ hour is of
33. If r1 is the radius of first orbit of hydrogen the order of-
atom , then the radii of 2nd , 3rd and 4th orbit in (A) 10-10 m (B) 10-20 m (C) 10-30 m (D) 10-40 m
term of r1 are- 43. The momentum of a particle which has a
(A) r12, r13 , r14 (B) 4 r1, 9 r1, 16 r1 de-Broglie wavelength of 0.1 nm is-
(C) 8 r1 , 27 r1 , 64 r1 (D) 2 r1 , 6 r1 , 8 r1 (A) 3.2 x 10-24 kg m s-1 (B) 4.3 x 10-22 kg m s-1
34. Electronic energy is negative because- (C) 5.3 x 10-23 kg m s-1 (D) 6.62 x 10-24 kg m s-1
(A) Electron has negative charge. 44. The uncertainty in velocity of an electron
(B) Energy is zero near the nucleus and decreases present in the nucleus of diameter 10-15 m
as the distance from nucleus increases. hypothetically should be approximately-
(C) Energy is zero at infinite distance from (A) 10-11 m/s (B) 108 m/s
nucleus and decreases as the electron come (C) 1011 m/s (D) 10 A0/s
towards nucleus. 45. The set of quantum numbers not applicable to
(D) These are interelectronic repulsions. an electron is-
35. An electron jump from lower orbit to higher (A) 1, 1, 1, + ½ (B) 1, 0, 0 , + ½
orbit when- (C) 1, 0 ,0, - ½ (D) 2, 0, 0, + ½
46. Principal and Azimuthal quantum number of (A) 4 (B) 6 (C) 2 (D) 8
electron in 4f orbital are- 59. The number of radial nodes in 4s and 3p
(A) 4 , 2 (B) 4 , 4 (C) 4, 3 (D) 3 , 4 orbitals are respectively-
47. How many 3d electrons can have spin (A) 2 , 0 (B) 3 , 1 (C) 2, 2 (D) 3 , 2
quantum number – ½ ? 60. Which of the following orbital is with four
(A) 5 (B) 7 (C) 8 (D) 10 lobes present on the axis-
48. The correct order of increasing order of (A) dz2 (B) dxy (C) dyz (D) dx2- y2
energy of atomic orbital is- 61. Which of the following statement concerning
(A) 5p < 4f < 6s < 5d (B) 5p <6s < 4f < 5d the four quantum numbers is incorrect-
(C) 4f <5p <6s < 5d (D) 5 p < 5d < 4f < 6s (A) n gives the size of atom
49. Which shell would be the first to have ‘g’ (B) l gives shape of an orbital
sub shell – (C) ml gives energy of electron in orbital
(A) L (B) N (C) M (D) O (D) ms gives direction of spin of electron
50. For which of the following set of quantum 62. The two electrons in K shell will not have the
numbers an electron will have the highest same value of –
energy- (A) Principal quantum number
(A) 3, 2, 1, + ½ (B) 4, 2, -1 , + ½ (B) Azimuthal quantum number
(C) 4, 1 ,0, - ½ (D) 5, 0, 0, + ½ (C) Magnetic quantum number
51. The energies of orbitals of H atom are in the (D) Spin quantum number
order- 63. Which of the following electronic
(A) 3s< 3p< 4s< 3d< 4p (B) 3s< 3p< 3d< 4s< 4p configuration is not possible-
(C) 3s=3p=3d<4s=4p (D) 3s=3p=3d<4s<4p (A) 2p3 (B) 2d5 (C) 4s1 (D) 5f6
52. Which of the following set of quantum 64. Which of the following electronic
numbers is possible- configuration is incorrect-
(A) n= 4, l= 2, ml= -2 , ms = -2 (A) 1s2, 2s2, 2px2, 2py2, 2pz2, 3s2, 3px1
(B) n= 4, l= 4, ml= 0 , ms = - ½ (B) 1s2, 2s1, 2px1, 2py1, 2pz1
(C) n= 4, l= 3, ml= -3 , ms = ½ (C) 1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d5
(D) n= 4, l= 0, ml= 0 , ms = 0 (D) 1s2, 2s2, 2px2, 2py2, 2pz2
53. The maximum number of electrons in an 65. The number of waves in third orbit of H atom
atom which can have n=4 is – are-
(A) 4 (B) 8 (C) 16 (D) 32 (A) 1 (B) 2 (C) 4 (D) 3
54. In the presence of magnetic field , the possible 66. Which one is wrong statement-
number of orientations for an orbital of (A) The total angular momentum of electron in ‘s’
Azimuthal quantum number 3, is- orbital is equal to zero.
(A) 3 (B) 1 (C) 5 (D) 7 (B) An orbital is designated by three quantum
55. For a ‘p’ electron , the orbital angular numbers but an electron in atom is
momentum is- designated by four quantum numbers.
(A) √6 h (B) √2 h (C) h (D) 2 h (C) The value of ml for dz2 is zero.
56. Which of the following electronic level would (D) The electronic configuration of N atom is
allow the hydrogen to absorb a photon but not 1s2 2s2 2px2 2py1 2pz1
emit a photon- ↑↓ ↑↓ ↑ ↑ ↓
(A) 3 s (B) 2p (C) 2s (D) 1s 67. Which one is wrong statement-
57. Which of the following transition will emit (A) De-Broglie wavelength = h/mv
maximum energy in hydrogen atom- (B) Uncertainty principle= ∆E x ∆t ≥ h/4π
(A) 4f →2s (B) 4d →2p (C) 4p →2s (D) All (C) Half filled and full filled orbitals have greater
58. How many electrons can a p- orbital stability due to greater exchange energy,
accommodate ? greater symmetry and more balanced
 arrangement. the electron is more loosely bound in the
(D) The energy of 2s orbital is less then the smallest allowed orbit.
energy of 2p orbital in case of hydrogen like (D) The negative sign in the equation simply
atoms. means that the energy of electron bound to
68. How many electrons can accommodate in the nucleus is lower than it would be if the
the orbital for which n=3 & l= 1- electron were at the infinite distance from the
(A) 2 (B) 6 (C) 10 (D) 14 nucleus.
69. Which of the following pairs of d- orbital will 78. The correct set of four quantum numbers for
have electron density along the axis- the valance electron of rubidium atom (Z=37)
(A) dz2 , dxz (B) dxz, dyz (C) dz2 ,dx2- y2 (D) dxy , dx2- y2 is-
70. Two electrons occupying the same orbital are (A) 5, 0, 0, + ½ (B) 5, 1, 0 , + ½
distinguished by- (C) 5, 1 ,1, + ½ (D) 6, 0, 0, + ½
(A) Principal quantum number 79. Maximum number of electrons in a subshell
(B) Azimuthal quantum number with l=3 & n=4-
(C) Magnetic quantum number (A) 10 (B) 12 (C) 14 (D) 16
(D) Spin quantum number 80. Angular momentum of ‘p’ orbital is equal to-
71. Angular momentum of ‘d’ orbital is equal to- (A) h/√2π (B) √3 h/2π
(A) 0 h (B) √6 h (C) √2 h (D) 2√3 h (C) √3/2 h/ π (D) √6 h/2π
72. What is the maximum number of orbitals that 81. Total number of atomic orbitals in fourth
can be identified with the following quantum energy level of the atom is-
numbers- n=3 , l=1, m=0 (A) 4 (B) 8 (C) 16 (D) 32
(A) 1 (B) 2 (C) 3 (D) 4 82. The energies E1 & E2 of two radiations are 25
73. Calculate the energy in joule corresponding to eV & 50 eV respectively. The relation
light of 45 nm- between their wavelengths i.e. λ1 & λ2 is-
(A) 6.67 x 1015 (B) 6.67 x 1011 (A) λ1 =1/2 λ2 (B) λ1 =λ2 (C) λ1 =2 λ2 (D) λ1 =4 λ2
(C) 4.42 x 10-15 (D) 4.42 x 10-18 83. If n=6 , the correct sequence for filling of
74. Be2+ is isoelctronic with which of the electrons will be-
following ions- (A) ns → np → (n-1)d → (n-2)f
(A) H+ (B) Li+ (C) Na+ (D) Mg2+ (B) ns → (n-2)f → (n-1)d → np
75. What is the maximum numbers of electrons (C) ns → (n-1)d → (n-2)f → np
that can be associated with the following set (D) ns → (n-2)f → np → (n-1)d
of quantum numbers- n=3 , l=1, m=-1 84. According to the Bohr theory , which of the
(A) 6 (B) 4 (C) 2 (D) 10 following transition in the hydrogen atom will
76. The value of Planck’s constant is give rise to the least energy photon-
6.63 x 10-34 Js. The speed of light is 3 x 1017 (A) n=6 to n= 5 (B) n=5 to n= 3
nm s-1. Which value is closest to the (C) n= 6 to n= 1 (D) 5=2 to n= 4
wavelength in nanometer of a quantum of 85. A 0.66 kg ball is moving with a speed of 100
light with frequency of 6 x 1015 s-1 - m/s. The associated wavelength will be-
(A) 25 (B) 50 (C) 75 (D) 10 (A) 6.6 x 10-32 m (B) 6.6 x 10-34 m
77. Base on the equation , (C) 1.0 x 10-35 m (D) 1.0 x 10-35 m
E= - 2.178 x 10-18 J(Z2/n2) certain conclusions 86. Which of the element with the following outer
are written. Which of them is not correct? orbital configuration may exhibit the largest
(A) Larger the value of n, larger is the orbit radius number of oxidation states-
(B) Equation can be used to calculate the change (A) 3d54s1 (B) 3d54s2 (C) 3d24s2 (D) 3d34s2
in energy when the electron changes orbit. 87. Maximum number of electrons in a subshell
(C) For n= 1 , the electron has more negative of an atom is determined by the following-
energy than it does for n=6 which means that (A) 2l+1 (B) 4l-2 (C) 2n2 (D) 4l + 2
88. Which of the following is not permissible
arrangement of electrons in an atom-
(A) n= 5, l= 3, ml= 0 , ms = + ½
(B) n= 3, l= 2, ml= -3 , ms = - ½
(C) n= 3, l= 2, ml= -2 , ms = ½
(D) n= 4, l= 0, ml= 0 , ms = + ½
89. If the uncertainty in position and momentum
are equal then uncertainty in velocity is-
(A) √h/π (B) 1/2m√h/π (C) √h/2π (D) 1/m√h/π

ANSWER KEY
1 C 21 B 41 B 61 C 81 C
2 B 22 D 42 C 62 D 82 C
3 C 23 A 43 D 63 B 83 B
4 D 24 B 44 C 64 B 84 A
5 A 25 C 45 A 65 D 85 C
6 D 26 A 46 C 66 D 86 B
7 C 27 B 47 A 67 B 87 D
8 B 28 B 48 B 68 A 88 B
9 C 29 B 49 D 69 C 89 B
10 A 30 B 50 B 70 D
11 C 31 D 51 C 71 B
12 D 32 C 52 C 72 A
13 A 33 B 53 D 73 D
14 B 34 C 54 D 74 B
15 B 35 B 55 B 75 C
16 C 36 C 56 D 76 B
17 D 37 A 57 D 77 C
18 C 38 A 58 C 78 A
19 D 39 D 59 B 79 C
20 B 40 C 60 D 80 A