29-06-2025

1001CJA106216250108 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A direct current following through the winding of a long cylindrical solenoid of radius R produces
in it a uniform magnetic field. An electron flies into the solenoid along the radius between the turns
(at right angles to the solenoid axis) at velocity v. After a certain time, the electron deflected by the
magnetic field leaves the solenoid. Then the time during which the electron remains inside the

solenoid. [n is number of turns per unit length] is

(A)

(B)

(C)

(D) None of these

2) Capacitor A has capacitance 3µF and rated voltage 40 V and capacitor B has 6µF capacitance and
rated voltage 20V. Choose the correct statement for the different combination of A & B :-

(A) If both are connected in parallel combination with 30 V battery then A will burst out
If both are connected in series combination with 40 V battery then B will work at its rated
(B)
capacity
If both are connected in series combination with 60 V battery then both will work at their rated
(C)
capacity
(D) If both are connected in parallel combination with 60 V battery then only B will burst out

3) Two co-axial conducting cylinders of same length ℓ with radii and 2 are kept, as shown in
Fig. 1. The charge on the inner cylinder is and the outer cylinder is grounded. The annular region
between the cylinders is filled with a material of dielectric constant κ = 5. Consider an imaginary
plane of the same length ℓ at a distance R from the common axis of the cylinders. This plane is
parallel to the axis of the cylinders. The cross-sectional view of this arrangement is shown in Fig. 2.
Ignoring edge effects, the flux of the electric field through the plane is (∈0 is the permittivity of free
space) :

(A)

(B)

(C)

(D)

4) The equation of state for a gas is given by where n is the number of moles
and is a positive constant. The initial temperature and pressure of one mole of the gas contained in
a cylinder are T0 and P0 respectively. The work done by the gas when its temperature doubles
isobarically will be :

(A)

(B)

(C)
(D)

SECTION-I (ii)

1) A uniform conducting rectangular loop of sides , b and mass m carrying current i is hanging
horizontally with the help of two vertical strings. There exists a uniform horizontal magnetic field B
which is parallel to the longer side of loop. Choose the CORRECT option(s)
(A)
The value of

(B)
The value of

(C)
The value of
(D) The value of T1 < value of T2

2) A uniform circular loop of mass 'm' and radius R is lying in space where a uniform magnetic field

. The loop carries constant current I in clockwise direction and lies in a gravity free
region at rest in xy–plane with its centre at origin. Then choose the CORRECT statement(s) :-

(A)
The initial angular acceleration of the loop has magnitude

(B)
The initial angular acceleration of the loop has magnitude

(C)
The unit vector in the direction of initial angular acceleration is

(D)
The initial acceleration of the point with coordinate is zero

3) The cross-sectional area and length of cylindrical conductor are A and respectively. The specific

conductivity varies as where x is the distance along the axis of the cylinder from one of
its ends. A potential difference V0 is applied across the cylinder. Choose the correct statement(s)

(A)
The resistance of the system along the cylindrical axis is .
(B) The current density is constant through out the length of the cylinder.
 The electric field E(x) at each point in the cylinder is
(C)

The electric field E(x) at each point in the cylinder is

(D)

4) An ideal gas is taken from state A (pressure P, volume V) to the state B (pressure P/2, volume 2V)
along a straight line path in P-V diagram. Select the correct statements from the following.

The work done by the gas in the process A to B exceeds the work that would be done by it if the
(A)
system were taken from A to B along an isotherm
(B) In T-V diagram, the path AB becomes a part of a parabola
(C) In P-T diagram, path AB becomes a part of a hyperbola
In going from A to B, the temperature T of the gas first increases to a maximum value and then
(D)
decreases

SECTION-II

1) Find the potential difference across point A and B in the circuit shown in figure.

2) A non-uniform magnetic field is present in region of space in between y = 0 &

y = d. The lines are shown in the diagram. A particle of mass 'm' and positive charge q is moving
from origin with an initial velocity . Velocity is sufficient for the particle to cross the region of
magnetic field. If x-component of velocity of particle when it leaves the magnetic field is

, find α.

3) The following figure shows a circuit diagram of an ammeter of three different ranges. The
specification of the ammeter is

The resistance of the galvanometer coil is 99 Ω. The range of the galvanometer is 10 mA. Find the

4) If at the input circuit (Figure) a voltage U1 = 100 V, is applied the potential difference at the
output U2 = 40 V. If at the output circuit a voltage U3 = 60 V is applied, the potential difference at
the input will be U4 = 15 V. resistor R2 = 60 ohms. Find electrical resistance of resistors R1 and R3 (in

Ohm) and fill .

5) Two large spherical object of charge Q each (uniformly distributed) are fixed as shown in figure. A
small point charge –q having mass m is projected from point A heading towards centre C2 of second
sphere. The minimum velocity of point mass so that it can reach upto second object at point B is

then calculate n. ​

6) Two moles of monatomic ideal gas is taken through a cyclic process as shown. Process CA follows

PT = constant. If the efficiency of cycle is , then find the value of x2.

7) A freezer with a coefficient of performance 30% that of a Carnot refrigerator keeps the inside
temperature at −23oC in a 27oC room. 3 kg of water at 20oC are placed in the freezer. Time taken by
water to cool upto 0oC is X minutes, if the freezer's compressor does work at the rate of 200 W while
the water is freezing value of X is : (Specific heat of water = 4200 J/kg/°C) BY YP Sir

8) Consider two convex lens with focal length fa and fb respectively. If placed appropriately, a small
object perpendicular to the optic axis can create an inverted image, the size and position of which
matches the size and position of object as shown in the figure. The distance between the lens is d

and distance between the object and the left lens is u. The ratio is (Take : fa = 1 cm, fb = 4 cm)

PART-2 : CHEMISTRY

SECTION-I (i)

1) An element "A" lies in VIII group of Mendeleev's periodic table consisting of exactly 29 electrons
having ℓ = 2.
A forms two compounds ;
Compound I ⇒ ACl2.3NH3
Compound II ⇒ ABr4.3NH3
Which of the following is INCORRECT regarding "A" & its compounds?

(A) Compound I is square planar and compound II is octahedral.

2+
(B) [A(pn)2] can be resolved in "d" & "ℓ" form.
Number of ions that undergo precipitation on treatment with excess AgNO3 will be greater for I
(C)
as compared to II.
(D) Compound II is low spin octahedral complex salt.

2) An ideal gas is subjected to two different reversible expansion

processes and from same initial state to same final volume. Which of the following statements is
correct regarding the two process
(A) Work done in second process is more as compared to first process
(B) Magnitude of work done can be compared only by knowing values of k1 and k2
(C) Heat capacity of gas for the two process is same
(D) Final state for the two processes will be same

3) For a certain reaction of order ‘n’, the time for half change t1/2 is given by t1/2 = ,
where k is the rate constant and C0 is the initial concentration. The value of n is

(A) 1
(B) 2
(C) 1.5
(D) 0.5

4)
Total number of stereoisomers of product (B) will be:

(A) 2
(B) 3
(C) 4
(D) 5

SECTION-I (ii)

1) Consider reaction of the following covalent compounds with water at ordinary condition.
SO2Cl2 , NCl3 , PCl3 , CCl4 , SF6 , IF7 , NF3
Select INCORRECT information regarding above specie(s).

(A) Only two species are not hydrolysed.

(B) Only two species gives diprotic oxyacid of central atom on hydrolysis.
(C) Only in two species oxyacid of central atom is form as a product.
(D) Only one specie gives a product which show corrosion of glass.

2)

One mole of an ideal triatomic gas undergoes expansion process adiabatically from same initial state
up to same final volume by two different processes reversibly and irreversibly. Then incorrect
option(s) is/are :

(A) Final temperature of gas will be more if process is carried out reversibly
(B) Magnitude of work involved during the process will be more if process is carried out reversibly
(C) Magnitude of change in internal energy of gas will be less if process is carried out reversibly
(D) Magnitude of change in enthalpy of gas will be less if process is carried out reversibly
3)
Which of the following product can be obtained as major product(s) in above reaction?

(A)

(B)

(C)

(D)

4) In which of the following reactions product will be aldehyde?

(A)

(B)

(C)

(D)

SECTION-II

1) When one electron is added , it must be entered in Gerade molecular orbitals and after adding
that one electron , total electron in ungerade molecular orbitals is 8, then count the number of
species from N2 , O2 , F2 & C2 which satisfied above given condition.

2) Experimental enthalpy of hydration of Cr2+ is –460 k cal mol–1. In the absence of crystal field
splitting the value of enthalpy of hydration of Cr2+ is –436 k cal mol–1.
(Use 1k cal mol–1 = 350 cm–1)
Find the value of for [Cr(H2O)6]2+ in cm–1 :

3) Given that :
MnO2 + 4HCl → MnCl2 + Cl2 + 2H2O ........ (1)
2KMnO4 + 16HCl → 2KCl + 2MnCl2 + 8H2O + 5Cl2 ........ (2)

If x and y are the n-factors of HCl in reactions (1) and (2) respectively, then the value of 5 × is.

4) A beaker containing 18g of glucose in 100g water and another containing 18g of urea in 100g
water are placed under a bell jar and air is removed. After a course of time when equilibrium
reaches, how much water (in gram) will be transferred from one beaker to the other ? (Divide the
value by 10 and report answer as nearest integer).

5) When 1 mole of A react with mole of B2, A(g) + B2(g) → AB(g) 100 kcal heat is liberated.
When 1 mole of A reacted with 2 mole of B2, A(g) + 2B2(g) → AB4(g) 200 kcal heat is liberated.
When 1 mole of A completely reacted with excess of B2 to form AB(g) and AB4(g), 140 kcal heat is
liberated. Calculate the moles of B2(g) used.

6) CH3CH2CH2–COOH
Number of sp2 carbon atoms present in product "P" is :

7) Number of hydrogen atom in product 'P' is :

8) Consider the following complex species :-

[Mg(EDTA)]–2 , [Co(ox)3]–3 , [Cr(en)2Cl2]+1 , [Zn(gly)2] , [CoF3(H2O)3] , [Ni(CO)4] , [PtCl2Br2]–2 , [Pd(gly)2]
, [Co(NH3)4Cl2]+1
If X = number of complex species showing geometrical isomerism
Y = number of complex species showing optical isomerism
Z = number of complex species showing only optical isomerism
then find the value of (X + Y – Z).

PART-3 : MATHEMATICS

SECTION-I (i)

1) For the system of equations

Which of following is true?

(A) there are infinite number of real solution

(B) there is unique solution with x, y, z ∈ Q
(C) there are exactly two solution with x, y, z ∈ Q
(D) there is no real solution

2) Let f(x) = , then value of expression

is (where [.] denotes the greatest integer function)

(A) 8
(B) –8
(C) 9
(D) –9

3) Let f(x + y) = f(x) + f(y) + |x|y + xy2 , x, y ∈ R and f' (0) = 0 then which of the following is true ?

(A) f(x) is twice differentiable at x = 0

area bounded by f(x), x = 1, y = 0 is
(B)

(C) f'(x) is continuous x∈R

(D) f'(x) is differentiable x∈R

4) Area bounded by the curve and x-axis between

is equal to (where [.] denote the greatest integer function and {.} denote
fractional part function)

(A)

(B) 1
(C) 2
(D) 4

SECTION-I (ii)

1) A chord of negative slope from the point is drawn to the ellipse x2 + 4y2 = 16 . This
chord intersects the ellipse at A and B (O is the origin).

(A) The maximum area of ΔAOB is 4

(B) The maximum area of ΔAOB is 8

(C)
If the area of ΔAOB is maximum, then the slope of line AB is

(D)
If the area of ΔAOB is maximum, then the slope of line AB is

2) Let g : R → {4} be a function given by g(x) = x3(f'(t) – 2) + x2 f"(t) + 4x(f(0) + 6) + 4 and h(x) is
defined as

Then choose correct statements

(A) h(3) = 15
(B) range of h(x) is [0,56]
(C) h(x) is not continuous at x = 4
(D) h(x) is non-differentiable at x = 6

3) Let f : R → [–1, 2], is onto function and f′(d) = f′(e) = 0. Then which of the
following is/are true ?

(A) eccentricity of curve can be

(B)
eccentricity of curve can be

(C) eccentricity of curve can be

(D)
eccentricity of curve can be

4) Let f and h are two real valued continuous function and let and f(x) = x3 + x +

sin 2πx + 2 and the value of is 'k', then the value of '4k' is

(A) 11
(B) 10
(C) 13
(D) 9

SECTION-II

1) Consider, , where t, x ∈ R.

Let and then |I1 – I2|

[Note: min(g (t)) denotes minimum value of g(t) for t ∈ R ]

2) Let , then the value of is equal to _____

3) Let f(x) = a0 + a1x + a2x2 + a3x3 + a4x4 + a5x5 be a polynomial of degree 5 which increases in the

interval (–∞, 1) and (3, ∞) and decreases in the interval (1, 3). Given that f(0) = 2, f(1) = and f′(2)
= 0, then a5 is equal to :-

4) Let tangents drawn to the parabola at A(1, 2) and B(5, 8) intersect at (–1, 8), then slope of

directrix is (where gcd(a, b) = 1), then (a + b) is

5) A line through the origin meets the circle x2 + y2 = a2 at P and the hyperbola x2 – y2 = a2 at Q. Then
locus of the point of intersections of tangent to the circle at P with the tangent at Q to the hyperbola
is the curve (a4 + 4y4)x2 = aK then K is equal to

6) A1 and A2 are the vertices of the conic C1 : 4(x – 3)2 + 9(y – 2)2 – 36 = 0 and point P is moving in the
plane such that |PA1 – PA2| = , then the locus of P is another conic C2. If D1 denotes the distance
between foci of conic C2. D2 denotes the product of perpendicular distance from the points A1,A2
upon any tangent drawn to the conic C2 and D3 denotes length of tangent drawn from any point on

auxiliary circle of conic C1 to the auxiliary circle of the conic C2, then is equal to.

7) Let f(x) = x3 + 3x2 – 6x + 11, g(x) = ln|x|. If A = f(g'(–1)), B = g(f'(–1), C = ,D=

evaluated at t = 3 and A(B + C) – D = kln(3) then the value of k is _______

8) Let f(x) be a continuous function defined from [0,2] → R and satisfying the equation

then the value of 2f(1) is equal to

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. A C C A

SECTION-I (ii)

Q. 5 6 7 8
A. B,C,D A,C,D A,B,D B,C

SECTION-II

Q. 9 10 11 12 13 14 15 16
A. 10.00 1.50 4.00 6.00 8.00 49.00 14.00 1.00

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 17 18 19 20
A. C A D B

SECTION-I (ii)

Q. 21 22 23 24
A. A,C A,C,D A,B B,C

SECTION-II

Q. 25 26 27 28 29 30 31 32
A. 3.00 1400.00 4.00 5.00 1.10 6.00 11.00 6.00

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 33 34 35 36
A. B D C C

SECTION-I (ii)

Q. 37 38 39 40
A. A,D A,B,D A,B,C A
 SECTION-II

Q. 41 42 43 44 45 46 47 48
A. 0.00 3.00 0.20 7.00 6.00 36.00 7.00 1.00
 SOLUTIONS

PART-1 : PHYSICS

1)

2)
Ceq = 2µF
q = 60× 2 = 120 µC

3)
Here we are assuming that "ℓ" is very large just for the sake of symmetry. Outside cylinder will
have zero electric field inside, so the flux generated on the plate will be due to inner cylinder
only in sections AB and CD, as section be will be at that place where electric field is zero.

flux through element will be

dy. ℓ. cos θ…….(1)

from figure we can say that

⇒ r = Rsecθ

tanθ = ⇒ y = R tanθ
⇒ dy = Rsec2θdθ

dϕ = 2kλℓ dq

ϕAB = 2kλℓ

4)

5) Taking torque about R.H. side of loop

6)

&

7)

8)
Area under isotherm < Area under line AB.
Wisothermal < WAB

9)

Use symmetry analysis

10)

;
 ;

11)

For connection between OA

....(i)
For connection between OB,

....(ii)
For connection between OB,

....(iii)
Solving (i), (ii) & (iii)

, &

12)
R3 = 40 Ω

13)

Since Wnon-constant = 0 ⇒ Energy is conserved

Once the charge –q passes the point of maximum potential it will reach the other sphere.
∴ From energy-conservation

14)

For process AB
TA = 300 K, TB = 600 K
W = nRΔT = nR(TB – TA) = 300 nR = 600 R

Q = nCpΔT = 2 × R (300) = 1500 R

For process BC

= nRTℓn2 = 1200 Rℓn2

Q = W = 1200 Rℓn2
For process CA

Q = nCvΔT + W

= –900 R – 1200R = –2100R

 15) η = 1

β = 0.3 x βCarnot = 1.5

16)

....(1)

....(2)
Using (1) and (2) we get

PART-2 : CHEMISTRY

17)

A is Platinum (Z = 78)

18)

19)

1–n= ⇒ n=
20)
Stereoisomers of (B)

21)

NF3 , SF6 , CCl4 = No hydrolysis

22)

Wrev < Wirrev

|Wrev| > |Wirrev|

23)

24)

Second reaction is Wacker process. It is environment friendly method to prepare aldehyde.

25)
g = gerade
u = ungerade

26) CFSE = –460 –(–436) = –24 k cal mol–1 = –24 × 350 cm–1
Cr2+ = 3d4
–0.6Δ0 = –24 × 350 ⇒ Δ0 = 14000 cm–1
 27) x = , y =
1 × 2 = 4 × nf
2 × 5 = 16 × nf

28) Water in the form of vapour will be transferred from solution of lower osmotic pressure to
that of higher one until both become equal. Let w g of water be transferred from glucose
solution to urea solution (higher concentration)

⇒ w = 50 g.

29) Suppose 1 mole of A produced x mole of AB(g) and (1 – x) mole of AB4

140 = 100x + 200(1 – x)
x = 0.6

Moles of B2(g) used = × 0.6 + 2 × (1 – 0.6) = 1.10

30)

P is benzene (C6H6)

31)

P is 4-ethylaniline

32) The value of (X + Y – Z) = 6

X=5
Y=4
Z=3

PART-3 : MATHEMATICS

33)

For x > 1, let

The three equation are f(x) = y2, f(y) = z2 and f(z) = x2
∴ x3 – x2 = x2(x – 1) is increasing, f is an increasing function
If, say x > y then y < z and z < x, yielding a contradiction
Thus we can only have that x = y = z and so log10 (x3 – x2) = log5x2
Let 2t = log5 x2 ⇒ t >0, x2 = 52t ⇒ x = 5t
⇒ 53t – 52t = 102t ⇒ 5t – 1 = 4t ⇒ 5t – 4t = 1

∵ 5t – 4t = 4t is an increasing function of t
⇒ This equation has unique solution i.e. t = 1, x = y = z = 5

34) let f–1 =t

n
x = (f(t))
dx = n f(t)n–1 f'(y)

nt dt

=–9

35) for x ≥ 0
f(x+y) = f(x) + f(y) + xy + xy2
diff. w.r.t y keeping × constant
f'(x+y) = f'(y) + x + 2 × y
put y = 0
f'(x) = 0 + × + 0 ⇒ f'(x) = x

f(x) =
Now for x < 0 ⇒ f'(x) = –x

f(x) will be

so f(x) =

36)

=
37)
Let A(α) ≡ (4cosα, 2sinα)
B(β) ≡ (4cosβ, 2sinβ)

Area of ΔOAB
= 4|sin(β – α)|

Maximum value of area = 4 at ...(1)

eqn of chord AB

it passes through

put (from (1))

Slope of AB

38)
g(x) = 4
x3(f'(t) – 2) + x2f"(t) + 4x(f(0) + 6) + 4 = 4 ; ∀ x
⇒ x3(f'(t) –2) + x2 f"(t) + 4x(f(0) + 6) = 0 ∀ x
Hence f'(t) – 2 = 0 and f"(t) = 0
and f(0) + 6 = 0 ⇒ f(0) = –6
So, f(t) = 2t – 6

39) ∵ Domain of function is real number so a = 0

Now
⇒ (y – 1)x2 + (by – 9b)x + (33y – 17) = 0
∵ x ∈ R so D ≥ 0
⇒ (by – 9b)2 – (y – 1)(33y – 17) ≥ 0
∴ b = 2 and –2
∴ For b = 2 ⇒ d = –5, e = 7
For b = –2 ⇒ d = –7, e = 5

40) Let
By parts,

f–1(4) = 1
f–1(2) = 0
We know,

Now,

= =

So,
Now,

41)
= 4 – |sinx|

∴
I2 = 2π – 1

I2 = 2π – 1
∴ |I1 – I2| = 0

42) can be written as

or
then

Replace

∵
Taking

= and when it t → 0 ⇒ k → 0
43)

f′(x) = k(x –1)(x –3) (x –2)2 and k > 0

⇒ f(x) = k

=k [x4 + 16x2 – 8x3 + 7(x2 – 4x) + 12] dx

=k

∵ f(0) = 2 ⇒ c = 2 ∴ f(1) =

⇒ =

⇒ =k× ⇒ k =1 ∴ a5 =

44) Q = mid-point of AB = (3, 5),

let P ≡ (–1, 8), m(PQ) =

Slope of directrix

45)
let slope of line OP is m

∴ slope of tangent PR = –

∴ eqn of PR ≡
........(1)

slope of OP = m =
& slope of tangent at

∴ eqn of QR ≡ y =
⇒ x-my =
& let R ≡ (h, k)
∴ h + mk = are h – mk =
⇒ (h + mK)2 = a2 (1 + m2) and (h – mK)2 = a2(1 – m2)
⇒ m2 (K2 – a2) + 2mhK + h2 – a2 = 0
& m2(K2 + a2) – 2mhK + h2 – a2 = 0
after eliminating m from these two equation and we get the required locus

46)
∴ A1 = (6,2), A2 = (0,2)
∴ |PA1 – PA2| =
Clearly locus of P is hyperbola for which

A1A2 = 2ae = 6 and 2a =

⇒e=
∴ Locus of P is rectangular hyperbola
Equation of conic

C2 : (x – 3)2 – (y – 2)2 =
Now, D1 = 2ae = 6

D2 = b2 =

∴
47) A = f(–1) = 19
B = g(–9) = 2 ln 3

C=

D=
A(B + C) – D = 7 ln 3 ⇒ k = 7

48)