SST Book Compilation - Science Category - Recompilation
SST Book Compilation - Science Category - Recompilation
MUNEER JUNEJO
Note:
Text books means that all content is compiled from Sindh Text Book Board’s Books (Syllabus) |
Class 6th to Class 10th | Prepared according to SELD GoS Policy.
1
A meaningful combination of words is called Sentence.
1. He and she sat on a wall.
BASICS OF GRAMMAR
Grammar is the science of language.
It contains rules for writing, reading and speaking the PARTS OF SPEECH
language correctly. There are eight (8) parts/kinds of speech.
The word Grammar comes from Latin and Greek, NOUN
(Gram = Write) which means writing. Noun is a naming word. A noun is a word used as the
ALPHABET name of a person, place, or thing.
The letters of any language are called alphabet. Functions of Noun
All the letters of any language together make the Noun works in sentence as a noun and an object.
alphabets. Example:
There are 26 letters in the alphabet of English 1. Rahim likes Dua.
language, i.e. A, B, C……..Z. Here in this sentence Rahim is noun and Dua is an
LETTER Object.
All the alphabetical symbols of any language are More examples
called letter. 2. Akbar was a great King.
3. Karachi is in Pakistan.
A letter is a certain sound, so it stands like a mark i.e.
4. Abubakar is playing.
A, C, H, D etc.
5. Zakaullah and Karim are studying.
There are two kinds of letter i.e. Vowel and
6. Book is on the table.
Consonant.
Akbar, king, Karachi, Pakistan, Abubakar,
Vowels: (Vocalis = Sounding) A letter which can be
Zakaullah, Karim, Book, and Table are the nouns.
pronounced itself.
PRONOUN
There are five vowels i.e. AEIOU (Y is semi/half
All those words which are used at the place of noun
vowel).
is called Pronoun.
Consonants: (Conso+nas = Sounding with) A letter
Pronoun is a word used instead of a noun; as,
which can be sounded with the help of vowel. All the
1. Ali likes Dua, because she is handsome.
letters of English alphabet except vowels are
2. Dua likes him too.
consonants.
3. He plays with her.
21 are the consonants.
4. She dances with him.
WORD
5. Sikandar is absent, because he is out of city.
A meaningful combination of letters is called word
She, him, he, her, are the pronouns
i.e. Cow, Cat, Take, Stand, Go, Come etc.
“Her” and “him” are the objective cases of “he” and
PHRASE
“she”.
A group of words, which makes sense, but not
ADJECTIVE
complete sense, is called a Phrase.
Expresses the quality of noun and pronoun.
In the following sentences, the group of underlined
An Adjective is a word used to add something to the
words are phrases
meaning of noun and pronoun; as,
1. The sun rises in the east.
1. Dua is beautiful.
2. It was a sunset of great beauty.
2. Dua is beautiful mother.
3. The tops of mountains were covered with snow
3. She is a good girl.
4. Show me how to do it.
4. Rehan is a brave boy.
CLAUSE
5. Sajjad is an intelligent.
Group of words which forms part of a sentence, and
6. There are twenty boys in this class.
contains a subject and a predicate, is called Clause.
Beautiful, good, brave, intelligent, twenty, and this
In the following sentences, group of underlined
are the adjectives.
words are clauses.
VERB
1. He has a chain of gold.
Action or doing word. A word used to express an
2. He has a chain which is made of gold.
action or state of subject.
Subject:
1. The girl wrote a letter to her cousin.
The part of sentence which names the person or
2. Karachi is a big city.
thing we are talking about, that is doing an action,
3. I am writing an essay.
focus of the sentence, is called Subject.
4. Iron and Copper are useful metals.
Predicate:
5. He was singing a song.
The part of sentence which tells something about
6. Dua and Simran were going to college.
the subject, contains the action, is called Predicate.
“Is, am, are, was, were” in above sentences are the
1. Mr. Zakaullah took a walk. (Mr. Zakaullah is
stative verbs, also called helping verbs when they
subject and took a walk is Predicate)
come before the main verb, showing state of noun
2. Dog is barking. (Dog is subject and is barking is
and pronoun.
predicate)
SENTENCE
2
“Wrote, writing, singing, and going” in above A Common noun is a name which is common to
sentences are action verbs, also called main verb, any and every person, place and thing of same
showing action of noun and pronoun. kind.
ADVERB So it denotes a name which is common to all the
Adverb is the word which qualifies/add something to things of same class or kind.
the meaning of an adjective, verb, and another Examples:
adverb in same sentence. Names of Common Persons:
1. He speaks fluently. (Fluently is adverb of manner) Father, Friend, Farmer, Doctor, Student, Patient,
2. He speaks quite fluently. (Quite is adverb of Boy, Child, Man etc.
degree) Names of Common Places:
3. He is a very fluent speaker. (Very is adverb of Home, Hospital, Mosque, School, Hotel, Country,
degree) State, Bazar etc.
4. He worked the sum quickly. (Quickly is adverb of Names of Common Things:
manner) Duster, Board, Chair, Table, Book, Newspaper,
5. This flower is very beautiful. (Very is adverb of Mobile, Jug, Light etc.
degree) Names of Common Living Organisms:
6. She pronounced the word quite correctly. (Quite is Horse, Sheep, Camel, Frog, Hen, Zebra, Parrot, Snake
adverb of manner and correctly is adverb of etc.
manner).
PREPOSITION A Common noun begins with capital letter,
Pre+Position. whenever used at the very beginning of a sentence.
Preposition is a word which is placed before noun or A Common Noun in its singular form always carries
pronoun to show its relation to other noun or the Indefinite Article “a” or “an” in the sentence and
pronoun in the same sentence. is written in smallletters when is used in between
1. There is a cow in the garden. the sentence or in the beginning of a sentence.
2. The girl is fond of music Example:
3. A fair little girl sat under a tree. 1 . A cat is running after a rat.
4. Bottle is on the table. 2. I saw an elephant.
“In, of, under, and on” are the prepositions. A Common Noun is used as a Proper Noun when it
CONJUNCTION denotes a particular person.
Con=Together, Junction=Join. Conjunction is the Example:
word which join the two words, phrases or clauses. 1. Our father loved us.
1. Ghani and Ghaffar are cousins. 2. My mother prays for me.
2. Two and two make four. Identification of Common Noun: If the Noun ends with
3. I ran fast, but missed the train. following letters then it is defined as Common Noun.
“And, but” in above sentences are the conjunctions. ar: Beggar, Liar, Scholar, Registrar, Tapedar,
INTERJECTION Mukhtiarkar etc.
A word which expresses some sudden feeling. ary: Diary, Library, Salary, Secretary, Granary, and
1. Hurrah! We have won the game. Dispensary etc.
2. Alas! She is dead. eer: Beer, Deer, Engineer, Volunteer etc.
3. Oh! I am so sorry. er: Brother, Father, Mother, Sister, Teacher,
“Hurrah, Alas, and Oh” in the above sentences are Writer, Driver, Farmer, Player, Gardener, Dancer
interjections. etc.
IDENTIFY THE PARTS OF SPEECH. or: Actor, Author, Tailor, Operator, Sailor, Editor,
1. She is pretty. Adjective Conductor, Governor, Director, Contractor etc.
2. She is pretty good in singing. Adverb of degree ist: Artist, Scientist, Dentist, Dramatist, Novelist,
3. I like this pen. Demonstrative adjective Chemist, Druggist etc.
4. This is a good idea. Demonstrative pronoun ian: Politician, Physician, Magician, Musician,
5. The train had left before I reached the station. Technician etc.
Conjunction 02. PROPER NOUN
6. I have met you before. Adverb of time (qualifies the The word “Proper” is derived from the Latin word
verb “met” it mean “before” qualifies the verb met) “Proprius” which means own.
7. You are sitting before me. Preposition Proper Noun is the name of some particular person,
THE NOUN: KINDS OF NOUN place and an object as his own.
Noun is a naming word. A noun is a word used as the A name which belongs to a particular person, place,
name of a person, place, or thing. and thing is called Proper Noun.
Note: Examples:
The word thing mean is used to mean anything that Names of Persons:
we can think of. Zakaullah, Abid, Sooraj, Lateef, Ganesh, Khan
01. COMMON NOUN: Muhammad, Gotam, Ghos Ali etc.
Name of Places, Cities and Countries:
3
Minar-e-Pakistan, Taj Mehal, Rani Kot, Karachi, which is used instead of a Noun in a
Japan etc. sentence.
Names of Things, Books, Days and Months: Anything which has no any name and used
Rado Watch, Tube Light, Holy Quran, Monday, March as a subject in a sentence is called Pronoun.
etc. Note:
Sometimes Proper Nouns are used as Common Nouns such The repetition of a Noun makes language absurd
as; and leads some serious errors.
1. Iqbal is often called the Shakespeare of Pakistan. It is not necessary that pronoun used instead of a
2. Faisalabad is the Manchester of Pakistan. Noun in a sentence, it is also can be used in
3. Dr.Abdul Qadeer Khan is the Newton of Pakistan. general way in a sentence.
03. COLLECTIVE NOUN 01. PERSONAL PRONOUN
A Collective Noun is the name of a number (or I, we, you, he, she, it and they are called Personal
collection) of persons or things taken together as Pronouns because they stand for the three persons.
one whole. The pronouns which only used for the persons
A name given to collective persons or things taken as called personal pronoun.
one whole is called a Collective Noun. Personal pronoun is further divided into three types
A collective Noun is always written in small letters discussed below:
and seems to be singular but plural in meaning. First Person Pronouns:
Examples: The pronouns I and We, which denote the person
Crowd, Mob, Team, Herd, Army, Fleet, Jury, Family, or persons speaking, are said to be Personal
Nation, Parliament, Committee, Brood, Grove, Flock, Pronouns of the First Person.
Bazar, Assembly, Government, Press, Audience, Examples:
Alliance, Party, Police, People, Library, Faculty,Tribe, 1. I am young.
Troop etc. 2. We are young.
04. ABSTRACT NOUN Second Person Pronouns:
The word “Abstract” is derived from the Latin word The pronoun you, which denotes the person or
“Abstractus” which means drawn away from. persons spoken to, is said to be Personal Pronoun of
An Abstract Noun is the name of a quality, action, the Second Person.
state or condition along with art and science. (You is used in both singular as well as plural)
An Abstract Noun is also defined as the name of Examples:
such things which we cannot see or touch but we 1. You are young.
can only think ofit in our mind. 2. You are going to market.
An Abstract Noun is the name of quality, action, Third Person Pronouns:
state or condition, which does not have any The pronouns He and She and They, which
existence materially so it cannot be perceived by denote the person or persons spoken of, are said
our senses. to be Personal Pronouns of the Third Person.
Examples: It, although it denotes the thing spoken of, is also
Quality: called a Personal Pronoun of the Third Person.
Goodness, Wisdom, Kindness, Whiteness, Examples:
Hardness, Brightness, Greatness, Vice, 1. He is young.
Bravery, Truth,Cruelty etc. 2. She is young.
Action: 3 . They are young.
Movement, Punishment, Growth, Flight, Play, 4. It is young.
Fight, Division, Theft, Pardon etc. Rule 01:
State or Condition: If three singular pronouns of different
Boy hood, Birth, Poverty, Sorrow, Youth, Death, persons are used together in a sentence. The
Health, Wealth etc. normal structure is secondperson + third
Art and Science: person + first person, it’s called 231.
Grammar, Physics, History, Music, Chemistry, Examples:
Medicine etc. 1. You, he and I are going to the market.
An Abstract Noun is formed from Adjective, Verb, and Rule 02:
Common Noun. If three pronouns of different persons are used
1. Kindness from Kind. together in a sentence but the sense of the
2. Honesty from honest. sentence is confess aguilt, crime and flaw etc.
3. Obedience from obey. The structure is first person + second person +
4. Growth from grow. third person, is called 123.
5. Childhood from child. Examples:
2. I, you and he have done this crime.
PRONOUN: KINDS OF PRONOUN Rule 03:
The word which is used to check the In the case of plural or mixture of the subject, 123
repetition of a Noun in a sentence, the word is used.
4
Examples: 04. You hurt yourself.
03. We, you and they are going to the market. 07. EMPHATIC PRONOUN
02. DEMONSTRATIVE PRONOUN An Emphatic pronoun is that which is used to add
Demonstrative pronouns indicate the object that emphasis to the subject of the sentence.
we try to describe or tell you the specific distance They are used to emphasize noun or pronoun.
(near or far) of the objects. Examples:
Examples: Self (My, Your, Him, Her and It)
Near (This = These) Selves (Our, Them and your)
Far (That = Those). 01. He himself opened the window.
01. This is my book. 08. DISTRIBUTIVE PRONOUN
02. These are my books. The pronouns, which refer to the person or things
03. That is your book. one at a time are known as Distributive Pronoun.
04. Those are your books. They are always singular.
03. I N D E F I N I T E P R O N O U N: Examples:
The pronouns, sometimes used in a sentence Neither /Either (Group of two people)
don’t refer to any particular thing or person. Each/None (Group of more than two people) etc.
They are used in a general way,such pronouns 01. Neither of girls was late.
are known as Indefinite Pronoun. 02. Either of you can go.
Examples: 09. RECIPROCAL PRONOUN
All, Anyone, Anybody, Anything, Everyone, Everybody, These Pronouns denote the exchange of action
Everything, Someone, Somebody, Something, No one, between them.
Nobody, Nothing, Some, None etc. These work as compound pronouns and are
01. Nobody can help you in this issue. separated by apreposition.
02. Did you ask anybody to come here? Reciprocal pronouns are used for persons or things
03. Somebody has stolen my watch. what act and react upon one another.
04. INTEROGATIVE PRONOUN Examples:
The pronouns that are used for asking the questions, Each other (Only for two persons).
called Interrogative Pronoun. One another (More than two persons).
Examples: 01. My students competed with each other.
What, Who, Which, Whose, Whom, Why etc. 02. Your friends faced each other.
01. Who is there? 03. You deceived one another.
02. What do you want?
03. Whom did you see? ADJECTIVE
05. RELATIVE PRONOUN
The word Adjective is derived from the Latin word
A Relative pronoun is one which is used to refer to
“Adjectivous” means “Adds to”.
nouns mentioned previously, whether they are
An Adjective is a describing word used to add
people, places, things,animals or ideas.
something to the meaning of a Noun or Pronoun.
Relative pronoun can be used to join two sentences.
An Adjective is a word used to qualify a Noun or
It is used to connect clause or phrase to a noun or
Pronoun by means of its quality, quantity and
pronoun.
number.
Example:
Examples:
01. A man who lost his wallet couldn’t buy his
01. Dua is good girl.
groceries.
02. Almas is an intelligent boy.
Examples:
03. Karachi is a large city.
Who, Whom, That, Which, Whoever, Whomever,
04. Your father is a rich man.
Whichever, Where etc.
05. I have some money.
01. This is a place where we met.
06. They had a red cow.
02. You can choose one person, whomever you like.
07. This is a fat dog.
06. REFLEXIVE PRONOUN
08. They are loyal to their country.
The pronouns, which represent the action performed 09. Your brother is an old man.
by the subject is on the subject itself. 10. There are thirty boys in the class.
They are used as objects of the verb when the action KINDS OF ADJECTIVE
of verb returns to the doer. Adjectives of quality (Descriptive Adjective):
The subject and object are the samepersons in Adjectives, show the kind, quality and the state of
reflexive pronoun. the persons or things.
Examples: Examples:
Self (Singular, added to my, your, her, him and it). Good, Bad, Thin, Thick, Full, Short, Tall, Long, Ugly,
Selves (Plural, added to our, them and your). Beautiful, Kind, Idle, Clever, Lazy, Active, Intelligent, New,
01. I hurt myself. Red, Dark, Honest, Fast, Foolish, Black, Old, Large etc.
02. He hurt himself. 01. Karachi is a large city.
03. They hurt themselves. 02. Aslam is a tall boy.
5
03. That is a thin blanket. These point out such adjectives used with noun to
04. This is a sweet mango. ask the questions.
Adjective o quality answers the questions, of what kind? Examples:
Adjectives of quantity: What, Which, Whose, and Where.
Adjectives, show the quantity of a Noun. These point 1. What color is your hair?
out how much of a thing is meant. 2. Which purse is hers?
Examples: 3. Whose gifts are these?
)نه ڻ.
Little (هئ برابر Adjectives are formed from Nouns, Verbs, and Adjectives.
A little ( ڪجهه،)ڪجهه قدر.
The little ( جيڪا ڪجهه،)جيڪو. VERB
Few ( گهڻو نه، )مشڪل سان. Action or doing word.
A few ()ڪجهه. A word used to express an action or state of subject.
The few (جيڪ ڪجهه ،)ڪجهه قدر.
ي The Verb is derived from Latin “Verbum” means the
Some, Many, Any, Enough, Sufficient, Whole, All, Half,
“Say word”.
Several, A lot of, No, Plenty, Any etc.
A Verb is a word that tells or asserts something
01. I ate some rice.
about a person or thing.
02. He showed much patience.
It is the most important word in a sentence.
03. He has little intelligence.
The word which indicates the action is known as
04. He have no sense.
Verb.
05. There is little milk in the jug.
06. There was a little hope of his recovery. A Verb may tell us; what a person or thing does?
07. The little amount he has, is saved. What is done to a person or thing? What a person
08. I have few biscuits. or thing is?
09. She has a few photos. KINDS OF VERB
10. The few mistakes he made were omitted. Transitive Verb:
Adjectives of number (Numeral Adjectives): Transitive is derived from the Latin “Transitivus”
Adjectives, show the number of persons or things means “That which passes over”.
meant and in what order the same stand. A Verb is said to be used transitively, when it
A) Definite Numeral Adjectives: indicates an action which is exercised directly upon
These adjectives point out some definite some object.
number of a Noun. A verb which requires an object after it to complete
Cardinal (One, Two, Three, Four, Five etc.) its sense is called “Transitive Verb”.
Ordinal (First, Second, Third, Fourth, Fifth etc.) A transitive verb is a verb that denotes an action
B) Indefinite Numeral Adjectives: which passes over from the doer or subject to an
These adjectives do not point out the exact or object.
accurate number of a noun, so these give the Examples:
idea of an indefinite number. 1. The boy kicks the football.
Examples: 2. Aslam kills the snake.
All, Many, Few, Some, Any, Much, More, Several, 3. He cooks rice.
Sundry, Certain, No etc. Intransitive Verb:
C) Distributive Numeral Adjectives: An intransitive verb is a verb that denotes an action
Such Adjectives point out or set apart each one which does not pass over to an object, or which
of the number or the groups. expresses a state or being.
Examples: Examples:
Each, Every, Either, Neither etc. 1. He ran a long distance (Action).
1. Each student did his homework. 2. The baby sleeps (State).
2. Everyone should do ones duty. 3. The boy runs.
3. Either bird will fly. 4. River flows.
4. Neither one is loyal. 5. The Sun shines.
Demonstrative Adjective: 6. He comes daily.
These adjectives point which person or thing 7. The bay cries.
is meant. VOICE
Examples: In grammar voice does not mean sound from the
This, That, These, Those and Such. mouth but it points out the way or manner of
1. This book is mine. expression.
2. That man is lazy. It is the form of verb which shows whether the
3. I like these apples. subject does something or something is done by the
4. Those students must be taught. subject.
5. She hates such things. There are two voices; Active voice and Passive Voice.
Demonstrative adjectives answer the question, which? Active Voice:
Interrogative Adjectives: The verb whose subject is active or when the subject
is doer of some action.
6
The active Voice is so called because its subject acts. 2. This story is well written.
Examples: 3. The child slept soundly.
1. Aslam writes a letter. Adverbs of Degree or Quantity:
2. She will sing the songs. Which show how much, or in what degree or to what
3. Your team has won the match. extent.
Passive Voice: 1. He was too careless.
The verb is in the Passive Voice when something is 2. Is that any better?
done to its subject. 3. These mangoes are almost ripe.
The Passive Voice is so called because the verb is not 4. The sea is very stormy.
active. 5. She sings pretty well.
Here the subject receives an action. 6. You are partly right.
Only a Transitive verb is used in the Passive voice Adverbs of Affirmation or Negation:
because Intransitive verb has no any object. 1. Surely you are mistaken.
Examples: 2. He certainly went.
1. A letter is written by me. 3. I do not know him.
2. A snake was killed by Almas. 4. Adverbs of reason:
3. The songs will be sung by her. 5. He is hence unable to refute the charge.
6. He therefore left the school.
ADVEERB
An Adverb is a word which modifies the meaning of a PREPOSITION
Verb, an Adjective or another Adverb. Preposition is derived from the Latin “Praepositionem”
Adverbs standing at the beginning of sentences which means “I place before”, thus the preposition
sometimes modify the whole sentence, rather than called that which is placed before.
any particular word; as, A preposition is a word which joins a Noun or Pronoun
1. Probably ( )غالئhe is mistaken. to another word and indicates some relation between
2. Possibly it is as you say. the Noun and Pronoun and that word.
3. Evidently ( )واضح طور يتthe figures are incorrect. A preposition is a word that makes the position of
4. Unfortunately no one was present there. different things specially Noun or Pronoun clear in a
5. Luckily he escaped unhurt. sentence, so it is used to show the ways in which other
KINDS OF ADVERB words are connected.
Adverbs of Time: A preposition is a word placed before a Noun or a
1. Which show when. Pronoun to show in what relation the person or thing
2. I have heard this before. denoted by it, stand in regard to something else.
3. We shall now begin to work. Uses of Preposition
4. He comes here daily. To another Noun or Pronoun:
5. I have spoken to him already. The Purse is in the pocket (Noun). He sat beside me
6. He once met me in Karachi. (Pronoun).
7. Mr. Almas formerly lived here. To an Adjective:
8. Wasted time never returns. 1. He was great in war.
9. He called here a few minutes ago. To a Verb:
10. The end soon came. 1. Come with me.
11. I hurt my knee yesterday. To an Adverb of time:
Adverbs of frequency: 1. He will work from now.
1. Which show how often. To a phrase:
2. I have told you twice. 1. He has stolen my purse from under my pillow.
3. He often makes mistakes. To a clause:
4. I have not seen him once. 1. I am interested in what he says.
5. He seldom comes here. When the object is an interrogative pronoun, the
Adverbs of place: Preposition is placed at the end:
1. Which show where. 1. What are they looking at?
2. Stand here. When the object is Relative Pronoun “that”, the
3. Go there. preposition is always placed at the end:
4. The little lamb followed Mary everywhere. 1. It is the picture that you are looking at?
5. He looked up. When the object is Relative Pronoun (Understood) the
6. My brother is out. Preposition comes at the end:
7. Come in. 1. The boy (whom) you spoke of has come.
8. Walk backward. KINDS OF PREPOSITION
Adverbs of manner: There are 5 main kinds of Preposition, discussed
Which show how or in what manner. below in detail.
This adverb clause includes nearly all those Adverbs 01. Simple Preposition:
which are derived from adjectives and end in –ly. Such prepositions contain simple words.
1. Govind reads clearly. Example:
7
At, By, For, From, In, Of, Off, On, Out, Over, Through, Till, To, 04. They aimed at doing well.
Under, Up, With etc. 05. The tiger growled at the farmer.
02. Compound Preposition: It is used to indicate work/occupation:
When a single/simple preposition is not sufficient to 01. He is hard at it.
express the idea then compound Prepositions are 02. They are at party.
used. 03. I am at work.
Such Prepositions are generally formed by adding 04. What is he at now?
“A=no”, and “Be=By”. It is used to denote
Examples: rate/degree/value/cost/sate/condition/order/manner/ag
Amidst, Amongst, Around, Before, Behind, Below, Beneath, e/distance and position:
Beside, Between, Beyond, Inside, Outside, Underneath, 01. He is driving the car at full speed.
Within, Without etc. 02. He sold his bike at a loss.
03. Double Preposition: 03. Both the parties are at peace nowadays.
These are two Prepositions used together. 04. Pakistan is not at war with India.
Examples: 05. I am glad at his success.
Against, as far, As regards, as to, From among, From under, 06. My father is anxious at my failure.
from within, Out of, Owing to, Within etc. 07. My friend passed the entry test at the second
04. Phrase Preposition: attempt.
These are the groups of words functioning as 08. He is at ease.
Preposition and used with the force of a single 09. My brother is busy at the movement.
Preposition. 10. It looks better at distance.
Examples: 11. He was working at the table.
According to, Agreeably to, Along with, Away from, 12. The vehicles are at the signals/lights.
Because of, By dint of, By means of, By reason of, For the IN:
sake of, In accordance with, In addition to, In case of, In It is used for the large towns, countries, and places
comparison to, In compliance with, In consequence of, In important to the speakers:
consequence of, in course of, In favor of, In lieu of, In order 01. He lives in Karachi.
to, In place of, In reference to, In regard to, Inspite of, 02. The statue of liberty is in America.
Instead of, In the event of, On account of, Owing to, With a 03. The Himalaya is the highest mountain in the world.
view to, With an eye to, With reference to, With regard to 04. They are in temple/church/mosque/prison.
etc. 05. He was born in London.
05. Participle Preposition: 06. Which is the biggest ocean in the world?
These are present ot past Participles used as It is used to denote a period of time:
Prepositions. 01. He gets up early in the morning.
Examples: 02. She reaches school in time.
Barring, Concerning, Considering, During, Not withstanding, 03. The flowers bloom in spring.
Pending, Regarding, Respecting, Saving, Supposing, 04. The train will be leaving in 10 minutes.
Touching, (Such words do not take a Preposition before or 05. He learnt to drive in four weeks.
after them). It denotes position or rest:
Different uses of Prepositions: 01. An old man has a stick in his hand.
AT – IN – INTO 02. My mother is lying in bed at home.
AT: 03. There is no one in the room/in the building/ in the
It is used to denote small, and less important places, 04. Park/in the garden/in the office.
villages, towns and definite part of space. 05. He is sitting in chair/he is in chair.
1. My brother lives at Chelhar. 06. There is something in the box.
2. I am at the door. It expresses manner:
3. The passengers are at the bus stop. 01. She sings in a sweet tune.
4. My brother is at home. 02. You must be polite in your attitude.
5. He lives at the top of hill. 03. Aslam prefers to sit in first row.
6. He will meet you at the college. 04. He always pay his bills in cash.
7. Open your book at page 50. 05. They fell in love with each other.
It is used to indicate definite point of time: 06. We trust in God.
1. The farmer came home at day break/sunset. 07. Write in ink.
2. The train arrives at mid night. 08. Write your name in block letters.
3. He died at early hour this morning. 09. The children always play in street.
4. They will meet the guest at breakfast. INTO:
5. The principal will reach at 9 O’ clock. It denotes motion towards the inside of anything from
6. The function will end at half past time. outside:
It is used to indicate the direction/towards: 01. The boy fell into the pond.
01. I did not laugh at the beggar. 02. He walked into the room.
02. He is looking at the picture. 03. An angry women jumped into the well.
03. The boy threw the stone at the dog. 04. Thieves broke into the room.
8
05. The river Indus flows into the Arabian sea. 04. He is with his father now but he will be with you
06. The lion rushed into its den. tomorrow.
BY – WITH – WITHIN 05. He has a good relationship with his parents.
BY: 06. He parted with his property.
It is used to indicate the doer or agent of an action after 07. I am bored with my job.
the verb in the Passive voice. WITHIN:
01. A letter was written by Almas. Which means before the end of:
02. He was murdered by a robber/a dacoit. 01. He will be there within two days.
It is used to denote time, measurement, division 02. I shall return your money within a week.
(arithmetic) 03. You must always try to live within your means.
01. What is the time by your watch? 04. Finish your work within a week/ in a day or two.
02. I shall return by 5 o’ clock in the morning. 05. To appoint him is not within my reach/power.
03. Eggs sell by dozen. ON – UP – UPON
04. Cloth is measured by meter. ON:
05. The prices have increased by 10 rupees. It is used to indicate time:
It is used to show the path or means of trave: 01. He was born on 25th December, 1980.
He prefers to travel by air/by sea. 02. We have holiday on Sunday.
1. She always go her home by train. 03. I gave him a gift on his birthday.
It is used to show how we do something or how 04. I sent him card on New Year’s Day.
something can happen: 05. The president addressed the nation on Labour
01. The streets are lighted by electricity. Day.
02. I sent him letter by post. It denotes something supported by/attached to/ lying
03. We pay our bill by cheque. against/in contact with:
04. They meet me at the party by chance. 01. Keep your book on the table.
05. He took my pen by mistake. 02. The book is on the table.
It is used to indicate a part of body that is touched. 03. They sit on the grass in the park.
01. He caught Abid by his neck. 04. Ice/wood floats on the water.
02. I took him by the hand. 05. There are many pictures on the wall.
It is also used in following cases: 06. The label is on the bottle.
1. He is Syed by caste. 07. There is no body living on the Island.
2. He has no child by his wife. 08. The guests are standing on the road.
3. He swore by God. It points out an activity/manner/state when followed by a
WITH: Noun or an Adjective:
It is used with the instrument with which the action is 01. He met me on the way.
done. 02. Aslam always goes school on foot/on a bicycle/ on
01. The teacher hit him with stick. a bike/ on horseback.
02. She cut an apple with knife. 03. The house is on fire. It is better, we may get out.
03. He hanged himself with a piece of cloth. 04. Keep on the left.
04. The farmer cut the tree with an axe. It is also used in following ways:
05. Let me write with a pencil. 01. They congratulated me on my success.
06. I always write with pen. 02. We cannot rely on him.
It is used to indicate manner: 03. He is dependent on his brother.
01. Why are you angry with me? 04. His income is not enough to live on.
02. My boss is pleased with me. 05. He goes on diet now.
03. I am satisfied with his progress. 06. Though I have some problems but on the whole I
04. Don’t quarrel with each other. enjoy my job.
05. The army fought with great courage. UP:
06. I agree/disagree with him on this matter. It is used in following ways.
07. The judge was satisfied with his statement. 1. Go upstairs/ladder.
08. He received guests with open arms. 2. Make up the loss.
It is used to indicate what is used for filling, covering, 3. The boy climbed up.
having or carrying: 4. The monkey ran up the trees.
01. The mountains were covered with snow. 5. You are walking too fast, I cannot keep up with
02. Fill this cup with tea. you.
03. She is the girl with red hair. 6. He gets up early in the morning.
04. The shopkeeper fill the bag with goods. 7. Ring up your father.
05. He went out with my permission. 8. We are square up now.
It is also used in following ways. 9. Time/game is up.
01. Compare Ali with Aslam. 10. He turned up late at night.
02. The pen is write with. 11. Give up all your bad habits.
03. The farmer rises with sun. UPON:
It is generally used in speaking of things in motion:
9
01. The dog sprang upon the box. 02. Put off old clothes.
02. The patient has been operated upon. 03. The cap is off the head.
03. He had no evidence to go upon. 04. Friends fall off in adversity.
04. I have hit upon a plan. 05. The river flows off the bridge.
05. You have conferred a great favour upon me. 06. Turn off the tap.
BESIDE – BESIDES 07. He switched off the fan.
BESIDE: 08. The strike will be called off tomorrow.
Beside means by the side of. It is used in following ways: 09. It was only a yard off me.
01. He sat beside his father. 10. I took off my shirt.
02. The dog is sitting beside the Kinjhar Lake. 11. He is off his head.
03. His answer is beside the question. BEHIND – BEFORE
BESIDES: BEHIND:
Besides means is addition to, so it is used in following It is used in the sense of “at the back of (place) remaining
ways. after (time, rank):
01. Besides doing my work I help my father. 01. My house is behind yours.
02. Besides giving advice, he gave me money also. 02. He lives behind my house.
03. Besides being fined he was prisoned also. 03. He hide himself behind the curtain.
04. Besides a book Aslam gave me a note book also. 04. There is a history behind the ruins of Moen Jo
05. Besides bread he had butter also. Daro.
06. Besides a home he has a flat also. BEFORE:
07. Nobody besides my brother supported me at the It is used to denote a point of time:
election. 01. He wrote a letter to his friend before this.
08. He bought some books besides pencil. 02. I always work hard before the examinations.
OF – OFF 03. The sun will rise before six O’ clock.
OF: 04. My father will come before 7 O’ clock.
It is used to indicate cause: 05. We should put honesty before profit.
01. We are afraid of a snake. BETWEEN – AMONG
02. We should be proud of our country. BETWEEN:
03. He should be ashamed of his such a behavior. It is used in speaking for two persons or things:
04. I am tired of him. 01. Divide the cake between these two boys.
They are not afraid of death. 02. The property was divided equally between two
05. He died of cholera/cancer/typhoid/TB. brothers.
06. What are you thinking of? 03. Islamabad is between Mari and Rawalpindi.
07. He speaks ill of you. It can be used for more when we have a definite number
It is used to denote connection/relation: in mind:
01. He is blind of one eye. 01. Pakistan lies between India, Iran, China, and
02. Your horse is lame of one leg. Afghanistan.
03. She is deaf of one ear. 02. They reached here between noon and evening.
04. Diplo is to the south of Mithi. 03. The difference between 8 and 12 is 4.
05. He is sure of his success. 04. It is only between you and me.
06. I am confident of his arrival. AMONG:
07. I am fond of mangoes. It refers to more than two persons or things:
08. I am fond of music/ 01. He was standing among the people.
09. Beware of pick pockets. 02. The foolish quarrel among themselves.
10. His wife delivered of a male child. 03. The father divided his property among his sons.
11. He was relieved of his duties. 04. My village is among the hills.
12. This patient has been cured of the disease. 05. He was happy to be among friends again.
13. Be loyal of your country. 06. The brave, soldiers never quarrel among
14. One should not be jealous of others. themselves.
15. He reminds me of his brother. 07. Even honesty/Honour prevailed among thieves.
It is used to indicate origin, material, measurement and FOR – FROM – SINCE
etc. FOR:
01. He is man of principles. It is used for indicating the purpose:
02. The chair is made of wood. 01. The boy is crying for his mother.
03. Our home is built of bricks. 02. He does not prepare well for the test.
04. The basket was full of fruit. 03. I paid ten rupees for it.
05. He bought six meters of cloth. 04. He sacrificed for his country.
06. I need a sheet of a paper. 05. My father reads for pleasure.
07. It is a sum of addition/subtraction. 06. I am getting late for school.
OFF: 07. Let’s hope for the best.
It is used to denote not on, down from and away from: It is used to indicate suitability:
01. Cut slice off the bread. 01. He is fit for this job.
10
02. Raw fruit is harmful for health. It is used in the sense of below, beneath
03. He has no clothes for this occasion. (anything/covered area on the surface) less than or lower
It indicates a period of time. than:
01. He stayed with me for two days. 01. The cat is under the table.
02. I have been waiting here for the last two years. 02. He may rest under the tree.
03. Aslam went Karachi for a week. 03. They are under the tree.
04. The fountains had been running for an hour. 04. He begins school from today.
It is also used in the following ways. It is used to show difference or distinction:
01. Please call/send for the doctor at once. 01. My pen differs from your pen.
02. The beggar begged him for money/charity. 02. God differs from brass.
03. I have no respect for a liar. 03. He does not know good from bed.
04. I always care for him. 04. These sights are different from others.
05. I am anxious for my father’s health. It is used to indicate the place and object, whose distance
FROM: and absence is stated:
It is used to indicate starting of a period of time. It is used 01. You must abstain from smoking.
for any form of tense. 02. He has run away from home.
01. He worked from morning to evening. 03. My father has come from Canada.
02. I am not your friend from today. 04. They prevented him from falling.
03. I shall join my job from the 1st of January. 05. Where do you come from?
04. She will read book from beginning to end. 06. Never deviate from the path of truth.
It is also used in the following ways: It is also used in the following ways:
01. Ice is scattered over the road. 01. The villagers draw water from a well in Thar.
02. Birds fly over hills and vales. 02. Boys over sixteen are debarred from competition.
03. The bridge is over the river. 03. He bought some gifts from the shop.
04. The old men has umbrella over his head. 04. The conditions are growing from bad to worse.
05. I have glanced over your letter. 05. Wine is made from grapes.
06. The cat jumped over the wall. SINCE:
07. He is over eighty years. It is used to denote some point of time. It comes after
08. Don’t cry over spilt milk. object/verb in the Present and Past perfect tenses:
09. River Indus is over seventeen hundred miles. 01. He has not met us since last night.
DURING: 02. I have been ill since Sunday.
It is used to indicate at some point a period of time: 03. The boss has been on leave since January.
01. He did not meet his friend during his visit to 04. The child has been sleeping since after noon.
Lahore. 05. They have not met since 1st January.
02. I do not talk during eating/taking meal. TO:
03. We did not greet each other during the meeting. It is used to denote preference/comparison:
04. We shall go to visit Lahore during summer 01. He is junior to me.
vacation. 02. This cloth is superior to that.
05. I fell asleep during the film. 03. He is like brother to me.
06. It must have rained during the night. 04. He prefers tea to coffee.
AFTER: 05. Your writing is similar to me.
It is used to denote the end of a period in the past: 06. Some people prefer wealth to health.
01. He came to his native place after twenty years. It is used to show any feeling/relation:
02. I met him after a long time. 1. My brother is very kind to me.
03. He went to see his ailing friend after a week. 2. I am graceful to you.
It is also used in the following ways: 3. We shall remain thankful to them.
01. The cat runs after the rats. 4. He is true to his words.
02. The parents looked after their children. 5. Smoking is dangerous to health.
03. A son takes after his father. 6. This road leads to Hyderabad.
04. It is poetry after Shah Lateef. 7. Let’s pray to God for rain.
05. I came after them. 8. What is he to you?
06. This building is after great Mughal architects. 9. She gave a birth to male child.
ABOUT: 10. He was admitted to hospital.
It is used in the following ways. 11. Mariam was married to Akram.
01. He is about to go now. 12. He invited us to tea.
02. The mother is worried/careful about her son’s 13. China is to North of Pakistan.
health. 14. Listen to me carefully.
03. Your father enquired about you. 15. Just listen to what I say.
04. Go about your business. 16. He spoke to us in English.
05. He is about seventeen now. 17. I agree/disagree to your proposal.
06. He complaints about pain in his stomach. 18. I can say this to his face.
UNDER: 19. Read the newspaper to me.
11
OVER: 4. My mother has done a lot towards my comfort.
It is used to denote superiority in rank and authority: 5. The soldiers besieged the city towards morning.
1. Lady Diana was famous all over the world. DOWN:
2. The great Akbar ruled over a vast empire. It is used in the following ways:
3. He has no control over his son. 1. The boys climbed down the tree.
4. The chief guest presided over the function. 2. The water flowed down the drain.
5. The cost of this book is under fifty rupees. 3. She went down town.
6. He works under me. 4. My friend came down in the world.
7. My feet are under the table. 5. They were walking down the road towards the
8. She put her necklace under her pillow. station.
ABOVE: THROUGH:
It is used in the sense of a little over the surface of any It is used in the following ways:
other thing: 1. I have gotten through the examination.
1. The roof is above all of us. 2. We shall get through the repair now.
2. He lives above his means. 3. The driver drove through the red light and was
3. They are above all these things. caught.
4. Its price is above RS. 50. 4. I have gotten through money yesterday.
5. Aslam is above 50. 5. They stayed there through the day.
6. Who is above you in the class? 6. Did you see the sights through the window?
7. His work is above praise. 7. I sent a letter through a messenger.
AGAINST: 8. The tourists passed through Pakistan and Iran.
It is used in the sense of in opposition/contrary to:
1. Was he against me? CONJUNCTION
2. Have you any complaint against us? It is derived from the Latin “Conjunctionem” means “A
3. The public is cautioned against thieves. joining together”.
4. The boy stood against the wall. A conjunction is a word used to join words or groups
5. They spoke against me in the court. of words or sentences together.
6. I strongly advise you to save against rainy days. Examples:
TILL/UNTILL: 1. Two and two make four.
It is used in the sense of not earlier than: 2. I am young but wise.
1. He will stay till Sunday. 3. She is poor but honest.
2. Wait for me till I come. 4. Boys and girls go to school.
3. Stay here till they return. The conjunctions joins different parts of speech together,
4. My brother will be working until 10PM. as
5. He will be away until Monday. Nouns: Aslam and Ali went away.
6. Let’s wait until it stops raining. Nouns and Pronouns: Aslam and I work together.
7. She did not get up until half past ten. Adjectives: A wise and clever man came here.
8. Let’s star now and work till/until dark. Pronouns: He as well as I fell down.
BELOW: Verbs: The man sat down and wept.
It is used in the sense of lower than: Adverbs: The ship floated over and across the sea.
1. He stands below me in the class. Conjunctions merely join, they do no other work.
2. My father gave him a cheque below five hundred. Some Common conjunctions are as under.
3. They live below us in this building.
And, As, Either, Hence, Likewise, Neither, Or, Also,
4. Today temperature is below 40C.
Accordingly, Further, However, Moreover, Nor, Since,
ACROSS:
As well as, Because, For, If, Oher wise, Before,
It is used in the sense of, from one side to another:
Therefore, So that, Still, Until, Both, unless and Yet etc.
1. The dog ran across the field.
Some Conjunctions are used in pairs, such conjunctions
2. He sailed across the river in thirty minutes.
are called Co-relative Conjunctions or Co-relatives.
3. The light must fall across the lane.
These are used as under,
4. When the signal was red, he ran across the road.
Either – or
BUT:
1. Either you or I must go. Either do it or go out.
It is used in the following ways:
2. Either he or you have stolen my purse.
1. No one but I could answer the question.
3. Either Aslam or his brother is criminal.
2. Who but my brother can guide me?
Neither – Nor
3. All but Iqra were present there.
1. Aslam is neither intelligent nor diligent.
4. She was the last but one to sing.
2. He is neither rich nor poor.
TOWARD/TOWARDS:
3. Neither does he come nor does he reply.
It is used in the following ways:
4. He can neither read nor write.
1. He was driving towards his home.
Both – And
2. What steps have you taken towards the solution of
1. He is both a poet and a philosopher.
your problem?
2. Both men and women are enlisted during census.
3. He has friendly relations towards me.
12
3. Both the buffalo and the cow give milk. Co-ordinating Conjunctions are of four kinds.
4. Both you and I were friends. 01. Cumulative or Copulative Conjunction:
Though/Although/Even though – Yet Which merely add one statement to another, as;
1. Though Aslam is ill, yet performs his duties. i. We carved not a line.
2. Though he has abused me, yet he is intelligent. ii. We raised not a stone.
3. Even though he hates me, yet I pray for him. 02. Adversative Conjunction:
4. Though your father is old, yet he is strong. Which express opposition or contrast between two
5. Although he is poor, yet he is generous. statements. As,
6. Although he is rich, he is miserly. I. He ran fast but missed the train.
Such –As II. You are not rich still, you could do something to
1. There is no such a person as you respect. help him.
2. There is no such a book as you referred. 03. Illative Conjunction:
3. There is no such a company as the students These Conjunctions express an inference. Illative is
mention. derived from Latin word “Illatus” means “that which is
4. There is no such a task as he performs. inferred”.
So – That I. He was punished for he was guilty.
1. He was so tired that he could not walk. II. Aslam did not do well in the test, therefore he
2. He was so simple that he could not get bribe. failed.
3. I have become so tired that I can work no longer. 04. Disjunctive or Alternative Conjunction:
Not only – But also Which express a choice between two alternatives; as
1. Shah Abdul Latif was not only a saint but also a I. She must weep, or she will die.
poet. II. Either he is mad, or he feigns madness.
Hardly/Scarcely – When Subordinating Conjunctions:
No sooner – Than These are the Conjunctions, which join the
2. No sooner did the bell ring, than the boys left the Main/Principal Clause to Sub-ordinate Clause.
class. Sub ordinate Conjunctions are those which join sub
3. No sooner does she return home than she begins ordinate Clause to any other clause on which it
to work. depends for its full meaning.
4. No sooner did they leave the home than it began Subordinating conjunctions are classified into 8 kinds.
to rain. Temporal or Time:
Such – That When: I shall go, when my father comes back.
1. His character is such that you can believe upon Before: Reach home, before it rains.
him. Till/Until: Wait till/until he returns.
2. His behavior is such that everyone admires him.
So long As: The name of martyr will live so long as
Whether – Or
the world lasts.
1. I cannot say, whether he will come or not.
As soon as: I will leave the home as soon as you
2. I do not care, whether you go or stay.
come.
Would – Rather
As: The teacher entered into the class as the clock
1. The thief would rather agree than refuse.
struck 9 O’ clock.
2. The boy would rather work than go to bed.
While: While there is life, there is hope.
Other – Than
Final or Purpose:
1. She was no other women than your mother.
2. He was no other boy than Aslam. Lest: Work hard lest you should fail.
Indeed – But So that: We read the books, so that we may gain
1. The thief was indeed caught red handed but knowledge.
escaped. That: We eat that we may live.
2. They are indeed friends but no body trusts. Causal or Reason/Cause:
CLAUSES AND KINDS OF CONJUNCTION Because: Aslam went to a doctor because he was
Conjunctions are divided into two classes. ill.
1. Coordinating For: Kapil Dev deserved to succeed, for he worked
2. Subordinating. hard.
Coordinating Conjunctions: Since: Since you already know, I will not tell a lie.
The sentence contains two independent statements or As: As I am ill, I cannot come.
two statements of equal rank or importance. Conditional or Condition:
Hence the Conjunction joining together these two If: She will achieve her target, if works hard.
statements or clauses of equal rank is called Co- Unless: He will not attend the party, unless he is
coordinating Conjunction. (Co-coordinating means “of invited.
equal rank”. Provided that: You can take the camera, provided
A Co-ordinating conjunction joins together clauses of that you will return in time.
equal rank. On the condition that: I forgave my younger
The chief co-ordinating conjunctions are; And, But, brother on the condition that he will give up bad
For, Nor, Or, Also, Either-or, Neither-nor. habits.
13
Whether: Nobody can say whether he will pass or An action in the Perfect Continuous Tense denoted
not. in a perfect or complete condition after the
Comparison or Contrast: continuous action.
Than: Your brother is clever than you. 01. PRESENT INDEFINITE/SIMPLE/INCOMPLETE
As: Thari Ashok is an intelligent as I. TENSE
As-so: As you work, so you will be paid. An assertion ( )بيانmade as of present time is said to
So-as: As for as I know he is an honest man. be in Present Tense.
Concession or supposition: It denotes an action that is done just now.
Though: Though he is un well, he is doing well. It can be used in the following ways.
Al though: A book is a book although there is 1. I am a student.
nothing in it. 2. We are boys.
However: However fast you run, you cannot win. 3. He is a doctor.
If: If he is there, I shall see him. 4. This is book.
Local or Place: 5. These are tables.
Where: He injured, where he fell. 6. Those are pictures.
Where ever: I shall sleep, where ever I like. 7. This is a museum.
Whence: He returned whence I came. 8. She is a nurse.
Consequent or Result: When there are three persons in the sentence,
So-that: second person, Third person and then First Person
I. He was so weak that he could not run fast. are taken respectively with to be verb.
II. The police man ran so fast that he caught the 1. You, he and I are good players.
thief. 2. You, she and I are free now.
III. Water is so hot that I cannot bath with it. For making Negative sentence only “Not” is place
INTERJECTION after “To be verb”.
1. I am not a student.
An interjection is a word which expresses some sudden
2. They are not tailors.
feeling or emotion.
3. My brother is not a clerk.
Interjection may express
For making Interrogative sentence mainly “To be”
Joy: Hurrah! Huzza!
verb is used before the sentence ending with
Grief: Alas!
“Question Mark”.
Surprise: Ha! What!
1. Am I a student?
Approval: Bravo! 2. Are they tailors?
Examples: 3. Is my brother a clerk?
01. Hellow! What are you doing there?
To express possession or ownership of something
02. Hurrah! We have won the game.
or person in current time. “Has” is used after
03. Alas! He is dead.
singular and “Have” for plural in numbers, only
04. Ah! Have they gone?
“Have” can be used with “I” and “You”.
05. Oh! I got such a fright.
1. I have a pen.
06. Hush! Don’t make a noise.
2. We have new uniforms.
Certain groups of words are also used to express some
3. He has a motor bike.
sudden feeling or emotion; as,
For making Negative sentences only “Not” or “No”
Ah me! For shame! Well done! Good gracious!
is used after “To have” verb.
TENSE 1. I have no pen/I have not a pen.
Tense is derived through French from Latin 2. My friend has not his own bike.
“Tempus” means time. 3. Aslam has not a son/Aslam has no son.
Tense is a change in the verb to express the time. For making Interrogative sentences only “To have”
Tense marks the time of an action whether it is verb is used before the sentence.
completed at that time or not. 1. Have I a pen?
There are three divisions of time (Tense); Present, 2. Has his brother his own bike?
Past and Future. 3. Have those students’ new bags?
The difference between Present and Past Tenses is To express any general matter and permanent
shown y conjugation whereas to express the Future truth.
Tense we have to use Auxiliary Verbs, Will and Shall. 1. Babies weep.
An action in the Present, Past and Future may be 2. Birds fly.
considered without reference to its completeness or 3. Dogs bark.
incompleteness. 4. Milk is white.
An action in the Continuous Tenses, carry the 5. Unity is strength.
Auxiliary Verb “To be”. 6. The Sun rises in the east.
An action in the Perfect Tense may be considered in 7. The Earth revolves around the Sun.
a perfect or complete condition. All the Perfect 8. The soul is immortal. We all are mortal.
Tenses as a rule contain Auxiliary verb “To have”. Also express the following conditions.
14
1. We go there daily (Habit). 7. I know what you mean (Present action).
2. This horse walks slowly (Habit). 8. Look! How it thunders (Present action).
3. The school opens at eight (Habit). 9. Look! How pretty it seems (Presentaction).
4. He gets up early in the morning (Habit). 10. Pakistan comes into existence on 14th August,
5. I take tea twice a day (Habit). 1947 (Past action).
6. Nurse looks after the patient (Habit). 11. Babar defeats his opponents (Past action).
STRUCTURE OF THE SENTENCE OF PRESENT INDEFINIT TENSE
Sentence Assertive/Affirmative/Descriptive sentences
Example (1) I don’t tell a lie. (2) We do not invite our friends. (3) They don’t ask the question.
Example (1) He does not/doesn’t do his homework. (2) She doesn’t prepare the breakfast.
(1) Do I decorate my room? (2)Do we obtain the good marks? (3) Do they achieve their targets?
Example
(4) Do your friends go for a walk? (5) Do you follow my principles?
Example (1) Does he do his homework? (2) Does it blow fast outside?
Examples (1) Do I not do my homework? (2) Does he not wait for his friend?
“WH” family are also used before the interrogative sentences for making Double Interrogative sentences.
“WH” family; What, When, Where, Which, Who, How, Whom, Whose, Why, With and In which.
(1) What is his age? (2) When does he inform you? (3) Where is your boss? (4) Which is your book?
(5) Who are you? (6) How are you? (7) Whom do you serve now? (8) Whose son are you? (9) Why is he late today?
(10) With what do you write? (11) In which class do you read?
15
02. PRESENT CONTINUOUS TENSE 4. Aslam is writing a letter.
It denotes an action going on at the time of To denote an action that will happen in near future.
speaking. It is used when we talk about things 1. My father is leaving for Islamabad tomorrow.
happening in a period around now. 2. He is going to appear in the next examination.
To point out an action going on at the time of
speaking. To point out the repeated action
1. We are laughing. 1. He is always working.
2. You are running fast. 2. She is always asking the question.
3. It is raining 3. Aslam is always losing his keys.
STRUCTURE OF THE SENTENCE OF PRESENT INDEFINIT TENSE
Sentence Assertive/Affirmative/Descriptive sentences
Case (1) Am is used with “I”, “is” singular and “Are” for plural and You.
Example (1) I am reading a new lesson. (2) We are telling a lie. (3) You are taking the meal.
Case (1) Am is used with “I”, “is” singular and “Are” for plural and You.
Example (1) I am not flying the kites. (2) It is not hailing. (3) The phone is not ringing now.
Case (1) Am is used with “I”, “is” singular and “Are” for plural and You.
Example (1) Am I calling them with bad names? (2) Is it getting dark now?
Case (1) Am is used with “I”, “is” singular and “Are” for plural and You.
Examples (1) Am I not waiting for you? (2) Is the teacher not teaching them properly?
“WH” family are also used before the interrogative sentences for making Double Interrogative sentences.
“WH” family; What, When, Where, Which, Who, How, Whom, Whose, Why
What is he buying from this shop? Where are they singing the national songs? Where is she making the speech?
Which dish are you testing? How is she spelling these words? Who is knocking at the door? Whom are you telling
the truth? Whose books are you looking for? Why is Aslam waiting for us?
03. PRESENT PERFECT TENSE 2. He has lived here all his life.
It is used to express an action that is completed at 3. He has been in the army.
the time of speaking or writing or whose time is not To denote an action whose time is not definite.
given.it always implies a strong connection with the 1. I have read “Shah Jo Risalo”.
present and is mainly used in conversation, letters, 2. The government has issued the notification.
newspapers, televisions and radio reports, it is said To denote an action completed in past may occur
to be a sort of mixture of present and past. again.
It is used to denote that an action has just now 1. I have seen Makli Graveyard.
been completed. 2. Our class has visited Moen Jo Daro.
1. I have finished my letter. To denote habitual action.
2. The sun has set. 1. He has always disturbed me during my study.
3. He has left for Karachi. 2. I have never been late for work.
4. She has just gone out. To denote an action finishes at the time of
02. To denote an action commenced in the past and speaking.
going on to the present. 1. I haven’t seen you, Aslam.
1. I have studied in this school for four years. 2. This room hasn’t been cleaned for month.
16
It is often used in newspapers and letters. It can also be used with so far, Till, Now, Yet, Today,
1. Some people have been killed in road Already, This week, never and ever.
accident. 1. Has the postman not come yet?
2. I am sorry, I haven’t written you letter before. 2. Have you seen him this month?
STRUCTURE OF THE SENTENCE OF PRESENT PERFECT TENSE
Sentence Assertive/Affirmative/Descriptive sentences
Case (1) “Has” is used with singular subject, “Have” for plural , “I” and “You”
Example (1) I have learnt by heart a new poem. (2) He has told me a lie. (3) He has done his work.
Case (1) “Has” is used with singular subject, “Have” for plural , “I” and “You”
(1) He has not gone to sleep yet. (2) You have not solved this question. (3) They have not came
Example
here.
Case (1) “Has” is used with singular subject, “Have” for plural , “I” and “You”
Example (1) Has Almas abused you? (2) Have you solved this mock test?
Case (1) “Has” is used with singular subject, “Have” for plural , “I” and “You”
Examples (1) Has the girl not learnt this lesson? (2) Have they not attended classes?
“WH” family are placed before any interrogative sentences for making Double Interrogative sentences.
What has he sent to you? Which toy has she chosen? Who has made such a speech? Who have identified the
thieves? When has he informed me? How has he known me? Whom has the teacher allowed to go out?
Case (1) “Has” is used with singular subject, “Have” for plural , “I” and “You”
(1) Aslam has been reading this newspaper for an hour. (2) I have been reading this book since
Example
July. (3) It has been blowing fast outside since midnight.
Case (1) “Has” is used with singular subject, “Have” for plural , “I” and “You”
Structure Subject + Has/Have + Not + Been + Present participle (ing form) + Object
(1) I have not been thinking over it. (2) We have not been running for 2 hours. (3) It has not been
Example
feeling cold since the end of February,
17
Sentence Changing the Affirmative into Interrogative Sentences
Case (1) “Has” is used with singular subject, “Have” for plural , “I” and “You”
Example (1) Has she been cooking since morning? (2) Has it been raining for two hours?
Case (1) “Has” is used with singular subject, “Have” for plural , “I” and “You”
Structure Has/Have + subject + not + been + Present participle (ing form) + object?
Examples (1) Has he not been taking bath? (2) Has your brother not been taking part in the games?
“WH” family can be used before the subject of any interrogative sentences for making Double Interrogative sentences.
Why have you been making a noise for two hours? How has your team been winning since last year? Where has he
been living since 2001? Who has been beating the drum?
Example I sent him some gifts. Our team won the match. The birds mad the nests.
Example We did not attend the class. It did not blow fast outside. Almas did not read lesson.
Example Did you take the breakfast? Did he do his homework? Did Aslam attend the class?
Examples Did Almas not come here? Did I not supervise you work? Did he not do homework?
“WH” family are also used before the interrogative sentences for making Double Interrogative sentences.
“WH” family; What, When, Where, Which, Who, How, Whom, Whose, Why, With and In which.
What were they? What was its color? What did you buy? When did she attend the class? Where was the guest?
Where did they arrange the party? Who was in the office? Which songs did he sing? Who took part in the game?
How was the patient? How did fight with them? Whom did you guide? Whom did he send a letter? Whose purse
was this? Why was she angry? Why did you fail in the test? With what did he paint? With what did he lift that box?
Example I was attending the function. Almas was playing PUBG. They were running.
Structure Subject + To be verb (Past) + Not + Present participle (Ing form) + Object
Example We were not waiting for them. They were not coming. He was not listening.
Example Was he going with his father? Was she going to Karachi? Were they dancing?
Structure To be verb (Past) + Subject + Not + Present participle (Ing form) + Object?
Examples Was he not going to Mithi? Were they not attending the class?
“WH” family are also used before the interrogative sentences for making Double Interrogative sentences.
“WH” family; What, When, Where, Which, Who, How, Whom, Whose, Why, With and In which.
What were you doing there? When was I gambling? Where was he sending letter? Why were you coming?
Structure Subject + To have verb (Past tense) + 3rd Form of Verb + Object
Example I had applied for the job. He had waited for the guests. The teacher had called the roll numbers.
Example They had not reached home yet. Your brother had not celebrated his birthday.
19
Sentence Changing the Affirmative into Interrogative Sentences
Example Had you ever seen a lion? Had you committed such a mistake?
Examples Had Almas not gone to Karachi? Had you not attended the class?
“WH” family are also used before the interrogative sentences for making Double Interrogative sentences.
“WH” family; What, When, Where, Which, Who, How, Whom, Whose, Why, With and In which.
What had he offered them? Who had won the first prize? Where had he favored us? Whom had you sold your car?
Structure Subject + Had been + Present participle (Ing form) + Object + Since/For
Example She had been working for two hours. Ali had been playing since morning.
Structure Subject + Hadn’t been + Present participle (Ing form) + Object + Since/For
Example Aslam had not been studying since 2019. They had not been listening me since last hour.
Structure Had + Subject + Been + Present participle (Ing form) + Object + Since/For?
Example Had Aslam been writing for 2 hours? Had you been doing job in this office since last year?
Structure Had + Subject + Not + Been + Present participle (Ing form) + Object + Since/For?
Examples Had Zakaullah not been understanding this lesson? Had they not been taking tea since 5 years?
“WH” family are also used before the interrogative sentences for making Double Interrogative sentences.
“WH” family; What, When, Where, Which, Who, How, Whom, Whose, Why, With and In which.
Why had she been waiting for you since morning? How had you been running this shop for five years?
Example I shall celebrate my birthday. You will keep your promise. It will blow fast outside.
Example Aslam will not iron her clothes. It will not hail today. She will not tell you a lie.
Examples Shall I not love my country? Will you not perform your duties?
“WH” family are also used before the interrogative sentences for making Double Interrogative sentences.
“WH” family; What, When, Where, Which, Who, How, Whom, Whose, Why, With and In which.
What will you drink? What shall we learn? When will he finish his homework? Which dress will suit you?
Example I shall not be doing my homework. You will not be attending the class.
Example Will Ghulam Nabi be speaking truth? Will peon be ringing the bell?
Examples Will be the sweeper not be removing filth? Shall I not be guiding your brother?
“WH” family are also used before the interrogative sentences for making Double Interrogative sentences.
“WH” family; What, When, Where, Which, Who, How, Whose, Why.
What will you be bringing for us? When shall I be inviting them? Where shall I be hiding your books?
Example We shall have revised our course. She will have helped them many times.
Example She will not have slept by now. We shall not have taken the examination.
Example Will the peon have rung the bell? Shall I have understood your problems?
Examples Will he not have offered his prayers? Shall we not have explained this topic?
“WH” family are also used before the interrogative sentences for making Double Interrogative sentences.
“WH” family; What, When, Where, Which, Who, Whom How, Whose, Why.
What will mother have cooked for you? Which film will they have seen? Who will have failed in the test?
Example I shall have been doing this work for three days from tomorrow.
Structure Subject + Shall/Will + Not + Have been + Present Participle + Object + Since/For
22
Example I shall not have been going to their home to meet them since Sunday.
Example Shall I have been applying for the leave? Will Aslam have been brushing his teeth for 10 minutes?
Structure Shall/Will + Subject + Not + Have been + Present Participle + Object + Since/For?
“WH” family are also used before the interrogative sentences for making Double Interrogative sentences.
Where will the shopkeeper have been dealing in sugar for ten years? Who will have been bringing the luggage for
you since noon? Whose clothes will the tailor have been mending since night?
Involved Made them take part Vehicles Cars, buses , lorries etc.
COMMUNITY LEVEL:
The members of different species living in specific habitat are called as Community.
A group of different kind of birds, living on tree, is called asbird community.
ECOLOGICAL SYSTEM:
Communities always depends upon their non-living environment in a reciprocal
interaction for their survival.
For example oxygen for respiration is obtained from environment and in turn given out
CO2.
This interaction is called Ecosystem or Ecological system.
BIOSPHERE LEVEL:
The part of earth where life exists is called biosphere. It consists of different kinds of eco
systems.
UNICELLULAR ORGANIZATIONS:
All single cell organisms carry out all activities of life.
Bacteria, Amoeba, Paramecium and Euglena are common examples of unicellular organisms.
COLONIAL ORGANIZATION:
In colonial type of cellular organization, each unicellular organism lives its own life, they are
not dependent on each other and never form any multicellular structure.
Volvox is a green alga, is an example of colonialform of organization.
MULTICELLULAR ORGANIZATION:
The organism formed by many cells is called as multicellular organism. Frog and mustard
plant are examples of multicellular organization.
MUSTARD PLANT:
Brassica campestris is commonly known as mustard plant and locally it is called “Sarsoon”.
It is multicellular and cultivated in the winter season.
The length of this plant is 1 to 1.5 meter.
FROG:
Rana tigrina is the scientific name of spotted frog found commonly in our region.
It is multicellular animal. It lives in both water as well as on land.
Its body is divided into head and trunk. There is no neck.
Different organs with the relative organ system.
ORGANS ORGAN SYSTEM
Mouth, buccal cavity, Pharynx, Esophagus, stomach, Digestive system
Small intestine, large intestine, cloaca, liver, gall
bladder,pancreas.
Heart, atria ventricle, Aortae, Vena cavae Circulatory system
Lungs, trachea, nostrils Respiratory system
AMOEBA:
Amoeba is a unicellular organism found in the mud of shallow pond, pools and at any
stagnant water.
Its size is about 0.25mm. Amoeba has a irregular shape.
It has a cell membrane which helps in movement of molecules and protects cytoplasm.
The outer part of cytoplasm is clear and transparent, called ectoplasm (gel) and inner part is
called endoplasm (sol).
The cytoplasm contains nucleus, food vacuoles, mitochondria etc. Amoeba moves by false
foot, called pseudopodia.
VOLVOX:
Volvox is a polyphyletic (many ancestors) genus of chlorophyte greenalgae in the family
Volvocaceae.
It forms spherical colonies of upto 50,000 cells.
They live in a variety of fresh water habitats and were first reported by Antonie Van
Leeuwen Hoek in 1700.
35
All the members of the particular species share the similar characteristics and can naturally
interbreed to produce a fertile offspring.
Closely related species are grouped together into genera(singular-genus).
Similar genera are grouped together into families, families into orders, orders into classes, classes
into phyla or division and phyla or division into kingdoms.
The science of classification is called Taxonomy.
SIMPLE CLASSIFICATION OF TWO ORGANISMS
Taxa Human Pea
Kingdom Animalia Plantae
Phylum Chordate Magnoliophyta
Class Mammalia Magnoliopside
Order Primates Fabales
Family Moninidae Fabaceae
Genus Homo Pisum
Species Sapiens Sativum
Scientific name Homo sapiens Pisum sativum
HISTORY OF CLASSIFICATION
Taxonomy's firstfather was the philosopher Aristotle (384-322 BC), sometimes called the
"father of science."
It was Aristotle who first introduced the two key concepts of taxonomy as we practice
it today: classification of organismsby type and binomial definition.
Aristotle was the first to attempt to classify all the kinds of animals in his book on Animals
(Historia Animalium in Latin).
He grouped the typesof creatures according to their similarities: animals with blood and
animals without blood, animals that live on water and animals that live onland.
Abu Usman Umer Aljahiz was the first eminent Arab zoologist of theMuslim world.
He used to slaughter animals for studying the internal organs of their bodies.
He also opened the abdomen of pregnant animals to find out the number of embryos and
the location of each one of them in the body.
His Encyclopedic work in seven big volumes Kitab al-Haywan (Book of Animals) is the most
famous work on zoology.
Carolus Linnaeus is considered as the father of Taxonomy.
TWO KINGDOM CLASSIFICATION
All the organisms possess cell wall were placed in plant kingdom and all the organisms do
not possess cell wall were placed in animal kingdom.
1665 Cell was first observed by Robert Hooke, an English scientist, discovered a
honeycomb-like structure in a cork slice using a primitive compound
microscope. He only saw cell walls as this was dead tissue. He coined the
term "cell" for these individualcompartments he saw.
1670 First living cells were seen by Anton van Leeuwenhoek, a Dutch
biologist, from pond water with a microscope.
39
1833 The center of the cell was seen by Robert Brown, an Englishbotanist,
discovered the nucleus in plant cells.
1839 This ended debates that plants and animals were fundamentally
different in structure. He also pulled together and organized previous
statement on cells into one theory, which states:
1- Cells are organisms and all organisms consist of one or more cells.
2 - The cell is the basic structure unit for all organisms.
1840 Where does life come from Albrecht von Roelliker discovered thatsperm
and eggs are also cells.
1845 Carl Heinrich Braun reworked the cell theory, calling cells thebasic unit
of life.
1855 3rd part to the cell theory added by Rudolf Virchow, a German
physiologist/physician/pathologist. Added that cell is not Denovo
structure. This translates mean that all cells develop only from existing
cells.
1862 Louis Pasteur was a French biologist; microbiologist and chemist provided
the experimental proof of this idea.
CELL THEORY
Cell is a basicstructural and functional unit of living organism.
This is known as a cell theory and was proposed jointly by two scientists in 1839.
A Belgian Botanist called Schleiden and the German zoologist called Schwan.
In 1855 Rudolf Virchow, a German physicians proposed an importantextension of cell theory-
that all living cells arise from pre-existing.
The postulates of cell theory are:
1. All Living organisms are made of one or more cells.
2. The cell is the fundamental unit of structure and function in all livingorganisms.
3. The new cell is derived from pre-existing cells dividing into two by celldivision.
4. The cell contains the hereditary material which is passed fromgeneration to
generation.
SUB-CELLULAR OR ACELLULAR PARTICLES
According to the first principle of the cell theory all organisms are composed of one or more
cells.
Viruses, prions and viroids are not composed of cells rather they are sub-cellular or acellular
particles but do not run any metabolic activity inside them.
They can increase in number and can transmit their characteristics to the next
generations.
CELL
Cells are the basic units of organisms and all tissues and organs are composed of cells.
There are different types of cells.
40
CENTRIOLES:
Animal cells contain a special organelle called a centriole.
The centriole is a cylindrical tube-like structure that is composed of 27 microtubules
arranged in a very particular pattern of triplets in rows. The site where two centrioles
arranged perpendicular to each other are referred to as a centrosome.
The centrosome plays a very important role incell division.
The centrioles are responsible for organizing the microtubules that position the
chromosomes in the correct location during cell division.
PLASTIDS
Plastids are large cytoplasmic and major organelles found in the cells of plants and
algae.
Plastids are the site of manufacture and storage of important chemical compounds
used by the cell.
Plastids often contain pigments used in photosynthesis, and the types of pigments
present canchange or determine the cell's colour.
There are three different types of plastids:
Chloroplasts: Green-coloured plastids found in plants and algae.
Chromoplasts: Contain red, orange or yellow pigments and are commonin ripening fruit,
flowers or autumn leaves.
Leucoplasts: Colour less plastids.
CHLOROPLAST:
The c h l o r o p l a s t is a do u bl e - membraned organelle.
Within the double membrane is a gel-like substancecalled stroma.
Stroma contains enzymes for photosynthesis.
Suspended in the stroma are stack-like structures called grana (singular = granum).
Each granum is a stack of thylakoid discs.
Thechlorophyll molecules (green pigments) are found on the surface of the thylakoid discs.
Chlorophyll absorbs energy fromthe sun for photosynthesis.
CELL SIZE AND SHAPE AS THEY RELATE TO SURFACE AREA TO VOLUME RATIO
The smallest cells are bacteria called mycoplasmas, with diameter between 0.1 μm to 1.0
μm.
The bulkiest cells are bird eggs, and the longestcells are some muscle cells and nerve cells.
Cell size and shape are related to cell function.
Bird eggs are bulky because they contain a large amount of nutrient for the developing
young.
Long muscle cells are efficient in pulling different body parts together. Lengthy nerve cells
can transmit messages between different parts of body.
Small cell size also has many benefits. For example human red blood cells are only 8
μm in diameter andtherefore can move through our tiniest blood vessels i.e. capillaries.
ANIMAL AND PLANT TISSUES
ANIMAL TISSUES
Humans and other large multicellular animals are made up of four basic types tissue: epithelial
tissue, connective tissue, muscular tissue and nervous tissue.
EPITHELIAL TISSUE:
Epithelial tissue covers the surface of the body, lines the spaces inside the body and forms
glands.
For instance, the outer layer of your skin is anepithelial tissue and the lining of small intestine
are made up of epithelialtissues.
Epithelial cells are polarized, means that they have a top and a bottom side.
There are different types of epithelial tissue depending on their function in a particular
location.
The simplest classification of these tissues is based on the number of cell layers.
When the epithelium is composed of a single layer of cells, it is called simple epithelial tissue and
those containing two or more layers of cells are called stratified epithelial tissues.
Simple squamous epithelium is found in the alveoli of lungs, and itsstructure is important
for the exchange of gases between the blood and lungs.
Simple cuboidal epithelia line the lumen of collecting ducts in the kidney and are present in
the thyroid gland around the follicles that secrete thyroid hormones.
Simple columnar epithelia are found in the female reproductive system and in the digestive
45
tract.
Stratified epithelia consist of more than one layer of cells and only one layer is in direct contact
with the basement membrane.
Stratified squamous epithelia are found in skin, with many dead, keratinized cells providing
protection against water and nutrient loss. Stratified cuboidal epithelia are found surrounding
the ducts of manyglands, including mammary glands in the breast and salivary glands in
the mouth.
Stratified columnar epithelia are rare, found predominantly in some organs of the reproductive
system.
Transitional epithelia are aspecial subset of stratified epithelia. They are exclusively found in
the excretory system.
CONNECTIVE TISSUE:
This tissue which connects or bind the different types of cells called connective tissues.
They also bind other tissues of the body with each other.
Connective tissue holds structures in the body together, such as tendons.
Cartilage is a type of supporting connective tissue.
It is a dense connective tissue. Cartilage has limited ground substance and can range from
semisolid to a flexible matrix.
Bone is another type of supporting connective tissue.
Bone can either be compact (dense) or spongy (cancellous), and contains the osteoblasts
or osteocytes cells.
Adipose is another type of supporting connective tissue that providescushions and stores
excess energy and fat.
Blood referred to as connective tissue. It is a type of fluid connectivetissue.
MUSCLE TISSUES:
Muscle tissue contains the cells that are responsible for the contraction of muscles.
There are three types of muscular tissues i.e. cardiac, smooth, and skeletal.
Skeletal muscle, which is also called striated (striped) muscle, is what we refer to as muscle in
everyday life.
Skeletal muscle is attached to bones bytendons.
For instance, the muscles in your legs and your arms are skeletalmuscle.
Cardiac muscle is found only in the walls of the heart.
Like skeletal muscle, cardiac muscle is striated, or striped.
But it's not under voluntary control.
Smooth muscle is found in the walls of blood vessels, as well as in thewalls of the digestive
tract, the uterus, the urinary bladder, and various other internal structures.
Smooth muscle is un-striped, (unstriated), it is involuntary, not under conscious control.
That means you don't have to think about moving food through your digestive tract!
NERVOUS TISSUES:
Nervous tissue is composed of neurons, which transmit information to other cells.
Nervous tissue is found in the brain, spinal cord, and nerves.
It is responsible for coordinating and controlling many body activities.
It stimulates muscle contraction, creates an awareness of the environment, and plays a major
role in emotions, memory, and reasoning.
PLANT TISSUES
There aretwo major categories of tissues in plants i.e. Meristematic tissues and
Permanent tissues.
MERISTEMATIC TISSUES:
These tissues are composed of cells, which have the ability to divide.
The cells are thin walled, have large nucleus and number of small vacuoles.
Two main types of meristematic tissues are recognized in plants.
(i) Apical meristems tissues are present at the apex of roots and stems. According to their
position they are Apical meristems.
Stem and rootincrease in length by the division of cells of these tissues.
This type ofgrowth is called primary growth.
(ii) Lateral meristems are located on the lateral sides of roots and shoot.By dividing, they are
responsible for increase in grith of plant parts. This growth is called secondary growth.
PERMANENT TISSUES:
Permanent tissues originate from meristematic tissue.
The cells of these tissues do not have the ability to divide and may have intercellular
spaces in between cells.
46
There are two types of permanent tissues i.e. (a) Simple permanent tissue (b) Compound
or complex tissue.
SIMPLE PERMANENT TISSUE:
Simple permanent tissues are made up of only one type of cell.
EPIDERMAL TISSUES:
Epidermal tissues are composed of a single layer of cells and they cover plant body.
They act as a barrier between environment and internal plant tissues.
In roots, they are also responsible for the absorption of water and minerals.
On stem and leaves they secrete cutin (the coating ofcutin is called cuticle) which
prevents evaporation.
Epidermal tissues also have some specialized structure that perform specific functions;
for example root hairs and stomata.
GROUND TISSUES:
Ground tissues are simple tissues made up of parenchyma cells.Parenchyma cells are
the most abundant cells in plants.
Overall they are spherical but flat at point of contact.
They have thin primary cell walls andhave large vacuoles for storage of food.
In leaves, they are called mesophyll and are the sites of photosynthesis. In other parts,
they are thesites of respiration and protein synthesis.
SUPPORTING TISSUES:
These tissues provide strength and flexibility to plants.
They are further of two types.
COLLENCHYMA TISSUES:
They are found in cortex (beneath epidermis) of young stems and in the midribs of leaves
and in petals of flowers.
They are made of elongatedcells with unevenly thickened primary cell walls. They are flexible
and function to support the organs in which they are found.
SCLERENCHYMA TISSUES:
They are composed of cells with rigid secondary cell walls.
Their cellwalls are hardened with lignin, which is the main chemical component ofwood.
Mature sclerenchyma cells cannot elongate and most of them are dead.
COMPOUND (COMPLEX) TISSUES:
A plant tissue composed of more than one type of cell is called a compound or complex
tissue.
Xylem and phloem tissues, found only in vascular plants, are examples of compound tissues.
Xylem tissue is responsible for the transport of water and dissolved substances from
roots to the aerial parts.
Two main types of cell are found in xylem tissue i.e. vessel and tracheids.
Vessels have thick secondary cell walls.
Tracheids are made up of slender cells with overlapping ends.
PHLOEM TISSUE:
Phloem tissue is responsible for the conduction of dissolved organic matter (food)
between different parts of plant body.
Phloem tissue mainlycontains sieve tube cells and companion cells. Sieve tube cells are long
and their end walls have small pores.
Cells are parenchymatous, narrow,elongated cells, and are closely associated with the
sieve tube.
CHAPTER 05
CELL CYCLE
CHROMOSOMES
The term Chromosomes is given by German embryologist Walter Fleming in 1882
He observed thatchromosomes colour is much darker than the rest of organelles.
The term chromosomes is misnomer because its means coloured body later it wasfound
that chromosomes are colourless bodies
Chromosomes are thread like structure appear at the time of cell division includes found
in specific numbers, made up of chromatin material in eukaryotic cell.
They contain heredity units called Genes.
Chromosomes are made up of DNA and basic protein, Histones,appear during the cell
division in the shape of rod.
It has two parts armsand centromere.
47
The chromosomes are of different types, depending upon position of centromere. These types
are:
Metacentric: Chromosomes with equal arms.
Sub-meta centric: Chromosomes with un equal arms
Acrocentric or sub-telocentric: Rod like chromosomes with one armvery small and other very long.
The centromere is subterminal.
Telocentric: Location of centromere at the end of chromosomes.
FORMATION OF CHROMOSOME
Each chromosomes in eukaryotes are composed of chromatin fiber, which is made of
nucleosomes.
Chromatin fibers are packaged by proteins into a condensed structure called chromatin.
During cell division chromatin condenses further to form microscopically visible chromosomes.
The structure of chromosomes varies through the cell cycle.
During cell cycle chromatin material replicate, divide and passed successfully to their daughter
cells for survival of their progeny.
Sometime cell-division is also responsible for genetic diversity
CELL CYCLE
The sequence of changes which occurs between one cell division and the next is called Cell
Cycle.”
It has two phases, Interphase, which is the period of non-division and M-phase, which is a
period of cell division.
The cell cycle undergoes a sequence of changes, which involve period of growth, replication of
DNA followed by cell division.
This sequence of changes is called cell cycle.
INTERPHASE:
The period of cell cycle between two consecutive divisions is called Interphase.
It is a period of growth and synthesis of DNA.
During this period the cell prepares itself for the M- phase.
The Interphase is divided further into three sub-phase, G1- phase, S-phase and G2-phase.
G1-(GAP ONE) PHASE:
It is the period of extensive metabolic activity in which Cell grows in size, specific enzymes are
synthesized and DNA base units are accumulated for the DNA synthesis.
At a point in G1, the cell may enter into a phase called G0 (G-knot) where cell cycle stop.
It remains for days, weeks or in some cases even for the life time of the organism.
S-(SYNTHESIS) PHASE:
During this phase, replication of DNA occurs.
As aresult of it chromatin material is duplicated.
G2– (GAP TWO) PHASE:
(Pre-Mitotic Phase): The following changes occur during this phase:
Cell grows in size, cell organelles are replicate in numbers as well as enzyme require for cell-
division also synthesized during this phase.
MITOSIS
In this type of cell division a parent cell divides into two daughter cells in a way that the number
of chromosomes in the daughter cells remainsthe same as in the parent cell.
Although mitosis is a continuous process, but for the study point of view we can divide it into
two phases;
(a) Karyokinesis - nuclear division
(b) Cytokinesis - cytoplasmic division.
The karyokinesis can be divided further for convenience into four phases which are Prophase,
Metaphase, Anaphase and Telophase.
PROPHASE:
During early prophase chromatin material condenses and becomevisible as thick coiled, thread
like structures called chromosomes.
Each chromosome at this stage is already double, consists of two chromatids.
The chromatids are attached to each other at centromere.
The nuclear membrane gradually disappears and at the same time centrosome divides to form two
centrioles, each moves towards the opposite pole of the animalcell and forms the spindle fibres.
The centrioles are absent in plant cells.
METAPHASE:
During this phase each chromosome arranges itself on the equatorof the spindle.
48
The separation is however incomplete and paired chromosomes are in contact with each other at
one or more points, called Chiasmata. Each homologous chromosome split longitudinally
except in the centromere region.
Now each bivalent is composed of four chromatids and therefore is known as bivalent tetrad.
(4) DIPLOTENE:
The homologous chromosomes exchange their parts of chromatid at Chiasmata.
This exchange of segments of chromatids at chiasmata between the homologous chromosomes is
called Crossing Over.
(5) DIAKINESIS:
During this sub stage; nucleoli and nuclear membrane are disappeared, whereas Mitotic
Apparatus (spindle) is completed. Chiasmata moves from the centromere towards the ends
of the chromosomes like a zipper.
This type of movement of chiasmata is known as Terminalization. At the end of Diakinesis
chromatids still remain compacted at their ends.
METAPHASE I:
Following changes occur in this phase:
The bivalent line up at the equatorial plane.
The centromere of each chromosome attaches with same Fibers of spindle.
ANAPHASE I:
At this stage one chromosome from each member of homologous pair (bivalent) begins to
separate and move towards its respective pole by the contraction of spindle fibers.
The actual reduction occurs at this stage because half the number of chromosomes moves to
each pole.
TELOPHASE I:
The nuclear membrane form around the chromosomes at each poleand chromosomes
become uncoil.
The nucleolus reappears and thus two daughter nuclei formed.
CYTOKINESIS:
Telophase may or may not be accompanied by cytokinesis and daughter cells formation.
INTERPHASE:
Following Telophase I (If this stage occurs), there is a short period called Interphase before
meiosis II.
It is similar to Interphase between Mitotic divisions except that DNA replication does not
occur.
Replication of DNA is unnecessary because each chromosome already has two chromatids.
SECOND MEIOTIC DIVISION (MEIOSIS II):
The second meiotic division is actually the mitotic division which divideseach haploid cell
formed during meiosis I into two daughter haploid cells.
The second meiotic division includes:
(1) Prophase II (2) Metaphase II (3) Anaphase II (4) Telophase II
PROPHASE II:
The spindle fibers are formed.
The nuclear membrane and the nucleolus disappear.
METAPHASE II:
The chromosomes are attached to half spindle fibers by their centromere and get arranged at
equatorial plane.
Each chromosome attach with separate fiber of spindle.
ANAPHASE II:
The spindle fibers attached to the centromeres shorten and the chromatids of chromosomes are
pulled away from one another.
This movement continues until one complete set of chromosomes is positioned at each pole of the
cell.
TELOPHASE II:
The spindle fibers disappear completely and chromosomes begin to uncoil.
They become longer and indistinct and form group at each pole. Around each group nuclear
envelope is formed.
After the kayrokinesis in each haploid meiotic cell the cytokinesis i.e. division of cytoplasm occurs
and thus four haploid cells are formed.
50
CHAPTER 06
ENZYMES
DEFINITION
The enzyme are defined as the biocatalyst which facilitate chemical reaction by lowering activation
energy.
CHARACTERISTICS OF ENZYMES
Enzymes are biocatalyst, made up of mostly proteins and therefore three dimensionally folded
chains of amino acids with a specific shape.
Their presence does not affect the nature or properties of end products.
Reactants of enzyme are called substrate.
They are very specific in their action; a single enzyme catalyzes only a single chemical
reaction or a group of related reactions.
A small portion of enzyme where substrate attaches with enzyme is called active site.
The shape of active site is complementary to shape ofthe substrate.
They are sensitive to even a minor change in pH, temperature and substrate
concentration.
Some enzymes require cofactor for their functioning; a cofactor is a non-protein substance
which may be organic or inorganic.
+2 +2 +2 +2 +2 +1 +1
Zn , Mg , Mn , Fe , Cu , K and Na the organic cofactors are NADP, NAD and
FAD are used in enzymes as cofactors.
Many enzymes work in a sequential manner to produce a specific product. This pathway is
called metabolic pathway.
Activity of enzymes can be enhanced by activator and can be decreased by inhibitors.
An enzyme inhibitor is a molecule that binds to an enzyme and decreases its activity.
Since blocking an enzyme's activity can kill a pathogen.
USES OF ENZYMES:
Many enzymes are used commercially in industries.
Paper industry- To get cellulose for paper making.
Food industry- For making bakery products and pizza.
Brewing industry- For conversion of sugar into alcohol.
Bio-detergents- Use to remove different type of stains.
FACTORS AFFECTING THE ACTIVITY OF AN ENZYMES:
Substrate Concentration
Temperature
pH
MECHANISM OF ENZYME ACTION
Enzyme catalyzes the reaction by attaching to substrate which endsto the product formation.
Enzyme exposes its active site to attract specific substrate, makes enzyme substrate complex (ESC)
after which the product is formed and enzyme is detached from it and used again for thesame
reaction.
ACTION OF ENZYME:
In order to understand the mechanism of enzyme action two theoriesare proposed; Lock and key
model and Induced fit model.
THE LOCK AND KEY MODEL:
This theory was first postulated by Emil Fischer in1894 shows thehigh specificity of enzymes.
This theory explains that the enzyme and the substrate possess specific complementary
geometric shapes that fit exactly into one another like a key into a lock.
INDUCED FIT MODEL:
The induced fit model suggested by Daniel Koshland in 1958,
It explains that active site continuously changes its shape until the substratebind to it.
It also says that active site of enzyme is flexible (lock and key theory does not explain it).
CHAPTER 07
BIOENERGETICS
BIOENERGETIC AND ROLE OF ATP
The study of this conversion of free energy into different forms by living organisms is called
Bioenergetics.
It is the part of biology, Physics and chemistry concerned with the energy involved in making and
51
CHAPTER 08
NUTRITION
INTRODUCTION
Process by which organisms obtain and use the nutrients required for maintaining life is called
nutrition.
Essential substances that our body needs in order to grow and stay healthy are known as
nutrients.
There are two processes by which food is obtained or prepared such as:
Autotrophic nutrition - it is the mode of nutrition in which an organism makes its own food
from the simple inorganic materials. The processes are photosynthesis or either
chemosynthesis.
Heterotrophic nutrition - it is the mode of nutrition in which an organism can't make its own
organic material but depends on other organisms for its food and use it for growth and energy.
Nutrition is the study of nutrients in food, how the body uses nutrients,and the
relationship between diet, health, and diseases.
NUTRITION IN PLANTS
There are two main modes of nutrition: autotrophic and heterotrophic.
AUTOTROPHIC NUTRITION:
The term 'autotroph' is derivedfrom two Greek words-autos (self) and trophe (nutrition).
In autotrophicnutrition, an organism makes its own food from simple raw materials.
HETEROTROPHIC NUTRITION:
The word 'heterotroph' is derived from two Greek words-heteros (other) and trophe (nutrition).
Heterotrophic organisms obtain food from other organisms. As heterotrophs depend on other
organisms for their food, they are also called consumers.
All animals, non-green plants like and fungi come under this category.
Consumers which consume herbs and other plants are called herbivores.
Those which consume animals are called carnivores.
Depending upon the mode of living and the mode of intake of food, heterotrophs may be parasitic,
saprotrophic or holozoic.
54
PARASITIC NUTRITION:
Parasitic organisms, or parasites, live on or inside other living organisms, called hosts, and
obtain their food from them.
The host doesnot get any benefit from the parasite.
This mode of nutrition is called parasitic nutrition.
Different parasites, like Cuscuta (akash-bel), hookworms, tapeworms, leeches, etc., have
different modes of feeding, depending upon habit, habitat and modifications.
SAPROTROPHIC NUTRITION:(GR: SAPROS=ROTTEN, TROPHIC=NUTRITION)
Saprotrophic organisms, or saprotrophes, derive their food from dead and decaying organic
material.
This mode of nutrition is calledsaprotrophic nutrition.
Common examples of saprotrophes are fungi (moulds, mushrooms, yeasts) and many
bacteria.
HOLOZOIC NUTRITION: (GR:HOLO=WHOLE, ZOIKOS=OF ANIMAL)
In holozoic nutrition complex organic substances are ingested (taken in) without their being
degraded or decomposed.
This kind of nutrition is found mainly in non-parasitic animals-simple ones like Amoeba and
complex ones like human beings.
HOW ORGANISMS OBTAIN NUTRITION?
Nutrition in unicellular organisms like Amoeba, involves ingestion by the cell surface,digestion
and egestion.
Amoeba takes in complex organic matter as food.
These pseudopodia enclose the food particle and prevent it from escaping.
The food enclosedin the cell membrane forms a food vacuole.
In Paramecium, a unicellular organism with a specific shape, food isingested through a special
opening, the cytostome (cell mouth).
Food is brought to this opening by the lashing movement of cilia that cover the entire surface of
the cell.
MINERAL NUTRITION IN PLANTS
The process involving the absorption, distribution and utilization ofmineral substances by
the plants for their growth and development is called mineral nutrition.
ROLE OF NITROGEN AND MAGNESIUM:
NITROGEN
Nitrogen is essential for plants to synthesize amino acids.
SYMPTOMS OF NITROGEN DEFICIENCY:
Nitrogen-deficient plants exhibit stunted growth, reduced yields and their foliage pale green.
MAGNESIUM
Many enzymes in plant cells require magnesium in order to performproperly and is a constituent
of the chlorophyll molecule, which is the driving force of photosynthesis.
SYMPTOMS OF MAGNESIUM DEFICIENCY:
The predominant symptom is interveinal chlorosis (dark greenveins with yellow areas between the
veins).
The bottom leaves are always affected first.
IMPORTANCE OF FERTILIZERS
Fertilizers are substances containing chemical elements such asmanure or mixture of
nitrates that improves the growth of plants.
They give nutrition to the crops and produce more fruit, faster growth, more attractive
flowers.
ENVIRONMENTAL HAZARDS RELATED TO CHEMICAL FERTILIZERS:
Soil nutrient holding capacity
Eutrophication
Emission of greenhouse gas
Soil acidity
Pest problemsCOMPONENTS OF HUMAN FOOD:
There are seven major classes of nutrients: carbohydrates, protein, fats, minerals, fiber,
vitamins, andwater.
CARBOHYDRATES:
Carbohydrates are necessary for your body specially glucose, whichis primary source of energy.
They are generally divided in two categories: simple carbohydrates such as sucrose, which digest
quickly and complexcarbohydrates such as starch etc, which digest slowly.
55
Sources of simplecarbohydrates include fruits, sugars and processed grains, such as whiterice or
flour.
The complex carbohydrates found in green or starchy vegetables, potatoes, whole grains,
beans and lentils.
The most commonand abundant forms are sugars, fibers, and starches.
PROTEINS
Proteins consist of units called amino acids, attach together in complex formations.
Proteins are complex molecules, the body takes longer to break them down.
As a result, they are much slower and long lasting source of energy than carbohydrates.
There are 20 amino acids.
The body synthesizes some of them from components within the body, but it cannot synthesize
9 of the amino acids called essential amino acids.
They must be consumed in the diet.
The body needs protein to maintain and replace tissues and theirfunction.
Protein is not usually used for energy. However, if the body is not getting enough calories from
other nutrients or from the fat stored in the body, protein is used for energy.
The energy obtained from carbohydrates, proteins, and fats is measured in units called
calories.
FATS
Fats are complex molecules composed of fatty acids and glycerol.
The body needs fats for growth and energy.
It also uses them to synthesize hormones and other substances needed for the body's activities.
Fats are the slowest source of energy but the most energy-efficient form of food.
The body deposits excess fat in the abdomen (omental fat) and under the skin (sub cutaneous fat) to
use when it needs more energy.
The body may also deposit excess fat in blood vessels and within organs,.
Some typical sources of saturated fats include:
o Fatty cuts of beef and lamb.
o High fat dairy foods (whole milk, butter, cheese, sour cream, ice cream)
o Tropical oils (coconut oil, palm oil, cocoa butter)
o Poultry skin.
VITAMINS
A vitamin is an organic molecule (or related set of molecules).
They are for maintaining normal health and development.
Lack of vitamins can cause several diseases.
They are divided into two types:
Fat-soluble Vitamins:
Vitamin which can soluble in organic solvent are called Fat-soluble vitamins (A, D, E and K).
Water soluble Vitamins:
Vitamin which are soluble in H2O.
These are vitamins B and C.
Cooking or heating destroys the water soluble vitamins more readily than the fat-soluble vitamins.
Vitamin generic Deficiency diseases
name
Vitamin K Bleeding disorder
Vitamin D Rickets and osteomalacia
Vitamin C Scurvey
Vitamin B Beriberi
Vitamin A Night blindness, eye-infection, rough skin,
respiratory infections
MINERALS
A class of naturally occurring solid inorganic substances with a characteristic crystalline form.
Minerals are vital for proper human health.
Essential minerals include calcium, iron, zinc, iodine and chromium.
Deficiencies can result in serious health conditions such as brittle bones and poor blood
oxygenation.
Minerals are found in a varietyof foods including dairy and meat products.
56
The demand for energy and most nutrients are relatively high.
Boys need more protein and energy than girls for growth.
Adulthood; a good supply of protein, calcium, iron, vitamin A and D, as part of a healthy,
balanced diet, are important.
Calcium is needed for healthy tooth development, and together with vitamin D, can help
develop strong bones.
Men are more active than women so they need more energy than women of same age group.
Muscular tissues are more in men, their body size is larger, and therefore, boys of growing age need
more body building nutrients (Proteins, Calcium) as compared to girls of same age.
PROBLEMS RELATED TO NUTRITION (MALNUTRITION)
Problems related to nutrition are grouped as malnutrition.
Themalnutrition is a condition that occurs when a body does not get enoughnutrients.
Malnutrition results from a poor diet or a lack of food.
It happens when the intake of nutrients or energy is too high, too low, or poorly balanced.
Consuming less than 2100 calories a day, one is considered to be under-nourished and suffering
from hunger.
There are two types of malnutrition:
Chronic malnutrition: characterized by delayed growth in the children.
Acute malnutrition: Characterized by insufficient weight in relation to the child's height
(emaciation).
Acute malnutrition can be moderate or severe according to the child's weight.
Worldwide, three nutrient deficiencies are of particular concern:
o Vitamin A deficiency is the world's most common cause of preventablechild
blindness and vision impairment.
o Iron deficiency is associated with decreased cognitive abilities andresistance to
disease.
o Iodine deficiency is the major preventable cause of mental retardationworldwide.
PROTEIN DEFICIENCY DISORDERS
Protein energy malnutrition (PEM) refers to inadequate availability or absorption of energy and
proteins in the body.
It is the leading cause of death in children in developing countries. PEM may lead to diseases
suchas;
KWASHIORKOR:
Kwashiorkor is a severe form of malnutrition, caused by a deficiencyin dietary protein.
The extreme lack of protein causes an osmotic imbalance in the gastro-intestinal system
causing swelling of the gut diagnosed as an edema or retention of water .
MARASMUS:
Marasmus is a form of severe malnutrition characterized by energy deficiency.
It can occur in anyone with severe malnutrition but usually occurs in children.
A child with marasmus looks emaciated.
Body weight is reduced to less than 62% of the normal (expected) body weight for the age.
MINERAL DEFICIENCY DISEASE
GOITER:
Goiter is a condition in which thyroid gland becomes enlarged and itresults in swelling in neck.
Goiter is caused by an insufficient amount of “Iodine” in diet.
Iodine is used by thyroid gland to produce hormones that control the body's normal functioning and
growth.
ANEMIA (MOST COMMON OF ALL MINERAL DEFICIENCY DISEASES):
The term anemia literally means “a lack of blood”.
The condition is caused when number of red blood cells reduced to a level lower thannormal.
OVER INTAKE OF NUTRIENTS:
It is a form of malnutrition in which more nutrients are taken than the amount required for
normal growth, development and metabolism.
The effects of over-intake of nutrients are usually intensified when there is reduction in daily
physical activity (decline in energy expenditure).
High intake of carbohydrates and fats leads to obesity, diabetes and cardiovascular problems.
Similarly, high dose of vitamin A causes loss of appetite and liver problems.
Excess dose of vitamin D can lead to deposition of calcium in various tissues.
THE EFFECTS OF MALNUTRITION
Starvation
58
Heart diseases
Constipation
Obesity
THE DIGESTIVE SYSTEM OF HUMAN
Digestion is important for breaking down food into nutrients, whichthe body uses for energy,
growth, and cell repair.
Digestion is the process in which large and non-diffusible molecules of food are converted into smaller
and diffusible molecules that can cross the membranes.
After absorption of the digestible material, indigestible material expelled out of the body through the
process of egestion.
ALIMENTARY CANAL OF HUMAN:
The digestive system is made up of the alimentary canal and the otherabdominal organs that play
a part in digestion, such as the liver and pancreas.
The alimentary canal (also called the digestive tract) is the long tube of organs - including the
esophagus, stomach, and intestines - that runs from the mouth to the anus.
An adult's digestive tract is about 30 feet (about 9 meters) long.
The digestion consists of following steps:
Ingestion: Intake of food.
Propulsion: Peristalsis-alternate waves of muscular contraction and relaxation in the primary
digestive organs.
The end result is to squeeze food from one part of the system to the next.
Mechanical Digestion: Physical preparation of food for digestion. Segmentation: Mixing of food in
the intestines with digestive juices. Chemical Digestion: Carbohydrates, Fat, and Proteins are
broken downby enzymes.
Absorption: Transfer of the digested portion of food into the blood fromthe digestive canal.
Egestion (Defecation): Removal/elimination of the waste products fromthe body.
FUNCTIONS OF ORAL CAVITY:
Digestion begins in the oral cavity, well before food reaches the stomach.
Oral cavity is the space behind mouth in-betweenupper and lower jaw and has many important
functions:
Food Selection:
When food enters the oral cavity it is tasted and felt.
Here food is selected or rejected due to the taste, hard object or dirt. Smell and vision also help in
selection.
GRINDING OF FOOD:
The second function of oral cavity is the grinding of food by teeth.
It is known as chewing or mastication.
It is useful because oesophagus can pass only small pieces through it as well as enzymes cannot
act on large pieces of food.
LUBRICATION OF FOOD:
The third function of the oral cavity is lubrication of food by mixing saliva secreted by saliva.
It has two main functions. (i) Addswater and mucus to the food. (ii) Partial digestion of starch by saliva
whichcontains an enzyme salivary amylase.
CHEMICAL DIGESTION:
Saliva contains an enzyme salivary amylase which helps in the digestion of starch partially.
Than the pieces of food are rolled up by the tongue into small, slippery, spherical mass called bolus.
SWALLOWING OF THE BOLUS:
Swallowing is accomplished by muscle movements by the tongue and mouth, food moves into the
throat, or pharynx.
FUNCTIONS OF PHARYNX AND OESOPHAGUS
The pharynx, a passageway for food and air, is about 5 inches (12.7 centimeters) long.
A flexible flap of tissue called the epiglottis reflexively closes over the wind pipe when we swallow to
prevent choking.
From the throat, bolus travels down a muscular tube in the chest called the esophagus.
Waves of rhythmic movements ofmuscle contractions and relaxation called peristalsis force
down food through the oesophagus to the stomach.
At the end of the oesophagus, a muscular ring called a sphincter allows food to enter the stomach
and then squeezes shut to keep food or fluid fromflowing back up into the oesophagus.
FUNCTIONS OF STOMACH:
Stomach is j-shaped thick walled, expandable bag, located in the left of abdomen just
beneath the diaphragm.
59
The stomach has three regions: cardiac, just after the oesophagus, fundus, the largest part
of stomachand pyloric, part located at the other end of stomach and opens into small intestine
The stomach muscles churn and mix the food with acids andenzymes, breaking it into much
smaller, digestible pieces.
An acidic environment is needed for the digestion that takes place in the stomach.
Glands in the stomach lining produce about 3 quarts (2.8 liters) of these digestive juices each
day.
When food enters into the stomach the gastric juice is secreted by gastric glands found in the
stomach wall.
It is composed of mucous, hydrochloricacid and protein digesting enzyme pe ps i n o ge n .
H y dro c hl o ri c acid c o n v e r t s t he i n a c t i v e e nz y m e pepsinogen into active form called
pepsin.
HCI al so ki ll s m i c r o - organisms present in food.
Stomachis protected against the action of acid by mucus.
Stomach has two sphincters (opening which are guarded by muscles).
The cardiac sphincter is between stomach and oesophagus.
Pyloric sphincter is between stomach and small intestine.
Pepsin partially digests the protein portion of the food into polypeptides and shorter peptide
chains.
In stomach food is further broken apart through a process called churning.
The walls of stomachcontract and relax and these movements help in mixing of the gastric juice
and food.
The churning action also produces heat which helps to melt the lipid contents of the food.
By the time food is ready to leave the stomach, it has been processed into a thick paste like
liquid called chyme.
The pylorus keeps chyme in the stomach until it reaches the right consistency to pass into the small
intestine.
Chyme is then squirted down into the small intestine, where digestion of food continues.
FUNCTIONS OF SMALL INTESTINE:
The small intestine is made up of three parts:
The duodenum, about 25 cm (10 inches) long, C-shaped first part.
The jejunum, the coiled mid section.
The ileum, the final section that leads into the large intestine.
The duodenum receives chyme from the stomach and it is a part of alimentary canal where most of
the digestive process occurs.
Ducts that empty into the duodenum deliver pancreatic juice and bile from the pancreas and liver,
respectively.
Bile salts have detergent action on particles of dietary fat which causes fat globules to break down or
be emulsified into minute, microscopicdroplets.
Pancreatic juice is a liquid secreted by the pancreas, which contains a variety of enzymes, including
protease like trypsinogen, pancreatic lipase and amylase, which digest protein, lipids and
carbohydrates respectively.
Intestinal juices produced from the small intestine contain enzymes andpancreatic juice break down
all four groups of molecules found in food (polysaccharides, proteins, fats, and nucleic acids) into
their componentmolecules.
The inner wall of the small intestine is covered with millions of microscopic, fi ng er -li ke
proj e ctio ns called villi (singular, villus).
LARGE INTESTINE AND ITS FUNCTIONS:
By the time food reaches the large intestine, the work of absorbing nutrients is nearly finished.
The large intestine's main function is to remove water from the undigested matter and form solid
waste that can be egested.
The large intestine is made up of three parts:
The caecum is a pouch at the beginning of the large intestine that joins the small intestine to the
large intestine.
This transition area expands in diameter, allowing food to travel from the small intestine to the
large.
The appendix, a small, hollow, finger-like pouch, hangs at the end of the cecum.
It no longer appears to be useful to the digestive process.
The colon extends from the caecum up the right side of the abdomen, across the upper
abdomen, and then down the left side of the abdomen, finally connecting to the rectum.
The colon has three parts: the ascending colon and transverse colon, which absorb fluids and
60
salts, and the descending colon, which holds the resulting waste (faeces).
Faeces mainly consist of undigested material, large number of bacteria, sloughed off
gastrointestinal cells, bile pigments and water.
Bacteria in the colon help to digest the remaining food products.
The rectum is where faeces are stored until they leave the digestive system through the anus as
a bowel movement.
LIVER AND ITS FUNCTIONS:
The liver produces bile, which helps the body to digest and absorb fat.
Bile is stored in the gallbladder until it is needed.
Bile travels through special channel (bile duct) directly into the small intestine.
The liver also plays a major role in the handling and processing of nutrients, whichare carried to the
liver in the blood from the small intestine.
The liver is a metabolically active organ responsible for many vital lifefunctions.
DISORDERS OF GUT
DIARRHEA:
It is a condition in which the sufferer has frequent watery, loose bowel movements due to fast
peristaltic movement.
This condition may be accompanied by painful abdominal cramps, nausea, fever and
generalized weakness.
CONSTIPATION:
Constipation is a condition, where a person experiences hard faecesthat are difficult to eliminate.
The main causes of constipation are hardening of faeces due to excessive absorption of water
through colon, insufficient intake of dietary fibre, dehydration, use of medicine (e.g. those
containing iron, calcium and aluminum) and tumors in rectum or anus.
To prevent Constipation is easier than treatment.
ULCER (PEPTIC ULCER):
It is a sore in gut lining and can be different organs such as; ulcer of stomach is called “gastric
ulcer”, Ulcer of duodenum is called “duodenal ulcer”, ulcer of oesophagus is called “esophageal
ulcer” and breakdown of tissues by acidic gastric juice.
It can be due to the long term use of anti- inflammatory medicine (e.g. aspirin), smoking, drinking
coffee, colas andeating spicy food.
Few of the signs are as under; abdominal burning after meals, abdominal pain, rush of saliva after
an episode of regurgitation, nausea and loss of appetite and weight.
Ulcer can be treated with medicine, containing (alkaline composition)
CHAPTER 09
TRANSPORT
TRANSPORT SYSTEM
If the distance between source and required organ is small enough, organism does not
require any transport system but if the distance is too long then the organism require to
develop a system called transportsystem.
The transport system requires at least two component.
(i) Transport of raw material from environment to organ where theyrequired for metabolism.
(ii) Transport of metabolites from cell to organs where they require.
TRANSPORT IN PLANTS
ROOT AS IMPORTANT ORGAN FOR WATER AND MINERAL TRANSPORT:
Internally, we can study the root by taking transverse section (T.S.) ofroot.
The T.S. of root shows that root is mainly consist of:
Epidermis (Epiblema) the outer layer of cells, some of these cellshave root hair.
The Cortex part of root between epidermis and endodermis,consist of number of cellular
layers.
WATER AND IONS UPTAKE:
The root absorb water and minerals from soil through root hairs.
There are two processes of transport:
(a) PASSIVE TRANSPORT:
The uptake of water and mineral by osmosis anddiffusion without using energy of ATP.
It is due to concentration gradient i.e. always takes place from high to low quantity of
substances.
(b) ACTIVE TRANSPORT:
Movement of substances from low quantity to high quantity i.e. against the gradient and it
requires energy of ATP.
61
Humidity
Wind
Atmospheric Pressure
TRANSPORT OF WATER AND FOOD IN STEM
Flowering plants have a system of vessels for transport of water, minerals and food.
These vessels are called transport or vascular tissues.
There are two types of transport tissues in plants.
XYLEM (WOOD):
In flowering plants xylem is made up of four type of tissues but the main tissues are the xylem
vessels.
A xylem vessel is a long, hollow, tubular structure from root to leaf. It is made up of many dead
cells arranged vertically.
The walls of these vessels b e c o m e s t r o n g b y t h e d e p o s i t i o n o f c h e m i c a l
substance called lignin.
PHLOEM (BAST):
Like xylem, phloem is also made up of four type of tissues but mainly consist of sieve
tubes and companion cells.
Phloem conducts manufactured food (sucrose) from part of plant where it is synthesized in
high quantity to other parts of plant where it is required.
The sieve tubes or sieve tube elements of phloem is made up of columns of elongated and
thin walled living cells.
The transverse walls separating the cells have lots of minute pores. The cross walls look like a
sieve and therefore called sieve plates.
TRANSPORT OF ORGANIC MATERIALS (FOOD) IN PLANTS:
The movement of organic materials (food) take place through phloem. Along with food, phloem
also conducts other substances such as vitamins, hormones etc.
The movement of prepared food from leaves to different parts of plant through phloem elements
(sieve-tubes) is calledtranslocation.
The excess water is released back into the xylem vessels.
TRANSPORT IN ANIMALS
The system involved inthe transport of various substances within the body of an animal is
calledCirculatory System.
The circulatory system transports gases like O2, CO 2 etc, nutrients, wastes, hormones and
defense proteins.
There are two types of Blood Circulatory Systems found in animals
(i) Open circulatory system
(ii) Closed circulatory system
OPEN CIRCULATORY SYSTEM:
In this type of Circulatory System blood flows through the spaces among tissue so it directly
comes in contact with tissues.
It remains filledin the open tissue spaces called Sinuses.
After exchange of materials with tissues, blood enters the pumping organs or heart which
pumps it into blood vessels.
These vessels again drain out blood into sinuses so it remains in Circulation.
This type of circulatory system found in arthropods and molluscs.
CLOSED CIRCULATORY SYSTEM:
This type of system allows blood to flow inside the closed tubular blood vessels and never comes
out in direct contact with tissues.
TRANSPORT IN MAN
In man, closed type of circulatory system is found, which consists offollowing components.
(i) Blood: A fluid with cells and other dissolved substances.
(ii) Heart: A pumping, pulsatile organ.
(iii) Blood vessels: Tubes i.e. Arteries, veins and capillaries. This is much more
efficient and rapid system of transport.
BLOOD:
Blood is a special type of tissue, found in the form of liquid which circulates in the body.
It transports substances in the body of an organism. It consists of two parts:
(i) Plasma (ii) Corpuscles
PLASMA:
Plasma is the liquid part of blood and constitutes about 55% by volumeof whole blood.
63
2% of Inactivates inflammation
Eosinophils Nucleus bilobed W.B.Cs producing substances, attack
parasite
(B) Agranulocytes
PLATELETS:
Platelets are the fragments of cells which are formed from large precursor cells in the bone
marrow.
On injury, exposure to the air stimulate the platelets at cut end to produce an enzyme in blood.
This enzyme causes the soluble plasma protein fibrinogen to form insoluble
BLOOD DISORDERS:
LEUKEMIA:
It is a type of cancer that affects the blood, bone marrow and lymphatic system.
In this type of blood cancer, number of W.B.Cs increases and R.B.Cs decreases.
SYMPTOMS:
Fever or chill
Persistent fatigue, weaknessFrequent or severe infections
Loss of weight without try Swollen lymph node
Enlarge liver or spleen
Easy bleeding or bruising
Recurrent nose bleeding
64
BIOLOGY CLASS 10
CHAPTER 01
GASEOUS EXCHANGE
INTRODUCTION:
All living organisms exchange oxygen and carbon dioxide gases with their environment to carry out their vital
functions such as respiration.
Plants do carry out gaseous exchange for the process of photosynthesis.
Aquatic organisms exchange gases with water.
Terrestrial ones with air.
GASEOUS EXCHANGE IN PLANTS
Plants exchange gases for the processes of photosynthesis and respiration.
During the process of photosynthesis, carbon dioxide is taken in while oxygen is given out.
In respiration, oxygen is taken in and carbon dioxide is given out. During daytime, green parts of the plants
carry out the process of Photosynthesis.
During this process, carbon dioxide gas is taken in while oxygen gas released as by-product is given out.
Respiration takes place in all living cells.
It is the process in which food is oxidized to release energy.
In aerobic respiration, it involves taking in of oxygen and given out of carbon dioxide.
The process of exchange of gases in plants takes place mainly through minute openings called stomata present
in leaves.
The roots and stem do exchange gases for respiration.
PHOTOSYNTHESIS
1. Anabolic process.
2. Synthesis of food from simple, inorganic substances.
67
CHAPTER 02
HOMOESTASIS
INTRODUCTION
Homeostasis is set of metabolism which maintain internal environment of an organism within suitable limits.
ADAPTATION OF PLANT FOR DIFFERENT INTERNAL CONDITION
There are three main aspect of homeostasis
OSMOREGULATION:
It is the maintenance of internal water and salt conditions by osmosis.
THERMOREGULATION:
The maintenance of temperature within suitable limits where enzymes can work optimally.
EXCRETION:
The process where metabolic toxic waste or excess metabolic substances from body i.e NH3,urea or uric
acid, gums, latex etc.
EXCRETION OR STORAGE OF CO2
At daytime plant perform photosynthesis in green cells and respiration in all living cells.
The CO2 produced in respiration utilized in photosynthesis.
When rate of photosynthesis will be higher than respiration the plant gets extra CO2 from air and release
extra O2 in air through stomata.
At night plant only perform respiration only CO2 is produced which is removed by the process of
diffusion through body surface. The green parts perform these gases exchange through stomata while non
green parts perform this gaseous exchange through body surface.
REMOVAL OF EXTRA WATER
The plant store large amount of water this water can be removed from plant in two ways i.e.
(a) Transpiration
(b) Guttation
Transpiration is the removal of water in the form of vapors from aerial part of plant.
It occurs only at day time.
Guttation is the removal of water in the form of liquid from the margin of leaves through special pores,
hydathodes.
It only occurs at night when water pressure is high in leaves and low temperature environment is present.
Plants modify their leaves size, structure and structure of stomata to control the rate of transpiration.
Plants produce some secondary products like latex, resin and gum. These secondary products are insoluble,
harmless compounds.
Some plants produce special types of gums for example Neem or keeker etc.
The extra amount of these are removed from special pores called lenticels.
The coniferous plants produce resins like material while the rubber plants produce latex which remove from scare
like openings.
Some of these carnivorous plants and okra produce mucilaginous material to capture insects.
OSMOTIC ADJUSTMENT IN PLANTS
The plants grow in different conditions of water and salts, on the basis of water and salt quantity there are four
type of plants
70
(a) Hydrophytes
(b) Halophytes
(c) Mesophytes
(d) Xerophytes
HYDROPHYTES (HYDRO = WATER; PHYTA = PLANTS)
The plant which grow in fresh water; they live completely or partially in fresh water so called totally or partially
submerged plants.
They adapt themselves for removal of excess water which can enter in this condition. These plants do not contain
roots or have poorly developed roots.
They have broad leaves if partially submerged and have stomata at upper epidermis e.g water lilly.
They may have thin and spongy tissues in leaves and stem in totally submerged plant e.g Hydrilla.
HALOPHYTES (HALOS= SALT)
They grow in sea marshes or in saltish water.
In salty condition water moves outside the cell which is not suitable for plants.
To move water from outside to inside the plant develop following characters.
Plants develop salt glands where plant store salts by taking it through active transport.
Plants oppose salt to move outside from vacuole.
Some salt accumulated at surface of leaf which attracts water from air
MESOPHYTES:
The plant grow in moderate water containing soil they will develop following characters.
They have developed root system which do not grow very deep.
They have moderate sized leaves.
XEROPHYTES:
Plants grow in soil of low water quantity.
They grow in desert or steep slopes or at high altitude.
To conserve water and absorb proper amount of H2O they develop following characters.
They have vertically growing deep root system to absorb proper amount of water.
They possess thick waxy cuticles over epidermis to conserve water.
They have short sized leaves or leaves are modi ed into spines to reduce loss of water by reducing the
number of stomata.
Some xerophytes has special parenchyma cells in stem, where they store water, this makes the stem soft,
wet and juicy called succulent organs e.g. cacti.
HOMEOSTASIS IN ANIMAL
OSMOREGULATION IN ANIMALS
Animals also live in aquatic and terrestrial habitat.
According to their environment their cells require more critical balance of water and solutes.
OSMOREGULATION IN AQUATIC ENVIRONMENT
The aquatic conditions are classified on the basis of the concentration of salt present in it.
The water which contains very low amount of salt called fresh water and the water contains high salt called
marine water.
Animal osmoregulate differently in both waters.
OSMOREGULATION IN FRESH WATER
Fresh water animals have hypertonic conditions inside their body or cells so they always facing the problem of
flooding of H2O and loss of salts.
We can classify further these animals in two groups.
UNICELLULAR
Pump out excess water by contractile vacuole e.g. Amoeba, Paramecium etc.
MULTICELLULAR
Loss of salt is compensated by active uptake of salt by gills and skin as well as use of salt containing food.
Pump out excess water by producing dilute urine.
OSMOREGULATION IN MARINE ANIMALS
Usually marine animals have hypotonic conditions (low salt) inside the body but some marine animals develop
hypertonic (high salt) or isotonic (same salt condition) by metabolism.
BONY FISH
Have low salt inside the body
Actively get sea water and have salt glands to increase the salt and desalination
Produce concentrated urine
CARTILAGINOUS FISH
Have high salt by storing urea inside
Eat food which contain nitrogenous compound i.e. meat
71
OSMO CONFORMER
Have equal amount of salt.
These animals do not require any activity to adjust their internal osmotic condition. i.e. unicellular.
OSMOREGULATION IN TERRESTRIAL CONDITION
Terrestrial conditions are harsh for living organism because the direct contact of heat to body causes loss
of water which leads to dehydration, major problem for terrestrial life.
Only arthropods, some molluscs reptiles, birds and mammals can survive in this habitat because:
Their bodies are covered by exoskeleton or thick skin, which prevent loss of water.
They conserve water by reabsorption in kidneys and rectum.
Some of them can produce water from fats catabolism with the help of peroxysomes i.e. camel, kangaroos.
Continuously drinking of water or using liquid food.
EXCRETION
These toxic compounds are mainly NH3 or urea or uric acid generally called nitrogenous waste.
The removal of these nitrogenous metabolic waste is called excretion.
EXCRETION IN ANIMALS
The animal cells produce their nitrogenous waste during metabolism and removed them either in tissue fluid
or in blood.
So the animals develop some organs to filter the tissue fluid or blood. These organs are called excretory organs.
HOMEOSTASIS IN MAN
Humans have well developed homeostasis systems.
The main organs which involved in homeostasis are
(i) Skin
(ii) Lungs
(iii) Kidneys
SKIN:
The skin is considered as the largest organ of the body, basically functions as a protective organ.
It works as a homeostatic organ by maintaining temperature, water and salt.
LUNGS:
They maintain levels of O2 and CO2 in the blood, body fluid and cells.
Maintenance of O2 and CO2 level, maintain rate of respiration and continuous ow of energy.
KIDNEYS:
Kidneys are called filters of the body liquids, they maintain internal water by removing excessive water,
also maintain urea, uric acids, creatinine and other waste by excreting them through urine
STRUCTURE OF HUMAN SKIN
Human skin consists of three layers called epidermis, dermis and hypodermis.
The outer layer of skin is epidermis, made up of fat, dead cells containing keratin protein.
This layer does not contain blood vessels.
It is impermeable to water and prevent water loss from the body as well as work as protective layer by
preventing entry to microorganisms.
Dermis is the layer present between epidermis and hypodermis, it contains many different structures i.e.
nerves ending receptors to detect temperature change, pain, pressure etc.
The dermis also contains sweat glands which secrete sweat on the surface to maintain temperature and
also secrete urea, water and salt.
A network of arterioles are also present in the form of network, which are involved in temperature
regulation.
The dermis also contain hair follicle and sebaceous glands which secrete oily sebum.
Hypodermis is the inner most layer of skin containing fats which act as insulation against loss of heat.
It also stores energy.
ROLE OF SKIN IN REGULATING BODY TEMPERATURE
The skin is the organ which help in regulating body temperature.
IF BODY TEMPERATURE START RISE
Production of sweat:
The sweat gland starts to produce and secrete sweat.
The sweat accumulates at the surface of skin which evaporates with heat energy so the body feels cooling.
Laying down of hairs:
In hot condition, muscles which are attached with hair relax.
It allows the hair to lie at against surface of the skin
72
Vasodilation:
Arterioles found in the form of network in dermis, dilate (become wide) which increase the ow of blood, as
well as it brings the blood vessels near the surface of skin which allows more heat loss.
This process of vessel dilation is called vasodilation.
IN COLD CONDITION WHEN BODY TEMPERATURE STARTS DECREASING
Erection of hairs:
The muscles contract pulling the hairs upright and trapping a layer of insulating air next to skin.
Now it is not very much effective in human.
Vasocontraction:
Narrowing of blood arterioles of dermis occurs which reduces the blood ow in capillaries of skin so less heat is lost.
Decrease in sweat production:
The sweat gland stops to produce and secrete sweat, so air prevent from energy loss.
Increase in metabolic rate:
In cold conditions the rate of metabolism in the organs increases generating more heat which is distributed
around the body in the blood stream.
It prevents loss through the adipose tissue in hypodermis which work as an insulation layer.
ROLE OF LUNGS TO KEEP THE CO2 CONCENTRATION LOW TO CERTAIN LEVEL
Tissue/cells produce a large amount of CO2 during aerobic respiration.
As blood passes through tissues via blood capillaries, this CO2 diffuses into the blood, where it reacts with water form
carbonic acid.
This reaction takes place by an enzyme called carbonic anhydrase present in R.B.C.
The level of H in blood is continuously monitored by special detectors (receptor) carotid bodies and aortic bodies.
Most of the bicarbonate ions diffuse out from R.B.C to blood plasma. A small amount of CO2 is also carried and
dissolved in R.B.C when the blood reaches lungs these bicarbonate ions diffuse back into RBC where again converted
into carbonic acid then into CO2.
The CO2 diffuses out of the blood capillaries and into alveoli, where from it is expelled out when breathing out.
If the CO2 level increases in blood, pH of blood start increasing so that the receptor sends a message to the control
centre which ultimately increases the breathing rate to expel out the CO2 efficiently.
URINARY SYSTEM IN MAN
The urinary system of human is consist of:
• Pair of kidney
• A pair of ureters
• A urinary bladder
• A urethra
Kidneys are reddish-brown bean shaped organs, situated at the dorsal side of the
abdominal cavity on either side of the vertebral column.
The kidneys lie above the waistline.
Each kidney has an area in the center of concave surface which faces the vertebral column; this area is called hillus.
The renal artery, renal vein, nerve and ureter are connected to each kidney at the hillus.
The ureter is a narrow tube which connects the kidney to the urinary bladder.
Urine passes through ureter to the urinary bladder.
The urinary bladder is a thin walled muscular bag situated towards the bottom of abdominal cavity in front of
the rectum which stores urine.
The urethra is a tube which comes out from the urinary bladder, runs down and opens outside the body
through urinary opening. It passes urine from bladder to outside the body.
STRUCTURE OF A KIDNEY
Kidney is enclosed in a membrane called peritoneum.
A fluid filled in between peritoneum and kidney called peritoneal f l u i d w h i c h r e d u c e s t h e friction.
A longitudinal section of kidney shows three main parts: the cortex, the medulla and the Pelvis.
Cortex is the outer dark brown portion.
It is covered and protected by a brous capsule.
The medulla is the inner lighter portion of the kidney.
It contains the conical projection called renal pyramids; the human Kidneys contain 12-16 pyramids.
The medulla contains nephrons.
Nephrons are the basic functional units of the kidney.
These are tiny kidney tubules where osmoregulation occurs to produce urine.
73
TYPES OF COORDINATION:
There are two types of coordination: 1) Chemical Coordination, 2) Nervous Coordination
1) CHEMICAL COORDINATION:
It takes place by releasing specific, signaling molecules such as hormones by special cells or glands.
This kind of coordination is helpful in lower animals as well as plants because of their simple body plans and
small size.
2) NERVOUS COORDINATION:
It is an advance type of coordination exhibited by most of the animals, which is a consequence of specially
designed cell, Neurons.
The neurons upon stimulation generate electrochemical signals. Since the signaling is in electric form so it is
very rapid.
A comparison of Nervous coordination with Chemical coordination:
NERVOUS COORDINATION
1) Activity of Neurons
2) Signal type is electro-chemical
3) Rapid in action
4) Response is shorter duration
5) Advance type of coordination
6) Exclusively related to animals
7) Involves neurotransmitters
CHEMICAL COORDINATION
1) Activity of special secretory cells
2) Signal type is purely chemical
3) Slower in action
4) Response is longer duration
5) Primitive type of coordination
6) Related to all organisms
7) Involves other signaling molecules such as hormones.
COORDINATION IN LOWER ORGANISMS AND PLANTS:
Lower organisms like prokaryotes, protozoa, algae, fungi and plants have chemical coordination through signaling
molecules released usually in the form of hormones to regulate their movements, growth, metabolism,
reproduction, etc.
HUMAN NERVOUS SYSTEM
Human nervous system like other vertebrates is “centralized-type nervous system” (CNS).
Stimuli from various organs of the body are sent simultaneously its control center or central nervous system
where they are integrated, analyzed and processed to develop command in the form of response.
Centralized nervous system consists of two major divisions, viz. Central Nervous System (CNS) and
Peripheral Nervous System (PNS).
CENTRAL NERVOUS SYSTEM:
It is the major command and control center to which stimuli are reported and decisions are made and
conveyed to effector organs.
It consists of two main components, brain and spinal cord.
BRAIN
It is the major command and control center of our body.
It is wrapped in three protective membranes called meninges.
Inside the brain, there are empty cavities or ventricles filled with a cerebro spinal fluid (CSF).
Bones of the skull provide another protection to brain.
Human brain consists of following important parts: Cerebrum, hippocampus, amygdala, thalamus,
hypothalamus, mid-brain, cerebellum, and medulla oblongata.
CEREBRUM:
It is the largest part of the brain where important decisions are made.
It is considered to be the seat of intelligence, all conscious activities and memory.
Its outer part, cortex or gray matter is grayish in color and consists of cell bodies of neurons while inner part white
matter is whitish and consists of cell processes which are hair-like outgrowths.
Cerebrum consists of two hemispheres, i.e. Right and left cerebral hemispheres.
The right cerebral hemisphere regulates the left side of the body
The left cerebral hemisphere to the right side of the body.
The cortex is associated with thoughts, plans, actions and determination.
It can be divided into four sections or lobes, viz., Frontal lobe, Parietal lobe, Temporal lobe and Occipital lobe.
75
In animals, it is a system of ductless glands which secrete hormones directly into the blood.
It carries hormones to their target tissues or organs.
Harmones act like chemical signals or chemical messengers for target organs either stimulating or inhibiting
their function.
Following are important endocrine glands in human body, Pituitary gland, Thyroid gland, Pancreas, Adrenal gland
and Gonads. They are located in different locations in our body.
PITUITARY GLAND:
It is located in brain and considered to be very important. It secretes number of hormones which influence upon other
endocrine glands also besides other organs. Pituitary gland consists of two lobes in human, an anterior lobe or
anterior pituitary gland and a posterior lobe or posterior pituitary gland.
ANTERIOR PITUITARY GLAND:
It has number of hormone secreting cells. Its important hormones and their effect with target organs are
summarized in the table:
Some important hormones of Anterior Pituitary gland, their target organs and important effects
POSTERIOR PITUITARY GLAND:
It is actually stores and releases some hormones of hypothalamus.
Few neurons of hypothalamus store and secrete their hormones from posterior pituitary.Examples of such
hormones are antidiuretic haromone (ADH) and oxytocin.
ADH maintains the blood pressure, blood volume and tissue water.
Oxytocin stimulates greater contraction of smooth muscles as well as social behavior.
THYROID GLAND:
It's a butterfly shaped gland located on trachea in the base of neck.
It secretes thyroxine and calcitonin.
Thyroxine has iodine as its important constituent.
It regulates the rate of the metabolic activities of cells.
It regulates the physical growth and mental development in children.
In case of its deficiency, physical and mental retardation occur in children.
If the intake of iodine in diet is low in adult, the thyroid gradually enlarges in size. This abnormal condition is termed
as “goiter”. Calcitonin released in response to high level of calcium in blood lowers the blood calcium.
PANCREAS:
Pancreas is about 6 inches long, leaf-like in structure located in the abdominal cavity in between stomach
and small intestine.
It is both exocrine as well as endocrine gland in nature.
The endocrine part consists of patches of cells called “Islets of Langerhan's”.
It is involved in regulating glucose metabolism.
In response to high level of glucose, it secretes Insulin which helps in decreasing the blood glucose levels.
On the other hand, low level of blood glucose, it secretes glucagon which increases the glucose level up to
normal.
The regulation of blood glucose through insulin and glucagon is a type of negative feed-back in which
opposite effect is observed in relation to stimulus.
DIABETES MELLITUS:
It's a disorder in which pancreas produces insufficient or no insulin.
As a result, the level of glucose in blood becomes very high.
The excess amount of glucose is excreted in urine so the frequency of passing urine increases many times.
Moreover, the patient feels very thirsty and hungry.
In the absence of using or storing glucose by the cells, the patient losses weight and get tired.
WAYS TO MANAGE DIABETES MELLITUS
• Balanced Diet
• Exercise
• Medication
• Blood Glucose Monitoring
ADRENAL GLAND:
Adrenal gland is located on the top of each kidney.
It is triangular shape and consists of two glands; the outer part is called Adrenal Cortex while the inner one is
Adrenal Medulla. Adrenal Cortex secretes number of steroid (lipid) hormones necessary for regulation of
body metabolism, maintenance of water and salts. Cortisol is one of the important hormones secreted by
adrenal cortex in response to illness or inflammation of any tissue.
It stimulates glucose production.
Adrenal medulla responds to emergency conditions to produce so called “fight or flight response”.
78
It secretes adrenaline or emergency hormone resulting in an increase in blood glucose level by breaking down
of glycogen.
GONADS:
Gonads are the reproductive organs, viz., testes in male while ovaries in female.
They are involved in gametes formation and hormones secretion.
TESTIS:
Each testis is oval shaped structure located in a pouch of skin, scrotum.
It secretes hormone known as testosterone, a type of androgen hormone.
Testosterone is responsible for the development of secondary characteristics in boys like appearance of
moustache and beard, deepening of voice, etc.
OVARIES:
Each ovary is about the size of a grape located in the lower abdominal cavity on either side of uterus.
Ovary secretes estrogen and progesterone hormones.
Estrogen is responsible for the development of secondary characteristics in girls like development of breasts,
sharpening of voice, etc.
Progesterone maintains and prepares uterus for pregnancy.
Feedback control mechanism of hormonal secretion:
Hormone secretion is regulated through feed-back control so that they are secreted whenever required.
There are two types of feed-back systems working in the body, negative and positive feed-back controls.
Negative feed-back control:
It refers to the opposite effect in relation to the stimulus.
For example, if there is an increase in blood glucose level (effect), the pancreas would secrete insulin (response)
which will bring down the blood glucose to its set point.
Positive feedback control:
It refers to enhancement of the effect in relation to stimulus.
For example, when an infant sucks the nipple of his mother's breast, she secretes hormone to secrete milk.
Further continuous sucking increases the hormonal secretion several folds.
DISORDERS OF THE NERVOUS SYSTEM:
PARALYSIS:
It is characterized by partial or complete loss of controlled movement caused by the inability to contract one
or more muscles.
EPILEPSY:
It is a brain disorder in which there is temporary alteration in one or more function or recurrent seizures.
It is due to the abnormal electrical activity in brain.
CHAPTER 04
SUPPORT AND MOVEMENT
INTRODUCTION
The cells of an organism have a living material, protoplasm, which sensitive, due to its sensitive nature it possess special
property called irritability.
Due to this irritability the living organism take some action to reduce its irritation these actions called movement.
The movement can also occur at cellular level, like cyclosis in cell or the movement of chromosomes towards their
respective poles during cell division etc. On the basis of stimuli there are two types of movement
AUTONOMIC OR SPONTANEOUS MOVEMENT
++
It is due to internal stimuli i.e. cramps due to involuntarily release of Ca ions.
Types of movement on the basis of responses.
PARATONIC OR INDUCED MOVEMENT
It is due to external stimuli i.e. reflex action.
LOCOMOTORY MOVEMENT OR TACTIC MOVEMENT.
Types of movement where organisms change its place either towards or away from stimulus.
Usually found in animals, bacteria and protozoa.
TROPHIC MOVEMENT
Types of growth movement organism move toward or away by g r o w i n g th eir organs.
U s u a l l y fou n d in plants, fungi or in bacterial colony.
G r o w t h of root towards water and mineral or growth of stem towards light.
NASTIC MOVEMENT
Typ es of movement wh ere change in osmotic water occur due to stimuli.
79
Purely found in plants like touch m e n o t p l a n t , which close leave when touch.
DIFFERENCE BETWEEN MOVEMENT AND LOCOMOTION
Movement is a broad term where organism response to stimuli in any way whereas locomotion is one of the
type of movement where organism change its place takes place either towards stimuli or away from stimuli.
SKELETON AND ITS TYPES
Skeleton are the frame work which gives shape to any structure. The skeleton performs three main functions
Provide shape to organs
Provide support to organs during movement
Provide protection to soft, vital organs.
TYPES OF SKELETON
There are three main types of skeletons.
1. Hydrostatic skeleton.
2. Exoskeleton
3. Endoskeleton.
HUMAN SKELETON
The skeletal system of human is basically made up of two types of skeletons
1. Cartilage
2. Bones
Both are rigid, cellular structure and type of endoskeleton.
CARTILAGE
Type of skeleton which is flexible.
It is made up of cells called chondrocytes embedded in a matrix of protein called collagen.
It is much softer than bones as well as flexible.
Calcification does not takes place.
It covers ends of the bones and joints.
No blood vessel penetrate into cartilage.
BONES
Type of skeleton which is harder
It is made up of cell called osteocytes embedded in a matrix of protein called collagen.
It is harder due to the deposition of calcium phosphate, process is called calcification.
Calcification takes place.
It support the organ consists of an outer shell of compact bone.
Blood vessels can penetrate into bone esp eci ally in spongy bones.
Skeleton Provide Support and Movement
SKELETAL SYSTEM IS A DYNAMIC SYSTEM
The dynamic property of skeletal system means that it is made up of living tissues, it is capable of quick growth.
It can adapt to stress and can repair itself after damage (injury). 5% to 10% of our bones dissolve away
annually and are replaced by a new one this process is called remodeling.
There are three types of cells associated with bones i.e. bones forming cells (osteoblast), mature bone
cell (osteocyte) and bone dissolving cells (osteoclast).
Bone remodeling is the result of coordinated activity of osteoclast and osteoblast.
HUMAN SKELETON
In humans 206 bones are present which can be categorized into two groups.The axial skeleton
The appendicular skeleton
The axial skeleton forms the main axis of the human body, includes the bone of the head (skull 22 bones ),
vertebral column (26 vertebrae) and rib cage (ribs 12 pairs and sternum 1 bone).
The appendicular Skeleton forms the appendages (Limbs) and their attachment to the axial skeleton includes
pectoral (shoulder) and pelvis (hip) girdles.
Pectoral girdle is consist of two bones i.e. scapula and clavicle.
The forelimb consists of humerus, radius and ulna, carpal (8), metacarpal (5), and phalanges (14).
Pelvic girdle consist of three bones ileum, ischium and pubis
Hind limb consists of femur, patella, tibia, fibula, tarsals (7), metatarsals (5) and phalanges (14).
JOINTS
The junction of two bones is called a joint.
There are two types of joints.Immovable and fixed joint.
Joint where bones are fixed like puzzle pieces and do not allow to move, like 8 bones of skull or 3 bones of pelvic
girdles.
80
Moveable joints where bones are allowed to move freely or partially. So there are two types of moveable joints i.e
freely moveable and partially moveable.
MOVEABLE JOINTS
Freely moveable joints
Hinge joint e.g. elbow, knee, phalanges etc.
Pivot joint e.g. elbow joint.
Ball and socket joint e.g. Hip joint, Shoulder joint.
Partially moveable joints e.g. sternum and ribs
Sliding joint e.g. wrist joint
Gliding Joint e.g. vertebrae
Hinge Joints (e.g. knee joint) allow movement in one plane only whereas ball and socket (shoulder joint)
allow movement in many plans such as forward, backward and sideways.
Both hinge joints and ball socket joints have the same basic structure.
LIGAMENT AND TENDON: THEIR ROLE IN MOVEMENT
The band of fibrous connective tissues by which bones are joined to one another at joints called ligament.
It works as strong firmly attached ropes, it stabilizes the joint or hold the ends of two bones together.T h e s t r o n
g connective tissue in the ligaments p rotects these structures and prevents them from bending twisting.
Skeletal muscles are attached to bones on either side of the joint by bands of tough, fibrous connective tissues
called Tendons.
They are tougher and less elastic than ligaments.
Tendon transfers the mechanical force of muscle contraction to the bones.
It is strongly connected to muscles fiber at one end and to components of the bones at its other end.
They are very strong, highly tensile.
LOCATION AND MOVEMENT OF HINGE JOINT
Hinge joints move back and forth like the hinge on a door and allow movements in one plane only.
The knee and elbow are hinge joints.
LOCATION AND MOVEMENT OF BALL AND SOCKET JOINTS
This joint allows movement in all directions.
The ball of humerus and femur t into the socket of pectoral and pelvic girdle respectively.
The hip and shoulder joints are ball and socket joints.
MUSCLES
Muscles are connective tissues consist of fibrous cells.
These tissues have a tendency to contract and relax.
The vertebrate possess three kind of muscles.
i. Skeletal muscles ii. Cardiac muscles iii. Smooth muscles
SKELETAL MUSCLES
The muscles which are attached to the skeleton called skeletal muscles.
They are associated with the movement of bones.
These muscles are voluntary in nature.
They are also called striped or stride muscles because they have alternate thick and thin means dark and light
bands.
CARDIAC MUSCLES
These are the muscles which build the walls of heart.
They are also striated muscles but unlike skeletal muscles they are branched in nature and arranging mash
work.
They are involuntary in nature, work under the control of SAN (Sino auricular node).
SMOOTH MUSCLES
Smooth muscles are the earliest form of muscles from evolutionary point of view.
They are made up of long and spindle shaped cells, each cell contain single nucleus.
They have no striations or stripes.
They are involuntary in nature.
These muscles are found in blood vessels, digestive tract and many other internal organs.
Support and locomotion is mainly due to skeletal system and skeletal muscles system.
The contraction and relaxation of skeletal muscles allows the bones to move.
The muscles which are attached with bones are called skeletal muscles. These muscles only exert a pulling
force.
When skeletal muscles relax, they are stretched by the contraction of another muscles.
81
CHAPTER 05
REPRODUCTION
INTRODUCTION
One of the processes where living organisms produce offspring of their own kind is called reproduction.
TYPES OF REPRODUCTION
Living organism can produce by two ways
(i) Asexually
(ii) Sexually
ASEXUAL REPRODUCTION
Type of reproduction which takes place without fusion of male and female gametes (sex Cells).
In this type of reproduction only one parent is involved.
The off springs are exactly similar to their parent.
Organisms are gen etically similar to each other as well as to their parent.
No new combination of genes (genetic recombination) occurs.
SEXUAL REPRODUCTION
Types of reproduction which takes place by the fusion of male and female gamete (sex cells).
In this type of reproduction usually two parents of opposite sexes are involved.
The off springs are not exactly similar to any one of the parent.
Organisms are gen etically dissimilar to each other as well as to their parent.
Genetic recombination occurs which causes variation and leads to evolution.
ASEXUAL REPRODUCTION IN PROTISTS, BACTERIA AND PLANTS
The bacteria, protists and plants reproduce asexually by a number of methods, whereas Bacteria only reproduce
by asexual reproduction.
Some of the asexual methods of reproduction in plants are described below.
1. BY FISSION (SPLITTING):
The splitting of cell into two or more cells is called Fission.
Fission is of two types. I.e. binary fission or multiple fission.
2. BINARY FISSION:
Type of fission where a mother cell divides into two daughter cells.
3. It takes place in bacteria under favorable conditions of temperature, nutrition and moisture, single
bacterium divides into two bacteria within 20 minutes and numerous bacteria are produced within very short
interval of time.MULTIPLE FISSION:
Type of fission where a mother cell divide into more than two daughter cells
4. BUDDING:
In this type of asexual reproduction the parent cell forms a small out growth which is called bud.
This bud detach from parent cell or body and grows into new organism. It takes place in yeast and plants.
5. BY SPORES
In fungi, algae and plants asexual reproductive structure sporangium is developed on their body.
These sporangia produce numerous unicellular spores. Spores are very small and light usually they dispersed by
wind.
Spores have thick, resistant walls which enable them to survive in unfavorable conditions.
When these spores drop on proper substratum, they develop into new organism in favorable conditions.
6. VEGETATIVE PROPAGATION
Vegetative means non-reproductive part of plant like, thallus, root, stem and leaf.
If any of this part develop into new plant called vegetative propagation.
Vegetative Propagation
It is natural development of new plant without human efforts.
Natural vegetative propagation usually occurs by root, stem, or leaves.
S t e m ; R u n n e r s g r o w horizontally above the ground.
Roots; new plant emerges out of swollen modified root known as tuber.
L e a v e s ; o f a f e w p l a n t s detached from parent plant and develop into new plant e.g. Bryophyllum.
Artificial Propagation
It is the method of development of new plant with the help of human efforts.
Artificial propagation can occur from cells, tissues, cutting of stem etc.
The method are
Tissue culture, Cutting, Grafting, Layering, Budding
Root may be used for artificial propagation
Any leave tissue may also use for artificial propagation.
83
Pollen grain develops in pollen sac of anther form microspore in the form of loose, dusty powder.
Each pollen grain is 4 celled structure, bounded by wall which consists of 2 layers, outer, the exine and inner,
the intine.
In angiospermic plants the main plant is sporophyte which consists of vegetative and floral parts.
The vegetative parts are root, stem and leaves while flower, fruit, seed are floral parts which develop from flower.
The floral part is reproductive part.
After two processes i.e. pollination and fertilization, it produces seed within fruit.
The seeds when disperse germinate into baby plant called seedling, when matures, it become a new plant like its
parents.
In flower androecium (male part) is consist of stamen (microsporophyll) has 2 to 4 pollen sac (microsporangia) in its
anther. These pollen sac are filled with microspore mother cell which produce microspore by meiotic cell division.
Each unicellular microspore divide its cells by mitosis and produce 2 to 4 cells, in this way unicellular
microspore become pollen grain (multicellular) but each of its cell is haploid.
When anther burst these pollen grains disperse in nature.On the other hand each carpel (megasporophyll)
has one or more ovules (megasporangium) in its ovary.
Each ovule has single megaspore mother cell.
This megaspore mother cell divided by meiosis to produce 4 haploid megaspores.
Only one will survive and develops into embryo sac (female gametophyte) inside ovule, which consists of 7
cells
The pollen grain disperse if dropped at the stigma of carpel the life cycle remain continues.
POLLINATION
Pollination is the process in which pollen
grains are transferred from anther to stigma of
carpel.TYPES OF POLLINATION
Self-pollination
Cross pollination
SELF-POLLINATION
It is the transfer of pollen grains from anther of stamen to the stigma of same
flower.
CROSS POLLINATION
It is the transfer of pollen grains from anther of one flower to stigma of other flower belongs to another plant of
same species.
Cross pollination is more common than self- pollination, the pollen grains are carried from one flower to
another flower through following agents.
(i) Wind
(ii) Water
(iii) Insects
(iv) Animals
CROSS POLLINATION
When pollen grain drops at stigma, it starts its development into pollen tube (male gametophyte), which
consists of 6 haploid cells, among them two are prothallial cells, two are male gametes, one stalk nucleus and
one tube nucleus.
The pollen tube grows from stigma to ovule through style and transfers two male gametes in ovule through
micropyle which ultimately reach to embryo sac.
One sperm nucleus fuses with ovum to produce diploid (2N) zygote while other gamete fuses with secondary
nucleus to form 3N (Triploid) cell which later develop into endosperm of seed.
This type of fertilization is called double fertilization which is the characteristic feature of angiospermic plant.
The 2N zygote after successive mitotic divisions develops into an embryo within the embryo sac, whereas
triploid (3N) secondary nucleus develops into endosperm.
The endosperm provides nourishment to the developing embryo.
During this development the ovule develops into seed the integument develop into seed coat whereas zygote
form small embryo and cotyledon during this the ovary outside ovule become swollen due to mitotic cell
division and become fruit.
Formation of fruit with out fertilization
Some fruit may formed without fertilization. This mechanism is called parthenocarpy i.e formation of seedless
fruit, like banana.
SEED AND ITS STRUCTURE
Seed may be defined as ripened ovule or it is fertilized, developed ovule which contains dormant embryo.
The seed consists of following parts:
1. Seed Coat
85
2. Embryo
3. Cotyledon
4. Sometime endosperm
The outer wall of seed which develops from integument of ovule called seed coat.
The seed coat consists of an outer thick layer called testa and inner thin wall called tegmen.
The embryo develops from diploid zygote. It is a small axis, lying between two cotyledons, the upper end
called plumule and the other lower end is called radicle.
The seed also contains leaf-like structure called cotyledon.
These are either one or two on the basis of these numbers the seeds are classi ed into monocot or dicot
seed, respectively.
The hilum is a scare, present at seed coat.
The water enters into the seed through a very small hole in the seed coat this pore is called micropyle.
In some monocot seeds, ripened ovary walls called pericarp.
Internally maize grain is divided into two unequal parts by a thin layer of cells called epithelium.
The larger portion is the endosperm and the smaller is embryo. In the embryonic part, a shield shaped
cotyledon is present called s c u t e l l u m .
Moreover t h e plmule and radicle are enclosed in protective sheath called coleoptile and coleorhiza,
respectively.
GERMINATION OF SEED
Breaking of seed dormancy is called seed germination.
As a result of germination seed develops into seedling.
CONDITIONS NECESSARY FOR SEED GERMINATION
Role of water (Moisture)
Role of oxygen
Temperature
Types of germination
EPIGEAL GERMINATION (Epi = above, geo = earth)
The type of germination where seeds come above the soil during germination.
The growth rate of hypocotyl is higher than epicotyl.
The hypocotyl grow in the form of arch.
The cotyledons become green when come above the soil and work as 1st foliage leaves.
HYPOGEAL GERMINATION (Hypo = below, geo = earth)
The type of germination where seeds remain in the soil during germination
The growth rate of epicotyl is higher than hypocotyl.
The hypocotyl does not grow in the form of arch.
The cotyledons do not turn green.
REPRODUTION IN ANIMALS
There are also two types of reproduction in animal. i.e. Asexual and sexual reproduction.
ASEXUAL REPRODUCTION
Animals reproduce asexually by different methods, some of them are as follows.
1. FISSION (SPLITTING)
Splitting of cell into two or many cells or organisms called fission.
2. BINARY FISSION:
The type of fission where an organism divides into two organisms is called binary fission.
It is commonly observed in unicellular organisms like protozoa. During this process the nucleus of the
parent organism divides into two nuclei, both of them move in opposite directions in the cytoplasm.
Meanwhile, a construction appears in cytoplasm which deepens from outside to inside finally organism
divides into two organisms.
3. MULTIPLE FISSION
Multiple fission involves the division of an organism into many small sized daughter organisms as found in
Plasmodium.
4. BUDDING
In this method one or more out growth develop on the body surface of organism which are called buds.
When buds separates from the parent body starts living independently and develop into new organism
e.g. Hydra.
5. FRAGMENTATION
It is found in lower, multicellular animals like liver fluke and nematodes.
When a living organism divides into fragments, each fragment recovers its lost part by regeneration and
develops into new organism.
SEXUALREPRODUCTION
The process of sexual reproduction involves fusion of specialized haploid sex-cells or gametes to form a single
86
In human body cells, there are 23 pairs of homologous chromosomes for a total of 46 chromosomes.
Chromosome is made of chromatin material (simply as chromatin).
Chromatin is a complex material, made of DNA and proteins (mainly histone proteins).
DNA wraps around histone proteins and forms round structures, called nucleosomes.
DNA is also present between nucleosomes.
In this way, the nucleosomes and the DNA between them look like “beads on a string”.
The fibres consisting of nucleosomes condense into compact forms and get the structure of chromosomes.
WATSON-CRICK MODEL OF DNA
In 1953, James Watson and Francis Crick proposed the structure for DNA.
According to the Watson-Crick model, a DNA molecule consists of two polynucleotide strands.
These strands are coiled around each other in the form of a double helix.
There is a phosphate- sugar backbone on the outside of double helix, and the nitrogenous bases are on the inside.
In double helix, the nitrogenous bases of opposite nucleotides form pairs through hydrogen bonds.
The nitrogenous base adenine of one nucleotide forms pair with the thymine of opposing nucleotide, while cytosine
forms pair with guanine.
There are two hydrogen bonds between adenine and thymine and there are three hydrogen bonds between
cytosine and guanine.
DNA REPLICATION
During (cell cycle) that before a cell divides, its DNA is replicated (duplicated).
It is done to make the copies of the chromatids of chromosomes.
During replication, the DNA double helix is unwound and the two strands are separated.
Each strand acts as a template to produce another strand.
Its Nitrogen- bases make pairs with the Nitrogen-bases of new nucleotides.
In this way, both template strands make new polynucleotide strands in front of them.
Each template and its new strand together then form a new DNA double helix, identical to the original.
DNA
DNA is the genetic material i.e. it contains the instructions to direct all the functions of cells.
It performs its role by giving instructions for the synthesis of specific proteins.
Some proteins perform structural roles while the others act as enzymes to control all biochemical reactions of cells.
In this way, whatever a cell does, is actually controlled by its DNA.
In other words, DNA makes the characteristic or trait of cell or organism.
DNA controls the sequence of amino acids by the sequence of its nucleotides.
During protein synthesis, the sequence of DNA nucleotides decides what will be the sequence of amino acids.
For this purpose, the specific sequence of DNA nucleotides is copied in the form of messenger RNA (mRNA)
nucleotides.This process is called transcription.
The mRNA carries the sequence of its nucleotides to the ribosome.
The ribosome reads this sequence and joins specific amino acids, according to it, to form protein. This step is
known as translation. The part of DNA (sequence of nucleotides) that contains the instructions for the
synthesis of a particular protein is known as a gene.
The locations or positions of genes on chromosomes are known as loci (Singular: locus).
For convenience, pairs of genes are represented by a letter or symbol.
The alternate forms of a gene are called alleles.
If an individual has Aa gene pair, ‘A’ and ‘a’ are the alleles of one another.
In this individual, allele ‘A’ is located on one of the two homologous chromosomes and the allele ‘a’ is on the
other chromosome.
When chromosomes separate during meiosis, alleles also separate and each gamete gets one of the two
alleles. When gametes of both parents unite, the zygote (and the offspring also) receives one allele from each
parent.
GENOTYPE AND ITS TYPES
The specific combination of genes in an individual is known as genotype.
It is of two types i.e. homozygous and heterozygous. The genotype in which the gene pair contains two
identical alleles (AA or aa), is called homozygous genotype.
The genotype in which the gene pair contains two different alleles (Aa), is called heterozygous genotype.
When in the heterozygous condition one allele masks or prevents the expression of the other, it is called the
dominant allele.
The allele which is not expressed is called recessive.
The dominant alleles are represented by capital letters and recessive alleles by lower case letters.
Albinism is a recessive trait i.e. it is produced when both alleles are recessive.
In humans, allele ‘A’ produces normal body pigments while allele ‘a’ does not produce pigments.
If genotype is AA or Aa, the individual will produce pigments.
88
On the other hand, if genotype is aa, no pigments will be produced and the individual will be albino.
The allele ‘A’ dominates over ‘a’, because in Aa indiviual pigments are produced and the effect of ‘a’ is
suppressed by ‘A’. The expression of this genotype in the form of trait is known as the phenotype.
MENDEL’S LAWS OF INHERITANCE
Gregor Mendel was a monk (priest) in Austria.
He developed the fundamental principles of genetics.
Mendel proposed that there are “special factors” in organisms, which control the expression of traits and their
transmission to next generations.
These factors were eventually termed genes.
Mendel selected pea plant (Pisum sativum) to carry out a large number of experiments.
He argued that an organism for genetic experiments should have the following features:
There should be a number of different traits that can be studied.
The organism should have contrasting traits e.g. for the trait of height there should be only
two very different phenotypes i.e. tallness and dwarfness.
The organism (if it is a plant) should be self-fertilizing but cross fertilization should also be
possible.
The organism should have a short but fast life cycle.
All these features are present in pea plant.
Normally, the flowers of pea plant allow self-pollination.
Mendel’s Law of Segregation
Mendel studied the inheritance of seed shape first. For this purpose, he crossed (reproduced) two plants
having one contrasting trait i.e. seed shape.
A cross in which only one trait is studied at a time, is called as a monohybrid cross.
Mendel crossed a true-breeding round-seeded plant with a true-breeding wrinkled-seeded plant.
All resulting seeds of the next generation were round.
Mendel declared the trait “round seeds” as dominant, while “wrinkled seeds” as recessive. The following year,
Mendel planted these seeds and allowed the new plants to self-fertilize. As a result, he got 7324 seeds: 5474 round and
1850 wrinkled (3 round : 1wrinkled).
The parental generation is denoted as P1 generation.
The offspring of P1 generation are F1 generation (first filial).
The cross in F1 generation produces F2 generation (second filial).
Similarly, when “true-breeding” tall plants were crossed with “true-breeding” short plants, all offspring of F1
were tall plants i.e. tallness was a dominant trait.
When members of F1 generation were self-fertilized, Mendel got the ratio of tall to short plants in F2 as 3:1.
LAW OF SEGREGATION
Mendel concluded that the traits under study were controlled by discrete (separable) factors or genes. In each
organism, the genes are present in pairs. During gamete formation, the genes (alleles) of each pair segregate from
each other and each gamete receives one gene from the pair.
When the gametes of male and female parents unite, the resulting offspring again gets the genes in pairs. These
conclusions were called the Law of Segregation.
Mendel’s Law of Independent Assortment
In the next crosses, Mendel studied two contrasting traits at a time. Such crosses are called dihybrid crosses.
He performed experiments on two seed traits i.e. shape and colour.
The trait of round seeds (controlled by allele R) was dominant over wrinkled (controlled by allele r) seeds.
Similarly, yellow seed colour (controlled by Y) was dominant over green (controlled by y).
Mendel crossed a true breeding plant that had round yellow seeds (RRYY) with a true breeding plant having wrinkled
green seeds (rryy).
All seeds in F1 generation were round yellow.
When F1 seeds grew into plants, they were self-fertilized. This cross produced seeds with four phenotypes.
There were 315 round yellow seeds, 108 round green seeds, 101 wrinkled yellow seeds and 32 wrinkled green
seeds.
The ratio of these phenotypes was 9:3:3:1.
The Punnett square is a diagram that is used to predict an outcome of a particular cross or breeding experiment.
It is named after R. C. Punnett (an English mathematician).
Mendel explained that the two traits i.e. seed shape and seed colour are not tied with each other. The segregation of
‘R’ and ‘r’ alleles happens independently of the segregation of ‘Y’ and ‘y’ alleles. From his second experiment, Mendel
concluded that different traits are inherited independently of one another. This principle is known as the law of
independent assortment.
It states as: “the alleles of a gene pair segregate (get separated and distributed to gametes) independently from the alleles
of other gene pairs”.
89
vegetables.
In artificial selection, humans favour specific variations for selection while in natural selection the environment selects
or rejects variations.
CHAPTER 07
MAN AND HIS ENVIRONMENT
INTRODUCTION
An organism’s environment is the sum of physical (abiotic) and biological (biotic) conditions which influence that
organism.
The study of the interrelationship between organisms and their environment is called ecology.
LEVELS OF BIOLOGICAL SELECTION
In ecology, the levels of organization range from organism to biosphere.
An organism may be unicellular or multicellular.
A group of the organisms of the same species inhabiting a specific geographical area (habitat) at a particular time is
called a population.
All the populations that live in a habitat and interact in various ways with one another are collectively called a
community.
The biotic and abiotic components of environment interact with each other to form a system. The self-sufficient unit
of an environment that is formed as a result of interactions between its biotic community and the abiotic components
is known as an ecosystem.
A pond, a lake and a forest are examples of natural ecosystems.
Ecosystems may also be artificial for example an aquarium.
All ecosystems of the world together form the biosphere.
It includes all the ecosystems of the planet Earth.
In other words, the biosphere consists of all organisms present on the Earth and all regions of the Earth where they
live.
Biosphere ranges from the floor of oceans to the tops of the highest mountains. It is about 20 kilometres thick.
COMPONENTS OF ECOSYSTEM
An ecosystem comprises of two basic parts i.e. abiotic components and biotic components. The abiotic components
include the non-living factors present in ecosystem.
The important non-living factors are light, air, water, soil and the basic elements and compounds.
The biotic components comprise the living part (organisms) of the ecosystem.
Biotic components are further classified as producers, consumers and decomposers.
The producers are the autotrophs present in an ecosystem.
Producers include plants, algae and photosynthetic bacteria.
These organisms are able to synthesize complex organic compounds (food) from inorganic raw materials.
In terrestrial ecosystems, plants are the main producers.
In aquatic ecosystems, the main producers are the floating photosynthetic organisms (mainly algae) called
phytoplankton and shallow water rooted plants.
The consumers are heterotrophs.
They cannot synthesize their food and so depend upon producers for food.
Consumers include all animals, fungi, protozoans and many of the bacteria.
The animals are the major consumers of ecosystems.
They are further classified as herbivores and carnivores.
Herbivores e.g. cattle, deer, rabbit, grasshopper etc. feed on plants.
They are the primary consumers.
They feed directly on plants or products of plants.
Carnivores feed on other animals.
Primary carnivores (secondary consumers) feed on herbivores.
Fox, frog, predatory birds, many fishes and snakes etc. are primary carnivores.
Secondary carnivores (tertiary consumers) feed on primary carnivores.
Wolf and owl etc. are secondary carnivores.
Tertiary carnivores e.g. lion, tiger etc. feed on secondary carnivores
Decomposers or reducers break down the complex organic compounds of dead matter (of plants and animals) into simple
compounds.
They secrete digestive enzymes into dead and decaying plant and animal remains to digest the organic material.
After digestion, decomposers absorb the products for their own use.
Many types of bacteria and fungi are the principal decomposers of biosphere.
The minerals, which are released by decomposers, are used as nutrients by the producers.
91
The balance of carbon cycle has been upset by human activities such as deforestation and excessive burning of
fossil fuels.
NITROGEN CYCLE
Nitrogen is an important component of many biomolecules, like proteins and nucleicacids (DNA and RNA).
Atmosphere is the reservoir of free gaseous nitrogen.
Living organisms cannot pickup this gaseous nitrogen directly from atmosphere (except for nitrogen fixing bacteria).
It has to be converted into nitrates to be utilised by plants. Nitrogen cycling involves several stages:
FORMATION OF NITRATES
It is done by the following ways:
NITROGEN FIXATION
Conversion of nitrogen gas into nitrates is called nitrogen fixation.
It occurs in the following ways.
Thunderstorms and lightning convert atmospheric gaseous nitrogen to oxides of nitrogen. These oxides dissolve in water
and form nitrous acid and nitric acid. The acids in turn combine with other salts to produce ‘nitrates’. It is called as
atmospheric nitrogen fixation.
Some bacteria also have the ability to transform gaseous nitrogen into nitrates. It is called biological nitrogen
fixation.
Some of these nitrogen fixing bacteria live as symbionts and many are free-living.
Nitrogen fixation is also done in industries.
In industrial nitrogen fixation, hydrogen is combined with atmospheric nitrogen under high pressure
and temperature.
It produces ammonia which is further converted into ammonium nitrate
AMMONIFICATION AND NITRIFICATION
Ammonification is the breakdown of the proteins of dead organisms and nitrogenous wastes (urea, uric acid
etc.) to ammonia.
It is done by ammonifying bacteria.
After the formation of ammonia, it is converted into nitrites and nitrates. It is called nitrification and is done by
nitrifying bacteria.
First, ammonia is converted into nitrites by bacteria (e.g. Nitrosomonas).
The nitrites are then converted into nitrates by other bacteria (e.g. Nitrobacter).
ASSIMILATION
The utilization of nitrates by organisms is called assimilation.
DENITRIFICATION
It is a biological process in which nitrates and nitrites are reduced to nitrogen gas by denitrifying bacteria.
By this process, nitrogen is returned to atmosphere.
INTERACTIONS IN ECOSYSTEMS
In all ecosystems, there are many kinds of interactions among living organisms.
The interactions between the members of the same species are called intraspecific interactions
while the interactions between the members of different species are called interspecific interactions.
Some important interactions among living organisms in ecosystems are given below.
COMPETITION
There is a competition among the organisms of ecosystem for the utilization of resources.
The competition may be intraspecific or interspecific.
Intraspecific competition is always stronger and more severe than the interspecific competition.
PREDATION
It is an interaction between two animals of different species or between a plant and an animal.
In predation, one organism (the predator) attacks, kills and feeds on other organism (the prey). Some examples of
predation are given below.
All carnivore animals are predators.
SYMBIOSIS
It is a relationship between members of different species, in which they live together for longer or shorter periods of
time.
Symbiosis is of three types.
PARASITISM
It is a type of symbiosis (between members of different species), in which smaller partner (parasite) derives food and
shelter from the body of larger partner (host) and, in turn, harms it.
In temporary parasitism, the parasite spends most of its life cycle as independent free-living organisms.
Leech, bed bug, mosquito are common temporary parasites of humans.
In permanent parasitism, the parasites spend their whole life cycle as parasites.
Many disease causing bacteria and all viruses are permanent parasites.
93
CHAPTER 08
BIOTECHNOLOGY
INTRODUCTION OF BIOTECHNOLOGY
Biotechnology is defined as the use of living organisms in processes for the manufacture of useful products or for services.
Genetic engineering i.e. the artificial synthesis, modification, removal, addition and repair of the genetic
material (DNA) is considered as modern biotechnology.
The work on genetic engineering started in 1944 when it was proved that DNA carries the genetic information.
In 1970s, they were able to cut and paste the DNA of organisms.
In 1978, scientists prepared human insulin by inserting the insulin gene in bacteria.
Human growth hormone was also synthesized in bacteria.
In 1990, the Human Genome Project was launched to map all the genes in human cell.
The complete map of human genome was published in 2002.
FERMENTATION
Fermentation is the process in which there is incomplete oxidation-reduction of glucose.
Fermentation has been in the knowledge of man since centuries, but it was believed that it is purely a chemical
process.
In 1857, Pasteur convinced the scientific community that all fermentations are the results of microbial activity.
There are many kinds of fermentation and each kind is a characteristic of particular microbial group.
Fermentations are classified in terms of the products formed.
The initial steps of carbohydrate fermentation are identical to those of respiration.
The two basic types of carbohydrate fermentation are described next.
Alcoholic Fermentation (by yeast)
This fermentation is carried out by many types of yeast such as Saccharomyces cerevisiae.
This process is quite important and is used to produce bread, beer, wine and distilled spirits.
Lactic Acid Fermentation (by bacteria)
In this process, pyruvic acid is educed to lactic acid.
It is carried out by many bacteria e.g. Streptococcus and many Lactobacillus species.
It is quite important in dairy industry where it is used for souring milk and also for production of various types of
cheese.
FERMENTER
Fermenter is a device that provides optimum environment to microorganisms to grow into a biomass, so that
they can interact with a substrate, forming the product.
Fermentation is carried out in fermenters, in the batch fermentation and continues fermentation.
GENETIC ENGINEERING
Genetic engineering or recombinant DNA technology involves the artificial synthesis, modification, removal, addition and
repair of the genetic material (DNA).
OBJECTIVES OF GENETIC ENGINEERING
The important objectives of genetic engineering are as follows.
• Isolation of a particular gene or part of a gene for various purposes such as gene therapy
• Production of particular RNA and protein molecules
• Improvementintheproductionofenzymes,drugsandcommerciallyimportantorganicchemicals
• Production of varieties of plants having particular desirable characteristics
• Treatment of genetic defects in higher organisms
BASIC STEPS IN GENETIC ENGINEERING
All the above mentioned objectives can be obtained by some basic methodologies, such as:
Isolation of the gene of interest
95
Antibiotics inhibit or kill bacteria and treat bacterial infections e.g. tetracycline, cephalosporin etc.
Sedatives induce sedation by reducing irritability or excitement e.g. diazepam.
Vaccinesareusedtodevelop immunityagainstviralandbacterialinfectionse.g.vaccinesagainst small pox, whooping cough,
hepatitis B etc.
Antiseptics reduce the possibility of infections on skin
Antibiotics inhibit or kill bacteria within or on the body
Disinfectants destroy microorganisms found on non-living objects.
Joseph Lister (1827 – 1912) was an English surgeon. He promoted the idea of sterile surgery for the first time. He
introduced carbolic acid to sterilise surgical instruments and to clean wounds.
ADDICTIVE DRUGS
The following are major categories of addictive drugs:
SEDATIVES
These drugs interact with central nervous system to depress its activities. Sedative drugs induce dizziness, lethargy,
slow brain function and depression. Long-term use of sedative induce suicidal thoughts.
NARCOTICS
Narcotics are strong painkillers.
These are used to relieve pain for patients with chronic diseases such as cancer.
These are also used to relieve acute pain after operations.
But some people may abuse narcotics for ecstatic effects.
Morphine and codeine are the narcotics, derived from opium (poppy). Morphine acts directly on central nervous
system to relieve pain.
Morphine has a high potential for addiction.
The most commonly abused narcotic i.e. heroin is a semi-synthetic drug from morphine.
It effects on central nervous system and causes drowsiness.
HALLUCINOGENS
Hallucinogens are the drugs that cause changes in perception, thought, emotion and consciousness.
The group includes mescaline, which comes from a cactus and psilocin, which comes from a mushroom.
Physiologically, hallucinogens affect on the sympathetic nervous system, causing dilation of pupils, constriction
of some arteries and rise in blood pressure.
MARIJUANA (HASHISH)
Marijuana is a hallucinogen, which is smoked.
It is obtained from the flowers, stems, and leaves of the marijuana plant (Cannabis sativa and C. indica).
ANTIBIOTICS AND VACCINES
Two important medicinal drugs are antibiotics and vaccines.
ANTIBIOTICS
An antibiotic is a drug that kills or retards the growth (reproduction) of bacteria.
They are the chemicals produced by or derived from microorganisms (bacteria and fungi).
BACTERICIDAL AND BACTERIOSTATIC ANTIBIOTICS
Antibiotics are used to treat many different bacterial infections.
Some antibiotics are ‘bactericidal’, meaning that they kill bacteria.
Others are ‘bacteriostatic’, meaning that they work by stopping bacterial growth.
Three major groups of antibiotics are described below.
CEPHALOSPORINS
Cephalosporins interfere with synthesis of bacterial cell wall and so are bactericidal.
Cephalosporins are used to treat pneumonia, sore throat, tonsillitis, bronchitis etc.
TETRACYCLINES
These are broad-spectrum bacteriostatic antibiotics and inhibit bacterial protein synthesis.
Tetracyclines are used in the treatment of infections of respiratory tract, urinary tract, intestine etc.
Tetracyclines are not used in children under the age of 8, and specifically during periods of tooth development.
SULPHA DRUGS - SULFONAMIDES
Sulpha drugs are synthetic antibiotics that contain sulfonamide group. Sulfonamides are broad spectrum
bacteriostatic antibiotics.
They inhibit the folic acid synthesis in bacteria.
They are used to treat pneumonia and urinary tract infections.
VACCINES
A vaccine is a material containing weakened or killed pathogens and is used to produce immunity to a disease by
stimulating the production of antibodies.
In 1796, a British physician, Edward Jenner, infected a young boy with cowpox, by injecting pus cells.
After the boy had recovered from cowpox, Jenner injected the pus cells from a smallpox patient into him.
The boy did not get smallpox.
97
So it became clear that intentional infection with cowpox protected people from smallpox. This method was named
“vaccination” and the substance used to vaccinate was called a “vaccine”.
THE MODE OF ACTION OF VACCINES
Pathogens contain special proteins called “antigens”.
When pathogens enter the body (blood) of host, these proteins stimulate the immune response in host i.e. synthesis of
“antibodies”.
Antibodies bind to pathogens and destroy them.
In addition, “memory cells” are produced, which remain in blood and provide protection against future infections with
the same pathogen.
B-lymphocytes recognize the weakened or dead pathogens as enemies and start producing antibodies against them.
These antibodies remain in blood and provide protection against pathogens.
If real pathogens enter blood, the already present antibodies kill them
CHEMISTRY CLASS 09
CHAPTER 01
FUNDAMENTALS OF CHEMISTRY
INTRODUCTION
The branch of science which deals with the composition, structure, properties and reactions of matter is called
chemistry.
BRANCHES OF CHEMISTRY
PHYSICAL CHEMISTRY
Physical Chemistry is defined as the branch of chemistry that deals with the relationship between the
composition and physical properties of matter along with the changes in them.
ORGANIC CHEMISTRY
Organic Chemistry is the study of covalent compounds of carbon and hydrogen (hydrocarbons) and their
derivatives.
Organic compounds occur naturally and are also synthesized in the laboratories. Organic Inorganic Chemistry
INORGANIC CHEMISTRY
Inorganic Chemistry deals with the study of all elements and their compounds except those of compounds of
carbon and hydrogen (hydrocarbons) and their derivatives.
BIOCHEMISTRY
It is the branch of chemistry in which we study structure, composition, and chemical reactions of substances found
in living organisms.
INDUSTRIAL CHEMISTRY
The branch of chemistry that deals with the manufacturing of chemical compounds on commercial scale, is called
industrial chemistry.
NUCLEAR CHEMISTRY
Nuclear Chemistry is the branch of chemistry that deals with the radioactivity, nuclear processes and properties.
ENVIRONMENTAL CHEMISTRY
It is the branch of chemistry in which we study about components of the environment and the effects of human
activities on the environment.
ANALYTICAL CHEMISTRY
Analytical chemistry is the branch of chemistry that deals with separation and analysis of a sample to identify its
components.
The separation is carried out prior to qualitative and quantitative analysis.
BASIC DEFINITIONS
Matter is simply defined as anything that has mass and occupies space.
All types of matters that can exist in any of three physical states: solid, liquid or gas.
A piece of matter in pure form is termed as a substance.
Every substance has a fixed composition and specific properties or characteristics. Whereas, impure matter is called
a mixture; which can be homogeneous or heterogeneous in its composition.
The properties those are associated with the physical state of the substance are called physical properties, like
colour, smell, taste, hardness, shape of crystal, solubility, melting or boiling points, etc.
The chemical properties depend upon the composition of the substance. When a substance undergoes a chemical
change, its composition changes and a new substances are formed. For example, decomposition of water is a
chemical change as it produces hydrogen and oxygen gases.
ELEMENTS, COMPOUNDS AND MIXTURES
ELEMENTS
Element is that it is a substance made up of same type of atoms, having same atomic number and cannot be
98
iii. Compounds always have fixed composition by Mixtures do not have fixed composition.
mass.
99
iv. The components cannot be separated by The components can be separated by simple
physical means. physical methods.
v. Every compound is represented by a chemical It consists of two or more components and
formula. does not have any chemical formula.
th th
One atomic mass unit is 1/12 the mass of one atom of carbon-12 .
When this atomic mass unit is expressed in grams.
How to write a Chemical Formula
Compounds are represented by chemical formulae as elements are represented by symbols. Chemical formulae of
compounds are written keeping the following steps in consideration.
1. Symbols of two elements are written side by side, in the order of positive ion first and negative ion later.
+ 2+
2. The valency of each ion is written on the right top corner of its symbol, e.g. Na , Ca , CI and O2 .
3. This valency of each ion is brought to the lower right corner of other ion by 'cross- exchange' method, e.g.
4. They are written as
5. If the valencies are same, they are offset and are not written in the chemical formula. But if they are different,
they are indicated as such at the same position, e.g. in case of sodium chloride both the valencies are offset and
formula is written as NaCl, whereas, calcium chloride is represented by formula CaCl2.
2+
6. If an ion is a combination of two or more atoms which is called radical, bearing a net charge on it, e.g. SO
3+
(sulphate) and PO (phosphate), then the net charge represents the valency of the radical.
7. The chemical formula of such compounds is written as explained in (iii) and (iv); writing the negative radical
within the parenthesis. For example, chemical formula of aluminum sulphate is written as Al2(SO4)3 and that of
calcium phosphate as Ca3(PO4)2.
EMPIRICAL FORMULA
Chemical formulae are of two types. The simplest type of formula is empirical formula. It is the simplest whole
number ratio of atoms present in a compound.
The empirical formula of a compound is determined by knowing the percentage composition of a compound.
For example;
The covalent compound silica (sand) has simplest ratio of 1:2 of silicon and oxygen respectively. Therefore, its
empirical formula is SiO2.
The simplest unit taken as a representative of an ionic compound is called formula unit. It is defined as the
simplest whole number ratio of ions, as present in the ionic compound.
In other words, ionic compounds have only empirical formulae. For example, formula unit of common salt
+ +
consists of one Na and one CI ion and its empirical formula is NaCl. Similarly, formula unit of potassium
bromide is KBr, which is also its empirical formula.
MOLECULAR FORMULA
Molecules are formed by the combination of atoms. These molecules are represented by molecular formulae that
show actual number of atoms of each element present in a molecule of that compound.
Molecular formula is derived from empirical formula by the following relationship:
Molecular formula = (Empirical formula)n Where n is 1,2,3 and so on.
For example, molecular formula of benzene is C6H6 which is derived from the empirical formula CH where the
value of n is 6.
The molecular formula of a compound may be same or a multiple of the empirical formula.
Some compounds may have same empirical and molecular formula e.g. water (H20), hydrochloric acid (HC1), etc.
SOME COMPOUNDS WITH THEIR EMPIRICAL AND MOLECULAR FORMULAE
102
23
Hence, the 6.02 x 10 number of atoms, molecules or formula units is called Avogadro's number that is
equivalent to one 'mole' of respective substance.
23
In simple words, 6.02 x 10 particles are equal to one mole.
MOLE
23
A mole is defined as the amount (mass) of a substance that contains 6.02 x l0 number of particles (atoms,
molecules or formula units).
It is abbreviated as 'mol'.
The masses are expressed in atomic mass units (amu). But when these masses are expressed in grams, they are
called as molar masses.
Quantitative definition of mole is the atomic mass, molecular mass or formula mass of a substance expressed in
grams is called mole.
CHEMICALCALCULATIONS
In chemical calculations, we calculate number of moles and number of particles of a given mass of a substance or
vice versa.
These calculations are based upon mole concept.
Few examples of these calculations.
Calculating the number of moles and number of particles from known mass of a substance.
First calculate the number of moles from given mass by using equation
Then calculate number of particles from the calculated number of moles with the help of following equation:
MOLE-MASS CALCULATIONS
In these calculations, we calculate the number of moles of a substance from the known mass of the substance
with the help of following equation:
When we rearrange the equation to calculate mass of a substance from the number of moles of a substance we
get,
MOLE-PARTICLE CALCULATIONS
In these calculations, we can calculate the number of moles of a substance from the given number of particles.
(These particles are the atoms, molecules or formula units).
CHAPTER 02
ATOMIC STRUCTURE
INTRODUCTION
Ancient Greek philosopher Democritus suggested that matter is composed of tiny indivisible particles called atoms.
th
The name atom was derived from the Latin word 'Atomos' meaning indivisible. In the beginning of 19 century
John Dalton put forward Atomic Theory. According to it 'all matter is made up of very small indivisible particles
called atoms'.
th
In the beginning of 20 century experiments performed by Goldstein, J. J. Thomson, Rutherford, Bohr and other
scientist revealed that atom is made up of subatomic particles like electron, proton and neutron.
THEORIES AND EXPERIMENTS RELATED TO STRUCTURE OF ATOM
According to Dalton, an atom is an indivisible, hard, dense sphere.
Atoms of the same element are alike.
They combine in different ways to form compounds.
In 1886, Goldstein discovered positively charged particles called protons.
104
In 1897, J.J. Thomson found in an atom, the negatively charged particles known as electrons.
It was established that electrons and protons are fundamental particles of matter.
Based upon these observations Thomson put forth his “plum pudding” theory.
He postulated that atoms were solid structures of positively charge with tiny negative particles stuck inside. It is
like plums in the pudding.
J.J. THOMSON (1856- 1940) :
He was a British physicist.
He was awarded the 1906 Noble Prize in Physics for the discovery of electron and for his work on the conduction
of electricity in gases
SIR WILLIAM CROOKS (1832-1919):
He was a British chemist and physicist.
He was pioneer of vacuum tubes.
He worked on spectroscopy.
Cathode rays and Discovery of Electron
In 1895 Sir William Crooks performed experiments by passing electric current through gases in a discharge tube at
very low pressure.
He took a glass tube fitted with two metallic electrode, which were connected to a high voltage battery.
The cathode rays were studied in detail and their properties were determined, which are given below:
i. These rays travel in straight lines perpendicular to the cathode surface.
ii. They can cast a sharp shadow of an opaque object if placed in their path.
iii. They are deflected towards positive plate in an electric field showing that they are negatively charged.
iv. They raise temperature of the body on which they fall.
v. JJ. Thomson discovered their charge/mass (e / m) ratio.
vi. Light is produced when these rays hit the walls of the discharge tube.
vii. It was found that the same type of rays were emitted no matter which gas and which cathode was used
in the discharge tube.
DISCOVERY OF PROTON
In 1886 Goldstein observed that in addition to cathode rays, other rays were also present in the discharge tube.
These rays were traveling in opposite direction to cathode rays.
He used a discharge tube having perforated cathode.
He found that these rays passed through holes present in the cathode and produced a glow on the walls of the
discharge tube.
He called these rays as "canal rays".
The properties of these rays were as following:
(i) These rays travel in straight lines in a direction opposite to the cathode rays.
(ii) Their deflection in electric and magnetic field proved that these are positively charged.
(iii) The nature of canal rays depends upon the nature of gas, present in the discharge tube.
(iv) These rays do not originate from the anode. In fact these rays are produced when the cathode rays or electrons
collide with the residual gas molecules present in the discharge tube and ionize them as follows:
(v) Mass of these particles was found equal to that of a proton or simple multiple of it. The mass of a proton is 1840
times more than that of an electron.
an atom.
He bombarded alpha particles on a 0.00004 cm thick gold foil.
Alpha particles are emitted by radioactive elements like radium and polonium.
2+
These are actually helium nuclei (He ).
He observed the effects of -particles on a photographic plate or a screen coated with zinc sulphide.
He proved that the 'plum-pudding' model of the atom was not correct.
Observations made by Rutherford were as follows:
(i) Almost all the particles passed through the foil un-deflected.
(ii) Out of 20000 particles, only a few were deflected at fairly large angles and very few bounced back on
hitting the gold foil.
(iii) Results of the experiment
(iv) Rutherford proposed planetary model for an atom and concluded following results:
(v) Since most of the particles passed through the foil un- deflected, therefore most of the volume occupied by an
atom is empty.
(vi) The deflection of a few particles proved that there is a 'center of positive charges' in an atom, which is called
'nucleus' of an atom.
(vii) The complete rebounce of a few particles show that the nucleus is very dense and hard.
(viii) Since a few particles were deflected, it shows that the size of the nucleus is very small as compared to the total
volume of an atom.
(ix) The electrons revolve around the nucleus.
(x) An atom as a whole is neutral, therefore the number of electrons in an atom is equal to the number of protons.
(xi) Except electrons, all other fundamental particles that lie within the nucleus, are known as nucleons.
RUTHERFORD
RUTHERFORD was a British- New Zealand chemist.
He performed a series of experiments using a - particles.
He won the 1908 Noble Prize in Chemistry.
In 1911, he proposed the nuclear model of the atom and performed the first experiment to split atom.
Because of his great contributions, he is considered the father of nuclear science.
BOHR'S ATOMIC THEORY
Neil Bohr presented another model of atom in 1913.
The Quantum Theory of Max Planck was used as foundation for this model.
According to Bohr's model, revolving electron in an atom does not absorb or emit energy continuously.
The energy of a revolving electron is 'quantized' as it revolves only in orbits of fixed energy, called 'energy levels'
by him.
The Bohr's atomic model was based upon the following postulates:
1. The hydrogen atom consists of a tiny nucleus and electrons are revolving in one of circular orbits of radius
‘r’ around the nucleus.
2. Each orbit has a fixed energy that is quantized.
3. As long as electron remains in a particular orbit, it does not radiate or absorb energy. The energy is
emitted or absorbed only when an electron jumps from one orbit to another.
4. When an electron jumps from lower orbit to higher orbit, it absorbs energy and when it jumps from higher orbit
to lower orbit it radiates energy. This change in energy is given by following Planck's equation
34
Where, h is Planck's constant equal to 6.63 x10 Js, and v is frequency of light.
Electron can revolve only in orbits of a fixed angular moment mvr, given as: Where 'n' is the quantum number or orbit
NEIL BOHAR:
Neil Bohr was a Danish physicist who joined Rutherford in 1912 for his post doctoral research.
In 1913, Bohr presented his atomic model based upon Quantum theory.
He won the 1922 Noble Prize for Physics for his work on the structure of an atom.
It was based upon classical theory. It was based upon quantum theory.
Electrons revolve around the Electrons revolve around the
nucleus. nucleus in orbits of fixed energy.
No idea about orbits was Orbits had angular momentum.
introduced. Atoms should produce Atoms should produce line
continuous spectrum. spectrum.
Atoms should collapse. Atoms should exist.
ELECTRONIC CONFIGURATION
Before discussing electronic configuration let us first understand the concept of shells and subshells.
Now we will discuss how the electrons revolve around the nucleus?
The electrons revolve around the nucleus in different energy levels or shells according to their respective energies
(potential energy).
Energy levels are represented by 'n' values 1, 2, 3 and so on.
They are designated by the alphabets K, L, M and so on.
A shell closer to the nucleus is of minimum energy.
Since K shell is closest to the nucleus, the energy of shells increases from K shell onwards. Such as:
N shell can accommodate 32 electrons.
Filling of electrons in subshells of a shell is such as that V subshell is filled first and then its p subshell and then
other subshells are filled.
The maximum capacity of subshells to accommodate electrons is:
‘s’ subshell can accommodate 2 electrons. ‘p’subshell can accommodate 6 electrons.
Let us write the electronic configuration of the elements and their ions with the help of a few examples. Keep in
mind, we should know three things:
1. The number of electrons in an atom.
2. The sequence of shells and subshells according to the energy levels.
3. The maximum number of electrons that can be placed in different shells and subshells.
Solution:
o When there are 5 electrons in M shell, it means K and L shell are completely filled with their maximum
capacity of 10 electrons. Hence the electronic configuration of the element is:
ISOTOPES
DEFINITION
Isotopes are defined as the atoms of an element that have same atomic number but different mass numbers.
They have same electronic configuration and number of protons but they differ in the number of neutrons.
Isotopes have similar chemical properties because these depend upon electronic configuration.
But they have different physical properties because these depend upon mass numbers.
ISOTOPES OF HYDROGEN:
The naturally occurring hydrogen is combination of its three isotopes, present in different abundances.
The three isotopes of hydrogen are named as protium, deuterium and tritium
Each one of them has 1 proton and 1 electron, but number of neutrons are different.
The isotopes are represented as:
o Protium ( 1 H )
o Deuterium ( 2 H)
o Tritium ( 3 H )
ISOTOPES OF CARBON:
12 13 14
There are two stable isotopes of carbon C and C and one radioactive isotope C.
12 13 14
The isotope C is present in abundance of 98.9 %, while C and C are both present only 1.1 % in nature.
All of them have the same number of protons and electrons but differ in number of neutrons.
ISOTOPES OF CHLORINE:
There are two isotopes of chlorine,
ISOTOPES OF URANIUM
There are three isotopes of uranium i.e. in nature nearly 99%.
Atomic Number, Mass Number, Number of Protons and Neutrons of H, C, CI and U
USES OF ISOTOPES:
Radiotherapy (Treatment of Cancer)
Tracer for Diagnosis and Medicine
Archaeological and Geological Uses
Chemical Reaction and Structure Determination
Applications in Power Generation
CHAPTER 03
PERIODIC TABLE AND PERIODICITY OF PROPERTIES
INTRODUCTION
On the basis of Periodic law, the elements known at that time, were arranged in the form of a table which is known
as periodic table.
108
The vertical columns of that table were called groups and horizontal lines were called periods.
That orderly arrangement of elements generally coincided with their increasing atomic number.
PERIODIC TABLE
Dobereiner's Triads:
A German chemist Dobereiner’s observed relationship between atomic masses of several groups of three elements
called triads.
One triad group example is that of calcium (40), strontium (88) and barium (137).
The atomic mass of strontium is the average of the atomic masses of calcium and barium.
Newlands Octaves
After successful determination of correct atomic masses of elements by Cannizzaro in 1860, attempts were
again initiated to organize elements.
In 1864 British chemist Newlands put forward his observations in the form of 'law of octaves'.
He noted that there was a repetition in chemical properties of every eighth element if they were arranged by
their increasing atomic masses.
MENDELEEV:
Mendeleev (1834-1907) was a Russian chemist and inventor.
He was the creator of first version of Periodic table of elements.
With help of the table, he predicted the properties of the elements yet to be discovered.
Mendeleev's Periodic Table
Russian chemist, Mendeleev arranged the known elements (only 63) in order of increasing atomic masses, in
horizontal rows called periods.
So that elements with similar properties were in the same vertical columns.
This arrangement of elements was called periodic table.
He put forward the results of his work in the form of periodic law, which is stated as "properties of the
elements are periodic functions of their atomic masses"
PERIODIC LAW
In 1913 H. Moseley discovered a new property of the elements i.e. atomic number. He observed that atomic
number instead of atomic mass should determine the position of element in the periodic table and accordingly
the periodic law was amended as "properties of the elements are periodic function of their atomic numbers".
Atomic number of an element is equal to the number of electrons in a neutral atom.
Modern Periodic Table
Atomic number of an element is more fundamental property than atomic mass in two respects, (a) It increases
regularly from element to element, (b) It is fixed for every element.
So the discovery of atomic number of an element in 1913 led to change in Mendeleev's periodic law which was
based on atomic mass.
The modern periodic table is based upon the arrangement of elements according to increasing atomic number.
When the elements are arranged according to increasing atomic number from left to right in a horizontal row,
properties of elements were found repeating after regular intervals such that elements of similar properties and
similar configuration are placed in the same group.
LONG FORM OF PERIODIC TABLE
Salient Features of Long Form of Periodic Table:
1. This table consists of seven horizontal rows called periods.
2. First period consists of only two elements. Second and third periods consist of 8 elements each. Fourth and fifth
periods consist of 18 elements each. Sixth period has 32 elements while seventh period has 23 elements and is
incomplete.
3. Elements of a period show different properties.
4. There are 18 vertical columns in the periodic table numbered 1 to 18 from left to right, which are called groups.
5. The elements of a group show similar chemical properties.
6. Elements are classified into four blocks depending upon the type of the subshell which gets the last electron.
PERIODS
First period is called short period.
It consists of only two elements, hydrogen and helium.
Second and third periods are called normal periods.
Each of them has eight elements in it.
Second period consists of lithium, beryllium, boron, carbon, nitrogen, oxygen, fluorine and ends at neon, a noble
gas.
Fourth and fifth periods are called long periods.
Each one of them consists of eighteen elements.
Whereas, sixth and seventh periods are called very long periods.
In these periods after atomic number 57 and 89, two series of fourteen elements each, were accommodated.
109
Because of space problem, these two series were placed separately below the normal periodic table to keep it in
a manageable and presentable form.
Since the two series start after Lanthanum (Z=57) and Actinium (Z=89), so these two series of elements are named
as Lanthanides and Actinides respectively.
GROUPS
Group 1 consists of hydrogen, lithium, sodium, potassium, rubidium, cesium and francium.
Although elements of a group do not have continuously increasing atomic numbers, yet they have similar electronic
configuration in their valence shells.
That is the reason elements of a group are also called a family.
For example, all the group 1 elements have one electron in their valence shells, they are given the family name of
alkali metals.
The groups 1 and 2 and 13 to 17 contain the normal elements.
In the normal elements, all the inner shells are completely filled with electrons, only the outermost shells are
incomplete.
For example, group 17 elements (halogens) have 7 electrons in their valence (outermost) shell.
The groups 3 to 12 are called transition elements.
In these elements 'af' sub-shell is in the process of completion.
DIFFERENT GROUPS OF THE PERIODIC TABLE
PERIODICITY OF PROPERTIES
ATOMIC SIZE AND ATOMIC RADIUS:
The common method to determine the size of an atom is to assume that atoms are spheres.
Half of the distance between the nuclei of the two bonded atoms is referred as the atomic radius of the atom.
When we move from left to right in a period although atomic number increases, yet the size of atoms decreases
gradually. It is because with the increase of atomic number, the effective nuclear charge increases gradually
because of addition of more and more protons in the nucleus.
But on the other hand addition of electrons takes place in the same valence shell i.e. shells do not increase.
There is gradual increase of effective nuclear charge which increases due to addition of protons. This force pulls
down or contracts the outermost shell towards the nucleus.
For example, atomic size in period 2 decreases from Li (152 pm) to Ne (69 pm).
The size of atoms or their radii increases from top to bottom in a group.
The trend of atomic size of transition elements has slight ariation when we consider this series in a period.
The atomic size of the elements first reduces or atom contracts and then there is increase in it when we move
from left to right in 4th period.
Shielding Effect
The electrons present in the inner shells screen or shield the force of attraction of nucleus felt by the valence shell
electrons. This is called shielding effect.
Ionization Energy
The ionization energy is the amount of energy required to remove the most loosely bound electron from the
valence shell of an isolated gaseous atom.
ELECTRON AFFINITY:
Electron Affinity is defined as the amount of energy released when an electron is added in the outermost shell of
an isolated gaseous atom.
Affinity means attraction.
ELECTRONEGATIVITY:
The ability of an atom to attract the shared pair of electrons towards itself in a molecule, is called electronegativity.
110
CHAPTER 04
111
CHEMICAL BONDING
INTRODUCTION
2 6
Atoms achieve stability by attaining electronic configuration of noble gases (He, Ne or Ar, etc) i.e. ns np .
Having 2 or 8 electrons in the valence shell is sign of stability.
Attaining two electrons in the valence shell is called duplet rule while attaining eight electrons in the valence shell
is called octet rule.
The noble gases do have 2 or 8 electrons in their valence shells.
All the noble gases have their valence shells completely filled.
Noble gases do not gain, lose or share electrons.
That is why they are non-reactive.
Atoms combine with one another, which is called chemical bonding.
In other words, atoms form chemical bonds to achieve stability by acquiring inert gas electron configuration.
Every atom has a natural tendency to have 2 or 8 electrons in its valence shell.
The atoms having less than 2 or 8 electrons in their valence shells are unstable.
The position of an atom in the periodic table indicates its group number.
Mode of reaction of an atom depends upon its number of valence shell electrons. CHEMICALBOND
A chemical bond is defined as a force of attraction between atoms that holds them together in a substance. In
other words, during bond formation there is some force which holds the atoms together.
TYPES OF CHEMICALBOND
The valence electrons, which are involved in chemical bonding, are termed as bonding electrons.
Four types of chemical bonds are
Ionic Bond Covalent Bond
Dative Covalent or Coordinate Covalent Bond Metallic Bond
IONIC BOND
Chemical bond, which is formed due to complete transfer of electron from one atom to another atom, is called
ionic bond.
The formation of NaCl is a good example of this type of bond.
The compounds formed due to this type of bonding are called ionic compounds.
COVALENT BOND
The elements of Group-13 to Group-17 when allowed to react with each other, they form a chemical bond by
mutual sharing of their valence shell electrons.
This type of bond, which is formed due to mutual sharing of electrons, is called a covalent bond.
Types of covalent bonds
The electrons that pair up to form a chemical bond are called 'bond pair' electrons.
Single Covalent bond
When one electron is contributed by each bonded atom, one bond pair is formed and it forms a single covalent bond.
Double Covalent bond
When each bonded atom contributes two electrons, two bond pairs are shared and a double covalent bond is
formed.
These bond pairs are indicated as double line between those atoms in the structure of such molecules.
Triple Covalent Bond
When each bonded atom contributes three electrons, three bond pairs are involved in bond formation. This type is
called triple covalent bond.
Three small lines are used to indicate these three pairs of electrons between those atoms in the molecules.
DATIVE COVALENT OR COORDINATE COVALENT BOND
Type of covalent bonding in which the bond pair of electrons is donated by one bonded atom only.
The atom which donates the electron pair is called donor and the atom which accepts the electron pair is called
acceptor.
A small arrow is usually used to indicate the atom and pair of electron being donated. The head of arrow is
towards the acceptor atom.
The non-bonded electron pair available on an atom, like the one available on nitrogen in ammonia NH3, is called a
lone pair.
POLAR AND NON-POLAR COVALENT BOND
If a covalent bond is formed between two similar atoms (homo-atoms), the shared pair of electrons is attracted by
both the atoms equally. Such type of bond is called non-polar covalent bond.
These bonds are formed by equal sharing of electron pair between the two bonding atoms.
112
This type of bond is called a pure covalent bond. For example, bond formation in H2 and CI2.
When there is difference of electronegativity between two covalently bonded atoms, there will be unequal
attraction for the bond pair of electrons between such atoms. It will result in the formation of polar covalent
bond.
METALLIC BOND
The metallic bond is defined as a bond formed between metal atoms (positively charged ions) due to mobile or
free electrons.
The different properties shown by metals such as high melting and boiling points, good conductions of heat and
electricity, hard and heavy nature, suggest existence of different type of chemical bond between atoms of metals.
INTERMOLECULAR FORCES
The forces that hold atoms in a compound are chemical bonds.
In addition to these strong bonding forces, relatively weak forces also exist in between the molecules, which are
called intermolecular forces.
It requires about 17 kJ energy to break these intermolecular forces between one mole of liquid hydrogen
chloride molecules to convert it into gas.
Whereas, about 430 kJ energy's required to break the chemical bond between hydrogen and chlorine atoms in 1
mole of hydrogen chloride.
DIPOLE - DIPOLE INTERACTION
All intermolecular forces, which are collectively called van der Waals forces, are electrical in nature.
They result from the attractions of opposite charges which may be temporary or permanent.
The unequal sharing of electrons between two different types of atoms make one end of molecule slightly
positive and other end slightly negatively charged called dipole – diploeinteration.
HYDROGEN BONDING
Partially positively charged hydrogen atom of one molecule attracts and forms a bond with the partially negatively
charged atom of the other molecule, the bonding is called hydrogen bonding. This force of attraction is
represented by a dotted line between the molecules.
NATURE OF BONDINGAND PROPERTIES
Properties of the compounds depend upon the nature of bonding present in them.
Let us discuss the effects of nature of bonding on the properties of compounds.
IONIC COMPOUNDS
Ionic compounds are made up of positively and negatively charged ions.
Thus they consist of ions and not the molecules.
These positively and negatively charged ions are held together in a solid or crystal form with strong electrostatic
attractive forces.
The ionic compounds have following properties:
1. Ionic compounds are mostly crystalline solids.
2. Ionic compounds in solid state have negligible electrical conductance but they are good conductors in solution and
in the molten form. It is due to presence of free ions in them.
3. Ionic compounds have high melting and boiling points. For example, sodium chloride has melting point 800 °C and
a boiling point 1413 °C. As ionic compounds are made up of positive and negative ions, there exist strong
electrostatic forces of attraction between oppositely charged ions. So, a great amount of energy is required to
break these forces.
4. They dissolve easily in polar solvents like water. Water has high dielectric constant that weakens the attraction
between ions.
COVALENT COMPOUNDS
The covalent compounds are made up of molecules that are formed by mutual sharing of electrons between
their atoms i.e. covalent bonds.
Covalent compounds are made up of two or more non-metals, e.g. H2, CH4, CO2, H2SO4, C6H12O6.
Lower molecular mass covalent compounds are gases or low boiling liquids. Contrary to it, higher molecular
mass covalent compounds are solids.
General properties shown by covalent compound are as follows:
1. They have usually low melting and boiling points.
2. They are usually bad conductors of electricity. The compounds having polar character in their bonding are
conductor of electricity when they dissolve in polar solvents.
3. They are usually insoluble in water but are soluble in non-aqueous solvents like benzene, ether, alcohol and
acetone.
4. Large molecules with three dimensional bonding form covalent crystals which are very stable and hard. They have
very high melting and boiling points.
POLAR AND NON-POLAR COMPOUNDS
On the Pauling Scale, fluorine has been given an electronegativity value of 4.0.
113
Non-polar covalent compounds usually do not dissolve in water while polar covalent compounds usually
dissolve in water.
Similarly non-polar compounds do not conduct electricity but an aqueous solution of a polar compound usually
conduct electricity due to the formation of ions as a result of its reaction with water.
COORDINATE COVALENT COMPOUNDS
They do not form ions in water.
Due to their covalent nature they form solutions in organic solvents and are very less soluble in water.
Usually they are rigid compounds with a dipole.
METALS
Metals have common property of conducting heat and electricity.
It gives them prime role in many industires.
Major properties shown by the metals are as follows:
1. They show metallic luster.
2. They are usually malleable and ductile. Malleability is the property by virtue of which a metal can be rolled into
sheets, while ductility is the property by virtue of which a metal can be drawn into wires.
3. They have usually high melting and boiling points.
+
4. Being greater in size they have low ionization energies and form cations (M ) very easily.
5. They are good conductors of heat and electricity in solid and liquid state due to mobile electrons.
CHPATER 05
PHYSICAL STATES OF MATTER
INTRODUCTION
Matter exists in three physical states i.e. gas, liquid and solid.
The simplest form of matter is the gaseous state.
Liquids are less common and most of the matter exists as solid.
Matter in gaseous state does not have definite shape and volume.
Therefore, gases occupy all the available space.
Their intermolecular forces are very weak.
Pressure is a significant property of gases.
The liquid state has strong intermolecular forces hence it has definite volume but it does not have definite shape.
Liquids evaporate and their vapours exert pressure.
When vapour pressure of a liquid becomes equal to external pressure, it boils.
Liquids are less mobile than gases therefore, they diffuse slowly.
The solid state has definite volume and shape.
They are rigid and denser than liquids and gases.
They exist in amorphous or crystalline forms.
GASEOUS STATE
TYPICALPROPERTIES
Gases have similar physical properties. A few typical properties are discussed here.
DIFFUSION
Gases can diffuse very rapidly.
Diffusion is defined as spontaneous mixing up of molecules by random motion and collisions to form a homogeneous
mixture.
Rate of diffusion depends upon the molecular mass of the gases.
Lighter gases diffuse rapidly than heavier ones. For example, H2 diffuses four times faster than O2 gas .
EFFUSION
It is escaping of gas molecules through a tiny hole into a space with lesser pressure.
For example, when a tyre gets punctured, air effuses out.
Effusion depends upon molecular masses, lighter gases effuse faster than heavier gases.
PRESSURE
Gas molecules are always in continuous state of motion.
Hence, when molecules strike with the walls of the container or any other surface, they exert pressure.
Pressure (P) is defined as the force(F) exerted per unit surface area (A). P = F/A
2 -2
The SI unit of force is Newton and that of area is m . Hence pressure has SI unit of N m . It is also called Pascal (Pa)
-2
One Pascal (Pa) = 1 Nm
Barometer is used to measure atmospheric pressure and manometer is used to measure pressure in the
laboratory.
STANDARD ATMOSPHERIC PRESSURE
114
As both equations have same constant therefore, their variables are also equal to each other.
This equation establishes the relationship between pressure and volume of the gas.
Robert Boyle (1627-1691) was natural philosopher, chemist, physicist and inventor.
He is famous for 'Boyle's law of gases'.
CHARLES'S LAW
The relationship between volume and temperature keeping the pressure constant was also studied.
French scientist J. Charles in 1787 presented his law that states "the volume of a given mass of a gas is directly
proportional to the absolute temperature if the pressure is kept constant'.
115
When pressure P is constant, the volume V of a given mass of a gas is proportional to absolute temperature T.
Mathematically, it is represented as:
As both equations have same value of constant, therefore, their variables are also equal to each other
J. Charles (1746-1823) was a French inventor, scientist, mathematician and balloonist. He described in
1802, how gases tend to expandPHYSICAL STATES OF MATTER AND ROLE OF INTERMOLECULAR FORCES
In the gaseous state, the molecules are far apart from each other.
Therefore, intermolecular forces are very weak in them.
But in the liquid and solid states intermolecular forces play a very important role on their properties.
In the liquid state molecules are much closer to each other as compared to gases
Compounds having stronger intermolecular forces have higher boiling points
The intermolecular forces become so dominant in solid state that the molecules look motionless.
They arrange in a regular pattern therefore they are denser than molecules of liquids.
LIQUID STATE
Liquids have a definite volume but their shape is not definite.
A liquid attains shape of the container in which it is put.
A few typical properties of the liquids are discussed here.
TYPICALPROPERTIES
EVAPORATION
The process of changing of a liquid into a gas phase is called evaporation.
It is reverse to condensation in which a gas changes into liquid.
Evaporation is an endothermic process (heat is absorbed).
The molecules having more than average kinetic energy overcome the attractive forces among the molecules and
escape from the surface. It is called as evaporation.
The rate of evaporation is directly proportional to temperature.
It increases with the increase in temperature because of increase in kinetic energy of the molecules.
Evaporation is a cooling process.
When the high kinetic energy molecules vapourize, the temperature of remaining
Evaporation depends upon following factors:
o Surface area
o Temperature
o Intermolecular forces
VAPOUR PRESSURE
The pressure exerted by the vapours of a liquid at equilibrium with the liquid at a particular temperature is called
vapour pressure of a liquid.
The equilibrium is a state when rate of vapourization and rate of condensation is equal to each other but in
opposite directions.
Vapour pressure of a liquid depends upon the following factors.
Nature of liquid:
Size of molecules
Temperature
Relationship of Vapours Pressure of Water with Temperature
Relationship of Vapour Pressure of Water with Temperature
Boiling point is defined as the temperature at which the vapour pressure of a liquid becomes equal to the
atmospheric pressure or any external pressure.
The boiling point of the liquid depends upon the following factors.
o Nature of liquid:.
116
o Intermolecular forces:
o External pressure
FREEZING POINT
When liquids are cooled, the vapour pressure of liquid decreases and a stage reaches when vapour pressure of a
liquid state becomes equal to the vapour pressure of the solid state. At this temperature, liquid and solid coexist in
dynamic equilibrium and this is called the freezing point of a liquid.
Freezing and Boiling Points of Common Liquids
DIFFUSION
The diffusion of liquid depends upon the following factors. Intermolecular forces:
Size of molecules:
Shapes of molecules:
Temperature:
DENSITY
The density of liquid depends upon its mass per unit volume.
Liquids are denser than gases because molecules of liquid are closely packed and the spaces between their
molecules are negligible.
As the liquid molecules have strong intermolecular forces hence they cannot expand freely and have a fixed
volume.
Like gases, they cannot occupy all the available volume of the container that is the reason why densities of
liquids are high.
3 3
For example: density of water is 1.0 g cm while that of air is 0.001 g cm .
That is the reason why drops of rain fall downward.
The densities of liquids also vary.
SOLID STATE
It is third state of matter which has definite shape and volume.
In solid state, the molecules are very close to one another and they are closely packed. The intermolecular forces
are so strong that particles become almost motionless.
Hence, they cannot diffuse.
Solid particles possess only vibrational motion.
TYPICALPROPERTIES
Solids exhibit typical properties, a few of which are discussed here.
MELTING POINT
The solid particles possess only vibrational kinetic energy.
When solids are heated, their vibrational energies increase and particles vibrate at their mean position with a
higher speed.
If the heat is supplied continuously, a stage reaches at which the particles leave their fixed positions and then
become mobile.
At this temperature solid melts. The temperature at which the solid starts melting and coexists in dynamic
equilibrium with liquid state is called melting point.
The ionic and covalent solids make network structure to form macromolecules. So all such solids have very high
melting points.
RIGIDITY
The particles of solids are not mobile.
They have fixed positions. Therefore, solids are rigid in their structure.
DENSITY
Solids are denser than liquids and gases because solid particles are closely packed and do not have empty spaces
between their particles.
Therefore, they have the highest densities among the three states of matter.
-3 -3 -3
For example, density of aluminium is 2.70 g cm , iron is 7.86 g cm and gold is 19.3 g cm .
TYPES OF SOLIDS
According to their general appearance solids can be classified into two types: amorphous solids and crystalline
117
solids.
AMORPHOUS SOLIDS
Amorphous means shapeless.
Solids in which the particles are not regularly arranged or their regular shapes are destroyed, are called
amorphous solids.
They do not have sharp melting points.
Plastic, rubber and even glass are amorphous solids as they do not have any sharp melting points.
CRYSTALLINE SOLIDS
Solids in which particles are arranged in a definite three-dimensional pattern are called crystalline solids.
They have definite surfaces or faces.
Each face has definite angle with the other.
They have sharp melting points.
Examples of crystalline solids are diamond, sodium chloride, etc.
ALLOTROPY
The existence of an element in more than one forms in same physical state is called allotropy.
Allotropy is due to:
1. The existence of two or more kinds of molecules of an element each having different number of atoms
such as allotropes of oxygen are oxygen (O2) and ozone (O3)
2. Different arrangement of two or more atoms or molecules in a crystal of the element. Such as, sulphur
shows allotropy due to different arrangement of molecules (S8) in the crystals.
They always show different physical properties but have same chemical properties.
Allotropes of solids have different arrangement of atoms in space at a given temperature.
The temperature at which one allotrope changes into another is called transition temperature.
For example, transition temperature of sulphur is 96 °C.
Below this temperature rhombic form is stable.
If rhombic form is heated above 96 °C, its molecules rearrange themselves to give monoclinic form.
Other examples are tin and phosphorus
White phosphorus is very reactive, poisonous and waxy solid.
It exists as tetra-atomic molecules.
While red phosphorous is less reactive, non-poisonous and a brittle powder.
CHAPTER 06
SOLUTIONS
INTRODUCTION
Solutions are homogeneous mixtures of two or more components.
Generally, solutions are found in three physical states depending upon the physical state of the solvent, e.g.
alloy is a solid solution; sea water is a liquid solution and air is a gaseous solution.
There are nine types of solutions ranging from gas-gas e.g. air we breathe to solid-solid solutions e.g. dental
amalgam for filling of tooth.
Liquid solutions are the most common solutions because of the most common solvent water.
Therefore, there is a wide variety of liquid solutions ranging from a drop of rain to oceans.
Sea water is a resource of 92 naturally occurring elements.
SOLUTION
A solution is a homogeneous mixture of two or more substances.
For example, the air we breathe is a solution of several gases, brass is a solid solution of Zn and Cu.
Sugar dissolved in water is an example of liquid solution.
The simplest way to distinguish between a solution and a pure liquid is evaporation. The liquid which evaporates
completely, leaving no residue, is a pure compound, while a liquid which leaves behind a residue on evaporation
is solution.
An alloy like brass or bronze is also a homogeneous mixture.
Although, it cannot be separated by physical means, yet it is considered a mixture as:
1. It shows the properties of its components and
2. It has a variable composition.
AQUEOUS SOLUTIONS
The solution which is formed by dissolving a substance in water is called an aqueous solution.
In aqueous solutions water is always present in greater amount and termed as solvent. For example, sugar in water
and table salt in water.
Aqueous solutions are mostly used in the laboratories.
Water is called a universal solvent because it dissolves majority of compounds present in earth's crust.
118
SOLUTE
The component of solution which is present in smaller quantity is called solute.
A solute is dissolved in a solvent to make a solution.
SOLVENT
The component of a solution which is present in larger quantity is called solvent. Solvent always dissolves
solutes.
SATURATED SOLUTION
A solution containing maximum amount of solute at a given temperature is called saturated solution.
On the particle level, a saturated solution is the one, in which undissolved solute is in equilibrium with dissolved
solute.
UNSATURATED SOLUTION
A solution which contains lesser amount of solute than that which is required to saturate it at a given temperature,
is called unsaturated solution.
Such solutions have the capacity to dissolve more solute to become a saturated solution.
SUPERSATURATED SOLUTION
The solution that is more concentrated than a saturated solution is known as supersaturated solution.
Super- saturated solutions are not stable.
Therefore, an easy way to get a supersaturated solution is to prepare a saturated solution at high temperature.
It is then cooled to a temperature where excess solute crystallizes out and leaves behind a saturated solution.
DILUTION OF SOLUTION
The solutions are classified as dilute or concentrated on the basis of relative amount of solute present in them.
Dilute solutions are those which contain relatively small amount of dissolved solute in the solution.
Concentrated solutions are those which contain relatively large amount of dissolved solute in the solution.
For example, brine is a concentrated solution of common salt in water.
TYPES OF SOLUTION
Each solution consists of two components, solute and solvent.
The solute as well as solvent may exist as gas, liquid or solid.
CONCENTRATION UNITS
Concentration is the proportion of a solute in a solution.
It is also a ratio of the amount of solute to the amount of solution or ratio of amount of solute to the amount of the
solvent.
PERCENTAGE
Percentage unit of concentration refers to the percentage of solute present in a solution. The percentage of
solute can be expressed by mass or by volume.
It can be expressed in terms of percentage composition by four different ways.
MOLARITY
3
It is a concentration unit defined as number of moles of solute dissolved in one dm of the solution.
It is represented by M.
Molarity is the unit mostly used in chemistry and allied sciences.
The formula used for the preparation of molar solution is as follows:
SOLUBILITY
Solubility is defined as the number of grams of the solute dissolved in 100 g of a solvent to prepare a saturated
solution at a particular temperature.
The concentration of a saturated solution is referred to as solubility of the solute in a given solvent.
SOLUBILITY AND SOLUTE-SOLVENT INTERACTION
The solute-solvent interaction can be explained in terms of creation of attractive forces between the particles of
solute and those of solvent.
To dissolve one substance (solute) in another substance (solvent) following three events must occur :
1. Solute particles must separate from each other
2. Solvent particles must separate to provide space for solute particles.
3. Solute and solvent particles must attract and mix up.
119
SOLUTION
Solutions are the homogeneous mixtures of two or more than two components.
Each component is mixed in such a way that their individual identity is not visible.
The simplest example is that of a drop of ink mixed in water.
This is an example of true solution.
COLLOID
These are solutions in which the solute particles are larger than those present in the true solutions but not large
enough to be seen by naked eye.
The particles in such system dissolve and do not settle down for a long time. But particles of colloids are big
enough to scatter the beam of light. It is called Tyndall effect.
Examples are starch, albumin, soap solutions, blood, milk, ink, jelly and toothpaste, etc.
SUSPENSION
Suspensions are a heterogeneous mixture of undissolved particles in a given medium.
Particles are big enough to be seen with naked eyes.
Examples are chalk in water(milky suspension), paints and milk of magnesia (suspension of magnesium oxide in
water).
Comparison of the Characteristics of Solutions, Colloidals and Suspensions
CHAPTER 07
ELECTROCHEMISTRY
INTRODUCTION
Electrochemistry is the branch of Chemistry that deals with the relationship between electricity and chemical
reactions.
It involves oxidation and reduction reactions, which are also known as redox reactions.
Spontaneous reactions are those which take place on their own without any external agent.
Non-spontaneous reactions are those which take place in the presence of an external agent.
These reactions take place in galvanic or electrolytic cells.
120
The oxidation states or oxidation numbers of all the atoms or ions in this reaction are indicated below:
Let us find out the atoms that are oxidized or reduced or whether there is a change in their oxidation state, it is
indicated as follows:
121
Similarly, in the case of formation of water from hydrogen and oxygen gases, redox reaction takes place as
follows:
The oxidation states or oxidation numbers of all the atoms or ions in this reaction
Let us find out the atoms that are oxidized or reduced in this reaction; with the help of figure below:
ELECTROCHEMICAL CELLS
Electrochemical cell is a system in which two electrodes are dipped in the solution of an electrolyte which are
connected to the battery.
Electrochemical cell is an energy storage device in which either a chemical reaction takes place by using electric
current (electrolysis) or chemical reaction produces electric current(electric conductance).
Electrochemical cells are of two types.
i. Electrolytic cells ii. Galvanic cells
CONCEPT OF ELECTROLYTES
The substances, which can conduct electricity in their aqueous solutions or molten states, are called electrolytes.
For example, solutions of salts, acids or bases are good electrolytes.
The electricity cannot pass through solid NaCl but in aqueous solution and in molten state, it does conduct.
Electrolytes are classified into two groups depending upon their extent of ionization in solution.
STRONG ELECTROLYTES
The electrolytes which ionize almost completely in their aqueous solutions and produce more ions, are called
strong electrolytes.
Example of strong electrolytes are aqueous solutions of NaCl, NaOH and H2SO4, etc.
WEAK ELECTROLYTES
The electrolytes which ionize to a small extent when dissolved in water and could not produce more ions are called
weak electrolytes.
Acetic acid (CH3COOH) and Ca(OH)2 when dissolved in water, ionize to a small extent and are good examples of
weak electrolytes. Weak electrolytes do not ionize completely. For example, ionization of acetic acid in water
produces less ions:
The electrochemical cell in which a spontaneous chemical reaction takes place and generates electric current is
called galvanic or voltaic cell.
Example of this type of cell is a Daniel cell.
Volta (1745-1827) was an Italian physicist known especially for the development of the first electric cell in 1800.
ELECTROCHEMICALINDUSTRIES
Manufacture of Sodium Metal from Fused NaCl
On the industrial scale, molten sodium metal is obtained by the electrolysis of fused NaCl in the Downs cell.
This electrolytic cell is a circular furnace.
In the center there is a large block of graphite, which acts as an anode while cathode around it is made of iron.
Manufacture of NaOH from Brine
On industrial scale caustic soda (sodium hydroxide) NaOH, is produced in Nelson's cell by the electrolysis of
aqueous solution of NaCl called brine.
CORROSION AND ITS PREVENTION
Corrosion is slow and continuous eating away of a metal by the surrounding medium.
It is a redox chemical reaction that takes place by the action of air and moisture with the metals.
The most common example of corrosion is rusting of iron.
RUSTING OF IRON
Corrosion is a general term but corrosion of iron is called rusting.
The important condition for rusting is moist air (air having water vapours in it).
There will be no rusting in water vapours free of air or air free of water.
PREVENTION OF CORROSION
REMOVAL OF STAINS
The regions of stains in an iron rod act as the site for corrosion.
If the surface of iron is properly cleaned and stains are removed, it would prevent rusting.
PAINTS AND GREASING
Greasing or painting of the surface can prevent the rusting of iron.
ALLOYING
Alloy is a homogeneous mixture of one metal with one or more other metals or non-metals.
Alloying of iron with other metals has proved to be very successful technique against rusting.
The best example of alloying is the 'stainless steel', which is a good combination of iron, chromium and nickel.
METALLIC COATING
The best method for protection against the corrosion of metals exposed to acidic conditions is coating the metal
with other metal.
Corrosion resistant metals like Zn, Sn and Cr are coated on the surface of iron to protect it from corrosion.
PHYSICAL METHODS (GALVANIZING AND TIN COATING)
ZINC COATING OR GALVANIZING
The process of coating a thin layer of zinc on iron is called galvanizing.
This process is carried out by dipping a clean iron sheet in a zinc chloride bath and then heating it.
TIN COATING
It involves the dipping of the clean sheet of iron in a bath of molten tin and then passing it through hot rollers.
ELECTROLYTIC METHOD (ELECTROPLATING)
Electroplating is depositing of one metal over the other by means of electrolysis.
This process is used to protect metals against corrosion and to improve their appearance.
CHAPTER 08
CHEMICAL REACTIVITY
INTRODUCTION
The property of substance to undergo chemical reaction with any material is called chemical
reactivity.
Reactivity of metals depends upon its tendency to lose electron and that of non metals depends upon
its tendency to accept electron.
Matter which undergoes chemical reactivity may be element, compound or mixture.
METAL
The element which readily loses electron and easily form cation is termed as metal.
All B group elements a r e m e t a l s a n d k n o w n as Transition Metals.
Some elements of A group are also metals.
Elements of group IA are called Alkali metals.
Elements of group IIA are called Alkaline earth metals.
123
Beryllium (Be) is a light strong and highly toxic metal. Its small grain of 0.25 mg may kill a rat.
Most abundant metal is aluminum (Al). Most useable metal is iron (Fe).
Most reactive metal is cesium (Cs).
The lightest metal is lithium (Li).
The heaviest metal is osmium (Os).
Most malleable, ductile metals are gold(Au) and silver (Ag).
ELECTROPOSITIVE CHARACTER (CATION FORMATION)
Metals are highly electro positive, due to this property they easily lose their valance shell electrons.
When an atom or a molecule loses electron then it changes into positively charged ion known as
Cation.
Electro positive character of metals increases down the group with increasing atomic size. Alkali metals
have large atomic size and low ionization potential values.
The valence shell electronic configuration of alkali metals is ns1• Alkali metals lose one electron and form
monovalent cation.
Example Lt, Na+, Rb+, Cs+
The valence shell electronic configuration of alkaline earth metals is ns2•
Alkali and Alkaline earth metals can be identified by the flame test.
IONIZATION ENERGY OF ALKALI AND ALKALINE EARTH METAL
The removal of electron from an element requires energy which is known as Ionization Energy. Atom
+ Energy---+ Cation + e-
Ionization energies values decreases with increasing atomic size and vice versa.
The Alkali metals and Alkaline earth metals show increasing trend of reactivity down the group
because their atomic size increases down the group.
Since Alkali metals have low Ionization Energy values than Alkaline earth metals, Alkali metals are highly
reactive than Alkaline earth metals.
Alkali Metals and Alkaline earth metals have low values of Ionization Energies due to which they easily
lose their valence electron and form Cation. Thus they are highly reactive.
SOME COMMON METALS AND NON-METALS IN THE PERIODIC TABLE
ATOMIC NUMBER, ELECTRONIC CONFIGURATIONS AND IONIZATION ENERGIES (KJ/MOL) OF ALKALI AND ALKALINE
EARTH METALS
Low ionization energies of alkali metals make them more reactive than alkaline earth metals.
COMPARISON OF REACTIVITIES OF ALKALI AND ALKALINE EARTH METALS
A comparison of physicals properties of alkali metals and alkaline earth metals
Comparison of Physical Properties of Alkali and Alkaline Earth Metals
The elements in first two groups of the periodic table Group 1 and Group 2 are called
‘Alkali’ and ‘Alkaline earth’ metals, respectively.
839
1
Alkali metals are extremely reactive elements because of their ns valence shell electronic configuration.
As there is only one electron in their valence shell, it can be easily given out.
It is the reason that they are always found in nature as cations with +1 oxidation state.
Therefore, they readily form salts with non-metals.
The alkaline earth metals atoms are smaller and have more nuclear charge.
2
They have two electrons in their valence shells i.e. ns .
They are also reactive but less than alkali metals.
USES OF SODIUM
Sodium-potassium alloy is used as a coolant in nuclear reactors.
It is used to produce yellow light in sodium vapour lamps.
It is used as a reducing agent in the extraction of metals like Ti.
USES OF MAGNESIUM
Magnesium is used in flash light bulbs and in fireworks. It is used in the manufacture of light alloys.
Magnesium ribbon is used in Thermite process to ignite aluminium powder
Magnesium is used as anode for prevention of corrosion.
USES OF CALCIUM
It is used to remove Sulphur from petroleum products.
It is used as reducing agent to produce Cr, U and Zr.
INERTNESS OF NOBLE METALS
125
The elements in which d-orbital are in the process of filling, constitute a group of metals called transition metals or
d-group elements.
They exhibit a variety of oxidation states.
There are three series of transition elements; each series consisting of ten elements.
The non-metallic character depends upon the electron affinity and electronegativity of the atom.
Small sized elements having high nuclear charge are electronegative in nature.
They have high electron affinity.
Therefore, they possess non- metallic character.
Hence, non-metallic character decreases in a group downward and increases in a period from left to right up to
halogens.
Fluorine is the most non-metallic element.
The non-metals are, therefore, elements in Group-14(Carbon), Group-15 (nitrogen and phosphorus), Group-16
(oxygen, Sulphur and selenium) and in Group-17 halogens (fluorine, chorine, bromine and iodine) of the
periodic table.
IMPORTANT PHYSICAL PROPERTIES OF NON-METALS ARE AS FOLLOWS:
Physical properties of non-metals change gradually but uniquely in a group of non-metals. Non- metals usually
exist in all three physical states of matter.
The non-metals at the top of the group are usually gases while others are either liquids or solids.
Solids non-metals are brittle (break easily).
Non-metals are bad conductors of heat and electricity (except graphite).
They are not shiny, they are dull except iodine (it is lustrous like metals).They are generally soft (except
diamond).
They have low melting and boiling points (except silicon, graphite and diamond).
They have low densities.
IMPORTANT CHEMICAL PROPERTIES OF NON-METALS ARE AS FOLLOWS:
Their valence shells are deficient of electrons, therefore, they readily accept electrons to complete their
valence shells and become stable.
They form ionic compounds with metals and covalent compounds by reacting with other non-metals e.g. CO2,
NO2, etc.
Non-metals usually do not react with water.
They do not react with dilute acids because non-metals are itself electron acceptors.
REACTIVITY OF THE HALOGENS
Elements of Group-17 of the periodic table consist of fluorine, chlorine, bromine, iodine and astatine. They are
collectively called halogens.
CHEMISTRY CLASS 10
CHAPTER 01
CHEMICAL EQUILIBRIUM
INTRODUCTION
A complete reaction is one in which all reactants have been converted into products.
Most chemical reactions do not go to completion because products react themselves to form the
reactants.
Quantities of reactants and products remain unchanged and it seems that the reaction has stopped.
In fact, these reactions do not stop; rather they take place on both directions at equal rate and attain
the equilibrium state. Such reactions are called reversible reactions.
Many examples of physical and chemical equilibrium are found in nature.
Many environmental systems depend for their existence on delicate equilibrium phenomenon.
For example, concentration of gases in lake water is governed by the principles of equilibrium
REVERSIBLE REACTION AND DYNAMIC EQUILIBRIUM
127
In a chemical reaction, the substances that combine are called reactants and the new substances formed
are called products.
For example, when H2 and O2 (reactants) combine they form H2O (product).
Most of the reactions, in which the products do not recombine to form reactants, are called irreversible
reactions.
They are supposed to complete and are represented by putting a single arrow between the reactants and
products.
On the other hand, reactions in which the products can recombine to form reactants are called reversible
reactions. These reactions never go to completion.
They are represented by a double arrow between reactants and products.
These reactions proceed in both ways, i.e., they consist of two reactions; forward and reverse. So, a
reversible reaction is one which can be made to proceed in either direction depending upon the
conditions.
A reaction between hydrogen and iodine:
Because one of the reactants, iodine is purple, while the product hydrogen iodide is colorless,
proceedings of the reaction are easily observable. On heating, hydrogen and iodine. vapours in a closed
flask, hydrogen iodide is formed. As a result, purple colour of iodine fades as it reacts to form colourless
hydrogen iodide.
In this case, hydrogen iodide acts as reactant and produces hydrogen and iodine vapours.
This reaction is reverse of the above. Therefore, it is called as reverse reaction.
When both of these reactions are written together as a reversible reaction, they are represented as:
WHEN CALCIUM OXIDE AND CARBON DIOXIDE REACT, THEY PRODUCE CALCIUM CARBONATE:
On the other hand, when CaCO3 is heated in an open flask, it decomposes to form calcium oxide and carbon
dioxide. CO2 escapes out and reaction goes to completion:
Initially only decomposition take place on (forward reaction), but after a while CO2 starts combining with
CaO to form CaCO3 (reverse reaction).
In the beginning, forward reaction is fast and reverse reaction is slow.
But eventually, the reverse reaction speeds up and both reactions go on at the same rate.
At this stage, decomposition and combination take place at the same rate but in opposite directions, as a
result amounts of CaCO3 , CaO and CO2 do not change. It is written as:
Suppose [A], [B], [C] and [D] are the molar concentrations (mol dm-3) of A, B, C and D respectively.
According to the Law of Mass Action:
129
2. For the reaction of nitrogen with hydrogen to form ammonia, the balanced chemical equation is
The expression for the equilibrium constant for this reaction is:
For reactions in which the number of moles of reactants and product are not equal in the balanced
chemical equation, K of course, have units, e.g., for the reaction
concentration of the reactants and products at that particular moment in the equilibrium
expression.
Consider the gaseous reaction of hydrogen with iodine.
We withdraw the samples from the reaction mixture and determine the concentrations of H 2(g)
, I2(g) and HI(g) . Suppose concentrations of the components of the mixture are:
The subscript ‘t’ with the concentration symbols means that the concentrations are
measured at some time t, not necessarily at equilibrium.
When we put these concentrations into the equilibrium constant expression, we obtain a value
called the reaction quotient Q .
c
The reaction quotient for this reaction is calculated as:
As the numerical value of Qc (8.0) is less than Kc (57.0), the reaction is not at equilibrium. It
requires more concentration of product. Therefore, reaction will move in the forward direction.
The reaction quotient Qc is useful because it predicts the direction of the reaction by comparing
the value of Qc with Kc .
Thus, we can make the following generalization about the direction of the reaction.
If Qc < Kc ; the reaction goes from left to right, i.e., in forward direction to attain equilibrium.
If Qc > Kc ; the reaction goes from right to left, i.e., in reverse direction to attain equilibrium.
If Qc = Kc ; forward and reverse reactions take place at equal rates i.e., equilibrium has been
attained.
PREDICTING EXTENT OF A REACTION
It indicates that the rates of decomposition of N 2O4 and combination of NO2 to form N2O4
are almost comparable to each other.
132
CHAPTER 02
ACID, BASE AND SALT
INTRODUCTION
Acids, bases and salts are three distinct classes in which almost all the organic and inorganic compounds are
classified.
A famous Muslim Chemist Jabir Bin Hayan prepared nitric acid (HNO3 ), hydrochloric acid (HCl) and sulphuric
acid (H2SO4 ).
In 1787, Lavoisier named binary compounds of oxygen such as CO2 and SO2 as acids which on dissolution in water
gave acidic solutions.
Later on in 1815, Sir Humphrey Davy discovered that there are certain acids which are without oxygen, e.g.,
HCl. Davy proved the presence of hydrogen as the main constituent of all acids.
It was also discovered that all water soluble metallic oxides turn red litmus blue, which is a characteristics of
bases.
The word acid is derived from the Latin word ‘Acidus’ meaning sour.
The first acid known to man was acetic acid, i.e., in the form of vinegar.
A little concentration of hydrochloric acid in our stomach, which helps to break down the food.
The alkali neutralizes the acid, producing a harmless chemical called a salt.
CONCEPTS OF ACIDS AND BASES
Acids and bases are recognized by their characteristic properties, such as:
ACID
Acids have sour taste. For example, unripe citrus fruits or lemon juice.
They turn blue litmus red.
They are corrosive in concentrated form.
Their aqueous solutions conduct electric current
BASES
Bases have bitter taste and feel slippery, for example, soap is slippery to touch.
They turn red litmus blue.
They are non-corrosive except concentrated forms of NaOH and KOH.
Their aqueous solutions conduct electric current.
ARRHENIUS CONCEPT OF ACIDS AND BASES
According to Arrhenius concept (1787):
Acid is a substance which dissociates in aqueous solution to give hydrogen ions.
In general, the ionization of acids take place as follows.
For example, substances such as HC1, HNO3 , CH3 COOH, HCN, etc., are acids because they ionize in aqueous solutions to
provide H+ ions.
On the other hand, base is a substance which dissociates in aqueous solution to give hydroxide ions
The general ionization of bases take place as follows;
133
The substances such as NaOH, KOH, NH4 OH, Ca(OH)2 etc. are bases because these compounds ionize in aqueous solutions
to provide OH ions
It is a reversible reaction. In the forward reaction, HCl is an acid as it donates a proton, whereas H O is a
base as it accepts a proton.
In the reverse reaction, Cl- ion is a base as it accepts a proton from acid H O+ ion.
CI ion is called a conjugate base of acid HCl and H O+ion is called a conjugate acid of base H2O.
It means every acid produces a conjugate base and every base produces a conjugate acid such that there is
conjugate acid-base pair.
Conjugate means joined together as a pair.
A conjugate acid is a specie formed by accepting a proton by a base.
A conjugate base is a specie formed by donating a proton by an acid.
Thus, conjugate acid-base pair differs from one another only by a single proton.
Similarly
134
According to Bronsted-Lowry concept, an acid and a base always work together to transfer a proton.
That means, a substance can act as an acid (proton donor) only when another substance simultaneously
behaves as a base (proton acceptor).
For example, H2O acts as a base when it reacts with HCl as stated above and as an acid when it reacts with
ammonia such as:
Such a substance that can behave as an acid, as well as, a base is called amphoteric.
All Arrhenius acids are Bronsted-Lowry acids, but except OH other Bronsted-Lowry bases are not
Arrhenius bases
CONJUGATE ACID-BASE PAIRS OF COMMON SPECIES
Acid Base Conjugate acid Conjugate base
CH3COOH(aq) + H2O(I)
H3O+(aq) + CH3COO (aq)
The product of any Lewis acid-base reaction is a single specie, called an adduct.
So, a neutralization reaction according to Lewis concept is donation and acceptance of an electron pair to form a
coordinate covalent bond in an adduct.
Acids are electron pair acceptors while bases are electron pair donors. Thus, it is evident that any substance which
has an unshared pair of electrons can act as a Lewis base while a substance which has an empty orbital that can
accommodate a pair of electrons acts as Lewis acid.
Examples of Lewis acids and bases are given below:
LEWIS ACIDS
According to Lewis concept, the following species can act as Lewis acids:
Molecules in which the central atom has incomplete octet. For example, in BF3 , AICI3 , FeCl3 , the central
atoms have only six electrons around them, therefore, these can accept an
Simple cations can act as Lewis acids. All cations act as Lewis acids since they are deficient in electrons. However,
135
cations such as Na+, K+, Ca2+ ions, etc., have a very little tendency to accept electrons. While the cations like H+,
Ag+ ions, etc., have a greater electron accepting tendency therefore, act as Lewis acids.
LEWIS BASES.
According to Lewis concept, the following species can act as Lewis bases:
Neutral species having at least one lone pair of electrons. For example, ammonia, amines, alcohols etc.
act as Lewis bases because they contain a lone pair of electrons:
Negatively charged species or anions. For example, chloride, cyanide, hydroxide ions, etc., act as Lewis bases:
Acids react explosively with metals like sodium, potassium and calcium. However, dilute acids (HCl, H 2SO4) react
moderately with reactive metals like: Mg, Zn, Fe and Al to form their respective salts with the evolution of hydrogen
gas.
Acids react with carbonates and bicarbonates to form corresponding salts with the evolution of carbon dioxide gas.
(aq)
Acids react with bases (oxides and hydroxides of metal and ammonium hydroxide) to form salts and water. This
process is called neutralization.
Acids react with sulphites and bisulphites to form salts with the liberation of Sulphur dioxide gas.
136
USES OF ACIDS
Sulphuric acid is used to manufacture fertilizers, ammonium sulphate, calcium superphosphate, explosives,
paints, dyes, drugs. It is also used as an electrolyte in lead storage batteries.
Nitric acid is used in manufacturing of fertilizer (ammonium nitrate), explosives, paints, drugs and etching designs on copper
plates.
Hydrochloric acid is used for cleaning metals, tanning and in printing industries.
Benzoic acid is used for food preservation.
Acetic acid is used for flavouring food and food preservation. It is also used to cure the sting of wasps.
Acid Source
i Citric acid Citrus fruits i.e., lemon, oranges
ii Lactic acid sour milk
iii Formic acid Stings of bees and ants
iv Butyric acid Rancid butter
v Tartaric acid Tamarind, grapes, apples
vi Malic acid Apples
vii Uric acid Urine
viii Stearic acid Fats
Bases react with acid to form salt and water. It is a neutralization reaction.
PRECIPITATION OF HYDROXIDES
Alkalis precipitate insoluble hydroxides when added to solutions of salts of heavy metals such as copper, iron, zinc,
lead and calcium.
137
USES OF BASES
Sodium hydroxide is used for manufacturing of soap.
Calcium hydroxide is used for manufacturing of bleaching powder, softening of hard water and neutralizing acidic soil
and lakes due to acid rain.
Potassium hydroxide is used in alkaline batteries.
Magnesium hydroxide is used as a base to neutralize acidity in the stomach. It is also used for the treatment of bee’s
stings.
Aluminum hydroxide is used as foaming agent in fire extinguishers.
Ammonium hydroxide is used to remove grease stains from clothes.
pH SCALE
Concentration of hydrogen ion [H+] in pure water is the basis for the pH scale.
Water is a weak electrolyte because it ionizes very slightly into ions in a process called auto- ionization or
self-ionization;
Since the pH scale is logarithmic, a solution of pH 1 has 10 times higher concentration of [H+] than that of a
solution of pH 2; 100 times than that of a solution of pH 3 and so on.
Hence, low pH value means strong acid while high pH value means a strong base and vice versa.
CONCLUSION
pH of a neutral solution is always 7.
Acidic solutions have pH less than 7.
Basic solutions have pH value greater than 7.
pH and pOH values range from 0 to 14.
USES OF PH
It is used to determine acidic or basic nature of a solution.
It is used to produce medicines, culture at a microbiological particular concentration of H+ ion.
It is used to prepare solutions of required concentrations necessary for certain biological reactions.
INDICATORS
Indicators are the organic compounds.
They have different colors in acidic and alkaline solutions.
Litmus is a common indicator.
It is red in acidic solutions and blue in alkaline solutions.
Each indicator has a specific color in acidic medium which changes at a specific pH to another color in basic
medium.
For example, phenolphthalein is colorless in strongly acidic solution and red in strongly alkaline solution. It
changes color at a pH of about 9.
This means phenolphthalein is colorless in a solution with pH less than 9.
If the pH is above 9, phenolphthalein is red.
MEASURING PH OF A SOLUTION
UNIVERSAL INDICATOR
ACIDIC SALTS
These salts are formed by partial replacement of a replaceable H+ ions of an acid by a positive metal
ion.
BASIC SALTS
Basic salts are formed by the incomplete neutralization of a polyhydroxy base by an acid.
DOUBLE SALTS
Double salts are formed by two normal salts when they are crystallized from a mixture of
equimolar saturated solutions.
The individual salt components retain their properties.
The anions and cations give their respective tests.
Mohr’s salt FeSO4 (NH4 )2 SO4 6H2 O; Potash alum K2SO4 . Al2(SO4)3 . 24H2O; Ferric alum K2SO4 .
Fe2(SO4)3 . 24H2O, are examples of double salts.
MIXED SALTS
Mixed salts contain more than one basic or acid radicals. Bleaching powder Ca(OCl) CI, is an example of
mixed salts.
COMPLEX SALTS
Complex salts on dissociation provides a simple cation and a complex anion or vice versa. Only the simple
ions yields the characteristics test for cation or anion. For example:
Potassium ferrocyanide K4 [Fe(CN)6) gives on ionization, a simple cation K+ and complex anion [Fe (CN)6] 4.
USES OF SALTS
Sodium chloride (NaCI):
It is commonly used as a table salt and for cooking purposes, it is also used for de-icing roads in winter and for the
manufacture of sodium metal, caustic soda, washing soda.
Sodium carbonate Na2CO3, 10H2O) Washing soda:
It is used as cleaning agent for domestic and commercial purposes, for softening of water, in manufacture of chemicals
like caustic soda (NaOH), borax, glass, soap and paper.
Sodium sulphate Na2SO4
It is used for the manufacture of glass, paper and detergents.
Sodium silicate (Na2SiO3)
It is used for the manufacture of detergents, cleaning agents and adhesives.
Sodium chlorate (NaCIO3)
It is used for manufacture of explosives, plastics and other chemicals.
Sodium tetraborate (Na2B4O7. 10H2O)
It is used for manufacture of heat resistance glass (pyrex), glazes and enamels, in leather industry for soaking and cleaning
hides.
Calcium chloride (CaCI2)
It is used for de-icing roads in winter, as a drying agent of chemical reagents and as freezing agent.
Calcium oxide (CaO) Quick lime
It is used as drying agent for gases and alcohol and in steel making, water treatment and other chemicals like slaked lime,
bleaching powder, calcium carbide. For purification of sugar, a mixture of CaO and NaOH called soda lime is used to remove
carbon dioxide and water vapours from air.
Calcium sulphate (CaSO4. 2H2O)
Gypsum is used as fertilizer, to prepare plaster of Paris which is used for making statues, casts, etc.
Potassium Nitrate (KNO3)
It is used as fertilizer and for the manufacture of flint glass.
NEUTRALIZATION REACTION
A reaction between an acid and a base is called a neutralization reaction.
It produces a salt and water.
141
ACID RAIN
Acid rain is formed by dissolving acidic air pollutants like oxides of Sulphur and nitrogen by rain water. As a
result pH of the rain water decreases, i.e., it becomes acidic.
When this acid rain falls down, it damages animals, plants, buildings, water bodies and even soil.
CHAPTER 03
ORGANIC CHEMISTRY
INTRODUCTION
The simplest class of organic compounds is hydrocarbons (compounds consisting of only carbon and hydrogen
elements).
Hydrocarbons are divided into four general classes, depending upon the nature of bonds present in their
molecules.
These are alkanes, alkenes, alkynes and aromatics.
Each carbon atom of a hydrocarbon has four bonds.
Hydrocarbons are further classified as saturated and unsaturated.
The members of these classes have different chemical properties because of different nature of bonds
present in them.
They are almost nonpolar and insoluble in water.
They dissolve readily in non-polar solvents.
They are gases or volatile liquids and their volatility decreases with the increase of molecular mass.
That is the reason low molecular mass hydrocarbons are gases at room temperature, such as: CH4 and
C2H6.
Moderate molecular mass hydrocarbons are liquids, such as, C6H14;
While higher molecular m a s s hydrocarbons are solids.
Fossil fuels are hydrocarbons.
They are not only major sources of energy but also are raw materials used to make thousands of consumer
products.
Hydrocarbons are the starting materials for the synthesis of organic chemicals of commercial importance.
These chemicals are essential for making plastics, synthetic rubbers, synthetic fibres and fertilizers, etc.
HYDROCARBONS
Hydrocarbons are those compounds which are made up of only carbon and hydrogen elements. Hydrocarbons
are regarded as the parent organic compounds since other organic compounds are considered to be derived from
them by the replacement of one or more hydrogen atoms by other atoms or group of atoms.
TYPES OF HYDROCARBONS
On the basis of structure, hydrocarbons are divided into two main classes:
OPEN CHAIN OR ALIPHATIC HYDROCARBONS:
These are the compounds in which the first and the last carbon are not directly joined to each other.
The open chains of carbon may be straight or branched.
For example
The hydrocarbons in which two carbon atoms are linked by a triple bond are called alkynes.
For example, ethyne and propyne.
The general formula of saturated hydrocarbons is CnH2n+2 , where n is the number of carbon atoms in one
molecule of the alkane.
UNSATURATED HYDROCARBONS:
The hydrocarbons in which two carbon atoms are linked by a double or a triple bond are called unsaturated
hydrocarbons.
The compounds in which two carbon atoms are linked by a double bond are called alkenes. For example, ethene and
propene.
These compounds have general formula CnH2n and functional group >C= C<.
CLOSED CHAIN OR CYCLIC HYDROCARBONS:
Compounds having rings of carbon atoms in their molecules are called closed chain or cyclic hydrocarbons, e.g.
benzene (C6H6), cyclobutane and cyclohexane.
ALKANES
The simplest hydrocarbons are alkanes.
In these compounds, all the bonds of carbon atoms are single that means valencies of carbon atoms are
saturated.
Therefore, they are least reactive.
That is the reason, alkanes are called paraffins (para means less, and affins means affinity or reactivity).
Alkanes form a homologous series of compounds in which each successive member of the
series differs by a CH2 group but they have similar structures and similar chemical properties.
The first member of the series is methane (CH4), next ethane (C2H6), then next propane (C3H8) and so on.
SOURCES OF ALKANES
The main sources of alkanes are petroleum and natural gas.
Methane forms about 85% of natural gas.
All the alkanes are obtained commercially by the fractional distillation of crude petroleum.
Marsh gas is formed by the bacterial decay of vegetable matter contains mostly methane.
Fuel gases obtained from coal gas contain alkanes in small amounts.
Methane occurs in gobar gas, sewage gas and biogas which are formed by the decomposition of cattle dung, excreta and
plant wastes.
PREPARATION OF ALKANES
HYDROGENATION OF ALKENES AND ALKYNES
Hydrogenation means addition of molecular hydrogen in alkenes and alkynes.
143
COMBUSTION
Alkanes burn in the presence of excess of air or oxygen to produce a lot of heat, carbon dioxide and water.
This reaction takes place in automobile combustion engines, domestic heaters and cooking appliances. It is highly
exothermic reaction and because of it alkanes are used as fuel.
OCCURRENCE
Alkenes being more reactive than alkanes, seldom occur free in nature.
Lower alkenes occur in coal gas in minute quantities.
Ethylene is present in natural gas sometimes to the extent of 20%.
Alkenes are produced in large amounts by cracking of petroleum.
PREPARATION OF ALKENES
Alkenes are prepared by the removal of small atoms (H,OH,X) from the adjacent carbon atoms of the saturated
compounds, so as to create a double bond between carbon atoms.
DEHYDRATION OF ALCOHOLS
Dehydration is removal of water.
Ethene is prepared by heating a mixture of ethanol and excess of concentrated sulphuric acid at 180°C.
In first step, ethyl hydrogen sulphate is formed which decomposes on heating to produce ethene, which is collected
over water.
compounds.
As a result, the double bond is converted into a single bond that is more stable.
Thus, addition reactions are characteristic property of unsaturated compounds.
These are the reactions in which the products are formed by the addition of some reagents like H2,Cl2, etc., to
an unsaturated organic compound.
In the process, one of the bonds of a double bond gets broken and two new single bonds are formed.
HYDROGENATION OF ALKENES
Hydrogenation means addition of molecular hydrogen to an unsaturated hydrocarbon in the presence of a catalyst
(Ni, Pt) to form saturated compound.
On industrial scale, this reaction is used to convert vegetable oil into margarine (Banaspati ghee).
HALOGENATION OF ALKENES
Halogenation means addition of halogen like chlorine or bromine.
Bromination of alkenes is very important reaction.
When bromine water (a solution of bromine in water having red-brown colour) is added to ethene in an inert
solvent like carbon tetrachloride, its colour is discharged at once.
In the reaction, double bond of ethene is converted into a single bond by the addition of a molecule of
bromine. This reaction is used to identify the unsaturation of an organic compound.
HYDROHALOGENATION OF ALKENES
Dry gaseous hydrogen halides (HI, HBr and HC1) react with alkenes to produce alkyl halides.
OCCURRENCE
Acetylene does not occur free in nature.
Traces of acetylene are present in coal gas (about 0.06%).
PREPARATION OF ALKYNES
Alkynes are prepared by the following methods.
DEHYDROHALOGENATION OF VICINAL DIHALIDES
When a vicinal dihalide is heated with alcoholic KOH, two hydrogen atoms along with two halogen atoms are
removed from two adjacent carbon atoms with the formation of a triple bond between the adjacent
carbons:
DEHALOGENATION OF TETRAHALIDES
When alkyl tetrahalides are heated with Zinc dust, the elimination of halogen atoms takes place to form ethyne.
PHYSICAL PROPERTIES
Alkynes also form a series of compounds. Its first member is acetylene. It is a colorless gas with faint garlic odour.
Acetylene is slightly soluble in water but soluble in organic solvents such a benzene, alcohol, acetone, ether, etc.
Acetylene is slightly lighter than air.
Alkynes are also flammable. They produce smokier flames than those of alkanes and alkenes.
CHEMICAL REACTIONS
Alkynes are reactive compounds because of presence of a triple bond.
A triple bond consists of two weak bonds and a strong bond.
When alkynes react with other substances, two weak bonds are readily broken one by one and addition takes place
easily.
The addition reactions of alkynes resemble those of alkenes.
ADDITION OF HALOGEN
Chlorine and bromine adds to acetylene to form tetrachloroethane and tetrabromoethane, respectively.
When bromine water is added to acetylene, red-brown color of bromine water is discharged rapidly due to
formation of colorless tetrabromoethane.
This intermediate product eliminates water molecules to for glyoxal, which is further oxidized to form oxalic acid.
USES OF ACETYLENE
Acetylene produces oxy-acetylene flame with oxygen. It is a highly exothermic reaction. Heat released is used for
welding purposes.
Acetylene is used to prepare other chemicals, such as alcohols, acetaldehyde and acids.
It is used for the ripening of fruits.
Itisusedforthemanufacturingof polymerproductslikepolyvinyl chloride,polyvinyl acetate and synthetic
rubber like neoprene.
It is polymerized to form benzene, which is used as raw material to form a variety of organic
compounds.
CHAPTER 04
BIOCHEMISTRY
INTRODUCTION
First time word “biochemistry” was used by a German chemist Carl Neuberg in 1903.
It deals with the naturally occurring macromolecules such as carbohydrates, proteins, lipids, nucleic acids
and vitamins.
These macromolecules are synthesized by living organisms from simple molecules present in the
environment.
Macromolecules are essential for us as they are reservoirs of energy. For example, carbohydrates we eat,
provide us energy.
Lipids are major source of energy. They are stored in the body to provide emergency energy supplies. They help
us to work during tough times.
Proteins not only provide us energy, they help us to stay strong by forming new bones and muscular tissues.
Moreover, proteins protect us against the diseases.
Nucleic acids are responsible for transmitting genetic information from generation to generation.
CARBOHYDRATES
Carbohydrates are macromolecules.
They have general formula Cn(H2O)n.
Carbohydrates are synthesized by plants through photosynthesis process.
Carbohydratesareclassified as:
1. Monosaccharides 2. Oligosaccharides 3. Polysaccharides
MONOSACCHARIDES
Monosaccharides are the simplest sugars which cannot be hydrolyzed.
They consist of 3 to 9 carbon atoms.
Therefore, they are classified according to the number of carbon atoms in their molecules as trioses, tetroses,
pentoses, hexoses, and so on.
The important monosaccharides are hexoses like glucose and fructose, etc.
Glucose is a pentahydroxy aldehyde while fructose is pentahydroxy ketone having the open chain structures and
general formula C6H12O6
These acids form esters (oils or fats) with glycerol in the presence of mineral acids.
Fats and oils are synthesized naturally by animals, plants and marine organisms.
Animal fats are found in adipose tissue cells. Animals secrete milk from which butter and ghee is obtained. Butter and
ghee are used for cooking and frying of food, for preparing bakery products and sweets.
Animal fats are used in soap industry.
Plants synthesize oils and store them in seeds, such as sunflower oil, coconut oil, groundnut oil and corn oil.
These oils are used as vegetable oils or ghee for cooking and other purposes.
Marine animals like salmon and whales are also source of oils. These oils are used as medicines, e.g. cod liver oil.
NUCLEIC ACIDS
Nucleic acids are essential components of every living cell.
They are generally long chain molecules made up of nucleotides.
Each nucleotide consists of three components; nitrogenous base, a pentose sugar and a phosphate
group.
There are two types of nucleic acids:
DEOXYRIBONUCLEIC ACID (DNA)
DNA consists of deoxyribose sugar.
Its structure was discovered by J. Watson and F. Crick in 1953.
It is long double stranded molecule consisting of two chains.
Each chain is made up of sugar, phosphate and a base.
The sugar and phosphate groups make the backbone of the chains and two chains are linked through bases.
The chains are wrapped around each other in a double helix form.
DNA is the permanent storage place for genetic information in the nucleus of a cell.
It carries and stores all genetic informations of the cell.
It passes these informations as instructions from generation to generation how to synthesize particular
proteins from amino acids.
These instructions are ‘genetic code of life’.
They determine whether an organism is a man or a tree or a donkey and whether a cell is a nerve cell or a muscle
cell.
The sequence of nitrogenous bases in DNA determines the protein development in new cells.
The function of the double helix formation of DNA is to ensure that no disorder takes place.
DNA carries genes that controls the synthesis of RNA.
Errors introduced into the genes synthesize faulty RNA.
It synthesizes faulty proteins that do not function the way they are supposed to.
This disorder causes genetic diseases.
RIBONUCLEIC ACID (RNA)
It consists of ribose sugar.
It is a single stranded molecule.
It is responsible for putting the genetic information to work in the cell to build proteins.
Its role is like a messenger.
RNA is synthesized by DNA to transmit the genetic information.
RNA receives, reads, decodes and uses the given information to synthesize new proteins.
Thus RNA is responsible for directing the synthesis of new proteins.
VITAMINS
In 1912 Hopkins noticed that in addition to carbohydrates, proteins and fats there are other substances needed for
normal growth.
Although these substances were needed in small quantity, yet these substances were called Accessory Growth
Factors.
Later Funk proposed the name Vitamin for these substances.
He discovered Vitamin B1 (Thiamin).
TYPES OF VITAMINS
Vitamins are divided into two types:
FAT SOLUBLE VITAMINS
The vitamins which dissolve in fats are called fat soluble vitamins.
These are vitamin A, D, E and K.
If these vitamins are taken in large quantity, they accumulate in the body and cause diseases. For example,
accumulation of vitamin D in the body causes bone-pain and bone- like deposits in the kidney.
However, their deficiency also causes diseases. Sources, uses and diseases because of deficiency
WATER SOLUBLE VITAMINS
The vitamins that dissolve in water are called water soluble vitamins.
These vitamins are B complex (this include 10 vitamins) and vitamin C (ascorbic acid). Water soluble vitamins are
151
products while others are used to improve texture or flavors of the product.
CHAPTER 05
ENVIRONMENTAL CHEMISTRY I
ATMOSPHERE
INTRODUCTION
The scientific study of chemical and biological events that occur in natural setting is called environmental
chemistry.
Our planet the Earth has four natural systems; lithosphere, hydrosphere, atmosphere and biosphere.
The study of composition of atmosphere provides us the knowledge about significance of gases present in the
atmosphere.
The earth is surrounded by a layer of gases called atmosphere. Or Atmosphere is the envelope of different gases around
the Earth.
Atmosphere is divided into four regions.
Each region has its natural characteristics.
COMPOSITION OF ATMOSPHERE
Atmosphere continuously from the Earth’s surface outwards without any boundary.
About 99% of atmospheric mass lies within 30 kilometers of the surface and 75% lies within the lowest 11 kilometers.
Percentage composition of atmosphere by volume is shown in Table
COMPOSITION OF DRY
AIR
Gas % by Volume
Nitrogen 78.09
Oxygen 20.94
Argon 0.93
Carbon 0.03
dioxide
153
DO YOU KNOW?
Sunlight has short wavelength radiations.
Solar energy absorbed by the Earth surface is transformed into heat energy which is of longer wavelength.
On the average, there is total 32% reflection of light: 6% being reflected from the Earth’s surface and 26% being
reflected back into space because of clouds, gases and dust particles in the atmosphere. 18% of sunlight is
absorbed by atmospheric gases.
The remaining 50% reaches upto the Earth and is absorbed by it.
This energy is radiated as heat energy of longer wavelength which is absorbed by water vapours and CO2 in atmosphere.
LAYERS OF ATMOSPHERE
Atmosphere consists of four spheres (layers) extending from the surface of the Earth upwards.
The concentration of the component gases decreases gradually upwards, that results in gradual decrease of
pressure.
Depending upon the temperature variation, atmosphere is divided into four regions.
Temperature decreases from 17°C to -58°C regularly in the lowest layer extending upto 12 km. This layer of
atmosphere is called troposphere. Above this layer lies the stratosphere that extends upto 50 km.
In this layer, temperature rises upto 2°C.
Beyond the stratosphere lies the mesosphere, covering upto 85 km.
In this region, again temperature decreases down to -93°C. Beyond 85 km lies the thermosphere, in which temperature
goes on increasing upwards.
TROPOSPHERE
The major constituents of troposphere are nitrogen and oxygen gases.
These two gases comprise 99 % by volume of the Earth’s atmosphere.
Both of these gases allow visible light to pass through but absorb infrared radiations emitted by the Earth’s
surface.
Therefore, these gases absorb much of the outgoing radiations and warm the atmosphere.
As the concentration of gases decreases gradually with the increase of altitude, correspondingly temperature also
decreases at a rate of 6°C per kilometer.
This is the region where all weathers occur.
Almost all aircrafts fly in this region.
STRATOSPHERE
This region is next to troposphere and extends up to 50 kilometers.
In this region, temperature rises gradually up to 2°C.
The presence of ozone (due to absorption of radiation) in this region is responsible for the rise of temperature in
stratosphere.
Within this region, temperature increases as altitude increases, such as lower layer temperature is about -58°C and
upper layer is about 2°C.
Since ozone in the upper layer absorbs high energy ultraviolet radiations from the Sun, it breaks down into
monoatomic (O) and diatomic oxygen (O2 ).
154
The lower stratosphere receives very low UV radiations, thus monoatomic oxygen is not found here and ozone is not
formed here.
POLLUTANTS
A pollutant is a waste material that pollutes air, water or soil.
Three factors determine the severity of a pollutant, its chemical nature, concentration and persistence.
These pollutants are being created and discharged to the environment by human activities. They make the
environment (air, water or soil) harmful to life.
So the pollutants are those substances which cause pollution.
While contaminants are those substances that make something impure.
The harmful substances present in air are called air pollutants.
Air pollutants change the weather, badly affect the human health, damage the plants and destroy buildings.
TYPES OF POLLUTANTS
Major air pollutants are classified as primary pollutants and secondary pollutants.
Primary pollutants are the waste or exhaust products driven out because of combustion of fossil fuels and organic matter.
These are oxides of sulphur (SO2 and SO3 ); oxides of carbon (CO2 and CO); oxides of nitrogen (specially nitric oxide NO);
hydrocarbon (CH4 ); ammonia and compounds of fluorine. Secondary pollutants are produced by various reactions of
primary pollutants. These are sulphuric acid, carbonic acid, nitric acid, hydrofluoric acid, ozone and peroxy acetyl nitrate
(PAN).
SOURCES OF AIR POLLUTANTS
Different sources of air pollutants are described as:
Oxides of Carbon (CO2 and CO)
Sources of oxides of carbon are as follows:
Both of these gases are emitted due to volcanic eruption and decomposition of organic matter naturally.
However, the major source for the emission of these gases is the combustion of fossil fuels (coal, petroleum and
natural gas). Fossil fuels burnt in combustion engine of any type of automobile, kiln of any industry or open air
fires emit CO2 and CO.
Forest fires and burning of wood also emit CO2 and CO. Especially, when supply of oxygen is limited, emission of CO
dominates.
GREENHOUSE EFFECT AND GLOBAL WARMING
The CO2 forms a layer around the Earth like an envelope.
It allows the heat rays of the Sun to pass through it and reach up to the Earth.
These rays are reflected from the Earth surface and go back to upper atmosphere.
Normal concentration of CO2 layer retains enough heat to keep the atmosphere warm.
So, normal concentration of CO2 is necessary and beneficial for keeping the temperature warm.
Otherwise, the Earth would have been uninhabitable.
The Earth’s average temperature would be about -20°C, rather than presently average
temperature 15°C.
CO2 is not an air pollutant.
Rather, it is an essential gas for plants as O2 is essential for animals.
Plants consume CO2 in photosynthesis process and produce O2.
While animals use O2 in respiration and give out CO2.
In this way, a natural balance exists between these essential gases as represented here.
155
But this balance is being disturbed by emitting more and more CO2 in air through different human activities.
Although, CO2 is not a poisonous gas, yet its increasing concentration due to burning of fossil fuels in different human
activities is alarming.
CO2 in the atmosphere acts like a glass wall of a green house.
It allows UV radiations to pass through it but does not allow the IR radiations to pass through it.
It traps some of the infrared radiations emitted by the Earth.
Hence, increased concentration of CO2 layer absorbs the infrared radiations emitted by the Earth’s surface that
prevents heat energy escaping from the atmosphere.
It helps to stop surface from cooling down during night.
As the concentration of CO2 in air increases, less heat energy is lost from the surface of the Earth. Therefore, the
average temperature of the surface gradually increases. This is called greenhouse effect
This effect is proportional to amount of CO2 in air. Greater is amount of CO2, more is trapping of heat or
warming. Due to increased warming this phenomenon is also called global warming.
EFFECTS OF GLOBAL WARMING
Accumulation of carbon dioxide in air is resulting in increasing atmospheric temperature about 0.05 °C every year.
It is causing major changes in weather patterns. Extreme weather events are occurring more commonly and intensely
than previously.
It melts glaciers and snow caps that are increasing flood risks and intense tropical cyclones.
Sea-level is rising due to which low lying areas are liable to be submerged, turning previously populated areas no longer
habitable.
ACID RAIN AND ITS EFFECTS
As you have studied, burning of fossil fuels produces oxides of sulphur and nitrogen in air.
Rain water converts SO2 into H2SO4 and NOx to HNO2and HNO3 .
Normal rain water is weakly acidic because it consists of dissolved CO2 of the air.
Its pH is about 5.6 to 6.
But rain water on dissolving air pollutants (acids) becomes more acidic and its pH reduces to 4. Thus, acid rain is
formed on dissolving acidic air pollutants such as Sulphur dioxide and nitrogen dioxide by rain water.
EFFECTS OF ACID RAIN
Acid rain on soil and rocks leaches heavy metals (Al, Hg, Pb, Cr, etc) with it and discharges these metals into rivers and lakes.
This water is used by human beings for drinking purpose.
These metals accumulate in human body to a toxic level.
On the other hand, aquatic life present in lakes also suffers because of high concentration of these metals.
Especially high concentration of aluminum ions clogs the fish gills. It causes suffocation and ultimately death of fish.
Acid rain attacks the calcium carbonate present in the marble and limestone of buildings and monuments. Thus, these
buildings are getting dull and eroded day by day.
Acid rain increases the acidity of the soil. Many crops and plants cannot grow properly in such soil. It also increases the
toxic metals in the soil that poison the vegetation.
Even old trees are affected due to acidity of soil.
Their growth is retarded. They get dry and die.
Acid rain directly damages the leaves of trees and plants, thus limiting their growth.
Depending upon the severity of the damage, plants growth can be hampered.
Plants capability to resist cold or diseases reduces and ultimately they die.
OZONE DEPLETION AND ITS EFFECTS
Ozone is an allotropic form of oxygen consisting of three oxygen atoms.
It is formed in atmosphere by the association of an oxygen atom with an oxygen molecule in the mid of stratosphere.
Ozone is present throughout the atmosphere.
But its maximum concentration called ozone layer lies in stratosphere region about 25 to 30 km away from the Earth’s
surface.
This layer surrounds the globe and protects Earth like a shield from harmful ultraviolet radiations ofsunlight.
Otherwise, ultraviolet radiations would cause skin cancer.
Thus ozone layer in stratosphere is beneficial for life on the Earth.
Under normal conditions ozone concentration in stratosphere remains nearly constant through a series of
156
But this ozone layer is being depleted through various chemical reactions.
However, chlorofluorocarbons (CFCs ) (used as refrigerants in air conditioners and
refrigerators) are major cause of depletion of ozone layer.
These compounds leak in one way or other escape and diffuse to stratosphere.
Ultraviolet radiations break the C-Cl bond in CFCI3 and generates chlorine free radicals
as:
These free radicals are very reactive. They react with ozone to form oxygen as:
A single chlorine free radical released by the decomposition of CFCs is capable of destroying upto many lacs of ozone
molecules.
The region in which ozone layer depletes is called ozone hole.
Signs of ozone depletion were first noticed over Antarctica in 1980s.
Since 1990s depletion has also been recorded over the Arctic, as well.
EFFECTS OF OZONE DEPLETION
Even minor problems of ozone depletion can have major effects.
Depletion of ozone enables ultraviolet radiations of Sun to reach to the Earth that can cause skin cancer to human beings
and other animals.
Decreased ozone layer will increase infectious diseases like malaria.
It can change the life cycle of plants disrupting the food chain.
It can change the wind patterns, resulting in climatic changes all over the world. Especially,
Asia and Pacific will be the most affected regions, facing climate induced migration of people crisis.
CHAPTER 06
ENVIRONMENTAL CHEMISTRY II
WATER
OCCURRENCE OF WATER
The oceans contain about 97% of world’s water.
The rest of the water is in the form of glaciers, ice caps, groundwater and inland water (rivers, lakes,
streams).
It is also present in atmosphere in the form of water vapours.
Sea water is unfit for drinking and agricultural purposes due to high percentage of dissolved salts.
Only 0.2% of the total water on the Earth is potable, i.e. fit for drinking purposes.
PROPERTIES OF WATER
Water is composed of two elements: oxygen and hydrogen.
One atom of oxygen combines with two atoms of hydrogen to form one molecule of water.
Pure water is a clear, colourless, odourless and tasteless liquid with following properties:
It is neutral to litmus.
Its freezing point is 0°C and boiling point is 100 °C at sea level.
Its maximum density is 1 gcm-3 at 4°C.
It is excellent solvent for ionic as well as molecular compounds.
It has unusually high heat capacity about 4.2 Jg-1K-1, which is about six times greater than that of rocks.
It has high surface tension. This unique property of water is responsible for its high capillary action. Capillary action is
the process by which water rises up from the roots of plants to leaves.
This process is vital for the survival of the land plants.
WATER AS SOLVENT
Water is the universal solvent because it can dissolve almost all the minerals.
Its ability to dissolve substances is because of two unique properties of water:
157
The analytical chemistry consist of two main types of analysis which are as follows
QUALITATIVE ANALYSIS:
The identification of elements, ions or compounds present in sample is called qualitative
analysis.
Qualitative analysis does not measure the quantity of substance but measure the quality of
that material.
Qualitative analysis is performed by selective chemical reactions or with the use of
instrumentation. For example: chemical test and flame test.
Qualitative analysis further divided on the basis of chemical test are as follows:
ORGANIC QUALITATIVE ANALYSIS:
It deals with the identification of presence of d i f f e r e n t c l a s s e s o f o r g a n i c c o m p o u n d s o r
functional groups by producing colors in chemical r e a c t i o n s .
F o r e x a m p l e : f o r m a t i o n o f w h i t e precipitate by adding silver nitrate (AgNO3) in dilute nitric
acid (HNO3) indicate the presence of halide (X-F, CI, Br,l) .
ORGANIC QUALITATIVE ANALYSIS:
It deals with the identification of elements.
For example: flame test of copper halide which shows bluish-green color due to
presence of copper.
QUANTITATIVE ANALYSIS:
The determination of how much amount or quantity of one or more substance present
in compound or sample is called quantitative analysis.
It deals with large number of quantifying methods which are classified as physical or
chemical.
Physical methods measure physical properties such as density, temperature, absorption
of light, magnetic influences, color, and texture.
The physical methods used to measure these properties are Fourier transform infrared spectroscopy
(FTIR), Atomic emission spectroscopy (AES), trace element analysis and energy d isp ersive X —ray
spectroscopy (EDS).
Chemical methods measure chemical reactions such as precipitation, oxidation or neutralization and
measured by volumetric analysis, gravimetric analysis and combustion analysis.
IMPORTANT PARAMETERS:
The parameter is measureable factor or boundary which define performance and quality of analytical
methods.
The validation of any analytical method is observed by parameters and various parameters of
validation are selectivity, linearity, range,accuracy, precision and error.
ERROR
Error can be defined as numerical difference between observed value and true value
All type of analytical methods or experiments we observe many errors and deviations.
These errors are due to 13% equipment failure, 13% human error, 16% sample preparation and 10% wrong
calibration.
So we can say that factors which produce the error are defect in instrument, lack in handling the apparatus or improper
functioning of the instrument.
Errors in analytical chemistry are dassified as systematic and random errors.
Systematic error are also known as determinate error and caused by defect in the analytical method
or improper functioning of instrument.
Systematic error may be instrumental, observational, environmental and theoretical. For example a
thermometer, peppet , burette ,analytical balance and volumetric ware shows error in measurement.
A systematic error can be estimated and eliminated but there is always some uncertainty in every
physical measurement and mostly avoided.
Random Errors are also known as indeterminate error and caused by variations of procedure,
environmental factors and limitations of instrumentation.
Random error are unavoidable and may be positive and negative.
Measuring a mass of a sample on analytical balance may produce different reading due to effect of
air or water on sample or analytical balance.
ACCURACY
The accuracy of analytical method is the closeness of obtained value to the true value of a sample,
for example if you obtain weight 2.5mg of sample or substance but actual or known weight of
sample is 10mg then your measurement is not accurate.
Accuracy is the most difficult parameter to validate.
Accuracy is degree of agreement between the measured value and true value.
160
An absolute true value is very rarely obtained due to this more realistic definition of accuracy is an
agreement between a measured value and the accepted true value.
PRECISION
The Precision Is defined as the degree of agreement between replicate measurements of the same
quantity. It is repeatability of a result and known as degree of exactness.
Precision is measured how much detailed information is given and how much exactly measurement
was taken.
CLASSICAL METHOD
The classical methods are the fundamental laboratory practicing techniques.
It is a traditional method of chemical analysis and also known as wet chemical method.
Classical methods are those analytical techniques which does not use any mechanical or electronic instrument rather
than weighing balance.
This method basically related with the chemical reactions between analyte and reagents.
The classical methods posses' quantitative as well as quantitative analysis.
Such as chemical and flame tests are qualitative and titrimatic and gravimetric analysis are quantitativeanalysis.
TITRIMETRIC ANALYSIS
The titrimetric analysis Is used to determine the volume of a solution with known concentration which react with the
measured volume of solution of a substance quantitatively .
The Titrimetric analysis is also known as volumetric analysis in which general rule of titration is applied in which
volumetric measurement of a reagent takes place which is known as titrant and this titrant complete its chemical reaction
with analyte .
What is titrant?
A-tit-rant is a solution of known concentration that is added to another solution to determine the
concentration of a second chemical species.for example NaOH ,Ha
What is analyte?
A chemical substance that is subject of chemical analysis or constituent going to be measure.
For example 24 karat gold, NaCI , water etc
What is indicator?
Indicator is a substance which change the color with acidic and alkaline solution.
Eg:Litmus, Phenolphthalein, Methyl orange
GRAVIMETRIC ANALYSIS
Gravimetric analysis is the oldest and important technique for quantitative estimation in chemical analysis
This technique involve determination of constituent by weight, it is one of the most accurate analytical
method for quantitative estimation.
In this analysis an amount of analyte is determined by converting the analyte to some product and
then weighing it. For example you want to determine the amount of chlorine (CI) present in solution of
AgCI then you have to go through following 4 steps for gravimetric analysis.
(1) Preparation of a solution with known weight of sample (Aga).
(2) Separation of the desired constituent (CI).
(3) Weighing Separated constituent.
(4) Computation of amount of separated constituent in the sample.
The gravimetric calculation based on gravimetric factor which convert the grams of the
compound in to grams of the single element.
There are four types of gravimetric analysis which are Physical, Therrno, Precompetitive and Electra
gravimetric analysis.
ADVANCED INSTRUMENTAL METHODS
The methods used as quantitative and qualitative analysis.
These analytical advanced instrumental methods includes spectroscopy,
,chromatography , electrochemical methods ,ultra violet and visible spectroscopy,
infrared spectroscopy ,HPLC, gas chromatography, potentiomcrtric and conduc -
tornetr.
SPECTROSCOPIC METHODS
Spectroscopy is the interaction of light with matter, light is composed of electromagnetic
waves so interaction of matter with radiative energy as function of wavel ength or
frequency is called spectroscopy.
Spectroscopy used in physical and analytical chemistry f o r t h e i d e n t i f i c a t i o n o f
s u b s t a n c e s t h r o u g h t h e e m i s s i o n o r a b s o r p t i o n spectrum. Interaction of light
with matter.
The spectroscopy used to assess concentration or amount of given chemical (atomic,
molecular or ionic) and the instruments used for measurement are called spectrometer,
161
spectrophotometer, spectrograph.
ULTRAVIOLET AND VISIBLE SPECTROSCOPY
The ultraviolet and visible spectroscopy is also known as electronic spectroscopy.
It is a quantitative technique which measure how much a chemical compound absorb light.
This is done by measuring the intensity of light passing through the sample.
The basic principal of this spectroscopy is interaction between light and matter but here light
wavelength is ultraviolet and process is formation of spectrum due to absorption of ultra violet light to
the chemical compound or sample.
The wavelength range of ultraviolet and visible spectroscopy is 192 to 900nm.
INFRARED SPECTROSCOPY
The Infrared spectroscopy is analytical technique introduced in 1950, which qualify and quantify the
information about samples in less time and cost effective.
It is non-hazardous because no any polluting chemical is required for this analysis.
It is basically used for specification of functional groups in food products, polymers and industries now
a days.
It is an effective tool for quality control in different industries.
Electromagnetic radiations lower in energy than visible radiations are called infra- red radiation.
The ordinary IR region extends from 2.5 pm(wavelength )to 15 pm(wavelength) or 4000 to
625 cm-' (wave number).
When IR radiations passed through an organic molecule, the energy absorbed by the molecule is sufficient to
produce vibrations in the molecules and the energy which is not absorbed is transmitted through the sample .
It is also known as vibrational spectroscopy.
CHROMATOGRAPHIC METHODS
Chromatography is the modem analytical technique which is used for separation of compounds.
Chromatography process starts with the mobile phase in which solutes are dissolved in substance and carry to next stationary
phase.
The different components of mixture travel from mobile to stationary phase with different speed and retention time.
Th e ma in ty p e s of ch ro mat og rap h y ar e g as chromatography and liquid chromatography.
HIGH PERFORMANCE LIQUID CHROMATOGRAPHY (H PLC)
What is H PLC?
The HPLC stands for high performance liquid chromatography, sometimes it also consider as high pressure liquid
chromatography.
It is the technique to separate out the substances.
HPLC instrument is consisting of reservoir of mobile phase, a pump, an Injector, a separation column, a detector
and data acquisition computer.
The mobile liquid phase is pumped through the column packed with the absorbent, hence separation
becomes more rapid.
The pressure mechanical pump ensures the rapid solvent flow.
These instruments are used in drug discovery, clinical analysis, cosmetic analysis, pharmaceutical,
enviormental chemistry and biochemical genetics.
What is mobile phase ?
Moving fluid stream of liquid containing sample up to stationary phase is called mobile phase .
What is stationary phase?
Stationary phase is not moveable.
What is retention time ?
T h e t i m e t a k e n f o r separation of components in compound from start to the elution or exit is called
r e t e n t i o n t i m e . T h i s retention time helps to identify the components of compounds.
GAS CHROMATOGRAPHY
A gas chromatography is a technique used in analytical chemistry for the separation of volatile
compounds.
The word gas chromatography is clear from its word that it is used for the separation of gases and volatile
liquids in gaseous state.
The separation takes place by the exchange between a mobile gas phase and a liquid or solid stationary
phase.
The first gas chromatograph was introduced by noble prizewinner John Porter Martin in 1950 and considered
as father of modem gas chromatography.
The instrument of Gas chromatography is consisting of Gas cylinder, sample injector, Gas chromartograph,
detector and data collection device.
Where Gas is mobile phase and Gas cylinder controls the gas passage up to sample injector, which proceeds toward
two columned gas chromartograph it is a stationary phase with uniform temperature.
162
When compound reach the detector it detect the elution and send signals to data collection device
(computer).
The gas chromatography used in analysis of inorganic compound, carbohydrates, proteins, lipids,
vitamins, pollutants like benzene, plastic materials and dairy product.
ELECTROCHEMICAL METHODS
The electrochemical method is an analytical technique which deal with measurement of potential, charge,
electrical quantity or property of a solution.
The measurement carried out by the use of certain instrument due to this known as advanced
instrumental methods. These methods are useful because of consuming less time and without any
suitable indicators.
The electrochemical analytical method is carried out with the help of electrochemical cell, generally
it consist of electrodes named as anode and cathode.
Anode possess negative sign due to liberation of electrons in oxidation reaction and cathode possess
positive sign due to consumption of electrons in reduction reaction.
The electrochemical cells consists of two half cells, both are connected with an electrode (anode
and Cathode) and each electrode is dipped in electrolytic solution which is ZnSO, at Anode and
CLASOI at cathode.
The half cells are connected by means of salt bridge (NaCI) which provides a platform for ionic
connectivity without mixing, as we discuss that one of half cell losses electron due to oxidation and
other half gains electrons in reduction process.
POTENTIOMETRY
Potentiometry is method used in electroanalytical chemistry to find the concentration of solute in solution
in potentiometric measurement.
The potential between two electrodes is measured by voltmeter.
There is no any flow of current.
Potentiometric analysis is used in analysis of pollutant in water, pharmaceutical and drugs, quality control in food
industry and clinical chemistry.
CONDUCTOMETRY
Conductometry is one of the important analytical technique which is used in physico —chemical analysis.
It can be defined as a technique of analysis which is based on the measurement of electrical
conductance.
It is done by the help of conductivity meter.
CHAPTER 08
INDUSTRIAL CHEMISTRY
INTRODUCTION
Almost everything used in human life for the human survival is made up of chemical products.
In the modem world Chemical industries play an important role.
In every industrial process chemical products are involved which play an essential vital role.
The Chemical industry is the one responsible industry for converting raw materials like Petroleum, water, air,
minerals, crops, metals and etc into more valuable products.
There are several chemical products which have assumed the status of integral part of our daily life some of
them are soaps, sugar, soft drinks, Medicines and several petroleum like Liquefied Petroleum Gas (LPG),
natural gas (stove gas) or compressed natural gas (CNG), polymers, petrol, diesel, lubricating oils and bitumen
(damar).
There are more than 70,000 different products that are manufactured through chemical industries.
PREPARATION OF SOAP
What is saponification?
Saponification is the reaction of triglycerides with sodium or potassium hydroxide to create glycerol and 'soap,'
a fatty acid salt.
Animal fats or vegetable oils are the most common sources of triglycerides.
A hard soap is created when sodium hydroxide is used.
The use of potassium hydroxide produces a soft soap.
When soap is dissolved in water, grime may be washed away.
It may be used to treat skin lesions cleansing your body in some situations.
However, we now use soap mostly for its aroma and as a cleaning.
Household uses for soaps include washing, bathing, and other types of housekeeping, where soaps act as
surfactants, emulsifying oils to enable them to be carried away by water.
In industry, they are used as thickeners, components of some lubricants, and precursors to catalysts.
MATERIAL NEEDED FOR SOAP PREPARATION:
163
The raw material needed for the preparation of soap are as follows:
• Animal Fat
• Plant Oil
• Caustic Soda
• Potassium hydroxide
• Additives (color, texture, scent )
• Abrasives (silica, talc, marble)
ANIMAL FAT:
Animal fat tallows from cows, such as lard, are often used for soap making.
PLANT OIL:
Soybean oil, like canola, safflower, and sunflower, is often used as a portion of a soap making recipe
in combination with other 'core' oils like coconut, olive, and palm. It's pretty unremarkable, but if
you have it on hand, use it 5-15% of your soap recipe.
It is mild, moisturizing and gives a low creamy lather.
CAUSTICSODA/ POTASSIUM HYDROXIDE (ALKALI)
Caustic soda (NaOH) causes saponification and is an essential ingredient in soap-making.
When flakes or beads of sodium hydroxide get added to a liquid, it forms a lye solution.
This solution, when mixed with oils or fats, will lead to the chemical reaction called saponification.
SODIUM HYDROXIDE:
Sodium hydroxide is employed as alkali for the saponification of soap now a days.
Soap may also be manufactured with potassium hydroxide (caustic potash) as the alkali.
Potassium soaps are more soluble in water than sodium soaps; in concentrated form, they are
called soft soap.
ADDITIVES:
The major raw materials for soap manufacture are fat and alkali.
Other substances, such as optical brighteners, colour, texture, scent, water softeners, are known
as additives.
ABRASIVE:
Water-insoluble minerals such as talc, diatomaceous earth, silica, marble, volcanic ash (pumice), chalk,
feldspar, quartz, and sand are often powdered and added to soap or synthetic detergent
formulations. Abrasives of an organic nature, such as sawdust, are also used. Abrasives help in
removing grease and dirt from skin.
PREPARATION OF SUGAR FROM SUGAR CANE
The preparation of sugar from sugar cane composed of following steps.
Harvesting and delivery
Juice extraction
Clarification
Concentration
Crystallization
Crystal separation and drying
MATERIAL NEEDED FOR SUGAR PREPARATION
The raw material needed for the preparation of sugar from sugar cane are as follows: • Sugar cane beads
• Lime
• Water
PREPARATION OF SOFT DRINKS
The basis of soft drinks, the syrup, is made up of water, sugar, acid, coloring and flavoring agents. This syrup
is prepared by dissolving these ingredients into water to 65° Brix.
MATERIAL REQUIRED FOR PREPARATION OF SOFT DRINK
The preparation of sugar from soft drinks compose of following steps.
Water
Cal c iu m an d oth er m in e ral s
Co lor in g an d fl a vor in g a gen t
Su gar for microb ial growth.
Citric acid for sour taste.
PETROLEUM INDUSTRY
PETROLEUM
Petroleum is a natural substance trapped in rocks beneath the Earth's crust.
The term "petroleum" refers to rock oil.
Water; salts, and earth particles are all present in this complex combination of gaseous,
liquid, and solid hydrocarbons.
164
PHYSICS CLASS 09
CHAPTER 01
PHYSICAL QUANTITIES
AND MEASUREMENT
Physics is the branch of science which observes the nature represents it mathematically and conclude with the
experiment.
Physics Derived from Ancient Greek ‘physicos’ meaning ‘knowledge of nature’.
It basically deals with the behavior and structure of matter and the energy that derives the matter.
Physics is the branch of natural science that studies matter, its motion, its behavior through space and time and
the related entities of energy and force.
MECHANICS
This branch of physics is mainly concerned with the laws of motion and gravitation.
THERMODYNAMICS
Thermodynamics deals with heat and temperature and their relation to energy and work.
ELECTRICITY
Electricity is the study of properties of charges in rest and motion
MAGNETISM
Magnetism is the study of magnetic properties of materials
ATOMIC PHYSICS
Atomic physics deals with the composition structure and properties of the atom.
OPTICS
Optics studies physical aspects of light and its properties with the help of optical instruments.
SOUND
165
MEASURING INSTRUMENTS
A physical quantity is a physical property of a phenomenon, body, or substance that canbe quantified by
measurement.
A physical quantity can be expressed as the combination of a magnitude expressed by a number –usually a real
number – and a unit.
Physical quantities are classified into two categories:
1. Fundamental quantities
2. Derived physical quantities.
Physical quantities which cannot be explained by other physical quantities are called fundamental physical
quantities.
Fundamental quantities S.I Unit Symbol of Unit
Length meter m
Mass Kilogram kg
Time second s
Electric current Ampere A
Temperature Kelvin K
Amount of substance mole mol
Luminous intensity candela cd
Physical quantities which are explained on the basis of fundamental physical quantities are called derived physical
quantities.
Derived Quantities S.I Unit Symbol of Unit
Volume Cubic meter m3
Velocity meter per second m/s
Force Newton N
Density kilogram per cubic meter kg/m3
Acceleration meter per second square m/s2
The notion of physical dimension of a physical quantity was introduced by Joseph Fourier in 1822 by convention,
physical quantities are organized in a dimensional system built upto base quantities, each of which is regarded as
having its own dimension.
Use of every instrument is restricted by smallest measurement that it can perform which is called least count.
THE STANDARD OF LENGTH
The length is defined as the minimum distance between two points lying on same plane.
For examples units of length include the inch, foot, yard, mile, meter etc.
The meter (m) is the SI unit of length and is defined as:
The length of the path traveled by light in vacuum during the time interval of 1/299 792 458 of a second.
The basic measurement of length can be obtained with the help of a meter rod or an inch tape.
1000m = 1km
100cm =1m
1cm = 10mm
1inch = 2.53cm
12 inch = 1 ft
1 yard = 3ft
METER RULE
A meter rule is a device which is used to measure length of different objects. A meter rule of length 1m is equal
to 100 centimeters (cm). On meter rule each cm is divided further in to 10 divisions which are called millimeters
(mm). So, a meter rule can measure up to 1mm as smallest reading.
VERNIER CALIPER
The Vernier Caliper is a precision instrument that can be used to measure internal and external distance extremely
166
accurate. It has both an imperial and metric scale. A Vernier caliper has main jaws that are used for measuring
external diameter, as well as smaller jaws that are used for measuring the internal diameter of objects. Some
models also have a depth gauge. The main scale is fixed in place, while the Vernier scale is the name for the sliding
scale that opens and closes the jaws.
MICROMETER SCREW GAUGE
Screw gauge in extensively used in engineering field for obtaining precision measurements.
Micrometer screw gauge is used for measuring extremely small dimensions.
Micrometer Screw gauge works on the simple principle of converting small distances into larger ones by measuring
the rotation of the screw. This “screw" principle facilitates reading of smaller distances on a scale after amplifying
them.
THE STANDARD OF MASS
The kilogram is the SI unit of mass and is equalto the mass of the international prototype of the kilogram, a
platinum-iridium standard that is kept at the International Bureau of Weights and Measures.
The kilogram is a cylinder of special metal about 39 millimeters wide by 39 millimeters tall that serves as the
world's mass standard.
The kilogram, originally defined as: The mass of one cubic decimeter of water at the temperature of maximum
density. It was replaced after the International Metric Convention in 1875 by the international Prototype Kilogram.
1000g = 1kg
1g = 1000mg
1g= 1000000mg
1g=1000000000ng
1g=0.002lb
THE PHYSICAL BALANCE
The Physical balance is an instrument used for measurement of mass. It is mostly used in laboratory. It works on
the principle of moments. It consists of a light and rigid beam of brass, a metallic pillar, a wooden base, two pans,
a metallic pointer and an ivory scale.
THE ELECTRONIC BALANCE
The digital mass meter is an electronic instrument configured with integrated circuits and it works on the principal
of balancing the forces.
The device is turned on and set to zero then object is placed on the plate. The reading on the screen gives the
mass of object.
THE STANDARD OF TIME
Before 1960, the standard of time was defined in terms of the mean solar day for the year 1900.
In 1967, the second was redefined to take advantage of the high precision attainable in a device known as an
atomic clock, which uses the characteristic frequency of the cesium-133 atom as the “reference clock”.
The second is now defined as 9 192 631 770 times the period of vibration of radiation from the cesium atom.
STOP WATCH
A stopwatch is used to measure the time interval between two events. There are two types of stopwatch :
Mechanical stopwatch and Digital stopwatch.
MECHANICAL / ANALOGUE STOPWATCH
A mechanical stop watch can measure a time interval up to 0.1 second.
DIGITAL STOPWATCH
A digital stop watch can measure a time interval up to 0.01 second.
HUMAN REACTION TIME
As analogue or digital or watch is operated by human manually i.e., they have to be started or stopped by hand.
This causes a random error in measurement of time i.e called human reaction time.
1 hour = 60 min
1 hour = 3600 sec
1min=60sec
1sec=1000ms
1sec=1000000ms
PREFIXES
167
Prefixes are the words or letters added before SI units such as kilo, mega, giga and milli.
SCIENTIFIC NOTATION
A simple but scientific way to write large or small numbers is to express them in some power of ten.
The Moon is 384000000 meters away from the Earth.
8
Distance of the moon from the Earth can also be expressed as 3.84 x10 m.
This form of expressing a number is called the standard form or scientific notation. This saves writing down or
interpreting large numbers of zeros.
Thus, In scientific notation a number is expressed as some power of ten multiplied by a number between 1
and 10.
3 4 5
For example, a number 62750 can be expressed as 62.75x10 or 6.275x10 or 0.6275x10 .
4
All these are correct. But the number that has one non-zero digit before the decimal i.e. 6.275x10 preferably
be taken as the standard form.
SIGNIFICANT FIGURES
The significant figures are all the digits that are known accurately and the one estimated digit.
More significant figure means greater precision.
The following rules are helpful in identifying significant figure:
1. Non-zero digits are always significant.
2. Zeros between two significant figures are also significant.
3. Final or ending zeros on the right in decimal fraction are significant.
4. Zeros written on the left side of the decimal point for the purpose of spacing the decimal
point are not significant.
5. In whole numbers that end in one or more zeros without a decimal point. These zeros may
or may not be significant. In such cases, it is not clear which zeros serve to locate the position
value and which are actually parts of the measurement. In such a case, express the quantity using
scientific notation to find the significant zero.
The direction of this acceleration is the same in which the body is moving without change in its direction.
Acceleration of a body is negative if velocity of the body decreases.
The direction of negative acceleration is opposite to the direction in which the body is moving.
Negative acceleration is also called deceleration or retardation.
EQUATIONS OF MOTION
There are three basic equations of motion for bodies moving with uniform acceleration. These equations relate
initial velocity, final velocity, acceleration, time and distance covered by a moving body.
To simplify the derivation of these equations, we assume that the motion is along a straight line.
Hence, we consider only the magnitude of displacements, velocities, and acceleration.
Consider a body moving with initial velocity vi in a straight line with uniform acceleration a.
Its velocity becomes vf after time t.
The motion of body is described by speed-time graph as shown in figure by line AB.
The slope of line AB is acceleration a.
The total distance covered by the body is shown by the shaded area under the line AB. Equations of motion can
be obtained easily from this graph.FIRST EQUATION OF MOTIONSpeed-time graph for the motion of a body is
shown in figure.
Slope of line AB gives the acceleration a of a body.
𝐵𝐶 𝐵𝐷−𝐶𝐷 𝑉𝑓−𝑉𝑖
Slope of line AB = a = = , As BD = Vf , CD = Vi and OD = t, Hence a = Or Vf – Vi = at, Vf = Vi + at
𝐴𝐶 𝑂𝐷 𝑡
SECOND EQUATION OF MOTION
In speed-time graph shown in figure. The total distance S travelled by the body is equal to the total area OABD
under the graph. That is Total distance S= area of (rectangle OACD + triangle ABC), Area of rectangle OACD = OA x
OD, = Vi x t
1 1
Area of triangle ABC = (AC x BC), = t x at
2 2
Since total area = area of rectangle OACD
OABD + area of triangle ABC
1 1
Putting values in the above equation , we get; S = V it + t x at , S = Vit + at2
2 2
Speed
Gain in
speed=at
Area = t at
Area = vi t
t
Time
Speed-time graph. Area under
the graph gives the distance
covered by the body.
of their masses.
He dropped various objects of different masses from the leaning tower of Pisa.
He found that all of them reach the ground at the same time.
The acceleration of freely falling bodies is called gravitational acceleration.
-2
It is denoted by g. On the surface of the Earth, its value is approximately 10 ms .
For bodies falling down freely g is positive and is negative for bodies moving up.
EQUATIONS OF MOTION FOR BODIES MOVING UNDER GRAVITY
Vt = V1 + gt
H = V1t = ½ gt2
2gh = Vt2 – V12
CHAPTER 03
DYNAMICS
The branch of mechanics that deals with the study of motion of an object and the cause of its motion is called
dynamics.
FORCE, INERTIA AND MOMENTUM
FORCE
We can open a door either by pushing or pulling.
The push may move an object or change the direction of its motion or may stop the moving object.
A force may not always cause a body to move.
A force moves or tends to move, stops or tends to stop the motion of a body. The force can also change the
direction of motion of a body.
Force can also change the shape or size of a body on which it acts.
INERTIA
Inertia of a body is its property due to which it resists any change in its state of rest or motion.
Galileo observed that it is easy to move or to stop light objects than heavier ones.
Heavier objects are difficult to move or if moving then difficult to stop.
Newton concluded that everybody resists to the change in its state of rest or of uniform motion in a straight line.
He called this property of matter as inertia.
He related the inertia of a body with its mass; greater is the mass of a body greater is its inertia.
MOMENTUM
Momentum of a body is the quantity of motion it possesses due to its mass and velocity.
The momentum P of a body is given by the product of its mass m and velocity v. Thus P = mv
Momentum is a vector quantity.
-1
Its SI unit is kgms .
NEWTON'S LAWS OF MOTION
Newton was the first to formulate the laws of motion known as Newton's laws of motion.
NEWTON'S FIRST LAW OF MOTION
First law of motion deals with bodies which are either at rest or moving with uniform speed in a straight line.
According to Newton's first law of motion, a body at rest remains at rest provided no net force acts on it.
A body continues its state of rest or of uniform motion in a straight line provided no net force acts on it.
Newton's first law of motion is also known as law of inertia.
For example, a book lying on a table remains at rest as long as no net force acts on it.
Similarly, a moving object does not stop moving by itself.
NEWTON'S SECOND LAW OF MOTION
Newton's second law of motion deals with situations when a net force is acting on a body.
When a net force acts on a body, it produces acceleration in the body in the direction of the net force.
The magnitude of this acceleration is directly proportional to the net force acting on the body and inversely
proportional to its mass.
Newton’s second law of Motion states; If a force produces an acceleration a in a body of mass m, then we can
1 𝐹
state mathematically that a ∝ F And; a=∝ OR a = ∝ , F ∝ ma
𝑚 𝑚
Putting k as proportionality constant, we get F = kma ……………………(3.2)
In SI units, the value of k comes out to be 1. Thus Eq. 3.2 becomes F = ma ……………….. (3.3)
SI unit of force is newton (N).
-2
One newton (1 N) is the force that produces an acceleration of 1 ms in a body of mass of 1 kg.
According to Newton's second law of motion:
Thus, a force of one newton can be expressed as 1N = 1kg x 1 ms-2 , Or 1N = 1 kg ms-2 ………(3.4)
172
Final momentum of mass m2= m2v2Total final momentum of the system after collision =
m1v1+m2v2 ………………3.16)
According to the law of conserv=a tion of momentum
(Total initial momentum of the system before collision) = (Total final momentum the system after collision
M1U1 + m2U2 = m2V2 ………………………..(3.17)
FRICTION
The force that opposes the motion of moving objects is called friction.
Friction is a force that comes into action as soon as a body is pushed or pulled over a surface.
The contact points between the two surfaces form a sort of coldwelds.
Greater is the pressing force greater will be the friction between the sliding surfaces.
Friction is equal to the applied force that tends to move a body at rest.
It increases with the applied force.
Friction can be increased to certain maximum value.
173
The maximum value of friction is known as the force of limiting friction (Fs).
It depends on the normal reaction (pressing force) between the two surfaces in contact.
The ratio between the force of limiting friction Fs and the normal reaction R is constant. This constant is called the
coefficient of friction and is represented by µ
𝐹𝑠
Thus µ = ……………. (3.20)
𝑅
or Fs = µR ……………. (3.21)
If m be the mass of the block, then for horizontal surface;
R = mg ………………….. (3.22)
Hence Fs = µmg …………………
Some Trigonometric
Ratios
174
Ratio/ 0 30 45 60 90
0.5
0.707
0.866
0
1
sin
0.866
0.707
0.5
cos
0
0.577
1.732
tan
0
1
TORQUE OR MOMENT OF A FORCE
We open or close a door by pushing or pulling it.
Here push or pull turn the door about its hinge or axis of rotation.
The door is opened or closed due to the turning effect of the force acting on it.
The turning effect of a force is called torque or moment of the force.
RIGID BODY
A body is composed of large number of small particles. If the distances between all pairs of particles of the body
do not change by applying a force then it is called a rigid body.
In other words, a rigid body is the one that is not deformed by force or forces acting on it.
AXIS OF ROTATION
Consider a rigid body rotating about a line. The particles of the body move in circles with their centers all lying
on this line. This line is called the axis of rotation of the body.
Turning pencil in a sharpener, turning stopcock of a water tap, turning doorknob and so on are some of the examples
where a force produces turning effect.
LINE OF ACTION OF A FORCE
The line along which a force acts is called the line of action of the force.
MOMENT ARM
The perpendicular distance between the axis of rotation and the line of action of the force is called the moment
arm of the force.
It is represented by the distance L .
The torque or moment of a force depends upon the force F and the moment arm L of the force.
Greater is a force, greater is the moment of the force. Similarly, longer is the moment arm greater is the moment
of the force.
Thus the moment of the force or torque 𝜏 is determined by the product of force F and its moment arm
L. Mathematically, Torque𝜏 = 𝐹 × 𝐿
SI unit of torque is newton-metre (Nm).
A torque of 1 N m is caused by a force of 1 N acting perpendicular to the moment arm 1 m long.
PRINCIPLE OF MOMENTS
A force that turns a spanner in the clockwise direction is generally used to tighten a nut.
The torque or moment of the force so produced is called clockwise moment.
On the other hand, to loosen a nut, the force is applied such that it turns the nut in the anticlockwise direction.
The torque or moment of the force so produced is called anticlockwise moment.
A body initially at rest does not rotate if sum of all the clockwise moments acting on it is balanced by the sum of all the
anticlockwise moments acting on it. This is known as the principle of moments. According to the principle of
moments: A body is balanced if the sum of clockwise moments acting on the body is equal to the sum of
anticlockwise moments acting on it.
CENTRE OF MASS
It is observed that the centre of mass of a system moves as if its entire mass is confined at that point.
Centre of mass of a system is such a point where an applied force causes the system to move without rotation.
CENTRE OF GRAVITY
A point where the whole weight of the body appears to act vertically downward is called centre of gravity of a
body.
175
CHAPTER 05
FORCES AND MATTER
176
PRESSURE
The force acting normally per unit area on the surface of a body is called pressure.
Pressure is a scalar quantity.
-2 -2
In SI units, the unit of pressure is Nm also called pascal (Pa). Thus 1 Nm = 1 Pa
ATMOSPHERIC PRESSURE
The Earth is surrounded by a cover of air called atmosphere.
It extends to a few hundred kilometers above sea level.
Air is a mixture of gases.
The density of air in the atmosphere is not uniform.
It decreases continuously as we go up.
Atmospheric pressure acts in all directions.
MEASURING ATMOSPHERIC PRESSURE
-2
At sea level, the atmospheric pressure is about 101,300 Pa or 101,300 Nm .
The instruments that measure atmospheric pressure are called barometers.
One of the simple barometers is a mercury barometer.
It consists of a glass tube 1m long closed at one end.
At sea level the height of mercury column above the mercury in the trough is found to be about 76 cm.
-2
Pressure exerted by 76 cm of mercury column is nearly 101,300 Nm equal to atmospheric pressure.
It is common to express atmospheric pressure in terms of the height of mercury column.
As the atmospheric pressure at a place does not remains constant, hence, the height of mercury column also
varies with atmospheric pressure.
Mercury is 13.6 times denser than water.
Atmospheric pressure can hold vertical column of water about 13.6 times the height of mercury column at a
place.
Thus, at sea level, vertical height of water column would be 0.76 m x 13.6 = 10.34 m.
Thus, a glass tube more than 10 m long is required to make a water barometer.
VARIATION IN ATMOSPHERIC PRESSURE
The atmospheric pressure decreases as we go up.
The atmospheric pressure on mountains is lower than at sea level.
At a height of about 30 km, the atmospheric pressure becomes only 7 mm of mercury which is approximately
1000 Pa. It would become zero at an altitude where there is no air. Thus, we can determine the altitude of a
place by knowing the atmospheric pressure at that place.
Atmospheric pressure may also indicate a change in the weather.
On a hot day, air above the Earth becomes hot and expands. This causes a fall of atmospheric pressure in that
region.
On the other hand, during cold chilly nights, air above the Earth cools down. This causes an increase in
atmospheric pressure.
The changes in atmospheric pressure at a certain place indicate the expected changes in the weather conditions of
that place.
PRESSURE IN LIQUIDS
Liquids exert pressure.
The pressure of a liquid acts in all directions.
If we take a pressure sensor (a device that measures pressure) inside a liquid, then the pressure of the liquid
varies with the depth of sensor.
Consider a surface of area A in a liquid at a depth h. The length of the cylinder of liquid over this surface will be h.
The force acting on this surface will be the weight w of the liquid above this surface. If is the density of the liquid
and m is mass of liquid above the surface, then
Mass of the liquid cylinder m = volume x density = (A x h) x 𝜌
Force acting on area A F = w = mg
=Ah𝜌
177
As pressure P = F/A
𝐴ℎ𝜌𝑔
=
𝐴
Liquid pressure at depth h = P = 𝜌 g h………….. (1)
Equation (1) gives the pressure at a depth h in a liquid of density .
It shows that its pressure in a liquid increases with depth.
PASCAL'S LAW
Pascal's law which is stated as: Pressure, applied at any point of a liquid enclosed in a container, is transmitted
without loss to all other parts of the liquid.
In general, this law holds good for fluids both for liquids as well as gases.
APPLICATIONS OF PASCAL'S LAW
Pascal's law finds numerous applications in our daily life such as automobiles, hydraulic brake system, hydraulic
jack, hydraulic press and other hydraulic machine.
HYDRAULIC PRESS
Hydraulic press is a machine which works on Pascal's law.
It consists of two cylinders of different cross sectional areas. They are fitted with pistons of cross-sectional
areas a and A.
ARCHIMEDES PRINCIPLE
Archimedes principle states that: When an object is totally or partially immersed in a liquid, an up thrust acts on it
equal to the weight of the liquid it displaces.
Archimedes principle is applicable on liquids as well as gases. We find numerous applications of this principle in
our daily life.
DENSITY OF AN OBJECT
Archimedes principle is also helpful to determine the density of an object. The ratio in the weights of a body with an
equal volume of liquid is the same as in their densities.
Let Density of the object = D Density of the liquid = Weight of the object = w1
Weight of equal volume of liquid = w = w1 - w2
Here w2 is the weight of the solid in liquid.
According to Archimedes principle, w2 actual weight w1 by an amount w.
𝐷 𝑤1 𝑊1 𝑊1
Since = is less than its D = × 𝜌 Or D = = × 𝜌…………………(2)
𝜌 𝑤 𝑊 𝑤2−𝑤1
Thus, finding the weight of the solid in air w1 and its weight in water w2, we can calculate the density of the solid
by using equation 2.
PRINCIPLE OF FLOATATION
The principle of floatation states that: A floating object displaces a fluid having weight equal to the weight of
the object.
SHIPS AND SUBMARINES
According to the principle of floatation, a body floats if it displaces water equal to the weight of the body when it
is partially or completely immersed in water.
Ships and boats are designed on the same principle of floatation. They carry passengers and goods over water. It
would sink in water if its weight including the weight of its passengers and goods becomes greater than the up
thrust of water.
A submarine can travel over as well as under water.
It also works on the principle of floatation.
It floats over water when the weight of water equal to its volume is greater than its weight.
It has a system of tanks which can be filled with and emptied from seawater.
When these tanks are filled with seawater, the weight of the submarine increases.
As soon as its weight becomes greater than the up thrust, it dives into water and remains under water.
To come up on the surface, the tanks are emptied from seawater.
STRESS
Stress is related to the force producing deformation. It is defined as: The force acting on unit area at the
surface of a body is called stress
𝐹𝑜𝑟𝑐𝑒
Thus Stress =
𝐴𝑟𝑒𝑎
-2
In SI, the unit of stress is newton per square metre (Nm ).
STRAIN
Stress acts on a body, it may change its length, volume, or shape.
178
A ratio of such a change caused by the stress with the original length, volume or shape is called as strain. If
stress produces a change in the length of an object then the strain is called tensile strain.
𝐶ℎ𝑎𝑛𝑔𝑒 𝑖𝑛 𝑙𝑒𝑛𝑔𝑡ℎ
Tensile strain =
𝑂𝑟𝑖𝑔𝑖𝑛𝑎𝑙 𝑙𝑒𝑛𝑔𝑡ℎ
Strain has no units as it is simply a ratio between two similar quantities.
HOOKE'S LAW
Hooke's law states that: The strain produced in a body by the stress applied to it is directly proportional to the
stress within the elastic limit of the body.
Thus; Stress strain or Stress = constant x strain or Stress/strain = constant
Hooke's law is applicable to all kinds of deformation and all types of matter i.e., solids, liquids or gases within
certain limit.
This limit tells the maximum stress that can be safely applied on a body without causing permanent deformation
in its length, volume or shape.
In other words, it is a limit within which a body recovers its original length, volume or shape after the deforming
force is removed.
When a stress crosses this limit, called the elastic limit, a body is permanently deformed and is unable to restore
its original state after the stress is removed.
YOUNG'S MODULUS
The ratio of stress to tensile strain is called Young's modulus.
Mathematically, Y = Stress/Tensile strain
-2
SI unit of Young's modulus is newton per square metre (Nm )
CHAPTER 06
GRAVITATION
The first man who came up with the idea of gravity was Isaac Newton in 1665.
THE FORCE OF GRAVITATION
Newton concluded that the force which causes an apple to fall on the Earth and the force which keeps the moon in
its orbit are of the same nature.
He further concluded that there exists a force due to which everybody of the universe attracts every other body.
He named this force the force of gravitation.
LAW OF GRAVITATION
According to Newton's law of universal gravitation: Everybody in the universe attracts every other body with a
force which is directly proportional to the product of their masses and inversely proportional to the square of the
distance between their centers.
According to the law of gravitation, the gravitational force of attraction F with which the two masses m1 and m2
1 𝑚1 𝑚2 𝑚1 𝑚2
separated by a distance d attract each other is given by: F ∝ 𝑚1 𝑚2, F ∝ , F∝ ,F=G
𝑑2 𝑑2 𝑑2
Here G is the proportionality constant. It is called the universal constant of gravitation. Its value is same
-11 2 -2
everywhere. In SI units its value is 6.673x1 10 Nm kg .
The weight of an object on the Earth is the result of gravitational force of attraction between the Earth and the
object.
LAW OF GRAVITATION AND NEWTON'S THIRD LAW OF MOTION
The action and reaction due to force of gravitation are equal in magnitude but opposite in direction.
This is consistent with Newton's third law of motion which states, to every action there is always an equal but
opposite reaction.
According to the Newton's law of gravitation, the gravitational force between a body of mass m and the Earth is
𝑚𝑀
given by F = G 2 𝑒
𝑟
Where Me is the mass of the Earth and r is the distance of the body from the centre of the Earth.
GRAVITATIONAL FIELD
The region of space surrounding a body in which another body experiences a force of gravitational attraction is
called gravitational field.
It is assumed that a gravitational field exists all around the Earth.
This field is directed towards the centre of the Earth.
The gravitational field becomes weaker and weaker as we go farther and farther away from the Earth.
In the gravitational field of the Earth, the gravitational force per unit mass is called the gravitational field
179
Various materials differ in their hardness, density, solubility, flow, elasticity, conductivity and many other
qualities.
KINETIC MOLECULAR MODEL OF MATTER
The kinetic molecular model of matter has some important features. These are
Matter is made up of particles called molecules.
The molecules remain in continuous motion.
Molecules attract each other.
Kinetic molecular model is used to explain the three states of matter - solid, liquid and gas.
SOLIDS
Solids such as a stone, metal spoon, pencil, etc. have fixed shapes and volume.
Their molecules are held close by strong forces of attraction.
However, they vibrate about their mean positions but do not move from place to place.
LIQUIDS
The distances between the molecules of a liquid are more than in solids.
Thus, attractive forces between them are weaker.
Like solids, molecules of a liquid also vibrate about their mean position but are not rigidly held with each other.
Due to the weaker attractive forces, they can slide over one another. Thus, the liquids can flow.
The volume of a certain amount of liquid remains the same but because it can flow hence, it attains the shape of
a container to which it is put.
GASES
Gases such as air have no fixed shape or volume. They can be filled in any container of any shape.
Their molecules have random motion and move with very high velocities.
In gases, molecules are much farther apart than solids or liquids.
Thus, gases are much lighter than solids and liquids. They can be squeezed into smaller volumes.
The molecules of a gas are constantly striking the walls of a container.
Thus, a gas exerts pressure on the walls of the container.
PLASMA - THE FOURTH STATE OF MATTER
The kinetic energy of gas molecules goes on increasing if a gas is heated continuously. This causes the gas
molecules to move faster and faster. The collisions between atoms and molecules of the gas become so strong
that they tear off the atoms. Atoms lose their electrons and become positive ions. This ionic state of matter is
called plasma.
Plasma is also formed in gas discharge tubes when electric current passes through these tubes.
Plasma is called the fourth state of matter in which a gas occurs in its ionic state.
Positive ions and electrons get separated in the presence of electric or magnetic fields.
Plasma also exists in neon and fluorescent tubes when they glow.
Most of the matter that fills the universe is in plasma state.
In stars such as our Sun, gases exist in their ionic state.
Plasma is highly conducting state of matter. It allows electric current to pass through it.
DENSITY
Density of a substance is defined as its mass per unit volume.
𝒎𝒂𝒔𝒔 𝒐𝒇 𝒂 𝒔𝒖𝒃𝒔𝒕𝒂𝒏𝒄𝒆
Density =
𝒗𝒐𝒍𝒖𝒎𝒆 𝒐𝒇 𝒕𝒉𝒂𝒕 𝒔𝒖𝒃𝒔𝒕𝒂𝒏𝒄𝒆
-3
SI unit of density is kilogramme per cubic metre (kgm ).
𝑀𝑎𝑠𝑠 𝑀𝑎𝑠𝑠
Density equations: Density = Mass = 𝐷𝑒𝑛𝑠𝑖𝑡𝑦 × 𝑉𝑜𝑙𝑢𝑚𝑒 Volume =
𝑉𝑜𝑙𝑢𝑚𝑒 𝑉𝑜𝑙𝑢𝑚𝑒
DENSITIES OF COMMON SUBSTANCES
Material Density (g/cm3) State of Matter
Hydrogen (At STP) 0.00009 Gas
Helium (At STP) 0.000178 Gas
Carbon Monoxide (At STP) 0.00125 Gas
Nitrogen (At STP) 0.001251 Gas
Air (At STP) 0.001293 Gas
Carbon Dioxide (At STP) 0.001977 Gas
Lithium 0.534 Solid
181
Earth's atmosphere extends upward about a few hundred kilometers with continuously decreasing density. Nearly
half of its mass is between sea level and 10 km. Up to 30 km from sea level contains about 99% of the mass of the
atmosphere.
The air becomes thinner and thinner as we go up.
CHAPTER 08
ENERGY SOURCES AND TRANSFER OF ENERGY
Generally, work refers to perform some task or job.
Scientifically, work is done only when an effort or force moves an object.
When work is done, energy is used.
Thus, work and energy are related to each other.
The concept of energy is an important concept in Physics, it helps to identify the changes that occur when work
is done.
WORK
In Physics, work is said to be done when a force acts on a body and moves it in the direction of the force.
Naturally, greater is the force acting on a body and longer is the distance moved by it, larger would be the work
done.
Mathematically, Work is a product of force F and displacement S in the direction of force. Thus
Work done = Force x displacement
W = FS…………. (6.1)
Work is a scalar quantity.
It depends on the force acting on a body, displacement of the body and the angle between them.
SI unit of work is joule (J). It is defined as the amount of work is one joule when a force of one newton displaces
182
KINETIC ENERGY
The energy possessed by a body due to its motion is called its kinetic energy.
A moving body has kinetic energy, because it can do work due to its motion.
The body stops moving as soon as all of its kinetic energy is used up.
K.E. of the body = Work done by it due to motion K.E = FS
POTENTIAL ENERGY
The energy possessed by a body due to its position is known as its potential energy.
Often a body has the ability to do work although it is at rest. For example, an apple on a tree is capable to do work as
it falls.
Potential energy (P.E) = F x h = w x h
(Here weight of the body = w = P.E = wh = mgh
Thus, the potential energy possessed by the body with respect to the ground is mgh and is equal to the work done
in lifting it to height h
FORMS OF ENERGY
MECHANICAL ENERGY
The energy possessed by a body both due to its motion or position is called mechanical energy.
Water running down a stream, wind, a moving car, a lifted hammer, a stretched bow, a catapult or a
compressed spring etc. possess mechanical energy.
HEAT ENERGY
Heat is a form of energy given out by hot bodies.
Large amount of heat is obtained by burning fuel.
Heat is also produced when motion is opposed by frictional forces.
The foods we take provide us heat energy.
The Sun is the main source of heat energy.
ELECTRICAL ENERGY
Electrical energy can be supplied easily to any desired place through wires.
We get electrical energy from batteries and electric generators.
These electric generators are run by hydro power, thermal or nuclear power.
SOUND ENERGY
Sound is a form of energy.
It is produced when a body vibrates; such as vibrating diaphragm of a drum, vibrating strings of a sitar and
vibrating air column of wind instruments such as flute pipe etc.
LIGHT ENERGY
Light is an important form of energy. Name some sources of light that you come across.
Plants produce food in the presence of light.
We also need light to see things.
We get light from candles, electric bulbs, and fluorescent tubes and also by burning fuel.
However, most of the light comes from the Sun.
CHEMICAL ENERGY
Chemical energy is present in food, fuels and in other substances.
We get other forms of energy from these substances during chemical reactions.
The burning of wood, coal or natural gas in air is a chemical reaction which releases energy as heat and light.
Electric energy is obtained from electric cells and batteries as a result of chemical reaction between various
183
8 -1
Here c is the speed of light (3x10 ms ).
The above equation shows that tremendous amount of energy can be obtained from small quantity of matter.
It appears that matter is a highly concentrated form of energy.
The process of getting energy from our nuclear power plants is based on the above equation.
The process is taking place on the Sun and stars for the last millions of years.
ELECTRICITY FROM FOSSIL FUELS
Fossil fuels are burnt in thermal power stations to produce electricity.
Various energy conversion processes involved in producing electricity from coal.
EFFICIENCY
The efficiency of a machine defined as “Efficiency of a system is the ratio of required form of energy obtained
from a system as output to the total energy given to it as input.”
𝑅𝑒𝑞𝑢𝑖𝑟𝑒𝑑 𝑓𝑜𝑟𝑚 𝑜𝑓 𝑜𝑢𝑡𝑝𝑢𝑡 𝑅𝑒𝑞𝑢𝑖𝑟𝑒𝑑 𝑓𝑜𝑟𝑚 𝑜𝑓 𝑜𝑢𝑡𝑝𝑢𝑡
Efficiency = OR % Efficiency = x 100
𝑇𝑜𝑡𝑎𝑙 𝑖𝑛𝑝𝑢𝑡 𝐸𝑛𝑒𝑟𝑔𝑦 𝑇𝑜𝑡𝑎𝑙 𝑖𝑛𝑝𝑢𝑡 𝐸𝑛𝑒𝑟𝑔𝑦
POWER
Power is defined as the rate of doing work.
Mathematically, Power (P) = (𝑊𝑜𝑟𝑘 𝑑𝑜𝑛𝑒)/(𝑇𝑖𝑚𝑒 𝑇𝑎𝑘𝑒𝑛) OR P = 𝑊/𝑡
Since work is a scalar quantity, therefore, power is also a scalar quantity.
SI unit of power is watt (W).
-1
It is defined as the power of a body is one watt if it does work at the rate of 1 joule per second (1 Js ).
Bigger units of power are kilowatt (kW), megawatt (MW) etc.
1Kw = 1000 W = 103 W , 1MW = 1000000W = 106W ,1 Horse power = 1hp
CHAPTER 09
THERMAL PROPERTIES OF MATTER
TEMPERATURE AND HEAT
Temperature of a body is the degree of hotness or coldness of the body.
To understand the concept of temperature, it is useful to understand the terms, thermal contact and thermal
equilibrium.
To store ice in summer, people wrap it with cloth or keep it in wooden box or in thermos flask. In this way, they
avoid the thermal contact of ice with its hot surroundings otherwise ice will soon melt away.
Heat flows from a hot body to a cold body until thermal equilibrium is reached.
The form of energy that is transferred from a hot body to a cold body is called heat.
Heat is the energy that is transferred from one body to the other in thermal contact with each other as a result of the
difference of temperature between them.
Heat is therefore, called as the energy in transit. Once heat enters a body, it becomes its internal energy and no
longer exists as heat energy.
The sum of kinetic energy and potential energy associated with the atoms, molecules and particles of a
body is called its internal energy.
Internal energy of a body depends on many factors such as the mass of the body, kinetic and potential energies of
molecules etc.
Kinetic energy of an atom or molecule is due to its motion which depends upon the temperature.
Potential energy of atoms or molecules is the stored energy due to intermolecular forces.
The crocus flower is a natural thermometer. It opens when the temperature is precisely 23°C and closes when
the temperature drops.
THERMOMETER
A device that is used to measure the temperature of a body is called thermometer.
Some substances have property that changes with temperature.
Substances that show a change with temperature can be used as a thermometric material.
A thermometric liquid should have the following properties:
It should be visible.
It should have uniform thermal expansion.
It should have a low freezing point.
It should have a high boiling point.
It should not wet glass.
It should be a good conductor of heat.
It should have a small specific heat capacity.
185
LIQUID-IN-GLASS THERMOMETER
A liquid-in-glass thermometer has a bulb with a long capillary tube of uniform and fine bore.
A suitable liquid is filled in the bulb. When the bulb contacts a hot object, the liquid in it expands and rises in the
tube.
The glass stem of a thermometer is thick and acts as a cylindrical lens. This makes it easy to see the liquid level in
the glass tube.
Mercury freezes at-39 °C and boils at 357 °C.
Mercury is one of the most suitable thermometric material. Mercury-in-glass thermometers are widely used in
laboratories, clinics and houses to measure temperatures in the range from -10 °C to 150 °C.
LOWER AND UPPER FIXED POINTS
A thermometer has a scale on its stem.
This scale has two fixed points. The lower fixed point is marked to show the position of liquid in the
thermometer when it is placed in ice.
Upper fixed point is marked to show the position of liquid in the thermometer when it is placed in steam at
standard pressure above boiling water.
SCALES OF TEMPERATURE
A scale is marked on the thermometer.
The temperature of the body in contact with the thermometer can be read on that scale. Three scales of
temperature are in common use. These are:
1. Celsius scale or centigrade scale
2. Fahrenheit scale
3. Kelvin scale
On Celsius scale, the interval between lower and upper fixed points is divided into 100 equal parts.
The lower fixed point is marked as 0 °C and the upper fixed point is marked as 100 °C.On Fahrenheit scale, the
interval between lower and upper fixed points is divided into 180 equal parts.
Its lower fixed point is marked as 32 °F and upper fixed point is marked as 212 °F.
In SI units, the unit of temperature is kelvin (K) and its scale is called Kelvin scale of temperature.
The interval between the lower and upper fixed points is divided into 100 equal parts. Thus, a change in 1°C is
equal to a change of 1K.
The lower fixed point on this scale corresponds to 273 K and the upper fixed point is referred as 373 K.
The zero on this scale is called the absolute zero and is equal to - 273 °C.
A clinical thermometer is used to measure the temperature of human body. It has a narrow range from 35 °C to
42 °C. It has a constriction that prevents the mercury to return. Thus, its reading does not change until reset.
Do You Know?
Here F is the temperature on Fahrenheit scale and C is the temperature on Celsius scale.
S P E C I F I C H E AT C A PA C I T Y
The specific heat of a substance is defined as Specific heat of a substance is the amount of heat required to raise
the temperature of 1 kg mass of that substance through 1K.
△𝑄
Mathematically, C =
𝑚△𝑇
Generally, when a body is heated, its temperature increases. Increase in the temperature of a body is found to
be proportional to the amount of heat absorbed by it. It has also been observed that the
quantity of heat △Q required to raise the temperature △T of a body is proportional to the mass m of the body.
Thus △Q ∝ m △T or △Q = c m △ T
Here △Q is the amount of heat absorbed by the body and c is the constant of proportionality called the specific
heat capacity or simply specific heat.
In SI units, mass m is measured in kilogramme (kg), heat △Q is measured in joule (J) and temperature
-1 -1
increase △T is taken in kelvin (K). Hence, SI unit of specific heat is Jkg K .
Heat energy required to change unit mass of a substance from solid to liquid state at its melting point without
change in its temperature is called its latent heat of fusion.
When a substance is changed from solid to liquid state by adding heat, the process is called melting or fusion.
The temperature at which a solid starts melting is called its fusion point or melting point.
When the process is reversed i.e. when a liquid is cooled, it changes into solid state. The temperature at which a
substance changes from liquid to solid state is called its freezing point.
Different substances have different melting points. However, the freezing point of a substance is the same as its
melting point.
△𝑄𝑓
Latent heat of fusion is denoted by Hf HF = , △Qf= m Hf
𝑚
o
Ice changes at 0 C into water.
5 -1 5
Latent heat of fusion of ice is 3.36 x10 Jkg . That is; 3.36x10 joule heat is required to melt 1 kg of ice into
water at 0 °C.
LATENT HEAT OF VAPORIZATION
The quantity of heat that changes unit mass of a liquid completely into gas at its boiling point without any change
in its temperature is called its latent heat of vaporization.
When heat is given to a liquid at its boiling point, its temperature remains constant.
The heat energy given to a liquid at its boiling point is used up in changing its state from liquid to gas without any
increase in its temperature.
△𝑄𝑣
Latent heat of vaporization is denoted by Hv. Hv = or △Qv = mHv
𝑚
When water is heated, it boils at 100°C under standard pressure. Its temperature remains 100°C until it is changed
6 -1
completely into steam. Its latent heat of vaporization is 2.26 x10 J kg . That is; one kilogramme of water
6
requires 2.26x10 joule heat to change it completely into gas (steam) at its boiling point.
EVAPORATION
Evaporation is the changing of a liquid into vapours (gaseous state) from the surface of the liquid without heating
it.
Evaporation takes place at all temperature from the surface of a liquid.
The rate of evaporation is affected by various factors.
Temperature
Surface Area
Wind
Nature of the Liquid
Cooling is produced in refrigerators by evaporation of a liquefied gas.
This produces cooling effect.
Freon, a CFC, was used as a refrigerant gas. But its use has been forbidden when it was known that CFC is the
cause of ozone depletion in the upper atmosphere which results increase in amount of UV rays from the Sun.
The rays are harmful to all living matter. Freon gas is now replaced by Ammonia and other substances which are
not harmful to the environment.
THERMAL EXPANSION
Most of the substances solids, liquids and gases expand on heating and contract on cooling.
The kinetic energy of the molecules of an object depends on its temperature.
The molecules of a solid vibrate with larger amplitude at high temperature than at low temperature.
Thus, on heating, the amplitude of vibration of the atoms or molecules of an object increases. They push one
188
△𝐿
From equation (1), we get α = …………… (3)
𝐿𝑜△𝑇
Thus, we can define the coefficient of linear expansion of a substance as the fractional increase in its length per
kelvin rise in temperature.
Like linear expansion, the change in volume △V is found to be proportional to its original volume V0 and change in
temperature △ T. Thus △V ∝ Vo△T Or β V-Vo = βVo△T V= Vo(1+β△T)……………….. (1)
△𝑉
Where β is the temperature coefficient of volume expansion. Using equation 1, we get β = ……(2)
𝑉𝑜△𝑇
Thus, we can define the temperature coefficient of volume expansion as the fractional change in its volume per
kelvin change in temperature.
The coefficients of linear expansion and volume expansion are related by the equation: Β = 3α
o -3 3
Hence, the volume of brass cube at 100 C will be 1.0057 x 10 m .
CONSEQUENCES OF THERMAL EXPANSION
Why gaps are left in railway tracks? The expansion of solids may damage the bridges, railway tracks and roads as
they are constantly subjected to temperature changes. So provision is made during construction for expansion
and contraction with temperature. For example, railway tracks buckled on a hot summer day due to expansion if
gaps are not left between sections.
Bridges made of steel girders also expand during the day and contract during night. They will bend if their ends are
fixed. To allow thermal expansion, one end is fixed while the other end of the girder rests on rollers in the gap
left for expansion. Overhead transmission lines are also given a certain amount of sag so that they can contract
in winter without snapping.
APPLICATIONS OF THERMAL EXPANSION
In thermometers, thermal expansion is used in temperature measurements.
To open the cap of a bottle that is tight enough, immerse it in hot water for a minute or so. Metal cap expands and
becomes loose. It would now be easy to turn it to open.
Iron rims are fixed on wooden wheels of carts. Iron rims are heated. Thermal expansion allows them to slip over
the wooden wheel. Water is poured on it to cool. The rim contracts and becomes tight over the wheel.
BIMETAL STRIP
A bimetal strip consists of two thin strips of different metals such as brass and iron joined together.
On heating the strip, brass expands more than iron. This unequal expansion causes bending of the strip.
Bimetal thermometers are used to measure temperatures especially in furnaces and ovens.
189
PHYSICS CLASS 10
CHAPTER 11
GENERAL WAVE PROPERTIES
WAVES
Waves are carrier of energy and information over large distances.
Waves require some oscillating or vibrating source.
A wave is a disturbance in the medium which causes the particles of the medium to undergo vibratory
motion about their mean position in equal intervals of time.
There are two categories of waves:
1. Mechanical waves
2. Electromagnetic waves
Mechanical Waves: Waves which require any medium for their propagation are called mechanical waves.
Examples of mechanical waves are water waves, sound waves and waves produced on the strings and
springs.
Electromagnetic Waves: Waves which do not require any medium for their propagation are called
electromagnetic waves.
Radio waves, television waves, X-rays, heat and light waves are some examples of electromagnetic waves.
Electromagnetic waves consist of electric and magnetic fields oscillating perpendicular to each other.
TYPES OF MECHANICAL WAVES
Depending upon the direction of displacement of medium with respect to the direction of the propagation
of wave itself, mechanical waves may be classified as longitudinal or transverse.
Longitudinal waves can be produced on a spring (slinky) placed on a smooth floor or a long bench.
A series of disturbances in the form of waves will start moving along the length of the slinky. Such a wave consists of
regions called compressions, where the loops of the spring are close together, alternating with regions called
rarefactions (expansions), where the loops are spaced apart.
The distance between two consecutive compressions is called wavelength.
The compressions and rarefactions move back and forth along the direction of motion of the wave. Such a wave is
called longitudinal wave.
In longitudinal waves the particles of the medium move back and forth along the direction of propagation of wave.
Longitudinal waves move faster through solids than through gases or liquids.
Transverse waves move through solids at a speed of less than half of the speed of longitudinal waves.
Transverse wave is defined as: In case of transverse waves, the vibratory motion of particles of the
medium is perpendicular to the direction of propagation of waves.
The crests are the highest points while the troughs are the lowest points of the particles of the medium from the
mean position.
The distance between two consecutive crests or troughs is called wavelength.
The crests and troughs move perpendicular to the direction of the wave.
Waves on the surface of water and light waves are examples of transverse waves.
190
Generating a high frequency wave, requires more energy per second than to generate a low frequency wave. Thus,
a high frequency wave carries more energy than a low frequency wave of the same amplitude.
Earthquake produces waves through the crust of the Earth in the form of seismic waves. By studying such waves,
the geophysicists learn about the internal structure of the Earth and information about the occurrence of future
Earth activity.
RELATION BETWEEN VELOCITY, FREQUENCY AND WAVELENGTH
Wave is a disturbance in a medium which travels from one place to another and hence has a specific velocity of
travelling. This is called the velocity of wave which is defined by Velocity = distance/time, V = d/t
If time taken by the wave in moving from one point to another is equal to its time period T, then the distance covered
𝝀
by the wave will be equal to one wavelength λ, hence we can write: V =
𝐼
1
But time period T, is reciprocal of the frequency f, i.e., T= Therefore, v= 𝑓𝝀………………….(1)
𝑓
Eq. (1) is true both for longitudinal and transverse waves.
RIPPLE TANK
Ripple tank is a device to produce water waves and to study their characteristics.
This apparatus consists of a rectangular tray having glass bottom and is placed nearly half metre above the surface
of a table.
Waves can be produced on the surface of water present in the tray by means of a vibrator (paddle).
This vibrator is an oscillating electric motor fixed on a wooden plate over the tray such that its lower surface just touches
the surface of water.
Reflection of waves defined as: when waves moving in one medium fall on the surface of another medium they
bounce back into the first medium such that the angle of incidence is equal to the angle of reflection.
The speed of a wave in water depends on the depth of water.
Refraction of waves defined as: When a wave from one medium enters into the second medium at some
angle, its direction of travel changes.
The bending or spreading of waves around the sharp edges or corners of obstacles or slits is called diffraction.
SIMPLE HARMONIC MOTION (SHM)
A body is said to be vibrating if it moves back and forth or to and fro about a point. Another term for vibration is
oscillation. A special kind of vibratory or oscillatory motion is called the simple harmonic motion (SHM).
Simple harmonic motion (SHM) is a to and fro oscillatory motion in which acceleration of the body is directly
proportional to the displacement of the body from the mean position and is always directed towards the
mean position.
Time taken by the simple pendulum to complete one cycle is called its time period. It depends upon the length of the
pendulum and is independent of the mass and amplitude of the pendulum.
The motion of mass attached to a spring on a horizontal frictionless surface, the motion of a ball placed in a
bowl and the motion of a bob attached to a string are examples of SHM.
Important features of SHM are summarized as:
A body executing SHM always vibrates about a fixed position.
Its acceleration is always directed towards the mean position.
The magnitude of acceleration is always directly proportional to its displacement from the
mean position i.e., acceleration will be zero at the mean position while it will be maximum at
the extreme positions.
Its velocity is maximum at the mean position and zero at the extreme positions.
DIFFERENT TERMS WHICH CHARACTERIZE SIMPLE HARMONIC MOTION
Vibration: One complete round trip of a vibrating body about its mean position is called one vibration.
Time Period (T ): The time taken by a vibrating body to complete one vibration is called time period.
Frequency ( f ): The number of vibrations or cycles of a vibrating body in one second is called its frequency. It is
reciprocal of time period i.e., f = 1/T
Amplitude (A): The maximum displacement of a vibrating body on either side from its mean position is called its
amplitude.
Christian Huygens invented the pendulum clock in 1656. He was inspired by the work of Galileo who had discovered
that all pendulums of the same length took the same amount of time to complete one full swing. Huygens
developed the first clock that could accurately measure time
DAMPED OSCILLATIONS
Practically, in all systems, the force of friction retards the motion, so the systems do not oscillate indefinitely.
The friction reduces the mechanical energy of the system as time passes, and the motion is said to be damped.
This damping progressively reduces the amplitude of the vibration of motion.
Shock absorbers in automobiles are one practical application of damped motion.
The oscillations of a system in the presence of some resistive force are damped oscillations.
191
CHAPTER 12
SOUND
All sounds are produced by the vibrations of objects.
Sound is a form of energy that travels in the form of waves from one place to another.
SOUND WAVES
Like other waves, sound is also produced by vibrating bodies.
Due to vibrations of bodies the air around them also vibrates and the air vibrations produce sensation of sound in
our ear.
Sound Requires Material Medium for its Propagation.
Sound waves are longitudinal in nature.
CHARACTERISTICS OF SOUND
Loudness:
Loudness is the characteristic of sound by which loud and faint sounds can be distinguished.
Loudness of a sound depends upon a number of factors.
Amplitude of the vibrating body:
The loudness of the sound varies directly with the amplitude of the vibrating body.
The sound produced by a sitar will be loud if we pluck its wires more violently.
Similarly, when we beat a drum forcefully, the amplitude of its membrane increases and we hear a loud sound.
Area of the vibrating body:
The loudness of sound also depends upon the area of the vibrating body.
For example, sound produced by a large drum is louder than that by small one because of its large vibrating area.
Loudness increases with the area of the vibrating body and vice versa.
Some people use silent whistle to call dogs whose frequency lies between 20,000 Hz to 25,000 Hz. It is silent for
human but not for dogs because the audible frequency range for dogs is much higher.
Distance from the vibrating body:
Loudness of sound also depends upon the distance of the vibrating body from the listener.
It is caused by the decrease in amplitude due to increase in distance.
Loudness also depends upon the physical condition of the ears of the listener.
A sound appears louder to a person with sensitive ears than to a person with defective ears.
However, there is a characteristic of sound which does not depend upon the sensitivity of the ear of the listener and
it is called intensity of sound.
Pitch:
Pitch is the characteristic of sound by which we can distinguish between a shrill and a grave sound.
It depends upon the frequency.
A higher pitch means a higher frequency and vice versa.
The frequency of the voice of ladies and children is higher than that of men. Therefore, the voice of ladies and children
is shrill and of high pitch.
Quality:
The characteristic of sound by which we can distinguish between two sounds of same loudness and pitch is called
quality.
Intensity:
The intensity of sound depends on the amplitude of sound wave.
Sound energy passing per second through a unit area held perpendicular to the direction of propagation of sound
waves is called intensity of sound.
Intensity is a physical quantity and can be measured accurately.
-2
The unit of intensity of sound is watt per square metre (W m ).
SOUND INTENSITY LEVEL
-12 -2 -2
The human ear responds to the intensities ranging from 10 W m to more than 1 W m (which is loud
enough to be painful). Because the range is so wide, intensities are scaled by factors of ten.
-12 -2
The barely audible and the faintest intensity of sound i.e., 10 W m is taken as reference intensity, called zero bel
(a unit named after Alexander Graham Bell).
The loudness of a sound depends not only on the intensity of sound but also on the physical conditions of the ear.
The human ear is more sensitive to some frequencies rather than the others.
The loudness (L) of a sound is directly proportional to the logarithm of intensity.
192
A sound wave with a frequency of 3500 Hz and an intensity of 80 dB sounds about twice as loud to us as a sound
of 125 Hz and 80 dB. It is because our ears are more sensitive to the 3500 Hz sound than to the 125 Hz.
Therefore intensity by itself does not mean loudness. Loudness is how our ears detect and our brain perceives the
intensity of sound waves.
REFLECTION (ECHO) OF SOUND
An echo and is a result of reflection of sound from the surface.
When sound is incident on the surface of a medium it bounces back into the first medium. This
phenomenon is called echo or reflection of sound.
The sensation of sound persists in our brain for about 0.1 s. To hear a clear echo, the time interval between our
sound and the reflected sound must be at least 0.1 s.
-1
If we consider speed of sound to be 340 ms at a normal temperature in air, we will hear the echo after 0.1 s.
The total distance covered by the sound from the point of generation to the reflecting surface and back should be
-1
at least 340 m s × 0.1 s = 34.0 m.
Thus, for hearing distinct echoes, the minimum distance of the obstacle from the source of sound must be half
of this distance, i.e., 17 m. Echoes may be heard more than once due to successive or multiple reflections.
A blue whale's 180 dB rumble is the loudest animal sound ever recorded.
Whale sounds also appear to be a part of a highly evolved communication system. Some whales are thought to
communicate over hundreds and may be thousands of kilometres.
This is possible, in part, because sound waves travel five times faster in water than in air.
In addition, the temperature characteristics of ocean water — decrease in temperature with depth — create a
unique sound phenomenon.
Elephants use low frequency sound waves to communicate with one another. Their large ears enable them to
detect these low frequency sound waves, which have relatively long wavelengths.
Elephants can effectively communicate in this way, even when they are separated by many kilometers.
SPEED OF SOUND
Sound waves can be transmitted by any medium containing particles that can vibrate.
They cannot pass through vacuum.
However, the nature of the medium will affect the speed of the sound waves.
In general, the speed of sound in a liquid is five times that in gases; the speed of sound in solid is about fifteen
times that in gases.
The speed of sound in air is affected by changes in some physical conditions such as temperature, pressure and
humidity etc.
-1
The speed of sound in air is 343 m s at one atmosphere of pressure and room temperature (21°C).
The speed varies with temperature and humidity.
The speed of sound in solids and liquids is faster than in air. Following relation can be used to find the speed of
sound: v = f λ , where v is the speed, f is the frequency and λ is the wavelength of sound wave.
The speed of sound in air was first accurately measured in 1738 by members of the French Academy.
Two cannons were setup on two hills approximately 29 km apart.
By measuring the time interval between the flash of a cannon and the “boom”, the speed of sound was calculated.
Two cannons were filled alternatively to minimize errors due to the wind and to delayed reactions in the observers.
0
From their observations, they deduced that sound travels at about 336 m s-1 at 0 C.
Table 11.1
Speed of sound in various
media
Medium -
Speed (m s
1
)
Gases
o
Air(0 C) 331
0
Air (25 C) 346
o
Air(100 C) 386
o
Hydrogen (0 C) 1290
o
Oxygen (0 C) 317
o
Helium (0 C) 972
0
Liquids at 25 C
Distilled water 1498
Sea water 1531
0
Solids 25 C
Wood 2000
193
Aluminium 6420
Brass 4700
Nickel 6040
Iron 5950
Steel 5960
Flint Glass 3980
NOISE POLLUTION
Sound which has jarring and unpleasant effect on our ears is called noise.
Noise corresponds to irregular and sudden vibrations produced by some sounds.
Noise pollution has become a major issue of concern in big cities.
A safe level of noise depends on two factors: the level (volume) of the noise; and the period of exposure to the
noise.
The level of noise recommended in most countries is usually 85-90 dB over an eight-hour workday.
IMPORTANCE OF ACOUSTICS
The technique or method used to absorb undesirable sounds by soft and porous surfaces is called acoustic
protection.
AUDIBLE FREQUENCY RANGE
A normal human ear can hear a sound only if its frequency lies between 20Hz and 20,000 Hz.
In other words, a human ear neither hears a sound of frequency less than 20 Hz nor a sound of frequency more
than 20,000 Hz.
Different people have different range of audibility.
It also decreases with age.
Young children can hear sounds of 20, 000 Hz but old people cannot hear sounds even above 15, 000 Hz.
The range of the frequencies which a human ear can hear is called the audible frequency range.
Bats can hear frequencies up to 120,000 Hz. Other animals cannot hear such high-pitched sound s.
Mice can hear frequencies up to 100,000 Hz, dogs up to 35,000 Hz, and cats up to 25,000 Hz.
Humans hear soundsonlyuptoabout20,000Hz, but children can usually hear higher-frequency sounds than adults.
ULTRASOUND
Sounds of frequency higher than 20, 000 Hz which are inaudible to normal human ear are called ultrasound
or ultrasonics.
USES OF ULTRASOUND
Ultrasonic waves carry more energy and higher frequency than audible sound waves.
Therefore, according to the wave equation v = f λ,the wavelength of ultrasonic waves is very small and is very useful
for detecting very small objects.
Ultrasonics are utilized in medical and technical fields.
In medical field, ultrasonic waves are used to diagnose and treat different ailments.
For Diagnosis of different diseases, ultrasonic waves are made to enter the human body through transmitters. These
waves are reflected differently by different organs, tissues or tumors etc. The reflected waves are then amplified
to form an image of the internal organs of the body on the screen.
Powerful ultrasound is now being used to remove blood clots formed in the arteries.
194
Ultrasound can also be used to get the pictures of thyroid gland for diagnosis purposes.
Ultrasound is used to locate underwater depths or is used for locating objects lying deep on the Ocean floor,
etc. The technique is called SONAR, (sound navigation and ranging). The sound waves are sent from a
transmitter, and a receiver collects the reflected sound.
The time-lapse is calculated, knowing the speed of sound in water, the distance of the object from the ocean
surface can be estimated.
SONAR ranging is also used to see the shape and the size of the object.
Cracks appear in the interior of moving parts of high speed heavy machines such as turbines, engines of
ships and airplanes due to excessive use. These cracks are not visible from outside but they can be very
dangerous. Such cracks can be detected by ultrasonics. A powerful beam of ultrasound is made to pass through
these defective parts. While passing, these waves are reflected by the surface of these cracks and flaws.
The comparison of the ultrasonic waves reflected from cracks and from the surfaces of these parts can give a clue of
the existence of the cracks.
Germs and bacteria in liquids can also be destroyed by using high intensity ultrasonic waves.
CHAPTER 13
ELECTROMAGNETIC SPECTRUM
DISPERSION OF LIGHT
Have you ever seen the rainbow?
What the physics behind this phenomenon is; Let us learn it by using a glass prism.
Suppose a narrow beam of white light entering from the air is passed through a prism of the denser medium.
A prism refracts the light at both the refracting surfaces, and it produces a range of colors called a spectrum.
Splitting white light into its constituent colors when it passes through a glass prism is called dispersion of white
light.
White light is not a single color but a mixture of all the spectrum colors.
The prism refracts each individual color differently depending on their refractive index.
THE SPECTRUM OF WHITE LIGHT
When a narrow beam of white light splits, the color sequence produced in the spectrum is indicated by the
acronym V I G Y O R, which stands for Violet, Indigo, Blue, Green, Yellow, Orange, and Red.
The speed and direction of white light vary depending on the wavelength.
The red color has a maximum speed in the glass prism, with the slightest deviation.
In contrast, the violet color has minimum speed, which with most deviation because color has its own refracted
path in the air and becomes distinct on the spectrum.
The color pattern produced in the dispersion is called a spectrum of light.
The red color is used in the traffic signals.
Red light has the highest wavelength of all the colors, and the as molecules least scatter it.
So, it can travel the longest distance and penetrate through rain, mist, and fog.
This is why red is being used in traffic signals to make the stop signal visible from a far distance.
For example, vibrating atoms in a hot, glowing bulb filament emit infrared and visible light in the house. An
oscillating electric current sends out radio waves from a radio station.
The other types of EM radiation that make up the electromagnetic spectrum are microwaves, ultraviolet light, X-
rays, and gamma rays that radiate out from their respective sources.
Electromagnetic waves are transverse waves.
It is electric and magnetic fields that are oscillating, not material.
Thus, they can travel through a vacuum or space.
Like all other waves, it obeys the equation
Speed = frequency x wavelength
c = fx ,
All electromagnetic waves travel through the space or vacuum at the same speed of 300000 kilometers per sec or
3 a lOg
Light-year is the distance that light travels in one year.
Light travels through interstellar space at 300,000 kilometers per second.
I year = 365 days
=365x24 days
= 365x 24x60 minutes.
=365x 20x 60x 60 seconds
= 31536000seconds
1 light year = Velocity x Time
= 3003001m/s x 31536000s
= 9.46x1012m
CHARACTERISTICS OF ELECTROMAGNETIC WAVES
Some of the common characteristics of electromagnetic waves are given as under;
I. Electromagnetic waves are transverse waves in nature. They are composed of varying electric and magnetic
fields that oscillate perpendicularly. The direction of wave motion is perpendicular to both electric and magnetic
fields.
2. It cannot carry electric charge.
3. It can travel through space, traveling at the speed of c= 3 x 108 ms-1
4. It will travel through a transparent medium; however, they will slow down when traveling through a denser
medium like water or glass.
5. It obeys the laws of reflection, refraction, and diffraction.
6. Its frequencies depend only on the source that produces the wave. Thus, frequencies do not change when it
travel from one medium to another (air to glass).
MAIN COMPONENTS OF THE ELECTROMAGNETIC SPECTRUM
The electromagnetic spectrum has a wide range of frequencies, wavelengths, and energies.
The spectrum covers the range of all electromagnetic radiation and consists of many sub-ranges that are generally
referred to as components, such as visible light or ultraviolet radiation.
There are no precise accepted boundaries between these continuous portions, so the ranges may tend to overlap.
The electromagnetic spectrum is the entire distribution of electromagnetic waves according to their frequencies
or wavelengths.
From the lowest to the highest frequency or longest to shortest wavelength, the entire electromagnetic spectrum
contains all radio waves, microwaves, infrared radiation, visible light, ultraviolet radiation, X-rays, and gamma
rays.
Radio waves have the longest wavelength, and gamma rays have the shortest wavelength.
196
They are commonly used in lighting houses, shops, and offices for decorating purposes.
Sterilization; as ultraviolet kills harmful bacteria, strong UVB and UV radiations are used to sterilize food and
medical equipment in hospitals.
APPLICATIONS OF X -RAYS
X-rays are produced when fast-moving electrons lose their energy quickly.
For example, in an x-ray tube, the radiation is given off when a beam of fast-moving electrons hits the metal target.
The long-wavelength or low-frequency x-rays are highly penetrating that can pass through flesh but not bones.
In the medical imaging field, radiologists use low-frequency x-rays lo produce the x-ray images to diagnose the
fracture in the bones or even tooth decay, tumors, and abnormal masses inside the body.
Computed Tomography (CT) scan is a computational diagnostic tool for detecting diseases and injuries. It uses a
series of low-frequency X-rays and a computer to produce a 3D image of soft tissues and bones.
Radiation Therapy is a cancer treatment that uses controlled doses of high-frequency x-rays to kill cancerous cells
and shrink tumors.
Industrial radiography is a technique of inspecting materials to detect inside defects by using high-frequency X-
rays. In this method, a beam of x-rays points at the tested item.
A detector is aligned with the beam on the other side of the item.
The detector records x-rays that pass through the material. The thicker the material, the fewer x-rays can pass
through.
More rays move through that region because the material is thinner with a crack or flaw.
The detector computes a picture from the rays that pass through, which shows cracks or flaws in that material.
APPLICATIONS OF GAMMA RAYS
Gamma rays come from radioactive materials.
They are produced when the nuclei of unstable atoms decay into a stable nucleus or lose energy. They tend to
have high energy than x-rays.
Gamma rays are used to treat cancer.
These high-energy rays are directed at the cancerous tumor to kill cancer cells in oncology.
The Gamma Knife Radiosurgery is a medical procedure that uses gamma rays to destroy small tumors in the brain
with less damage to surrounding cells.
Positron Emission Tomography (PET) is a functional medical imaging method.
In a PET scan, a short-lived positron-emitting radioactive sampling taken suitable for a particular function (e.g.,
brain function) is injected into the body.
Radiated positrons quickly fuse with nearby electrons and lead to two gamma rays of 511-keV traveling in opposite
directions.
After detecting the gamma rays, a computer generates an image that highlights the location of the biological
process being examined.
Gamma rays are highly penetrating and can pass through metals; because of their extreme power, gamma rays
used to radiograph holes and defects in metal castings and other structural parts.
CHAPTER 14
GEOMETRICAL OPTICS
REFLECTION OF LIGHT
When a ray of light approaches a smooth polished surface and the light ray bounces back, it is called the reflection
of light.
The ray of light that hits the polished surface is called the incident ray.
The ray that gets reflected away is called the reflected ray.
The point at which the light hits the surface is called the point of incidence.
If a line is drawn perpendicular to that point, it is called the normal.
If a perpendicular were drawn on a reflecting surface, it would be called normal. The figure
below shows the reflection of an incident beam on a plane mirror.
Here, the angle of incidence and angle of reflection are with respect to normal and the reflective surface.
The angle formed between the normal and the incident ray at the point of incidence is called the angle of
incidence.
Similarly, the angle formed between the normal and the reflected ray at the point of incidence is called the angle
of reflection.
198
LAWS OF REFLECTION
The laws of reflection determine the reflection of incident light rays on reflecting surfaces, like mirrors, smooth
metal surfaces and clear water.
Let’s consider a plane mirror as shown in the figure above. The law of reflection states that
1. The incident ray, the reflected ray and the normal all lie in the same plane
2. The angle of incidence = Angle of reflection
TYPES OF REFLECTION OF LIGHT
1. Regular reflection is also known as specular reflection
2. Diffused reflection
3. Multiple reflection
REGULAR/ SPECULAR REFLECTION
Specular Reflection refers to a clear and sharp reflection, like the ones you get in a mirror.
A mirror is made of glass coated with a uniform layer of a highly reflective material such as powder. This
reflective surface reflects almost all the light incident on it uniformly.
There is not much variation in the angles of reflections between various points.
This means that the haziness and the blurring are almost entirely eliminated.
DIFFUSED REFLECTION
Reflective surfaces other than mirrors, in general, have a very rough finish.
This may be due to wear and tear such as scratches and dents or dirt on the surface.
Sometimes even the material of which the surface is made of matters.
All this leads to a loss of both the brightness and the quality of the reflection.
In the case of such rough surfaces, the angle of reflection when compared between points is completely
haphazard.
For rough surfaces, the ray’s incident at slightly different points on the surface is reflected in completely
different directions.
This type of reflection is called diffused reflection and is what enables us to see non-shiny objects.
SPHERICAL MIRRORS
A mirror whose polished, reflecting surface is a part of a hollow sphere of glass or plastic is called a spherical mirror.
In a spherical mirror, one of the two curved surfaces is coated with a thin layer of silver followed by a coating of
red lead oxide paint.
Thus, one side of the spherical mirror is opaque and the other side is a highly polished reflecting surface.
Depending upon the nature of reflecting surface, there are two types of spherical mirrors.
Concave Mirror:
A spherical mirror whose inner curved surface is reflecting is called concave mirror.
In concave mirror the size of the image depends on the position of the object.
Both virtual and real images can be formed by a concave mirror.
Convex Mirror:
A spherical mirror whose outer curved surface is reflecting is called convex mirror.
In convex mirror the size of the image is always smaller than the object.
Only virtual and erect image is formed by a convex mirror.
TERMINOLOGIES
Pole: It is the midpoint of the curved surface of spherical mirror. It is also called vertex.
Centre of Curvature (C): A spherical mirror is a part of a sphere. The centre of this sphere is called centre of
curvature.
Radius of Curvature (R): It is the radius of the sphere of which spherical mirror is a part.
Principal Axis: It is the line joining centre of curvature and pole of the spherical mirror.
The Principal focus (F): After reflection from a concave mirror, rays of light parallel to the principal axis converge
to a point F. This point is called “The Principal Focus” of the mirror.
Hence, Concave mirrors are also called converging mirrors. Since rays actually pass through this point,
therefore, it is called real focus.
199
Focal length ( f ): It is the distance from the pole to the principal focus measured along the principal axis..
The focal length is related to the radius of curvature by f =R/2.
This means that as the radius of curvature is reduced, so too is the focal length of the reflecting surface.
CHARACTERISTICS OF FOCUS OF A CONCAVE AND A CONVEX MIRROR
CONVEX MIRROR:
The Focus lies behind the mirror.
The focus is virtual as the rays of light after reflection appear to come from the focus..
CONCAVE MIRROR:
The focus is in front of the mirror.
The focus is real as the rays of light after reflection converge at the focus.
THE MIRROR FORMULA:
Mirror formula is the relationship between object distance p image distance q from the mirror and focal length f
of the mirror.
Thus we can write mirror formula as: 1/f = 1/p + 1/q ………………(1)
Equation (1) is true for both concave and convex mirrors.
REFRACTION OF LIGHT
The bending of light as it passes from one transparent medium into another is called refraction.
The process of bending of light as it passes from air into glass and vice versa is called refraction of light.
Substance Index of Refraction
(n)
Diamond 2.42
Cubic Zirconia 2.21
Glass (flint) 1.66
Glass(crown) 1.52
Ethyl Alcohol 1.36
Ice 1.31
Water 1.33
Air 1.00
LAWS OF REFRACTION
The incident ray, the refracted ray, and the normal at the point of incidence all lie in the same plane.
The ratio of the sine of the angle of incidence ‘i’ to the sine of the angle of refraction ‘r’ is always equal to a
constant i.e., sin i / sin r = constant = n.
Where the ratio sin i / sin r is known as the refractive index of the second medium with respect to the first
medium. So we have sin I / sin r = n. It is called Snell's law.
SPEED OF LIGHT IN A MEDIUM
Refraction of light is caused by the difference in speed of light in different media.
8 -1
For example, the speed of light in air is approximately 3.0 × 10 m s However, when light travels through a
medium, such as water or glass, its speed decreases.
8 -1 8 -1
The speed of light in water is approximately 2.3×10 m s ,while in glass, it is approximately 2.0 × 10 m s .
To describe the change in the speed of light in a medium, we use the term index of refraction or refractive index.
REFRACTIVE INDEX
The refractive index ‘n’ of a medium is the ratio of the speed of light ‘c’ in air to the speed ‘v’ of light in the
medium:
𝑠𝑝𝑒𝑒𝑑 𝑜𝑓 𝑙𝑖𝑔ℎ𝑡 𝑖𝑛 𝑎𝑖𝑟 𝑐
Refractive index = or n =
𝑠𝑝𝑒𝑒𝑑 𝑜𝑓 𝑙𝑖𝑔ℎ𝑡 𝑖𝑛 𝑚𝑒𝑑𝑖𝑢𝑚 𝑣
TOTAL INTERNAL REFLECTION
When a ray of light travelling in denser medium enters into a rarer medium, it bends away from the normal.
If the angle of incidence ‘i’ increases, the angle of refraction ‘r’ also increases.
o
For a particular value of the angle of incidence, the angle of refraction becomes 90 .
200
o
The angle of incidence that causes the refracted ray in the rarer medium to bend through 90 is called critical
angle
When the angle of incidence becomes larger than the critical angle, no refraction occurs.
The entire light is reflected back into the denser medium. This is known as total internal reflection of light.
APPLICATIONS OF TOTAL INTERNAL REFLECTION
Totally Internal Reflecting Prism
o o
Many optical instruments use right-angled prisms to reflect a beam of light through 90 or 180 (by total internal
reflection) such as cameras, binoculars, periscope and telescope.
o
One of the angles of a right-angled prism is 90 .
When a ray of light strikes a face of prism perpendicularly, it enters the prism without deviation and strikes the
o
hypotenuse at an angle of 45 .
o o
Since the angle of incidence 45 is greater than critical angle of the glass which is 42 , the light is totally reflected
o
by the prism through an angle of 90 . Two such prisms are used in periscope.
o
The light is totally reflected by the prism by an angle of 180 . Two such prisms are used in binoculars.
Optical Fibre
Total internal reflection is used in fibre optics which has number of advantages in telecommunication field. Fibre
optics consists of hair size threads of glass or plastic through which light can be travelled. The inner part of the
fibre optics is called core that carries the light and an outer concentric shell is called cladding.
The core is made from glass or plastic of relatively high index of refraction.
The cladding is made of glass or plastic, but of relatively low refractive index.
Light entering from one end of the core strikes the core-cladding boundary at an angle of incidence greater than
critical angle and is reflected back into the core.
In this way light travels many kilometers with small loss of energy.
In Pakistan, optical fibre is being used in telephone and advanced telecommunication systems.
Light Pipe
Light pipe is a bundle of thousands of optical fibres bounded together.
They are used to illuminate the inaccessible places by the doctors or engineers.
For example, doctors view inside the human body. They can also be used to transmit images from one place to
another.
Endoscope
An endoscope is a medical instrument used for exploratory diagnostics, and surgical purposes.
An endoscope is used to explore the interior organs of the body.
Due to its small size, it can be inserted through the mouth and thus eliminates the invasive surgery.
The endoscopes used to examine the stomach, bladder and throat are called Gastroscope, Cystoscope and
Bronchoscope respectively.
An endoscope uses two fibre-optic tubes through a pipe.
A medical procedure using any type of endoscope is called endoscopy.
The light shines on the organ of patient to be examined by entering through one of the fibre tubes of the
endoscope. Then light is transmitted back to the physician’s viewing lens through the other fibre tube by total
internal reflection.
Flexible endoscopes have a tiny camera attached to the end. Doctor can see the view recorded by the camera on
a computer screen.
REFRACTION THROUGH PRISM
Prism is a transparent object (made of optical glass) with at least two polished plane faces inclined
towards each other from which light is refracted.
In case of triangular prism the emergent ray is not parallel to the incident ray. It is deviated by the prism from its
original path.
The incident ray PE makes an angle of incidenace ‘i’ at point E and is refracted towards the normal N as EF.
The refracted ray EF makes an angle ‘r’ inside the prism and travels to the other face of the prism.
This ray emerges out from prism at point F making an angle ‘e’.
Hence the emerging ray FS is not parallel to the incident ray PE but is deviated by an angle D which is
called angle of deviation.
LENSES
A lens is any transparent material having two surfaces, of which at least one is curved.
Lenses refract light in such a way that an image of the object is formed.
Lenses of many different types are used in optical devices such as cameras, eyeglasses, microscopes, telescopes,
201
and projectors.
They also enable millions of people to see clearly and read comfortably.
TYPES OF LENSES
There are different types of lenses.
The lens which causes incident parallel rays to converge at a point is known as convex or converging lens. This
lens is thick at the centre but thin at the edges.
Another type of lens causes the parallel rays of light to diverge from a point. This is called concave or diverging
lens. This lens is thin at the centre and thick at the edges.
LENS TERMINOLOGY
Principal Axis: Each of the two surfaces of a spherical lens is a section of a sphere. The line passing through the
two centres of curvatures of the lens is called principal axis.
Optical Centre, C: A point on the principal axis at the centre of lens is called optical centre.
Principal Focus, F: The light rays travelling parallel to the principal axis of a convex lens after refraction meet at a
point on the principal axis, called principal focus or focal point F. Hence, convex lens is also called converging lens.
For a concave lens, the parallel rays appear to come from a point behind the lens called principal focus F .Hence
concave lens is also called diverging lens.
Focal Length, f : This is the distance between the optical centre and the principal focus.
POWER OF A LENS
Power of a lens is defined as the reciprocal of its focal length in metres. Thus
Power of a lens = P = 1 / focal length in metres
The SI unit of power of a lens is “Dioptre”, denoted by a symbol D.
-1
If f is expressed in metres so that 1 D = 1 m . Thus, 1 Dioptre is the power of a lens whose focal length is 1 metre.
Because the focal length of a convex lens is positive, therefore, its power is also positive.
Whereas the power of a concave lens is negative, for it has negative focal length.
IMAGE FORMATION BY LENSES
In mirrors images are formed through reflection, but lenses form images through refraction.
Image formation in convex lens can be explained with the help of three principal rays.
1. The ray parallel to the principal axis passes through the focal point after refraction by the lens.
2. The ray passing through the optical centre passes straight through the lens and remains undeviated.
3. The ray passing through the focal point becomes parallel to the principal axis after refraction by the lens.
The study of light behavior is called optics.
The branch of optics that focuses on the creation of images is called geometrical optics, because it is based on
relation sh ip s between angles and lines that describe light rays.
With a few rules from geometry, we can explain how images are formed by devices like lenses, mirrors, cameras,
telescopes, and microscopes.
Optics also includes the study of the eye itself because the human eye forms an image with a lens.
LENS FORMULA
The relation between the object and image distance from the lens in terms of the focal length of the lens is
called lens formula. 1/f = 1/p + 1/q
SIGN CONVENTIONS FOR LENSES
Focal length:
f is positive for a converging lens
f is negative for a diverging lens.
Object Distance:
p is positive, if the object is towards the left side of the lens. It is called a real object.
p is negative, if the object is on the right side of the lens. It is called virtual object.
Image Distance:
q is positive for a real image made on the right side of the lens by real object.
q is negative for a virtual image made on the left side on the lens by real object.
APPLICATION OF LENSES
Cameras, telescopes, microscopes, and film projectors all use lenses.
There are also two lenses in our eyes that allow us to see the world around us.
Many different types of lenses are used in optical devices such as cameras, spectacles, microscopes, telescopes,
and projectors.
Convex lenses are used in eyeglasses to correct farsightedness, which occurs when the distance between the eye's
lens and retina is too short, causing the focal point to be behind the retina.
Concave lenses are used to magnify objects in telescopes and binoculars.
202
SIMPLE MICROSCOPE
A magnifying glass is a convex lens which is used to produce magnified images of small objects. Hence, it is also
called simple microscope.
The object is placed nearer to the lens than the principal focus such that an upright, virtual and magnified image
is seen clearly at 25cm from the normal eye.
RESOLVING POWER
The resolving power of an instrument is its ability to distinguish between two closely placed objects
or point sources.
COMPOUND MICROSCOPE
Compound microscope has two converging lenses, the objective and the eyepiece and is used to investigate
structure of small objects.
Following are some features of compound microscope:
It gives greater magnification than a single lens.
The objective lens has a short focal length, ƒo< 1 cm.
The eyepiece has a focal length, ƒe of a few cm.
USES OF COMPOUND MICROSCOPE
A compound microscope is used to study bacteria and other micro objects.
It is also used for research in several fields of sciences like, Microbiology, Botany, Geology, and Genetics.
TELESCOPE
Telescope is an optical instrument which is used to observe distant objects using lenses or mirrors. A telescope
that uses two converging lenses is called refracting telescope.
In refracting telescope, an objective lens forms a real image of the distant object, while an eyepiece forms a
virtual image that is viewed by the eye.
THE HUMAN EYE
Human eye acts like a camera. In place of the film, the retina records the picture.
The eye has a refracting system containing a converging lens.
The lens forms an image on the retina which is a light sensitive layer at the back of the eye.
In the camera, the distance of lens from film is adjusted for proper focus but in the eye, the lens changes focal
length.
Light enters the eye through a transparent membrane called the cornea.
The iris is the colored portion of the eye and controls the amount of light reaching the retina.
It has an opening at its centre called the pupil. The iris controls the size of the pupil. In bright light, iris contracts
the size of the pupil while in dim light pupil is enlarged.
The lens of the eye is flexible and accommodates objects over a wide range of distances.
The variation of focal length of eye lens to form a sharp image on retina is called accommodation.
The near point of the eye is the minimum distance of an object from the eye at which it produces a sharp image on
the retina.
The far point of the eye is the maximum distance of a distant object from the eye on which the fully relaxed eye
can focus.
DEFECTS OF VISION
The inability of the eye to see the image of objects clearly is called defect of vision.
The defects of vision arise when the eye lens is unable to accommodate effectively. The images formed are
therefore blurred.
NEARSIGHTEDNESS (MYOPIA)
Some people cannot see distant objects clearly without the aid of spectacles. This defect of vision is known as
short sight or nearsightedness and it may be due to the eyeball being too long.
Light rays from a distant object are focused in front of the retina and a blurred image is produced.
The nearsighted eye can be corrected with glass or contact lenses that use diverging lenses.
FARSIGHTEDNESS (HYPERMETROPIA)
The disability of the eye to form distinct images of nearby objects on its retina is known as farsightedness.
This defect can be corrected with the aid of a suitable converging lens.
The lens refracts the light rays and they converge to form an image on the retina.
To an observer, these rays appear to come from near point to form a sharp virtual image on the retina.
CHAPTER 14
ELECTROSTATICS
The study of charges while they are not moving is referred to as electrostatistics or static electricity.
ELECTRIC CHARGE
203
This law states that the magnitude of electrostatic force of attraction or repulsion between two point charges is
directly proportional to the product of magnitudes of charges and inversely proportional to the square of the
distance between them.
Consider two point charges q1 and q2 which are (r) distance a part, than according to coulomb's law.
1
F∝ 𝑞1𝑞2, …………….(1) and F∝ ………………(2)
𝑟2
By combining the equation (1) and (.2) F ∝ q1q2/r2 or F= K q1q2/r2 …………….(3)
Where k is the constant of proportionality
1 𝑞1𝑞2 1
K= , = 8.99 x 109N-m2/C2 , K ≅ 9.0 x 109N-m2/C2 , 𝜀 = 8.85 x 10-12C2/N-m2
4𝜋𝜀 𝑟2 4𝜋𝜀
ELECTRIC FIELD AND ELECTRIC FIELD INTENSITY
Positively charged particle exerts a force of attraction on negatively charged while exerts a force of repulsion on
positively charged particle. It is important to remember that the second charged particle also exerts an
electrostatic force on the first one.
As a result, it may be deduced that the area surrounding the charge is constantly under stress and exerts a force
on another charge put around it.
The area or space surrounding a charge or charged body where electrostatic force or stress occurs is termed
electric field, dielectric field, or electrostatic field.
A region around the charged particle or object within which a force would be exerted on other charged particles
or objects.
An electric field is often referred to as the electric force per unit of charge.
𝐹
The formula of electric field is given as; E =
𝑄
Whereas, E is the electric field.
F is a force.
Q is the charge.
Changing magnetic fields or electric charges are the most common causes of electric fields.
The magnitude of an electric field is expressed using the SI unit is N/C.
The force acting on the positive charge is assumed to be pointing in the same direction as the field's direction.
The electric field extends outwards radially from the positive point charge and inwards radially toward the
negative point charge.
ELECTRIC FIELD LINES
The electric field that surrounds a charge may be imagined as the existence of a line of force all the way around
it. Electric or electrostatic lines of force refer to a system of imaginary lines around a charged object and indicating
while the arrangement of lines of force around an isolated negative charge.
Such lines of force originate from the positive charge and terminate on the negative charge, when these charges
are placed near each other.
They exert the force of attraction on each other.
When two like charges are near each other, such lines will be in opposite direction.
There exists a force of repulsion between them.
ELECTROSTATIC POTENTIAL
The electrostatic potential, also known as the electric field potential, electric potential, or potential drop, is
defined as; the amount of work that is done in order to transport a unit charge from a reference point to a given
location within the field without causing an acceleration.
The volt is the standard SI unit for measuring electrostatic potential.
Electric potential energy is possessed by an object by the virtue of two elements, those being, the charge
possessed by an object itself and the relative position of an object with respect to other electrically charged
objects.
The magnitude of electric potential depends on the amount of work done in moving the object from one point to
another against the electric field.
When an object is moved against the electric field it gains some amount of energy which is defined as the electric
potential energy.
For any charge, the electric potential is obtained by dividing the electrical potential energy to the quantity of
𝑊 𝐸𝑙𝑒𝑐𝑡𝑟𝑖𝑐𝑎𝑙 𝑝𝑜𝑡𝑒𝑛𝑡𝑖𝑎𝑙 𝑒𝑛𝑒𝑟𝑔𝑦
charge. V = =
𝑞 𝐶ℎ𝑎𝑟𝑔𝑒
VOLT
Volt is the unit of electrical potential, potential difference, and electromotive force in the SI system.
The potential difference that exists across a resistance of one ohm while a current of one ampere is flowing
through it.
The unit of voltage known as the volt was named after the Italian scientist Alessandro Volta (1745-1827).
POTENTIAL DIFFERENCE
The energy possessed by Electric charges is known as electrical energy. A charge with higher potential will have
more electric potential energy and the charge with lesser potential will have less electric potential energy.
The current always moves from higher electric potential to lower electric potential. The difference in these
energies per unit charge is known as the electric potential difference.
It is the work done per unit charge to move a unit charge from one point to another in an electric field.
Electric potential difference is usually referred as Voltage difference.
205
APPLICATIONS OF ELECTROSTATICS.
There are many applications of electrostatics which are given below:
The Van de Graaff generator.
Xerography.
Laser Printers.
Ink Jet Printers and Electrostatic Painting.
Smoke Precipitators and Electrostatic Air Cleaning.
CAPACITOR AND CAPACITANCE
The capacitor is a simple electronic device or component and is used to store charge.
It is a system of two isolated conductors that can store electric charge.
A Capacitor stores a large amount of charge per volt in a very small area of the conductor.
Two conductors of any shape (plates) carrying equal and opposite charges, separated from each other by an
insulating material medium called Dielectric formed a Capacitor.
Different types of capacitors categorized according to the shape of plates.
CAPACITANCE
The ability of storing charges in a Capacitor is known as Capacitance.
When the Capacitor is connected to a battery of V volts, one plate draws positive charge and the other plate draws
negative charge from the battery till the potential difference between the plates also becomes V volts.
Charge Q which resides on any one of the plate is directly proportional to the potential difference between the
plates.
Q∝V Or Q = CV
The constant C is called Capacitance of the Capacitor and the equation Q = CV is called equation of Capacitor.
𝑄
So, C =
𝑉
This shows that unit of capacitance is Coul/Volt and this unit is also called Farad because 1 farad = 1 Caoul/Volt.
FACTORS ON WHICH CAPACITANCE DEPENDS
Capacitance depends on these factors:
Area of the plate. Capacitance increases if area of the plate increases. Hence C ∝A.
Distance between the plates. Capacitance increases if the separation distance between the plates
1
decreases. Hence C ∝
𝑑
Dielectric Constant (𝜖𝑟) capacitance increases if insulating medium of high dielectric constant is used.
Hence C ∝ 𝜖𝑟.
COMBINATION OF CAPACITORS
For a circuit the capacitance of a desired value can be obtained by different combination of capacitors and that
combination may be:
Parallel combination
Series combination
Series Parallel combination.
USES OF CAPACITORS
They are utilized, for instance, in the process of tuning transmitters, receivers, and transistor radios.
Also, they are utilized to run table fans, ceiling fans, exhaust fans, air conditioner motors, coolers, washing
machines, air conditioners, and many other appliances to keep them running at a high efficiency.
It is also common to find capacitors in the electronic circuitry of computers and other products like smartphones.
It is possible to utilize capacitors to distinguish between high and low frequency signals, which makes them
valuable in electronic circuits.
For instance, resonant circuits, which are responsible for tuning radios to specific frequencies, require the use of
variable capacitors.
These kinds of circuits are referred to as filter circuits.
One capacitor may not work in all situations.
In general, ceramic capacitors outperform other types and can be found M a wide variety of applications.
CHAPTER 15
CURRENT ELECTRICITY
Charges in motion constitute electric current.
ELECTRIC CURRENT
The rate of flow of electric charge through any cross-sectional area is called current.
If the charge Q is passing through any area in time t, then current I flowing through it will be given by Current =
charge / time or I = Q/T
SI unit of current is ampere (A).
Smaller Unitsof current are milli ampere (mA), micro ampere (µA), which are defined below as:
-3 -6
1 mA = 10 A, 1 µA = 10 A
206
Battery is one of the sources of current. The electrochemicalreaction inside a battery separates positive and
negative electric charges.
CONVENTIONAL CURRENT
Current flowing from positive to negative terminal of a battery due to the flow of positive charges is called
conventional current.
Conventional current produces the same effect as the current flowing from negative terminal to the positive
terminal due to the flow of negative charges.
THE MEASUREMENT OF CURRENT
Galvanometer and ammeter are some common examples ofcurrent measuring instruments.
POTENTIAL DIFFERENCE
Potential difference across the two ends of a conductor causes the dissipation of electrical energy into other
formsof energy as charges flow through the circuit.
SI unit of potential difference is volt.
A potential difference of 1 V across a bulb means that each coulombof charge or 1 ampere of current that
passes through the bulb consumes 1 joule of energy.
When a bulb is lit, the energy is taken from the current and is transformed into light and heat energy.
ELECTROMOTIVE FORCE (e.m.f)
It is the energy supplied by a battery to a unit positive charge when it flows through the closed circuit. Or the energy
converted from non-electrical forms to electrical form when one coulomb of positive charge passes through the
battery.
emf = energy / charge or E = W/Q
Where E is the e.m.f., W is energy converted from non- electrical forms to electrical form and Q is positive charge.
-1
The unit for e.m.f. is JC which is equal to volt (V) in SI system.
Hence, if the e.m.f. of the battery is 2 V, the total energy supplied by the battery is 2 joules when one coulomb
of charge flows through the closed circuit.
THE MEASUREMENT OF POTENTIAL DIFFERENCE
The potential difference across a circuit component (e.g. lightbulb) can be measured by a voltmeter, connected
directly across the terminals of the component.
The positiveterminalof the battery is connected to the positive terminal ofthe voltmeter and the negative terminal of the
battery is connected to the negative terminal of the voltmeter.
OHM'S LAW
The amount of current passing through a conductor is directlyproportional to the potential difference applied across
its ends, provided the temperature and the physical state of theconductor does not change. i.e., IV or VI or
V = IR
Where R is the constant of proportionality, and is the resistance of the conductors. Its SI unit is ohm,
denoted by a symbol Ω. If a graph is plotted between the current I and thepotential difference V, a straight line will
be obtained.
RESISTANCE
The property of a substance which offers opposition to the flow of current through it is called itsresistance.
This opposition comes from the collisions of moving electrons with atoms of the substance.
The SI unit of resistance R is ohm. If we put V = 1 V, and I = 1 A,the value of R will be 1 Ω. Thus
When a potential difference of one volt is applied across theends of a conductor and one ampere of current passes
through it, then its resistance will be one ohm.
CONDUCTORS
A conductor, or electrical conductor, is a substance or material that allows electricity to flow through it.
In a conductor, electrical charge carriers, usually electrons or ions, move easily from atom to atom
when voltage is applied.
Most metals like copper are considered good conductors, while nonmetals are considered bad conductors -- that
is, insulators.
INSULATORS
Insulator, any of various substances that block or retard the flow of electrical or thermal currents.
COMBINATION OF RESISTORS
(i) Series combination (ii) Parallel combination
RESISTORS IN SERIES COMBINATION
Two or more resistances are said to be connected in series when they are connected end to end and the same
current flows through each of them in turn. In this case, the equivalent or the total resistance equals the sum
of the number of individual resistances present in the series combination.
207
Mathematically, the equivalent resistance of any number of resistances (R 1, R2, R3, R4, R5…) connected in
series is given as: Req = R1 + R2 + R3 + R4 + R5 + ……..
RESISTORS IN PARALLEL COMBINATION
Two or more resistances are said to be connected in parallel connected when they are connected between
two points and each has a different current direction. The current is branched out and recombined as the
branches intersect at a common point in such circuits.
Mathematically, the equivalent resistance of any number of resistances (R1, R2, R3, R4, R5…) connected in
parallel is given as: 1/R eq = 1/R1 + 1/R2 + 1/R3 + 1/R4 + 1/R5 + ……..
ELECTRICAL ENERGY AND JOULE'S LAW
The Joule’s law defined as the amount of heat generated in a resistance due to flow ofcharges is equal to the
product of square of current I, resistance R and the time duration t.
ELECTRIC POWER
The amount of energy supplied by current in unit time is knownas electric power.
Hence power P can be determined by the formula Electric power P = electrical energy/time = W/t
Where W is the electrical energy given by W = QV
Therefore, above equation becomes
𝑄𝑉
Electric power P = = 𝐼𝑉 = 𝐼 2R
𝑡
-1
The unit of electric power is watt which is equal to one jouleper second (1 Js ). It is represented by the symbol W.
Electricbulbs commonly used in houses consume 25 W, 40 W, 60 W,75 W and 100 W of electric power.
KILOWATT-HOUR
The amount of energy delivered by a power of one kilowatt in one hour is called kilowatt-hour.
5
One kilowatt-hour1 kWh= 1000 W ×1 hour =1000 W × (3600 s) = 36 × 10 J=3.6 M J
The energy in kilowatt-hour can be obtained by the followingformula:
𝑤𝑎𝑡𝑡 ×𝑡𝑖𝑚𝑒 𝑜𝑓 𝑢𝑠𝑒 𝑖𝑛 ℎ𝑜𝑢𝑟𝑠
The amount of energy in kilowatt-hour =
1000
DIRECT CURRENT AND ALTERNATINGCURRENT
The current derived from a cell or a battery is direct current(D.C) - since it is unidirectional.
The positive and negative terminals of D.C sources have fixed polarity, therefore, level of
D.C remains constant with time.
On the contrary,there is also a current which changes its polarity again and again.
Such a current that changes direction after equal intervals oftime is called alternating current or A.C.
This type ofcurrent is produced by AC generators.
The time interval after which the a.c voltage or current repeats its value is known as its time period.
SUPPLY TO A HOUSE
The electric power enters our house through three wires.
One is called earth wire or ground wire (E). This carries no electricity.
The earth wire is connected to a large metal plate buried deep in the ground near the house.
The other wire is maintained at zero potential by connecting it to the Earth at the power station itself andis
called neutral wire (N).
This wire provides the returnpath for the current. The third wire is at a high potential and is called livewire (L).
The potential difference between the livewire and the neutral wire is 220V.
FUSE
A fuse is a safety device that is connected in series with thelivewire in the circuit to protect the equipments when
excesscurrent flows.
CIRCUIT BREAKER
The circuit breaker acts as a safety device in thesame way as a fuse. It disconnects the supply automatically ifcurrent
exceeds the normal value.
CHAPTER 16
ELECTROMAGNETISM
Electromagnetism is the study of magnetic effects of current.
Electromagnetic force acts between charged particles.
The direction of magnetic field around a current carrying wire can be determined by using the Flemings right hand
rule for conductors.
The region in which the influence of magnetism may be felt is known as magnetic field.
Magnetic field is strongest near the poles and weakest in the centre.
A current carrying wire has a magnetic field around it, when this field interacts with external magnetic field there
is a force on it. Which is given by F = I L x B.
208
The number of lines of force is maximum when the surface is held perpendicular to the magnetic lines of force.
It will be minimum when surface is held parallel to the magnetic lines of force.
If we place a coil in the magnetic field of a bar magnet, some of the magnetic lines of force will pass through it. If the coil is
far away from the magnet, only a few lines of force will pass through the coil. However, if the coil is close to the magnet, a
large number of lines of force will pass through it.
This means, we can change the number of magnetic lines of force through a coil by moving it in the magnetic
field. This change in the number of magnetic field lines will induce an e.m.f. in the coil. This is the basic
principle of the production of electricity.
The process of generating an induced current in a circuit by changing the number of magnetic lines of force
passing through it is called electromagnetic induction.
The value of induced e.m.f. in a circuit is directly proportional to the rate of change of number of magnetic lines
of force through it. This is called Faraday's law of electromagnetic induction.
FACTORS AFFECTING INDUCED E.M.F
The magnitude of induced e.m.f. in a circuit depends on the following factors:
Speed of relative motion of the coil and the magnet
Number of turns of the coil
DIRECTION OF INDUCED E.M.F. – LENZ’S LAW
Lenz devised a rule to find out the direction of a current induced in a circuit.
The direction of an induced current in a circuit is always such that it opposes the cause that produces it.
A.C. GENERATOR
If a coil is rotated in a magnetic field, a current will be induced in the coil. The strength of this induced current
depends upon the number of magnetic lines of force passing through the coil. The number of lines of magnetic
force passing through the coil will be maximum when the plane of the coil is perpendicular to the lines of
magnetic force. The number of lines of magnetic force will be zero when plane of the coil is parallel to the lines
of force. Thus, when a coil rotates in a magnetic field, the induced current in it continuously changes from
maximum to minimum value and from minimum to maximum value and so on. This is the basic principle on
which an A.C generator works.
The e.m.f. developed by the generator depends on the length of the wire rotating in the field. Increasing the
number of loops in the armature, increases the wire length, thereby increasing the induced e.m.f.
MUTUAL INDUCTION
The phenomenon of production of induced current in one coil due to change of current in a neighboring coil is
called mutual induction.
TRANSFORMER
The transformer is a practical application of mutual induction.
Transformers are used to increase or decrease AC voltages.
Usage of transformers is common because they change voltages with relatively little loss of energy.
In fact, many of the devices in our homes, such as game systems, printers, and stereos use transformers for
their working.
APPLICATIONS OF ELECTROMAGNET
Magnetic effect of current is called electromagnet.
This effect is used in many devises like relay, electric bell, etc. Soft iron can easily be magnetized and
demagnetized.
CHAPTER 17
INTRODUCTORY ELECTRONICS
INTRODUCTION TO ELECTRONICS
In 1897 electron was identified.
Vacuum tube was invented in the same period of time.
Vacuum tube can amplify and rectify small electrical signals.
The invention of vacuum tube opens up a new field of technology called electrons.
Electrons comprises the physics, engineering and technology.
Electrons also has applications that deal with the emission, flow and control of electrons in vacuum and
matter using different devices.
Electrons may have two fields i) Analogue and ii) Digital
DIFFERENCES BETWEEN ANALOGUE AND DIGITAL ELECTRONS:
210
Analogue electrons deals with circuits which have continuously varying signals, for example; radio television ,
oscillator etc.
The term digital derived from a Latin word Digitus means for fingers. This is because fingers are usually used
for discrete counting.
Digital electrons deals with circuits which have discrete signals. For example; computers, calculators, MP3
Players etc.
THERMIONIC EMISSION
In the 1850's, physicists started to examine the passage of electricity through a vacuum by putting two
electrodes in a sealed vacuum tube. Some kind of rays were emitted from the cathode or the negative electrode.
These rays were called cathode rays. J.J. Thomson in 1897 observed the deflection of cathode rays by both
electric and magnetic fields. From these deflection experiments, he concluded that cathode rays must carry a
negative charge. These negatively charged particles were given the name electrons.
The process of emission of electrons from the hot metal surfaces is called thermionic emission. Metals
contain a large number of free electrons. At room temperature electrons cannot escape the metal
surface due to attractive forces of the atomic nucleus.
If the metal is heated to a high temperature, some of the free electrons may gain sufficient energy to
escape the metal surface.
Thermionic emission can also be produced by electrically heating a fine tungsten filament. Typical
values of the voltage and current used are 6 V and 0.3 A respectively.
PROPERTIES OF ELECTRONS
An electron gun is used to investigate the properties of electron beam
The electrons are produced by thermionic emission from a tungsten filament heated by 6 V supply.
A high positive potential (several thousands) is applied to a cylindrical anode (+). The electrons are
accelerated to a high speed and pass through the hole of the anode in the form of a fine beam of electrons.
The whole set up is fitted in an evacuated glass bulb.
CATHODE-RAY OSCILLOSCOPE (C.R.O)
The cathode-ray oscilloscope is an instrument which is used to display the magnitudes of changing electric
currents or potentials.
The information is displayed on the screen of a “cathode-ray tube”.
This screen appears as a circular or rectangular window usually with a centimeter graph superimposed on it.
For example, the picture tube in our TV set and the display terminal of most computers are cathode-ray tubes.
The cathode-ray oscilloscope (C.R.O) consists of the following components:
The electron gun with control grid
The deflecting plates
A fluorescent screen
THE ELECTRON GUN
The electron gun consists of an electron source which is an electrically heated cathode that ejects electrons.
Electron gun also has an electrode called grid G for controlling the flow of electrons in the beam. The grid is
connected to a negative potential.
The more negative this potential, the more electrons will be repelled from the grid and hence fewer
electrons will reach the anode and the screen.
The number of electrons reaching the screen determines the brightness of the screen.
Hence, the negative potential of the grid can be used as a brightness control.
The anode is connected to positive potential and hence is used to accelerate the electrons.
The electrons are focused into a fine beam as they pass through the anode.
THE DEFLECTING PLATES
After leaving the electron gun, the electron beam passes between a pair of horizontal plates.
A potential difference applied between these plates deflects the beam in a vertical plane.
This pair of plates provides the Y-axis or vertical movement of the spot on the screen.
A pair of vertical plates provides the X-axis or horizontal movement of the spot on the screen.
THE FLUORESCENT SCREEN
The screen of a cathode-ray tube consists of a thin layer of phosphor, which is a material that gives light as a
result of bombardment by fast moving electrons.
The CRO is used in many fields of science; displaying waveforms, measuring voltages, range-finding (as in radar),
211
either a high voltage ‘1’ or a low voltage ‘0’ - it is either ON or OFF. Whether the output voltage of logic gate is
high ‘1’ or low ‘0’ will depend upon the condition at its input.
AND OPERATION
In order to understand the logic AND operation consider a lamp is connected to a battery using two switches
S1 and S2 connected in series considered as two inputs.
There are four possible states of these two switches which are given below:
i. When S1 and S2 are both open, the lamp is OFF.
ii. When S1 is open but S2 closed, the lamp is OFF.
iii. When S1 is closed but S2 open, the lamp is OFF.
iv. When both S1 AND S2 are closed, the lamp is ON.
Symbol for AND operation is dot (.). Its Boolean expression is: X =A. B and is read as “ X equals A AND B”.
The circuit which implements the AND operation is known as AND gate.
AND gate has two or more inputs and only one output.
The value of output of AND gate is always in accordance with the truth table of AND operation.
It means output of AND gate will be '1' only when all of its inputs are at logic '1', and for all other situations output
of AND gate will be '0'.
OR OPERATION
In order to understand the logic OR operation consider the circuit in which a lamp is connected to a battery using
two switches S1 and S2 connected in parallel considered as two inputs. There are four possible states of
these two switches which are given below:
i. When S1 and S2 are open, the lamp is OFF.
ii. When S1 is open and S2 closed, the lamp is ON.
iii. When S1 is closed and S2 open, the lamp is ON
iv. When both S1 and S2 are closed, the lamp is ON.
OR operation is represented by the symbol of plus (+).
Boolean expression for OR operation is : X = A + B and is read as “ X equals A OR B”.
The electronic circuit which implements the OR operation is known as OR gate.
It has two or more inputs and has only one output.
The values of output of OR gate are always in accordance with the truth table of OR operation.
It means, the value of output of OR gate will be '1' when anyone of its inputs is at '1'.
The output will be '0', when all inputs are at '0'.
NOT OPERATION
In order to understand NOT operation, consider the circuit in which a lamp is connected to a battery with a switch S,
in parallel when the switch is open, current will pass through the lamp and it will glow.
When switch is closed, no current will pass through the lamp due to large resistance of its filament and it will not
glow.
NOT operation is represented by a line or bar over the symbol i.e., X = A and is read as “X equals A NOT”.
It means NOT operation changes the state of a Boolean variable.
For example, if the value of a Boolean variable is 1, then after NOT operation its value would change to ‘0’.
Similarly, if its value before NOT operation is 0, then after NOT operation it would change to ‘1’. Thus NOT operation
inverts the state of Boolean variable.
The electronic circuit which implements NOT operation is known as NOT gate.
NOT gate performs the basic logical function called inversion or complementation.
NOT gate is also called inverter.
The purpose of this gate is to convert one logic level into the opposite logic level.
When a HIGH level is applied to an inverter, a LOW level appears on its output and vice versa.
NAND GATE
NAND operation is simply an AND operation followed by a NOT operation.
For example, NAND gate is obtained by coupling a NOT gate with the output terminal of the AND gate.
The NOT gate inverts the output of the AND gate.
The output of the NAND equals A . B and is written as X = A . B. It is read as X equals A AND B NOT.
NOR GATE
The NOR operation is simply an OR operation followed by a NOT operation.
The NOR gate is obtained by coupling the output of the OR gate with the NOT gate.
Thus, for the same combination of inputs, the output of a NOR gate will be opposite to that of an OR gate.
Its Boolean expression is X = A + B. It is read as X equals A OR B NOT.
USES OF LOGIC GATES
213
The term hardware refers to machinery. This includes the central processing unit (CPU), and all of its support
equipment. Among the support equipments are input and output devices, storage devices and
communication devices.
Software:
The term software refers to computer programs and the manuals that support them. Computer programs are machine-
readable instructions that direct the circuitry within the hardware parts of the CBIS to produce useful information
from data. Programs are generally stored on some input / output medium, often a disk or tape.
Data:
Data are facts and figures that are used by programs to produce useful information. It may be in the form of text,
graphic or figure that can be recorded and that have specific meaning. Like programs, data are generally stored in
machine-readable form on disk or tape until the computer needs them.
Procedures:
These are set of instructions and rules to design and use information system. These are written in manuals and
documents for use. These rules or methods may change from time to time. The Information System must be flexible
to incorporate these changes.
People:
Every CBIS needs people if it is to be useful, who influence the success or failure of information systems. People
design and operate the software, they feed input data, build the hardware for the smooth running of any CBIS.
People write the procedures and it is ultimately people who determine the success or failure of a CBIS.
FLOW OF INFORMATION
Flow of information means the transfer of information from one place to another through different electronic and optical
equipments.
In telephone, information is sent through wires in the form of electrical signals.
In radio, television and cell phone information is sent either through space in the form of electromagnet waves, or
through optical fibres in the form of light.
There are three essential parts of any communication system: transmitter, transmission channel, and receiver.
The transmitter processes the input signal.
214
The transmission channel is the medium which sends the signal from source to destination.
The receiver takes the output signal from the transmission channel and delivers it to the transducer after
processing it.
The receiver may amplify the input signal to compensate for transmission loss.
TRANSMISSION OF ELECTRICAL SIGNAL THROUGH WIRES
Alexander Graham Bell in 1876 made a simple telephone model to send voice in the form of electrical signal
from one place to another. It consists of a metal reed, an electric coil, and a vibrating diaphragm.
Modern telephone also uses diaphragms to turn voices into electrical signal that are transmitted over phone
lines.
Telephone system has two parts: the mouthpiece and the earpiece.
The mouthpiece and receiver contain carbon granules and a thin metal diaphragm.
When we speak into the mouthpiece, the sound vibrations also vibrate the diaphragm.
A slight vibration of the diaphragm compresses the carbon and thus an electrical current can flow through the
wire.
This process is reversed at the other end of the line by the receiver.
The electrical current flowing through an electromagnet in the receiver produces a varying magnetic field. This
magnetic field attracts the thin metal diaphragm in the receiver, causing it to vibrate. This vibration of the
diaphragm produces sound waves.
TRANSMISSIONS OF RADIOWAVES THROUGH SPACE
Electrical signals representing information from a microphone, a TV camera, or a computer can be sent from
one place to another place using either cables or radio waves.
Information in the form of audio frequency (AF) signals may be transmitted directly by cable. However, in order
to send information over a long distance, it has to be superimposed on electromagnetic waves.
Sound waves produced at the radio station are changed into electrical signals through microphone.
These electric signals are then fed into the transmission antenna which consists of two metal rods.
Signals falling on the transmission antenna oscillate the charges which then emit these electrical signals in the
form of electromagnetic radio waves.
At the receiving end, the receiver selects and amplifies the modulated signal.
The demodulator then extracts the information signal and delivers it to the receptor.
FAX MACHINE
Telefacsimile's or Fax machines are must for many businesses around the world.
A fax machine basically scans a page to convert its text and graphic into electronic signals and transmits it to another
fax machine through telephone line.
The receiving machine converts the signals and uses a printer (usually built in) to create the copy of the message
that was sent.
CELL PHONE
Radio technology is applied in mobile phone.
It is a type of radio having two way communications.
A cell phone carries a radio transmitter and a receiver inside it.
It sends and receives the message in the form of radio waves.
Cell phone network system consists of cells and Base Stations (BSs) and Mobile Switching Centre (MSC)
A base station is a wireless communication station set up at a particular geographical location. The geographical
area covered by a single base station is known as a cell.
The group of cells forms a cluster.
All BSs within a cluster are connected to a MSC using land lines.
The MSC stores information about the subscribers located within the cluster and is responsible for directing calls
to them.
When a caller calls another cell phone, sound waves of the caller are converted into radio waves signal.
This radio signal of particular frequency is sent to the local base station of the caller where the signal is assigned
a specific radio frequency.
This signal is then sent to the base station of the receiver through MSC. Then the call is transferred to the cell
phone of the receiver.
Mobile receiver again changes the radio waves into sound.
PHOTO PHONE
Contrary to a common telephone, users can see the pictures of each other.
By using the photo and phone numbers of our friends or family members on this telephone, we can call them by
pressing the pad with their photos.
Thus, we can communicate with our relatives or friends on photo phone with the physical appearance of each
other.
215
MAGNETIC DISKS
There are different types of magnetic disks coated with a layer of some magnetic material.
The read/write head of disks are similar to the record replay head on a tape recorder. It magnetizes parts of the
surface to record information.
The difference is that a disk is a digital medium– binary numbers are written and read.
A floppy disc is a small magnetically sensitive, flexible plastic wafer housed in a plastic case. It is coated with a
magnetic oxide similar to the material used to coat cassettes and video tapes.
Most personal computers include at least one disk drive that allows the computer to write it and read from
floppy disk
Floppies are inexpensive, convenient, and reliable, but they lack the storage capacity and drive speed for many
large jobs.
Data stored on floppy disks is also subject to loss as a result of stray magnetic fields.
As far as floppy disks are concerned, they are reliable only for short-term storage and cannot be used longer and
no attempts should be made to save the data for a longer period.
As the magnetic fields weaken the data will also be lost.
HARD DISK
Hard disk is a rigid, magnetically sensitive disk that spins rapidly and continuously inside the computer chassis or in a
separate box connected to the computer housing.
This type of hard disk is never removed by the user.
A typical hard disk consists of several platters, e a c h accessed via a read/write head on a moveable arm.
COMPACT DISC (CDs)
This is based on laser technology.
It is a molded plastic disc on which digital data is stored in the form of microscopic reflecting and non-reflecting
spots which are called “pits” and “lands” respectively.
Pits are the spiral tracks encoded on the top surface of CD and lands are the areas between pits. A fine laser beam
scans the surface of the rotating disk to read the data.
Pits and lands reflect different amount of the laser light falling on the surface of CD. This pattern of different amount
of the light reflected by the pits and the lands is converted into binary data.
The presence of pit indicates ‘1’ and absence of pit indicates ‘0’.
A CD can store over 680 megabyte of computer data.
A DVD, the same size as traditional CD, is able to store upto 17gigabytes of data.
FLASH DRIVE
It is also an electronic based device and consists of data storage ICs.
A flash drive is a small storage device that can be used to transport files from one computer to another.
They are slightly larger than a stick of gum, yet many of these devices can carry all your homework for an entire year!
DATA MANAGEMENT – MONITORING AND CONTROL
To collect all information regarding a subject for any purpose and to store them in the computer in more than one
inter linked files which may help when needed, is called 'data managing'.
INTERNET
Internet is basically a large computers network, which extends all across the globe.
In Internet, millions of computers remain connected together through well-laid communication system.
INTERNET SERVICES
The main services used on the internet include:
Web browsing - this function allows users to view web pages.
E-mail - Allows people to send and receive text messages.
BROWSERS
A browser is an application which provides a window to the Web.
All browsers are designed to display the pages of information located at Web sites around the world.
The most popular browsers on the market today include Internet Explorer, The World, Opera, Safari, Mozilla Firefox,
Chrome, etc.
We can search anything through search engine like Google Chrome, Internet Explorer, Mozilla Firefox, etc.
ELECTRONIC MAIL
One of the most widely used application of internet is electronic mail (or e-mail), which provides very fast
delivery of messages to any enabled site on the Internet.
Communication through e-mail is more quick and reliable.
Through our e-mail, we can communicate with our friends and institution with more ease and pace. Some
advantages of e-mail are as follows:
Fast Communication– We can send messages anywhere in the world instantly.
217
Cost Free Service– If we have an internet access, then we can avail the e-mail service free of cost.
Simple to Use-After initial setup of e-mail account, it is easy to use.
More Efficient– We can send our message to many friends or people only in one action.
Versatile- Pictures or other files can also be sent through e-mail. Internet has proved to be very beneficial to us.
Here is the list of use of internet.
Faster Communication
Big Source of Information
Source of Entertainment
Access to Social Media
Access to Online Services
E-commerce
E-Learning
CHAPTER 19
ATOMIC STRUCTURE
ATOM AND ATOMIC NUCLEUS
THE STRUCTURE OF AN ATOM IN TERMS OF A NUCLEUS AND ELECTRONS.
Atom is the smallest unit into which matter can be divided without releasing electrically charged particles.
The simple Rutherford’s atomic model is often used to explain the basic structure of an atom.
Every atom is composed of two parts;
The central hard-core of an atom is the nucleus which is the small, dense region consisting of
closely packed protons and neutrons.
Around the nucleus, electrons revolve at high speed. The number of particles (electron and
protons) depends on the type of atom.
Most of the atom is empty space.
The rest comprise a positively charged nucleus surrounded by negatively charged orbiting electrons.
The nucleus is tiny and dense compared with the electrons.
Electrons are bound by a positively charged nucleus with the electrostatic force.
NUCLEAR MODEL OF THE ATOM
Rutherford put forward one of the earliest model of the nucleus, which he derived from experiments carried out
by Geiger and Marsden.
GEIGER AND MARSDEN α SCATTERING EXPERIMENT
Geiger and Marsden, the two scientists, used a beam of positively charged α - particles to bombard a thin gold
foil placed in a vacuum surrounded by a ring-shaped fluorescent screen.
After bombarding the foil, the scattered α - particles were detected using a rotating detector.
When α - particles hit the screen of light was observed through the detector.
Geiger and Marsden found quite unpredicted experimental results that most of the α – particles were not
deflected or only a few deflected through small angles.
The unexpected result was that a small number of the α – particles were deflected through considerable larger
angles of more than 90 degree and few of the α – particles were even deflected back through nearly 180 degree.
To explain these observations, Rutherford postulated an atomic model.
The nucleus carries all the positive charge of atom and nearly all its mass, as a large number of α –particles
passing through the foil undeflected suggest that there exist large empty spaces in an atom and those positively
charged α –particles that deflected through large angles had come very close to the positively charged nucleus.
However, a few were repelled so strongly that they bounced back or deflected through large angles.
PROTONS AND NEUTRONS
The outermost region of the nucleus is called electron shell.
It contains electrons.
Electrons have a negative (-) charge.
The nucleus contains the neutrons and the protons bound tightly together by the nuclear forces (gluons).
Neutrons carries no charge.
The mass of a neutron is slightly larger than that of a proton.
Proton have an equal positive (+) charge that of an electron in magnitude.
An atom usually has an equal number of protons as electrons, so its net charge is zero.
Therefore atom is considered neutral.
Atoms have different properties depending upon the arrangement and number of their elemental particles;
218
The branch of physics concerned with the study and understanding of the atomic nucleus, including its
composition and the forces which bind it together, is called nuclear physics.
ELEMENTS
All materials are made from about 100 essential substances known as elements.
The smallest part of an element is an atom.
Each element have a unique number of protons.
The number of protons in the nucleus of an atom in an element is called atomic number (Z).
The atomic number distinguishes one element from another.
For example, the atomic number (Z) of carbon is six because it has 6 protons, and the atomic number (Z) of
nitrogen is seven because it has 7 protons.
There are some other examples given in table. The atomic number also tells you the number of electrons in that
atom.
NUCLIDES
An atom of an element has all the characteristics of that element.
The nucleus is at the center of the atom and contains the protons and neutrons, which are collectively called
nucleons.
The number of protons in an atom of an element is called the atomic number, (Z).
The number of neutrons in the nucleus is the neutron number, (N).
The number of protons and neutrons is collectively known as nucleon number (A) or atomic mass (A).
The total number of nucleons is the atomic mass, A.
These numbers are related by the symbol A. A = Z + N
A nucleus is represented symbolically by: zXA
Where X represents the nuclide of a chemical element, A is the nucleon number, and Z is the atomic number.
For example, 6C12represents the carbon nucleus with six protons and twelve nucleons. Thus, the total orbiting
electrons are also six, and the neutron number is: A = Z + N , N = A - Z ,N = 12 - 6 , N = 6
ELEMENTS AND ISOTOPES
ISOTOPES
The atoms of an element are not exactly alike.
Some may have more neutrons than others. These different variants of the elements are called isotopes.
Two or more species of atoms of an element with the same atomic number, (Z) have different atomic mass, (A)
is called Isotopes.
Most elements have mixture of two or more isotopes.
For example, the hydrogen atom (atomic number I) has three isotopes with atomic masses 1, 2, and 3. You can
see how to represent an atom of Hydrogen using symbols and numbers in the table given below.
Every element has a specific position in the periodic table and nearly identical chemical behavior or properties
with the same number of electrons.
Many other essential properties of an isotope depend on its mass.
The total number of neutrons and protons in the nucleus of mass number (symbol A) gives it different physical
properties, i.e. mass, surface area, volume, and density.
219
Isotopes are two or more species of atoms of an element with identical chemical properties that have different
physical properties.
CHAPTER 20
NUCLEAR STRUCTURE
The nuclear structure is the area of physics that studies the nuclei of atoms.
NATURAL RADIOACTIVITY
Atomic nuclei consist of protons and neutrons, whereby protons repel each other through electrostatic force
due to their positive charges.
In contrast, nuclei bind the nucleons through another specific binding energy. These two forces compete with
each other, leading to various nuclei stability. There are only certain neutron-proton pairings that form stable
nuclei. As a result, an increasing ratio of neutrons to protons is required to form a stable nucleus. Some
proportions of neutrons to protons are more stable than others in a nucleus if the neutron number, N, is plotted
against the proton number, Z; for all different isotopes of all the elements.
If an isotope undergoes radioactive decay is called radio-isotope or radioactive element.
The emission of α, β and 𝜸 radiation with the release of energy is known as radioactivity.
TYPES OF RADIATION α, β AND 𝜸
Salient features as given below.
Stable isotopes lie along with the stability line.
Isotopes above the stability line have too many neutrons to be stable. The decay for β-
(electron) emission reduces the number of neutrons.
Isotopes below the line of stability have few neutrons to be stable. The decay for β+ (positron)
emissions increases the number of neutrons
The heaviest isotopes (proton number, Z > 83) decay by α emissions. Many other infrequent
types of decay, such as spontaneous fission or neutron emission, are also observed.
NATURE OF RADIOACTIVE EMISSION
To describe the nature of three types of radiation α, β and 𝜸, the radioactive source is placed inside the electric
field.
The radiation emitted from the source breaks down into three components: α and β -radiations bend in the
opposite direction in the electric field, while 𝜸 -radiation does not change its direction.
This result describes that.
α deflected towards a negatively charged while the plate is positively charged,
β deflected towards a positive plate that is negatively charged. It is deflected more in the field,
thus, much lighter than a particles.
𝜸 rays are not deflected by the field and carry no electric charge.
Further, it was found by further explorations that;
An alpha particle is a helium nucleus comprising two protons and two neutrons with a charge
of +2e.
Beta radiation is a streamlet of high-energy electrons.
Gamma radiations are photons that are electromagnetic radiations of ultra-high frequency.
RELATIVE IONIZING EFFECTS OF RADIOACTIVE EMISSION
Ions are charged atoms or charged molecules.
Atoms become ions when they lose or gain electrons.
Nuclear radiations, i.e., alpha, beta, and gamma, can knock out electrons from atoms in their paths, resulting in
an ionizing effect.
However, alpha particles have the most significant ionization power than beta particles and gamma rays. It is
due to the large positive charge and large mass of alpha particles.
Beta particles ionize a gas much less than alpha particles.
The ionization power of gamma rays is even less than that of beta particles.
The phenomenon by which radiations split matter into positive and negative ions is called ionization.
RELATIVE PENETRATING ABILITIES OF RADIOACTIVE EMISSION
An alpha particle has the shortest penetrating ability because of its strong interacting or ionizing power.
Alpha particle has a penetrating range of only a few centimeters in the air; they can be stopped by a thick sheet
of paper or by the skin.
The beta radiation interacts with the matter due to its charge and has a high penetrating range compared to
alpha particles.
Beta particles have a range of several meters in the air.
They can penetrate through thick paper but are stopped by a few millimeters of aluminum. However, gamma
rays range several hundreds of meters in the air.
220
The gamma rays are very penetrating, never completely stopped through lead, and thick concrete will reduce
their intensity. It is due to their high speed and neutral nature.
The strength of radiations to penetrate a certain material is called penetrating power.
NUCLEAR TRANSMUTATIONS
If an isotope is radioactive, it has an unstable arrangement of neutrons and protons.
The emission of alpha or beta particles makes the nucleus more stable, whereas it changes the number of
protons and neutrons.
So it transmutes to the nucleus of a different element.
The original nucleus before decay is called the parent nucleus.
The nucleus formed after decay is called the daughter nucleus.
Radioactive disintegration causes nuclear transmutation and converts one chemical element or isotope into
another chemical element or isotope.
Now we can represent changes in the composition of the nucleus using a nuclear equation in which an unstable
parent nuclide X decays into a daughter nuclide Y by the emission of alpha, beta, and gamma decay products
with the release of energy.
Alpha (α)-decay
In alpha decay, the proton number or atomic number, Z of the parent nuclide reduces by 2, while its atomic
mass or nucleon number, A, decreases by 4.
Beta (β)-decay
In beta decay, the atomic number Z of the parent nuclide increases by one, and its atomic mass or nucleon
number remains unchanged.
Its general equation is;
BACKGROUND RADIATION
There are a small number of radiations around us due to the radioactive elements present in the surroundings.
These radiations mainly originate from various natural sources such as soil, rocks, air, building materials, food
and drinks, and even from space.
These natural radiations that come from the surroundings are called background radiations.
In some areas, over half of these radiations come from radioactive radon 86Rn222 gas, rocks seeping, and some
types of granite;
Our planet Earth is also exposed to radiation from outer space called cosmic radiations, consisting of electrons,
protons, alpha particles, and larger nuclei.
The cosmic radiation interacts with atoms in the atmosphere to create a shower of radiation; including X-rays,
muons, protons, alpha particles, electrons, and neutrons.
Radioactive emissions occur randomly over space and time
Spontaneous decay is a process in which environmental factors cannot influence.
Radioactive decay takes place naturally (all by itself).
There is no way of predicting when a particular nucleus will disintegrate, and the process is unaffected by
pressure, temperature, chemical conditions, and other physical conditions. However, some nuclei undergo
nuclear disintegration at different rates.
A random decay is a process in which the exact time of decay of a nucleus cannot be predicted. A detector like a
221
Geiger-Muller (GM) tube can demonstrate the random nature by observing the count rate of radioactive
disintegration.
When a GM tube is placed near a radioactive source, the counts are irregular.
Each count represents a decay of an unstable nucleus.
The variation of count rate over time of a sample radioactive source is plotted on the graph.
You can see the fluctuations in count rate against time; on the graph that provides evidence for the random
nature of radioactive decay over space and time. It can be concluded from the experiment that
• The time of each decay cannot be predicted
• The direction in which radiation is emitted is not possible to determine.
HALF-LIFE
The half-life of a radioactive isotope is the time taken for half of the nuclei present in any given sample to decay.
Iodine-131 is a radioactive isotope of iodine.
Iodine-13l has an eight-day half-life, which means that half of an iodine-I31 sample will be converted to other
elements within 8 days.
Half of the remaining iodine will decay in the next eight days, leaving eight only one-fourth of the original
amount of radium, and so on, the decaying process continues.
Every radioactive element has its characteristics half-life.
The half-lives of some radioactive isotopes are given in the table below.
It might seem strange that some isotopes have short half-lives while others have long half-lives.
A radioactive tracer is a chemical compound in which a short-lived radioisotope has replaced a few atoms.
Tracers monitor the metabolism of chemical reactions inside the human body, animals, or plants. Radioisotopes
are used as tracers in medicine, industry, and agriculture.
Medical treatment
In nuclear medicines, radioisotopes are used for curing various diseases.
For example, cobalt-60 is a strong gamma emitter.
These rays can penetrate in-depth into the body and kill the malignant tumor cells in the patient. Treatment like
this is called radiosurgery.
Testing for cracks
Gamma rays have high penetrating power, so they can photograph metals to check cracks.
A cobalt-60 is a natural gamma rays source and does not need electrical power like an x-ray tube.
FISSION AND FUSION
Nuclear reactions are processes in which one or more nuclides are produced from the collisions between two atomic
nuclei.
The nuclides produced from nuclear reactions are different from the interacting nuclei or parent nuclei. Two notable
nuclear reactions are nuclear fission reactions and nuclear fusion reactions.
NUCLEAR FISSION
Nuclear fission occurs when a heavy nucleus, such as U-235 absorbing a slow-moving neutron, splits or fissions
into two smaller nuclei with the release of energy.
For example:
When U-235 captures a neutron, an intermediate, highly unstable nucleus, U-236 is formed that disintegrates
only for a fraction of a second into two smaller nuclei of nearly equal fragments, Kr-144 and Barium-89, called
fission fragments accompanied by two or three neutrons.
NUCLEAR FUSION
Nuclear fusion occurs when two light nuclei combine to form a heavier nucleus with the release of energy.
For example:
When a nucleus of Deuterium (H2) is fused with a nucleus of Tritium (H3), then a Helium nucleus or alpha particle
is formed as represented by the equation,
The total mass of the final nuclei is always less than the mass of the original nuclei. This loss of mass produces
nuclear energy.
223
CLASS – 6
Things described in previous classes are not typed again in this class 6
A Set is collection of well defined and distinct objects
George cantor was mathematician who gave the concept of set in 19th century
Symbol 𝝐 is read as “belongs to” and ∉ is read as “does not belongs to”
Set is described in two forms Tabular form like {a,e,i,o,u} and Descriptive form is like set of vowels
The name of set is denoted by Capital letter of English Alphabet
A set which is limited in number of elements is finite set and unlimited elements is infinite set
A set which has no element is called an empty or null or void set denoted by { } or ∅
A set which has only one element is called singleton set like {5}
All the elements of both sets are same are Equal sets and both sets are same in number are Equivalent
sets
Equal sets are represented as A=B and equivalent are represented as A~B
All the sets are also equivalent sets but all equivalent may not equal sets
If each element of set A is also an element of set B then set A is called subset of set B. Denoted as A⊆B
Every set is subset of itself
If A is subset of B then the set B is called superset of A. Denoted as A⊃B
If A is subset of set B and A is not equal to B then “A is proper subset of B”. Denoted as A⊂B
If A is subset of B and A is also equal to set B then “A is improper subset of B”. Denoted a⊆B
A number is divisible by 4 if number formed by the last two digits of the number is divisible by 4 or
two digits are zeros like 1002316 and 1002300
A number is divisible by 6 if the number is exactly divided by 2 and 3. Like 2142
A number is divisible by 8 if the number formed by last three digits is exactly divided by 8 or last digits
are 0.
A number is divisible by 9 if sum of numbers is exactly divided by 9
A number is divisible by 11 if the difference of sum of digits at odd places from the sum of its digits at
even places is either 0 or exactly divided by 11. Like 7546 and 907665(9+7+6-0-6-5=22-11=11)
A number is divisible by 12 if the number is exactly divisible by 3 and 4 like 234084
A number is divisible by 15 if the number is divided by 3 and 5. Like 26130
A number is divisible by 25 if the number by last two digits is exactly divisible by 25 or last two digits
are 0.
The natural numbers 1,2,3,….. are also called positive integers and corresponding numbers are -1,-2,-
3,…. Are negative integers while 0 is neither positive nor negative like ….,-3,-2,-1,0,1,2,3,…...
Integer numbers are also called directed numbers
Absolute value or numerical value of a number is its distance from 0 on the number line and its
always positive or 0 and denoted by | | e.g. |+7|=7 or |-15|=15
There are four kinds of brackets ̶ bar or vinculum, () parenthesis, {} curly brackets and [] square
brackets
In proportion a:b::c:d, a and d are called extremes & b and c are called means
Ratio of two numbers a and b, where b≠ 0 is written as a:b and a is antecedent and b is consequent
To find quantity if percentage is given, rule is “Quantity= Percent of quantity ÷ Rate” where rate is
percent and percent of quantity is given quantity like find the quantity if 75% of it is 123. Hence it is
164 by rule “”
Profit=Selling Price (SP) – Cost Price (CP) and Lost=Cost Price – Selling Price
Discount percent is calculated on the marked price and not on SP or CP
“Profit Percent = Profit / CP * 100%” and “Loss Profit = Loss / CP * 100%”
In 820 AD, Muslim Mathematician Muhammad Ibne Mosa Al Khawarzmi wrote book algebra-wal-
almuqabila.
The term algebra is an extension of arithmetic in which letters and symbols replace the numbers or
quantities.
Any of the letters of English alphabet, which is used to denote number in algebra, is called variable.
E.g. x+5>2
224
Complement of a set if U is universal set and A is subset then U-A, or A’ is called complement of the
set A.
Commutative property of union of sets is A∪B = B∪A will get same result by solving
Associative property of union of sets is A∪(B∪C) = (A∪B)∪C will get same result by solving
Commutative property of Intersection of sets is A∩B = B∩A will get same result by solving
Associative property of Intersection of sets is A∩(B∩C) = (A∩B)∩C will get same result by solving
Venn diagrams is representation of sets through rectangle circle or oval and introduced by John Venn
𝑝 2 1 3
Rational number is a number that can expressed in the form 𝑞 where q≠0 like 3 , 7 and 4 are rational
numbers
Zero can never be denominator because division of zero is undefined
Every N and Z is also a rational number and there are infinite rational numbers between any two
numbers
𝑎
If the sum of two rational numbers is zero then they are called additive inverse of each other. (𝑏 ) +
𝑏
(− 𝑎) = 0
If product of two non-zero rational numbers is 1 then they are multiplicative inverse of each other like
𝑎 𝑏
× =1
𝑏 𝑎
𝟏
𝑝 𝒑 𝒒
If is non-zero rational number then is reciprocal and
𝑞 𝒒 𝒑
𝑎 𝑐 𝑐 𝑎
Commutative property w.r.to addition of rational number 𝑏 + 𝑑 = 𝑑 + 𝑏
𝑎 𝑐 𝑐 𝑎
Commutative property w.r.to multiplication of rational number 𝑏 × 𝑑 = 𝑑 × 𝑏
𝑎 𝑐 𝑒 𝑎 𝑐 𝑒
Associative property w.r.to addition 𝑏 + (𝑑 + 𝑓) = (𝑏 + 𝑑) + 𝑓
𝑎 𝑐 𝑒 𝑎 𝑐 𝑒
Associative property w.r.to multiplication 𝑏 × (𝑑 × 𝑓) = (𝑏 × 𝑑) × 𝑓
𝑎 𝑐 𝑒 𝑎 𝑐
Distributive property of rational numbers w.r.to multiplication over addition. 𝑏 × (𝑑 + 𝑓) = 𝑏 × 𝑑 +
𝑎 𝑒
𝑏
×𝑓
𝑎 𝑐 𝑒 𝑎
Distributive property of rational numbers w.r.to multiplication over subtraction. 𝑏 × (𝑑 − 𝑓) = 𝑏 ×
𝑐 𝑎 𝑒
− ×
𝑑 𝑏 𝑓
Ascending and descending order of rational number is decided by 2 conditions
2 7 1 1 2 7
If the denominator is same then numerator will decide like ascending of 5 , 5 , 5 is 5 , 5 , 5
If the denominators are different, we get LCM and multiply & divide LCM with denominators to get
3 4 1 30 35 56 3 1 4
same denominators like , , . Hence LCM is 70 so , , is ascending , ,
7 5 2 70 70 70 7 2 5
A decimal which contains finite number of digits after decimal point is called terminating decimal e.g
0.5, 0.25
A decimal which contains infinite number of digits after decimal point is called non-terminating
decimal e.g 0.555…., 0.2555….. and 0.90909……… etc
A non-terminating decimal in which a ‘single digit’ or ‘block of digits’ is repeated infinite number of
times after decimal point, is called recurring decimal e.g 0.90909…. and 0.838383……
A number is repeatedly multiplied by itself then it can be represented in index or exponential notation
like 2 × 2 × 2 × 2 × 2 = 25. Hence 2 is base, 5 is exponent or index and 32 is value
Basically exponents expresses that base is repeated number of times
Exponents Laws: (I) when bases are same but exponents are different, then product law is: am×an=
2 2 2
am+n where a may be rational number and m , n are natural numbers e.g ( )4 × ( )5 = ( )4+5 as per
7 7 7
product law (II) when bases are different but exponents are same, then product law is: an×bn= (ab)n
3 4 3 4
where a,b are rational number and n is natural number. E.g (4)2 × (5)2 = (4 × 5)2 as per product
law
Quotient Laws: (I) when bases are same but exponents are different, then Quotient law is: am÷an= am-n
where a may be rational number and m , n are natural numbers e.g 36÷32 = 36-2 (II) when bases are
226
𝒂
different but exponents are same, then Quotient law is: an÷bn = (𝒃)n where a, b are rational number
𝟓
and n is natural number. E.g 52 ÷ 32 = (𝟑)2 as per quotient law.
If a is a rational number and m, n are natural numbers, the power law is: (am)n = amn e.g (73)2= 73*2 = 76
Value of exponential expression when exponent is Zero is 1. E.g a0=1 or 50=1, a is rational number
1 1 1
Value of exponential expression when exponent is negative a-m = 𝑎𝑚 e.g 5-3 = 53 so a-1 = 𝑎 generally
Negative integer in base: (-a)n = +an if, n is Even and (-a)n = -an if, n is Odd e.g (-5)11 = -511 and (-3)20 =
+320
A positive number which is the square of any number is called perfect square. E.g 1, 4, 9, 16, 25 etc
Properties: (I) The square of even number is even e.g 22 = 4, 42 = 16, 62 = 36, 82 = 64 etc
(II) The square of odd number is odd e.g 12 = 1, 32 = 9, 52 = 25, 72 = 49 etc
𝟑 𝟗
(III) The square of a proper fraction is less than itself. E.g (𝟒)2 = 𝟏𝟔
(IV) The square of a decimal less than 1 is smaller than the given decimal e.g (0.2)2 = 0.04
The symbol of radical sign ‘√’ is used to show square root of a number. Square root of √𝟗 = √𝟑 ∗ 𝟑 =
𝟑
By factorization method: √3969 = 3 × 3 × 3 × 3 × 7 × 7 = 3 × 3 × 7 (Pairing factors) = 63 is square root
The number inside radical sign is called radicand.
There are two methods to find square root of a number (i) Factorization Method (ii) Division Method
If two ratios containing A, B and C are A : B = x : y and B : C = y : z then their continued ratio is A : B : C
=x:y:z
Find A : B : C if A : B = 5 : 6 and B : C = 6 : 7 then A : B : C = 5 : 6 : 7
Share = Component of Ratio × Total quantity / Sum of Ratio
A fee Charged (Levied) by the government on a product, income or activity is called Tax.
Property tax (generally 2%) is levied and collected under Sindh Urban Property Tax Act 1958 in
province
Formula for finding property tax = Rate × Value of property /100 and property tax may vary in each
province
General Salex Tax (GST) is a tax paid to Government for the sales of certain good and services
Total GST = Item of cost × Rate of GST e.g A seller charge Rs. 2500 for shoe with GST 17% so it will be
425.
Markup is an additional charge by bank or organization with the borrowed amount. Markup = P × R ×
T /100 (where P = Principal amount, R = Markup Rate and T= Time period)
The collection and distribution of zakat and Ushr system was enforced in 1980. Zakat = Annual saving
× 2.5%
Ushr is paid by land owner & Ushr Rate is 5 % (if Land irrigates artificial) or 10% (if water of river,
stream or rain)
In Algebra Polynomial represents an algebraic expression containing a single term as well as two or
more terms with exponents of variable must be whole numbers like 6, 2x, x2+5 and 3x3+ 3x2 are
polynomials and x2 + 1/x2 or 𝑦 3.5 + 3 are not polynomials
An expression having one term is called monomial or simple expression i.e 2, 3x, 4ab etc
An expression having two terms is called binomial i.e x+y and 3a-bx2, x2+x etc
An expression having three terms is called Trinomial i.e x+y+z and 3a-bx2-2b , x3+x2+x etc
Formula 1: (𝒂 + 𝒃)(𝒂 + 𝒃) 𝒐𝒓 (𝒂 + 𝒃)𝟐 = (𝒂𝟐 + 𝟐𝒂𝒃 + 𝒃𝟐 )
Formula 2: (𝒂 − 𝒃)(𝒂 − 𝒃) 𝒐𝒓 (𝒂 − 𝒃)𝟐 = (𝒂𝟐 − 𝟐𝒂𝒃 + 𝒃𝟐 )
Formula 3: 𝒂𝟐 − 𝒃𝟐 = (𝒂 − 𝒃)(𝒂 + 𝒃)
Factorization in Algebra can be expressed as the product of given number or expression e.g 4a2 = 2 ×
2×a×a
Factorize = 𝑎2 + 6𝑎𝑏 + 9𝑏 2 will be (𝑎 + 3𝑏)(𝑎 + 3𝑏)
Factorization can be done through perfect square to meet criteria of formulas like Factors of 9𝑦 2 −
81 will be 9 (𝑦 2 − 9) = 9 (𝑦 + 3)(𝑦 − 3) for formula 3
Factorization can be done through Middle term breaking. E.g 𝑥 2 + 5𝑥 + 6 will be 𝑥 2 + 2𝑥 + 3𝑥 + 6 to
make common factor as (𝑥 2 + 2𝑥) + (3𝑥 + 6) = 𝑥 (𝑥 + 2) + 3 (𝑥 + 2). So Result is (𝑥 + 3)(𝑥 + 2)
227
Four major steps to solve real life linear equation: (I) Identify, what to find and determine (II) Choose a
variable to assign to unknown quantity (III) Relationship among known & unknown quantities to form
to form equation (IV) Solve the equation. Determine value of variable and use result to find unknown
quantities in problem
Problem 1: 20 years from now, Nazia will become three times as old as she is now, find her present
age. Solution: Nazia = 𝒙 years, 20 years from now = 𝑥 + 20, after twenty she becomes = 3𝑥 so 𝑥 +
20 = 3𝑥 𝑜𝑟 𝑥 = 𝟏𝟎 𝑖𝑠 𝑡ℎ𝑒 𝑎𝑔𝑒 𝑜𝑓 𝑛𝑎𝑧𝑖𝑎 𝑏𝑦 𝑠𝑜𝑙𝑣𝑖𝑛𝑔 𝑙𝑖𝑛𝑒𝑎𝑟 𝑒𝑞𝑢𝑎𝑡𝑖𝑜𝑛. 𝑝𝑙𝑒𝑎𝑠𝑒 𝑣𝑒𝑟𝑖𝑓𝑦
Problem 2: The sum of two consecutive odd numbers is 36. Find the numbers. Solution: Odd 1 = x, odd
2 = 𝑥 + 2 so required Linear equation is 𝑥 + (𝑥 + 2) = 36 Result: 𝑥 = 17. Odd numbers are 17 and
19
Congruent Figures: They have exactly the same size and same shape; they not need to be identical.
They may have different colors or textures. Symbol of congruent is ‘≅ ′ e.g
Congruent figures in examination are always given for judge the size and shape
There are two triangles of same size and shape are congruent
In this figure, there is rectangle rounded and another is different.
Two or more geometrical figures are said to be similar if their shape is same
A Line segment joining any two points on the circle is called chord of circle. See Figure
The segment of a circle is a shape whose boundary is an arc and chord of a circle. See figure
Geometrical figures which have exactly same shape are called similar figures denoted by ‘~’
A triangle is polygon having three sides and three angles with the sum of interior angles 180° is called
triangle.
A quadrilateral whose opposite sides are congruent and parallel is parallelogram
Base angle = (180° − Vertex angle)/2
Isosceles triangle has two sides congruent and quadrilateral triangle has three sides congruent
The circumference is slightly more than 3 times the diameter
Surface area of cylinder = 𝟐𝝅𝐫(𝐫 + 𝐡) and Volume of cylinder = 𝝅𝒓𝟐 𝐡
Base angle of an isosceles triangle is 𝟔𝟕°. When the vertex angle is 56°
CLASS - 8
Things described in previous classes are not typed again in this class 8
Important Sets: Natural Set N = {1,2,3,…….}, Whole numbers W = {0,1,2,3,4,…….}, Integars Z = {…..,-3,-
2,-1,0,1,2,3,…..}, Even numbers E = {….,-6,-4,-2,0,2,4,6,……}, Odd Number O = {….,-5,-3,-1,1,3,5,…..},
𝑥 𝑝
Prime number P = {2,3,5,7,11,13,17,…..}, Rational numbers Q = {𝑥 = 𝑞 ᴧ 𝑝, 𝑞 ∈ 𝑍, 𝑞 ≠ 0}
All number of possible subsets found by formula 2n. e.g set A = {a,b,c,d} here n = 4, so 24=16 will be
subsets and 15 subsets will be proper but last subset is improper subset = {a,b,c,d}. Verify by solving
subsets
De Morgan’s Laws (i) (AUB)’ =A’∩B’, (ii) (A∩B)’ = A’UB’. Kindly prove by U = {1,2,…,6}, A ={1,2,3} & B =
{2,4,6}
Venn diagram is geographical representation of sets and operations using geometrical shapes.
Practice book e.g
Real numbers are combination of rational and irrational numbers. Like 0, -1, -0.384, ¾, 12.9, 𝜋 are real
numbers
Irrational numbers are non terminating, non-repeating decimals. Denoted by Q’ and cannot be
expressed in the form of p/q, where p, q∈ Z and q ≠ 0.
𝟏
√𝟐, √𝟑, √𝟖, 𝝅, √𝟑 , √𝟕, √𝟒𝟖 𝒂𝒏𝒅 √𝟏𝟐𝟐 𝑎𝑟𝑒 𝑖𝑟𝑟𝑎𝑡𝑖𝑜𝑛𝑎𝑙 𝑛𝑢𝑚𝑏𝑒𝑟𝑟𝑠
Real numbers are union of Rational and Irrational and denoted by R. R = Q U Q’
Rule to determine number of digits in the square root of a perfect square is:
𝒏 𝒏+𝟏
𝟐
𝐷𝑖𝑔𝑖𝑡𝑠 𝑤ℎ𝑒𝑛 𝑛 𝑖𝑠 𝒆𝒗𝒆𝒏 𝑎𝑛𝑑 𝟐
𝑑𝑖𝑔𝑖𝑡𝑠 𝑤ℎ𝑒𝑛 𝑛 𝑖𝑠 𝒐𝒅𝒅. E.g Root of 240100 will be 3 digits because
n = 6 and n/2=3. Verify by finding square root through division method
The Cube of a number is the number obtained by raising it to the power of 3. 23 = 8, 43 =
64 𝑎𝑛𝑑 63 = 216
Perfect cube root by factorization method. E.g 1728 = 2×2×2×2×2 ×2×3×3×3 =(2×2×3)3 = 123
228
The square root of a positive number is another positive number whose square is the given number.
A number system formed, by two digits, 0 and 1 is known as a number system (Binary number) with
base 2.
0 is represented 02, 1 = 12, 2 = 102 and 3=112 and so on
A number system with base 5 involve 0, 1, 2, 3, 4 numbers. 0 represents 05, 2 = 25, 4 = 45, 5 = 105 and 6
= 115
A number system with base 8 involves 0-7 (octal numbers). 0 represents 08, 7 = 78, 8 = 108, and 9 = 118
A number system with base 10 involves 0-9 (decimal numbers). 9+1=10 (decimal) and 45+15=105 (Base
5)
Decimal number system is most familiar to us because we use in daily life but computer understand
Binary system. For digitalizing decimal, Octal and Base 5 must be converted to Binary number system
To convert decimal to binary, we must divide with 2. E.g 19 is divided to save remaining are 100112
To convert decimal to base 5, we must divide with 5. E.g 678 is divided to save remaining are 102035
To convert decimal to octal, we must divide with 8. E.g 728 is divided to save remaining are 13308
To convert Binary to decimal, we must multiply with 2 with highest to lowest power. E.g 1012 is
multiply by 2 as 1 × 22 + 0 × 21 + 1 × 20 = 4 + 0 + 1 = 5
To convert Octal to decimal, we must multiply with 8 with highest to lowest power. E.g 5068 is
multiply by 8 as 5 × 82 + 0 × 81 + 6 × 80 = 320 + 0 + 6 = 32610
In Algebra, Literal is a letter used to represent a constant or a variable in an expression. E.g 2𝑥 − 5𝑦 +
𝑝, here x,y & p are literals but 2 is not a literal
Variable is a symbol or letter used to show the unknowns, usually we write x,y,z to represent
variables.
The father of Modern Algebra is Alkhawarzmi (780-850).
𝑥
Polynomial whose degree is 1 are called Linear Polynomial, e.g 5x, 2x+3y, 5𝑥 − 9𝑦 − 𝑧, + 4
4
1
Polynomial whose degree is 2 are called Quadratic Polynomial, e.g 𝑥𝑦, 3 𝑦 2 , 2𝑥𝑦 + √3, 𝑝2 + 𝑞 2 + 𝑟
Polynomial whose degree is 3 are called Cubic Polynomial e.g 𝑥 2 𝑦, 𝑥𝑦𝑧, 3𝑥 + 1, 𝑥 3 + 𝑦 3 𝑎𝑛𝑑 5𝑝𝑞 2 +
2𝑝2 + 5𝑞 2
Polynomial whose degree is 4 are called Bi-quadratic Polynomial e.g 2𝑥 4 , 𝑥 3 𝑦 − 𝑥𝑦 3 , 𝑝2 𝑞𝑟 + 𝑝𝑞 +
𝑞𝑟 + 𝑝𝑟
Formula 1: (𝒂 + 𝒃)𝟑 = 𝒂𝟑 + 𝟑𝒂𝟐 𝒃 + 𝟑𝒂𝒃𝟐 + 𝒃𝟑 and Formula 2: (𝒂 − 𝒃)𝟑 = 𝒂𝟑 − 𝟑𝒂𝟐 𝒃 + 𝟑𝒂𝒃𝟐 −
𝒃𝟑
Construction of linear equation with two variables. Step 01: Represent unknown quantity with English
alphabet
Step 02: Write the equation that matches the criteria of problem or statement. E.g The sum of ages of
two students is 30 should be x + y = 30, amount spends on 5kg apple & 3kg mangoes is 550 will be 5x +
3y = 550
Two lines are said to be parallel if they are coplanar and do not intersect at any place
A plane closed figure bounded by three or more sides is called polygon
A pentagon (five sided closed bounded figure) in which all sides are congruent to each other. See
figure
A Hexagon (Six sided closed bounded figure) in which all sides are congruent to each other. See figure
An Octagon (Eight sided closed bounded figure) in which all sides are congruent to each other. See
figure
A line which intersects the circle at any two of its points is called secant. See figure
A line is called Tangent to the circle if it intersects the circle at one and only one point only. See figure
A portion of circular region bounded by two radical segments and an arc is called sector. See figure
If four or more points are such that a circle passes through all the four or more points are concyclic
points.
Two or more circles having the same centre and different radii are called concentric circles
Angle between converging lines without producing them is180°.
The relation between three sides of right angle triangle was first introduced by Greek Mathematician
Pythagoras (570-495 B.C). Formula: (Hypotenuse)2 = (Perpendicular)2 + (Base)2
229
A side opposite Right angle is always Hypotenuse and a side vertical is perpendicular & horizontally is
Base
Pythagoras found this concept by Egyptians to measure width of Nile River with triangle formed by
chains.
Hero’s Formula is Area of Triangle ∆𝑨𝑩𝑪 = √𝑺(𝑺 − 𝒂)(𝑺 − 𝒃)(𝑺 − 𝒄) , where S is semi perimeter of
triangle
𝒂+𝒃+𝒄
𝑺= 𝟐
, In Hero formula, there is no right angle
Sphere is solid thing bounded by a single curved surface and is such that all the points on its outer
surface are at an equal distance from a fixed point called its centre which is inside the sphere.
𝟒
Surface Area of sphere = 𝟒𝝅𝒓𝟐 , Volume of sphere V = 𝝅𝒓𝟑
𝟑
Demonstrative Geometry is branch of mathematics in which statements concerning geometrical
figures are proved through logical reasoning. Demonstrate means ‘To prove with certainty’
Fundamental agreements related to numbers are axioms and related to geometrical figures are
postulates
Q.E.D stands for ‘Quod Erat Demonstrandum’ means ‘which was to be proved’
Trigonometry (greek word) is branch of mathematics that deals with the relation of measures of sides
and angles of a triangle. Tri = three, Gono = angle and Metron = measurement
𝒂 𝒃 𝒂
Trigonometric ratios with acute angles are 𝐬𝐢𝐧 𝜽 = , 𝐜𝐨𝐬 𝜽 = , 𝐭𝐚𝐧 𝜽 = , 𝐜𝐨𝐭 𝜽 =
𝒄 𝒄 𝒃
𝒃 𝒄 𝒄
𝒂
, 𝐬𝐞𝐜 𝜽 = 𝒃 , 𝒄𝒐𝒔𝒆𝒄 𝜽 = 𝒂
Sine is inverse of cosecant, cosine is inverse of secant and Tangent is inverse of cotangent and vice
versa.
𝑐𝑜𝑠𝑥 𝑠𝑖𝑛𝑥 1 1
𝑠𝑖𝑛𝑥
= cot 𝑥 , 𝑐𝑜𝑠𝑥 = 𝑡𝑎𝑛𝑥 𝑎𝑛𝑑 cot 𝑥 𝑇𝑎𝑛 𝑥 = 1. 𝑣𝑎𝑙𝑢𝑒𝑠 sin 45° = , cos 45° = , tan 45° =
√2 √2
1, cot 45° = 1
1 √3 1
sec 45° = √2 , 𝑐𝑜𝑠𝑒𝑐 45° = √2 , sin 30° = 2 , cos 30° = 2
, tan 30° = , sin 60° =
√3
√3
𝑎𝑛𝑑 cos 60° = √3
2
𝑻𝒂𝒏(𝟗𝟎° − 𝜽) = 𝐜𝐨𝐭 𝜽, 𝐜𝐨𝐭(𝟗𝟎° − 𝜽) = 𝐭𝐚𝐧 𝜽, 𝐬𝐞𝐜(𝟗𝟎 − 𝜽) = 𝒄𝒐𝒔𝒆𝒄 𝜽, 𝒄𝒐𝒔𝒆𝒄(𝟗𝟎° − 𝜽) = 𝐬𝐞𝐜 𝜽
Statistics is the branch of mathematics concerned with classifying, analyzing and interpreting data
The number of times a value occurs in the data is called its frequency, denoted by ‘f’
The tabular arrangement of data together with class frequencies is called frequency distribution or
table
𝐿𝑎𝑟𝑔𝑒𝑠𝑡 𝑣𝑎𝑙𝑢𝑒−𝑆𝑚𝑎𝑙𝑙𝑒𝑠𝑡 𝑣𝑎𝑙𝑢𝑒
Size of class interval =
𝑁𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑐𝑙𝑎𝑠𝑠𝑒𝑠
A histogram is constructed from frequency table; it consists of a set of adjacent rectangles for each
class. All the rectangles are of equal width but their heights are different, as they represent frequency
for all classes.
𝑠𝑢𝑚 𝑜𝑓 𝑎𝑙𝑙 𝑚𝑒𝑎𝑠𝑢𝑟𝑒𝑠
Mean (Average) = 𝑛𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑚𝑒𝑎𝑠𝑢𝑟𝑒𝑠 e.g Mean for 1,3,5,7,9 is 5 and Mean for 5, 15, 25, 35, 45 is 25
When different values have different importance then these values are known as weights
£ 𝑥𝑖 𝑤𝑖
Weighted mean = £ 𝑤𝑖
, xi have weighs and we can find weighted mean
Median is the middle value of given data; it divides into two parts first half and 2nd half of the data
before the median value and second half after the median value. Middle term (M.T) (i) if given data is
𝑛+1
odd in M.T, M.T will be 2
𝑡ℎ 𝑡𝑒𝑟𝑚 and (ii) if data is even then mean of two terms will be the median.
Median of 2, 10, 6, 8, 9, 5, 3, 7, 4. Arrange in ascending order as 2, 3, 4, 5, 6, 7, 8, 9, 10. Data consists
9+1
of 9 numbers so Median = 2
= 𝟔, Median for 3, 5, 7, 10, 15 is 7, and 13, 15, 17, 20, 25 is 17
230
Mode is that value which occur maximum number of times in a group of data. When none of value is
repeated means no mode and two or more repeated values means multiple modes are there. E.g 70,
50, 40, 65, 45, 65, 70, 65, 50, 45, 70, 65. Here 65 is the greatest mode.
231
MATH CLASS - 9
CHAPTER 01
REAL AND COMPLEX NUMBERS
CHAPTER 2
232
LOGARTHIMS
CHAPTER 3
233
CHAPTER 04
FACTORIZATION
234
CHAPTER 5
ALGEBRAIC MANIPULATION
CHAPTER 6
LINEAR EQUATION AND INEQUALITIES
235
CHAPTER 7
LINEAR GRAPH AND THEIR APPLICATION
CHAPTER 8
QUADRATIC EQUATION
236
CHAPTER 9
CONGRUENT TRIANGLES
CHAPTER 11
LINE BISECTOR S AND ANGLE BISECTORS
CHAPTER 12
SIDES AND ANGLES OF A TRIANGLE
237
CHAPTER 13
PRACTICAL GEOMETRY – TRIANGLE
CHAPTER 14
THEORAMS RELATED TO AREA
238
CHAPTER 15
PROJECTION OF A SIDE OF A TRIANGLE
CHAPTER 16
INTRODUCTION TO COORDINATE GEOMETRY / ANALYTICAL GEOMETRY
239
MATH CLASS 10
CHAPTER 17
SETS AND FUNCTIONS
CHAPTER 18
VARIATIONS
CHAPTER 19
240
CHAPTER 20
THEORY OF QUADRATIC EQUATION
CHAPTER 22
BASIC STATISTICS
241
CHAPTER 23
PYTHAGORAS THEORAM
CHAPTER 24
RATIO AND PROPORTION
CHAPTER 25
CHORDS OF A CIRCLE
242
CHAPTER 26
TANGENTS OF A CIRCLE
CHAPTER 27
CHORDS AND ARCS
243
CHAPTER 28
ANGLES IN A SEGMENT OF CIRCLE
CHAPTER 29
PRATICAL GEOMETRY – CIRCLES
CHAPTER 30
INTRODUCTION TO TRIGNOMETRY
244