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Alomlc -Struc bures-
Atom: Moclolcs-
Aleta dicouty of dienl_sualomi thls.
desiouation oF these subatonle parkele
cage tae. ie da of query. bitterent pies Stee
modlele were nme _inapor lank meodtls af
atoms are '-
Thomson’ atoule model€Cnol in ram)
Ruther Ford atomic moclel
*| hohr'c abtudie node!
el wave mech ouical mode! $$ $$$
Thomson's atownc model Cplum pudlclivag motel ar
watermelon oe Ge fer) ae ee
.
Proposed ly ET. Thowesor tut —
Shis_m b e
atom _theoré br lly
facta ‘
bin me puddieg
D9) if eS |
cradled uia_tk hai fem
tl4n alm as a whole ic ele bntcally neutral. 4
OQ + Me v'ca)
Clow
. a
for e aol poet five a
\ © 9S HlledionNha t Li 2 o
: ls 2, petisely chargel
farheles and the red fark of __
ac y chier ged
Aforrie? mele] Weler melon
aa ; elec teow
7D
pedis of thomsov's atom i clel.
h atom
berause as madel of _atom fi led to Ae
me
howd afi ¢ the née
chan f i Mh te T's
theory ako filled lo Qctounk br the pec fion
e Ww
Mo esperimeutal evr'leute_n_i'ls suppoth.
bathorford!s atomic model Calpha tay Scalleisg eatin Jecinenl
_ gad Feil expec'uceut)
This model was pul forward bi Eenest Katha ford
inl91l soit heyp_ol ecray. scat erg experiment
Tan tls eign he bouburded a thin sheek
of pure gold ful (0.0000 ucm thitkwess) wile beam
vt _a-far hele Alpha _pachiles are hehum nucler
ie mite! ) Gh a particle: were obtamed fon radium‘
Tadoat hi f site
|A_small piphole init. The gold Pil uses surrounded
by movoble rine culphabe screen to defect the
Statler I a
Stattered d-pachloles tam gold fail. when b-flarhiles
tk zinc sulphide cron they ee
fla sca hi'e he Md. be ohseld
byob mizosoge
fhe experimental celup ae
in “fet :
vee bork Head veTe
Fig hu ter cl’ A-patlicles scattering Eifel end.
Fhehellewhegobsecuahions ie wta ale toma the sak
experimen! .
&
Most of me o-parlicles Gbout 25:4) passed mrovg h the
Foil voithout lec hon,
2
Santor kev o-pathdles. Cubed th sec Willa Feih patight
——_|| small angle sts ese ean Jo
&
very. few opr hi out Ie Lavcco) were deffectect
beck tough angle more kan 20° or even veterned —~ate
He made fol owing conclusion frou above
\
1)| Most of Me o-pachicles passed Maroy h- bg
i! witr out jh deflection. Wis shows thal _
¢
mest of Me spéce_Mnsicle Ihe alom_is “ehly — nae nlon
ter holloa-
2. fea Oetutices watt deleted Hough cwclt
“aap Si onal ee
——_| 2 ole pe ae
a SO ‘hvely char,
Tein haat ae ae veemeal fois
—1#te_thost_tahte passed very close bo tes
a itve bo cy. \;
2 very fe potholes. wt fle Sh
_ pari Q, bl hah
te dle k sea
— hawir PAA ahem Te i
m thal wok f fet oe
heuer a.
wilh in tae atom is uely. Gee
fo_tho_lotal volume of the atom.
Gis sueall dense positively charelged. aay —
with nthe Qtom In aich whole mess ef —
alm is concen trated was called nucleus ——Page.
o— — > b-por ka,
seoltened deflechon Fal
fig Gabecing of ot pac hile ba cing le alm
th
L
a hy f ah i
to_this_mode/
—— nucleug —vahich ts very emall In-eize Compared
toa / t
! the atom
2) Most part of atom _ic_emply. Te Ny
2), he clam os. whole sa als eae
sluce he ae clet hon. 1's= -flawel_revalue ab round Whe sum in regularly
defined orbit
—2
es af fal poe lee bx orbits belated _
7 by electro Stahe force of Qhtravtton between
| he centr of an electron which tends ___
Mi tud_electrong _
| 1 tite Hons “Drea boat ting of Ku toer Forde
Atomic Model, :
Although the hutae tard ato mic_model was
_ base: fart 4 : 1
fo explain Certain —thinge
| his ma del could nol ex lun Me stabllity
‘4 Le
lof atom. Acco ere
a he 7 ct eh ahous
haged pachclec_emit electromagnehe tacdiahone __
and_heuce_an_elet tron revolving around the
nucleus choulll uit electromague He vachatin
Dus_radiahlon would ca eneegy Lont_lhee
of the 4 a (
mi
mohon of Ke electron falle and electron __—
moves towird closer aud closer_te_the wucleue
follouat» Mt Bi.th end ulti neately tee ____
electrons woul cl collapce ta he Mucleuc.
Gil Gide ee
model, an tlechon wold collapse in the Muclas
model,
tn less han (0% seconds ) tut ally Hus
en because alow _'s stable iz. nahure.
: ,
aMaw well’ theory and could vol explora tee
slability of an atom. poss GE Ee
SU
Cechow gue
Vrediahon
oN pel Gs
i Figure! Spiral Path of the elechrong
D. his model could vot explain the origlt of Une ‘nthe origla of Une
peclra of hydrogen atom.
When hydrogen gas_is passed through electric ___
—_. dischar geal low pressure, there is forme flow
of spectral lines. Mu: ‘
futher ford. ahownle model
Bahr’ alomic Medel oe
Tn 19138_iels bobr proposed _an.atouric_model ___-
_.fo_overcome the limitahions of Rutter bord’
_alomic_mocle/ keeping its essential spin'te. He
Lopplied. Black's quan tuw ee oF racia hon
ifo_an atom. the basic postulates of Bore. -
atomic model areas Follows:
oe weae
at Ty_an..atom, el trom_revelveasociucl pasitivety 3
& “| dharved—nucleesin_a.olefini te circular puke2)
®
Soe
sarees —
called orbs or shells or energy level...
As long as electrons remaln sina ry er |
ih neler enu'ls nor absorbs energy. Tk wears.
Me energy oF reveling elechon Ina pathtculer
orbit remaing coustawl. Hence Meese orbite are
alo called shalonery orb IL. slaloway ete rgy
level ov sigh eneigy level or hey shell Such _
a_slate of lect ts called iiss shale,
Mis poshelute eaplatns stability ofanatom.
dhe energy Ny levels are repre seuled bi ae
=(,2,3, 6.) known asthe firinc’ale 9 kan tum
maw ber. Energy associated witha. ees
level increases with he tacreace of te dhs
how the nucleus. The orbits. A ee
wale Gs kt, 4M, - shells aud when an
velechon altains the loin b _euers ppleveloit se
said to be inthe, ground stale _—___—
Fiy, Stafon ay nay levels acound He nucleus.
Glechoy can. revolve only i tn. Mase avgih me
wilich the. aupular mowentuna of revtling—+ aes blown. Thal 1 _why ee
(einrh
lection ground te nucleus ican nbeg
eae
| wahece Set ee
| me mace of elec fron
ive Vélocily of elec hon
Lre elles of erbit ta colt elechon reucluiag
unzAa ule ger called priucple quanhem member _
| Fhe, 3, 2-2... 00 (number of axkill
the tenk'’s cons tav ft.
220 tar
gee ene
Zt Lh etc. but tt Can never have Frachona,
alg ae geen a
——|lguanhrahon of angular ncomen: hegre
¢)| the Ceubcihegal ‘force ofan el tron _walaich habe
be pull awey elechon bom i's orbit 1's bulenced —
electro stahic force of attrathon veheen
nucleus and electrons.
6)
Gat ous could jum Frow_one orbit to_ano Keer oly
ay au thie Hing or _absot blea Arxed qucui of Seer. —S
| @ ms pe )
—_— lahen energy is “etgplied/ fo_au olechron ,1t
— past fare. from_louer. eHergy leva! ht'g hoy
———enetdy level Ly ab corbin ved quanta of
—— The Rew ‘onsite state of euerg ¥
p Lis_talled excited state. the excited stile
: ei ate so Cahon
jump hom _luty her Ene Y love ( fo lower
CHENEY devel by emt ting “Rxed quanta of
energy in. the fen of radia Hou.
The cumount of energy obcar burl 01 cunt Hed
Is equal to the eusrgy chitfereme behieen
fewer Gnd bulg her ener yg evel of fal alton.
DEF b2-€. = hv :
a ees absorbed
x= fuergy of higher. energy. (evel Ss
Fiz fuergy of (owe, energy level
Eee _gxin tum enenyy
Lhe Plenk's constant C 6.626 r10%*7s)
a etuy- of rodia bon Crea)
eae Gaeta es rata model:
— 10) bole’, atomic model explained the stabil by
— | fan _alom. According to ohe, as long Gs.
elections remains In a pathtulor orbit,
it nether emits nor absorbs energy. Also,
th con not jump, from Airct orbit to
the tooer —arkil other ik 10. orbit less
[han one, he gratual loss oF energy by ———we ee
electronic not poscible. Hence, akon stable.
Dibokr cululated the radi! of varé, 2
aut _euergy of au elechonw Ino puthtular
orbit or Ay i'ke_syskem
rodivs of vith 6) bit Gules wth?
i ____ Yn ne*kz oo
3)| Bonr’s atomic moclel pronled salts factory expla ruben
bout he Brmchon of bey drogen spect rum
Acorthiug fo Bohr when elechon jum
z l t level_th Cuts!
I lahov Uh atte,
| redlahion ic respousi,lo fy frwah'on of atomic eo
cpechum
Plas ‘ou of Hydrosen jpeclrew by bob's teary
then electric dt charge ts passed Mnrougls a febe
re
is 6
——contulnieg hg dimgen gas af loo pressure ,at rst
hydrogen molecules dissocinte fe frm hydrogen ess
ke
atoms. Sluce Mae bay dleog er gas cou fats large et
lnumber of Ay dog Gta atous, blec tous tu dittecent —
fous absorb di freceut avcount of energies —
Aca __resull, electrou iin he rst elee energy
level Ground otate) of by duogen alowes get
fo jump tuto cleftereat higher eel y ——_—~
level 224.6, eh clepouchug upon Mee amouel —
of energy absorbed. che excited electrons in —~
H a ev, come unstable ancl ___—~
C ud state in One or more —~
7,
a Ljuinps by. Genithing energy in the forme of radiation. —SS SS
| for_evample, come alectrows Come back bp
le ec Frow. |
ground chute Cu=1) andl oler_to_z2,-n=3, ‘
meet. from higher energy level. These
chifleceut clowonvoucd junep “emit radio hous of ml
ditferewt voweleng ta Cor _treguewtes) avd
produce cbifterent spectrul hines at Me same
Hime tw oe Spechuw Herotagebr- alhough
a -ouly ous electrons. ‘ae
eles oF guch a spectral bvec le calle ch
ul seri
of he radighou ¢ ascocitoted
Aue uaiveleng tte
wih_lifferent doon " é
are given by ky dberg equa Hou
___ Where, A= lew,
eek R
aes an
Cre n> )
4 bt,
L
| a
4 ut (hz OG? rl0? wm?)
ny> lower energy levi / ee
m= higher energy level
drogen atom, S different “specttul series 2
are obtained clepan cling upon tee various
lactron'c_trancittons. For every spectralsedes,
ny is fixed aud mais variable the name
of vadtous spectral series along voita__the___
values of Wi andl M2 aud their co 110s poxdieg
1e9 ion _are ta buloted “belong! 82 eos SN| Lymow Series | __
Bulmer Series.
ea =
Fir Inhared style |
+
Sets by
=
‘
\n
—+—|
defel +4
= 4 |
|
TT
nlaer
> Ly {I grovthelf
eee (Nl) sat i aa
sth oh
q
byweon S005 Fs cous sPecbral_lines. hy eopen ebechaneo
Me difberent hyec of speckal saiee of by
spectum are as fllors!
2D) Laman —_seaies: ;
—,ne_sfeuteal Wines iu these series are obhuued when
_-eléchon jeeps Ron higher energy level 0. y= 2 hoo
fo Rik energy fe level tne. 2t Mis series bes ia
— | he ulhavilolel region within wavelen gh conge of
QO nm.
| Rn fo
The. wove lew ty for the tne be
Sevies art Given oo
pai te. Weak ‘
os
ne )
22), Galwer Series!
dhe spectral l'nes {q these caries ore obhu'ne)
wohen elec trou _j Rom _higher-e leve :
Lie ng=3 to @ to se e.g =
dts sertee tes i'n ucsiole reg/on vaittetg ___
-oouveleng th__range of YOOum to 65Onm
dae waveleug br fot the cpecteal t've ta Belweer
Series ave given by cs a
| aS em re
2) Pas chen _secies' ——
he spectral tines in hese sorties are oblginod __
i
hen lechou hom Al ghey exergy leve |
[ise m24 to 02 fo steowel Cnoryy loutl se. Wte22.
|ahis series ies sn inhared regior sllary
vacvelespth range of 950 um to I €2s: aon.
dian Be fec_the _spectyal [ine 11m ashen| senies_are__givew by, *
| We Qo fet et ) oe
[ed CPT
bran chet series
| She spechul Wines in Meese _ser'es are obhenod 2.
whey electron jumps fom higher energy leve)
[be w2= 6° foot bo th forth energy level te. y= 4
dhis series I'es in inbra red region volth/n
“wanvel (VS nm fo YOSD wy
the sctoreleng Mt foc_tee spectro! Vue | byund&ett
series are givew by
7
i
Ty
i
OO. Phun series
She spectre! lines in tese series ave obku'weack
hen electro juiaps thaw lijher euergy love]
bem, 76 to w@ bo fifty energy level pe. mirc.
ats sen'es Wes ta fer nbrared regio within
ive lovey tof rouge above Y0SO ym
ie tong fl the spectral line ta Pheed
series are given by
1 =¢fi- 2 ee
a So Wy ;
Limi tatlous [short cin of Bol ’s. “theory:
1) Thee explained the sete ak sgl —
it cy
bhi
hike systena _}. i
Tl tana.$ Tee aac Baal
of