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Notes on SSC class 12 transition and inner transition elements
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3. Transiton and inuer transitien selemmentas onyeri ?
——
‘| thts part outy eating win A> block cement = (for terminal,
Gust? 10... [WW
Dc Dim CALI
3d
4d Zr CD |b CuD|tne (sa) |-Te Cus) [ra_(40 lay cudea cer)
ad Le. (s3).|we (2 | To (12| OD |e 0r5) pe (#1) [aw (4g Ce
6d Ae. (2D | Re (wD) yb (w9) $9.0) fam (0) |Hsles) He (ed), (08) [ka for) fon. Co
nie) leyDlznls) *
Trausition. eleneurs belovigs fo --d block -oF periodic Table -
Transitiou mer) dtom hasan Incomplete d-subshell.
appears From..group <3.r0,12.0%..as Along. periods -
Bd__- _Scandinun..(2i)o-, ine (30)
Hd - Yeriumn..(89) => ctdmium (4a)
Sd. - Lauthanum (57) - Merewry (90)
without) ~Certum' re luredum -
bd = Achiniuns (89) — Copernicium (ue)
witeent thorium tt laweurium «
General electronst Contiqurarion (n-)d" "ns va
oF TransiHou elements
Position —— _dbleck. in periodic table -
transition elements are placed ;
Periods 47 tousHture 3d, 4d, 5d) bd
groups 3 told
Placed at centre witr g blow ou one side aud Pluk eu ober side,Sf
|
Bectrinic Coufrquration -
[3d begins wit Se (2221) and ends wits 2n(2=30)-
Argow, Ay is the noble gas preceediug fhe ad sexless
hence Scandium (Z=21)
[sex Lav]3d'hs*] “> as trl
Why zinc is nor regarded As transition element 2,
Zine has complerély Aited (nit)d ovbitatiin ground srare (34° 4s")
im Tks common exidattend erare 42+, vewee uot regarded os trausten tle.
Cadmium - 4d 7 also wet regarded as transitfou elements .
meray - 6a
Ell why cepperregarded a8 transition eemeur > és
—— | Gpper tm Hee elementary crare kas (3d '°4s') coutanis fryed 3d
evbital burin +2 srare (3d D— vere nas party Killed Sd oxbiral |
renee FH ts trausitou Element:
General electrouic Courrqurateen «fF d-bleck eteuierch «
GD | 34 series [ry gat teus® viet “V |
Gid| 4d series Tk) 4a 5g : was |
Giiy_s& = [xD 46" Copceprla) 5A? bs *
(iy) 6h “TR FF" Conperme bd!” 15%
‘| Flectroule Configuration oF chromium and. copper.
PUPP TVR ESTP py
upeoustis pable judicates tat Hie \eleutouic Cons oF Chromium [2224
Coppey( 2 = 24) in 3d Series GWE, from expecred 0-0 fe observey
e7. Cou.
Tus corm be explasue cl ou me basi's of He ouep}t of ardaiWoucr
Skabiity f Completely and balk Filled Substeel) ,Jf
fais tsidue, as the geucral. @C of adecartee 1S
: 457. Here all Hae oie eleuneuds are obecrved i Hues
7 vaanner leaving Gr ¢ cu as, extepriou. The expe shed ele: Can
+E crs CAV) Sd" U5" insread He :
_ leaving Ys party Filled , wis & due mas jue Sel aud 4S
- orbitals arein close energ yaud inorder fe gaia owe
_ Stability me. task eat fusread of Oceupy jug 4s orbital
= skitrs re GA giving Cre CAD 3d 24s! as expen
- —fsame wie Cu
i
ss : : L as
__Elemeurs | sym | ape | Expected efectroul observed electrour’ 5
Ne] _Confiqurakten couFiguratlen - ‘
Seandiumy | Sc ler | [Ai 3d'4s? Z =
~_Trrantum. |T..| 92 | Lav) 3d*4s * 2 g
—Vanadiuer | y. | 23) [ai.3d34s*. eer concen 7
~ Chromium [Cr [24 | Cai) 3d" 4s? fad ad Sus! 7
| Mangavese | mn |25 | Lav 3ds¥s* e
| Lren re {24 | Car] 3d*4s? =
-_ Cobalt @ | 27} Cagad7ys* a
-_ wicke] ni |2e Le) Bd*Y4s2 =
;_pper te [wy | Lad ad*ust \ [Av] 34's) S
-_ Zine zn [eo] Ca¥) ga" 4st s
—s
=. = Oxidaprouigpare\9d + 2
LC r 2
~_Eteraen?s lOater EC | oxtdatio Stare Brerieus | Ourr EC, .| oxvidarim Share.
;— adiys” Bias Fe__|sdta?® lea earu as te es
h Ti. 3ad*4o*./ +243) +4 Co Pays | ters eyes >
Mi [sd?us* fea tans | wi [od8 46? [re bs e4 =
[ oe we 4s a 3 Cy jad" 4s! +r, t2 +3 =
7 F
Mn Zn lau? ys® | +0: =
: ea
FF
&—/L
oxidation Stare oF Hest fraustrtoy] sevtes
as the number of unpaired Clettrores In 3d whole Mancreases »
He number oF oxidation crake juwectee |
The element whee give te greakest uuimberoh oxtdartern ehdles
slot tn ornear te middle ofsertes.
9 PIN. Shows 0:5, From #2 to rT.
Physical propertit of ad .
Here ail fransttor Creunrcnss arew cha) .
Shows, lusture, mallegble, Uigh cwuducttviry , Auch! e, can form
alloys
Except — 2n,td,HatM yp alt ereer have oue or nore Fypicat
merillic structule at auitbieut tenip-
This frausttion metals are very hard plow volaHiiny ), eacepr
possess biqk meltiug t beliiug petuts 2n,Cdl,
AQ
Trende tu atomic propertes of mae Firth tromsirien series #,
Brome and fous'c rade?
shonnis: radit. detrecve. frown leFt te WqUer.ta Praistpie elerrrte
P21 wuy te aremic rads decrease from felt be viqur?e
A We move acrose tansiHon Series From Jetr te vigus Hee nuclear
Onatfe Iuefeone by oue Unt Hine. The last fede” cuters a-
peaulHurare (N14 subslell . yewerer dl. orbira!s su an abort art
more: etuseeh anol. tereFore dl elechrous sher smaller scree
stheck. The vesutt is tet effective UUcleay charge MMereates ax
ahoute numbver (Uerttes . Hence Ahowuic wuclif decrease
gradually acrots a Hausihien Ser/es from lett W vais.for tonic rad u
Hends aa be. sinolied, by
~__ elements le
, w
qviug Same-O-S -
Varlous 0.$ ot pene cletee
~_ with luerealce.pu mutleay ChATge |)
Wher -liqher 0-5 the effewive
@D ar
[0.8 L sane ele. te 2 Mt nin
gradual checreasei toute radil aloseved.
maalear charge tucreone., 1 nic
ee
crt - 32pm 9 sane OS vad" deurenre .
Cu
zi
= 78 pm.) ot Fen HF
receleas CLakae A Grievadil LcteaN Ae ay wi
Nuvear charge is gol
Paci} ACTEM. 7 bon Znrcemn bef. ewe. ¢
\P peek Mere AS MUU CAR AAA B Rs |r Oe fea ft 0
fortic pects?
fo juurcalge Prova leFh.Po aig We
bot for Ahoywe wad tl, ad Mayer Oborye avrors atawic
toe rechy
ridings Line Lord WAAL, ALU ALE EO 22. tite mall
Lont2ariom Eutralples
-G of trausivin Cemeuds- are bukermediale between
S$ block 4 P blo. BQ ou Ys th
Traysitien elements. are less SEPT Htc cest
| group t- 2.
|In lower 9-5 efeweus -forrm —— loure Compouucts
Sal East ae Ae Eee
[ue atom oF. elements of Hiirof papas Seren
| posses Ailled 4F crbottets
The UF orbltal glows povr staedineg effet 0s 4
eS lr Hie Foleuce e = posse W'7k nuclear Atraition
Jreater Guountr of energy /S veguiye fo /oureg
third transition Sexes ,
ak er i
Ba Aight 0-5: eles rm, — Coa leiths Lourtpouscle x
TELS) PLE LL | |
err abe ds ala
The louization en Healpes oF Hilrd tS As greater tenn | — 2.
ws, Sh? 4d 273A. donizatrou eumalpy .
~
Metalite charatrer.
|
Lew tourzaHow entalpy 2 are respouclole For
Vacaur d orbital iq sureroothsuent Nepalis Charaoe” oF
The conipe umes oF treat on meres entiolr miag uel pro pexty
\ S
» The bard Hature oF tese elements sugges Me formatlen of
7 covalent wouds Iu ruem. Thats Is Possible due re presente oF
y uupalred (n-l)d electrous tu Kees element.
¥ | Aware
: [Ad transite wmeray havesinple, hep.» Cepybee patbieg
ae
; ahtelr are Hue ctemctEe nis Hes .
¢ of merals - ; .
, ‘ : ;
7 FA 41 travistrtom Ceriea Weirtug polct jncrens es ckeaolity -uphy d.?
‘ Gutigurarten »
» Cry 0, W show Liauest melHug. poluk in Hur sates.
’ Ma, Te display anomalous valuesoF. m-P. .
y
H Abter pals wie iWtrense Arete Nuuthey Me melHug potnr decrease
+ requiavty..
,
, Pha
r ewe’ ,
be 4 | Maquenc™ properties ayo.
L
'
due pe Me unpatrecl electrors preseut fix Healy a
“
Subsravie whica attra due bo appued Hien wun field. >(fara, wath
Subpauce why'elr repel tN hnmeg mere
Subsrene . Strongly apres ~ Ferrevumguere +Fey) Gop Wi. —. -Ferromaguet{C,., - otis
When maqrette Frld Is. applied Ho rhe elena 148 Lup parwe ck
electrons align io hue divection of applieo maquenc Med -
duc te Hats maquerte Sucesphouity ts enkatted -
Formuhe « fy ela(nta) en spin outy Formule «
ns hes oF Unpalred. e J
fot maquentc Moment expressed ' Bol Magueron (87)
Stugle wupaired, « ~ ez TB a].
colour
The coleurlof frausiloumeral fous. -relates fo,
presennte,oF uupaired A electrous
d-d transits — 7
narete of ligands atakled fs ume Wtetal for
geometry oF complex formed by jer! fen»
El why. do te d- block elenreuts form. coleured Compounds >
+ Compounds. (Jou) of: A bIOK elects of Hrausitfot efenunt;
Are usualy coloured. ‘
+ tris ie die fo presetuce OF unpatred electrous.tu Cn-l4
arblidle. Me trausitton Clements, wave Intoupletely Pi'llecf =
A orbital. =
+ The Curvgy required t promore-oue oroier cletrou, =
tn h-orbita) tnvelviug acd frausitou fs very fot
o S
1 the energy. changes Fev d-d pansies lee ar Hy &
visible rauge Sf eleGromaqueH'e peciahon
+ Therefore the pranaliion elermeth absorb Hee radia on
spa visible areq aud appear coloured --
+ he.colelir °F fous of d bled elements depeud pou Ma
2
ao OF wupatred elec jr An) orbital Te ap
wan 3Same unpalred e- have gatatncoloudesiccrins
Me colour of merral fous Is complementary to the radlaHer)
abgasbeds: :
I A eet + subsraner
r ¥ | Catalytic Propernes (AMEE
F SS eur Ulead
: (Fansitiou uAthdl aur es good) mers! provides a.surbare for fue, reacrene-
cxanaple,
Mud, +t catatyst for decompositan oF KClOg
Mo{ Fe: ued Catalyst: for: manufacture oFaumour'a ;
Co-Th alloy ased. lu, syutuesisF Gasoline tu his ther eee proced
.
Ni ae Caraiyst hydro qeuation oF ethene te eeare ot [40'C x
s
Goutact process of Industrial producteu oF Saipuric add, sul dphar dtertde
laud oxygen from aly reath revercibly wey sou la balyst x pintntcd a ashes bes)
— ASo,tog Sutebed . 2505 wu
arberhs
Cop b Hy Formed by reacthu of CO 4 MeO at Soo’c wink Fe-br Carty
Corh,o —U& co tHe.‘ Feremariee of marersialcemapotiis ‘ Tan te
when small ateuts oF Hudregeu, Carbou aud Mitrogen are areal
In the Interstat spaces $Peryskal lattice , uch compounds ave called
nbersitHal covapeueds-
_ | steel ¢ CasrLrouv IntersHHal Compounds of carbou. 4. (ran +
~ | Here, duc to preseuce oF Carbon malleabiitty: 4. duchy Bs vedtuce/
|audre tenaerny lereases. : Us. ay ho 6
= | Souse propersies oF--tatersHiHal .Compouucle >
1 |Are hard aud goed toadustors of heat and. electrl
a-| their chemical propery ls similar to Huat of parent
3. | thety metttug pours ave Ligher tian pure metal
4. | Density ts lees eau. parent metas ~ yh
5.| meted Cavbides are theutaly jaert aud exenuly awd an diavesee
6. |Hydrids of traustHon Lwteral are used, a8 _pewerhul Fecurticy - ageurs
=
it =
Formariou oF-alfoys e ‘=
= | transivou meral formalioy's =
a the metals with similay radit aud siuulay Papas readily ie
forms alloys. i {Ss
&
Allows » i &
ce
; .
_ _ |_Wen-Ferrous alteys a
alleys Lave dtova oF crue eles paudewsey | alloys Lave Aton oF frangHhon
distribured (A arows oF jron. The perceut-| cleus oruer fuan Fe aud nuxkey
of pron ls prove: Henge Ferrous alloys» lwith mou. Hau SHY Clement~ t
ie nickdl precl, sraiuless steel, Cheanaiaus shed. 6g brass ~ “orrer *
all sree have Rf of arbour “paer.
iFa
anasiyia
Bronze alloy oF .Copper+ HA.— 15 tong ) strong 5 corrosion Fes!s rant
— used Pormaklug Hophies, statues yedals »
Copra-nickel = alloy 6F Copperaudnickel - used formakiug machin,
parts \ok marine sulps,, vocts.
Staluless Sted - wed For Coustruchen rFourer fuselage of ultra
hia Speed air craFe:
Corumon propertes OF d- block elemeuls. .\)" No sey
-| Mang mtetdls auol ere \tondpouuds 7% pardauea gq vetse
Phystal propertes... svi. 1
AN_traustHo -elemeuss are.lustorus 4 Sutulug u
They are hard wit uiple deushy
Are good couduttoss Af ledt-4 elechreiry
Have high melting artol beiliugspoluts -.
Have good tenadty anol malledbliity .
Gu form alloys cust trauslHon 4 non-trqausitte vatemeuts
Can be used as good cupalysts
chentca! properttes\!
. |All d= block elements are ue te
2. | they extibl) yarluble valenues (0 forus cobured Comptercs
B.| ate gerd weduisuy ageuHt ow
Y-| form Msoluble adds f hepatertcid
S+| Tron, Cobalt Cy,“Melybdecuum are bigtogitally used—
6. Catalyse Trolepdend rectlors eat ama=
+ | olfterentes.- :
——Ee
ticenents ef Firsprow ditfey Foun aad avd wee ‘powei
habitation .L uigher oxtdabiou srates:ju compouvrds: «
eqn MO ‘
cgz- Ho (V)-sud WCW) .commpouds are move Shable Har
er (Dud tin(wil)--
: Hiqhesr O-S For erenreuts In f°" row > +7
c Pend 99g 2 PB
1
4
‘
7 ‘
oi ‘
¢ | Extractou of meats. > 22.0.9 + .
7 ‘
“_Mimeral_— | A naturally ecoving subskaure from earths cmsk courgiurg ©
i Inorganic salts; Soltds, siliceous matter ete». €
= 4 é
€
ore - Mineral wutde couratas. Wig, Rerceurage oF smektl and from wulee
[. Hie mural Cau be Casily txtraced. are ee. €
Metallurgy | commercial atraction OF. metal frous ove .
t
Ta
Aydro merallurg: Elecromerau:
meral is extratred by aquety | mefal ts extratred bey
7 f solution of Hs salts ustig -elechroly He, reduuten of
: hugh reupransre wiles | sutpable reageuis» | Meier mettitie Lovapeccent <
yedudug agehte Ue. E 1
6AM.
YUNG Gale et ae= ae
steps involved in process. oF Extractton -
Eee ee
poget
(| Couceutration :- atrer miutug Hue ove from me Cartes crust
impurities termed as gaugue areremoved From exe.
love gets coucettrared «
The sand, mud aud oruer Umoauted trnpurities Witte, remain mixed
wt ite
fH ove cleposit e
ere Fs seperated trom gavque by
fl h(araute clastificalion
Y
“a He Maquette sepration
lo a tation.
=
Metals Mineral - Ore.
Iron. Haemarire = Fe, 0 Hawatite
Maquetite whi Fe: Oy rem buts frou Caen be
Limouire 2Fe, 03. SH.0 extracted.
Trou pyxtrs Fes
Sidevire FeCox
Copper: Chateopyrire CuFeSy - |Chaleo pyrite
Chalcoctrre Cus S Chaltocite .
Caprire Cug0 |
Kine. Kine blende ZnS Zine blende.
Lrudre ZNO
Calamine 2n 60Hacmattre - (2,02
a
Extraction oF Tron From Haematite 07e using, blast fumace .
Composition oF Haematite ore
—_____ | Fe On + Sion FAIZO3 +phosphares:
gwgue.
iren gs extract from haemalre by bts yeduchion “sing
GoKe and limestone.
Limestone acts as flux lt cambraes with gangue te fom
moiten slag-
Exrrauton mvolves following Ireps :
1-|Coucentatou :- - powdered ore —» washed by Hydratt{c
- Wgurergaugue are seperdledt ClasstFrep
- ore 's coucentared .
@- | Roasting :- Cou" ore ts heared in a current -eF air. i
conver
Sulfur 4 arseutc tmpuxites —~—. oxide here pooats’
Ferous oxide ove Is converted tuto Fe, 0 :
Haentibe. |
[Arco +02 ——> 2Fese
3-| Reduction (ametting): Step carried outta blasrRemace. +
Compuibiun 3 PUR. 7
| Blast Furnace: tall cylindrical. tower > FP
Haig Biws Seen I, Bock
dlamerer - 5-lom,
mh Shade
works on - (Commuter Current principle.
ot
CMorge coms chewen, hor ques
Weve “p Hee Fox.AL
The charge contting oveaudime sroue bs tAbreduced into Furnace.
A blast of prekeated air Js fuwoduced Wp tre Furnace below Mee host,
Reactens to dae blast firmace :- There One differedt Lemprabars he blurs
Ar top temp = 500K gerne,
Max bem)? of furnace = 80008 above tuyers
Mrsree ber tone
-|zone oF Combustion - Combustion of coke wi'th Oo In alr.
Zoue oF Reducton - Reductten oF Fe 03 fe metalic fron.
Xone of Slag Formahen — Fermatien of Slag by reattten of garigua
arith limestone.
Cenvieal reactions baking plac in Ay «zins ef blah fernate.
FMT RE TEE FT Pte
Zoue oF Combustion :-
5 -l0m Frova bottom
het air blown reacts wit colce from charge R= Co
charge coming
aud racks with
2 1 Fee
a fuel halo a
reductug agen.
u
hot gas rich is Co vise upwarok .
Zone F Reductim (22-25 m near the top). )
temp around - 400K J 33 Hh lao oF
Fe,04 reduced tocpougy iron hy Con “LEP
Legeed penta
FeO, + 360 ——> Qre)+ 300 9
Haenaspire ud
Hee IT0ATS pepe
Wa Vex crep_Httats Corto the
YORAIVG tag 4 TEE Tron.&
Removay # gaugu
\can_ Cao t CO
pines with gaugue ber form moften (AF of
Calerum Silicate aad calcium -aluminadre -
‘Xone oF Fusion (15m ht)
height - 5m 2
a?
EEL Mn k P.
A rinos 4 Ca; (PO,,), present Im Irom ove
The speugy Iron corning down in Furnace melt absorbs
impurities UKE Cy St, Nin, 4S.» This molten tren CNet
at bolton oF furnace.
molten frou fs poured tuto moulds
The solid blodce arecalled pigs
fig fron Contains - 4% Carbon
— |@hen pig tren, remelted vun Inte moulds 4 cooled ft
Gecomes cast-iron -
| REF ing
| pure iron can be obtained by eletrrolyHe vetining of
Impure Iron: 3
4.
1) Mature OF or
Choice of extratron fechnique gererned by
biuiry and cost oF reducing &9 eur. cheap Coke seg
| Havilabitiy oF Ay drauue power.
[Purity of preduct requrred
(alue % by Produc.
eSamimercal forms oF fron
1
Cast laroug lt Steel. ee
ast tron Wroug ut Sel
frou 7
—___j Z
Hard and_britHe | very sort 1. Netter too kard
hor be SFr.
-| Cotas 4% Corb
2. Contairs (e535 Hien
8. O-2f2y,
O-2¥. Carbon
Carbon.
Used - makiug
B. pipe, 4425 for
38. Used in bullddes
DIPS, raanfars
Stay bolts, engiue lakrastruchurr, feo
automohve ~|. bors t& xivetts Ships , quronie bits
AYES) POS, MO CAP OV Efe»
Pe 2 Ip.
Pars , ureseS 8 |Sunertrausiion (F-block) clemeuts) -
LANTHANOLDS and ACTINOIDS
-|Elemen!s whore F-orbirals get Hiled up by electton s. are
Called - £- block elements -
-| tuese elements have t= 14 e7 in Mele f-orbital t
owt in Me penuinmate energy level
2 en ie outermost orbital.
4 | properties of F-block elerment-
= properttes similar to _d- block elements
~ electrons are added fo P-Subsuel’s F (n= 2)level.
=| placed ber cn-i)d ns block element -
generate oF La 2 (A-2) ett (a-Dd" ng?
general e~ofAc= (n-) P 4 Ca-Dd'ns®
Lanthanoids beg)" with afamic Ne. 57 — cud -T/.
They are called Rare earth metals :- «4 of difAicuity IN Ext athys
them economically in pure formeF Lan taqnetds. (
These metals are soft witha moderate density |
Have high mening (1000) b betting potnis (- 3000")
~| Lanthanclds fy metalic stdke are vey deqthive & Feserrible
alkali alkaline _earta metals.
-| eur? 4 Ub** ave Hre most Stable dipositive metal tary
A cerium js exception Whivh Frrms @ Stable +H speve -
-|Lanthanolds fave liwer heat of dhemizatien -
fic tadi? decreases trom Mipm oF La 4 'Obpm for Lu .
3 Is 15 because 5F orbitals do vot Sleitd “the outer Ss 4 Sp
NX [aro effectively ,Jeading ta Increase in offecHre putea’
rge £ decrease in pnie site,
Lantranerds Form hydroxides _Of general Arm
3 (04! — > qumare tonic £hasic
___-| Since_fonte Size decreases from Lor hho Lut} fy, partei,
| 4 eydroniets bevwases ,=A L_
=| in +3.0+S , many ef Lanthanoits Are Wloured, MesHy green
| PINK ¢ yellow +
CL —————————————————————————————————————————————
due fo fee? Slieleliug thpeet tre Vadis pluncays
+ | properties of Lanthanoids
5 =
1: | Soft Metals uume Silvery whire colour | moderate deasive A 7Zqeri
Color + briqutness reduces on expesure In ar.
: 2: | Good condacthors & yeart electricity .
ein demic
ahd tonic rad of |
autiquoids.
3-|All are non-radioactive except = Promemium Lanteanotd
ahnte ¢ tonic rade’ decreases From La fo Lu This fs AnowNn -S
Lan te anotd Contra erion «
5.| Binding to water ts commen.
6-| CN are usually Ae gredher tan ¢ Eypiealiy @;F .
~7| Lanthauctds are Strongly favramag netic
Gadolinium becomes Ferromagnec below 16° e
hi terbium | ‘dy spresium, holmlum erbium , thultun 4 Ylrorbiun
become ferromaguertc wt lower temp, *
3-| Magueric and ophical properties ave larglg independent oF
Gnviernment-.Electroute ntonkiquiatou :
ec ef lantuaneis ts [Xe] AF" 5d°* 687-
lauthanoids inyolve gradual Hiding of F-crbital.
the energies aF $d and 4F orbitals are very Close,
for Lanruanum YF is sliqutty higher ran 5d. :
The lanthanum Has ec [xe]es*5d' and mor (Ke 65 4e!
Gadolinium (Gd) and lubiam (tw) have 5h eledven te
make F-orbritat taait-Filled 4 ull- Pulled which vender Hrern
| extra srabiv'tg .
Fonizattea tntealples.
leutzation entudlpy clecreases from Lf fol (wits some Frregulas
vartaHen
The successive Loursatton ennalpy fer element Increases
as (TEs >Le2> 16)
9) oxidation stare -
—| t3 0-5 is Common in elemevits In whith Q € of 8-Subshea
{hrm dor F— gubshell are removed
the HP elecrousare Strongly screened by inner 554 Fpem_|
Thus 4f e~ are not involved in bonding
|
|
D) Qlour.aud spectra. i
= =
ome Hivalen, lous C ih 34) are Coloured in Solid shire & Lely
& tu Sof? .
| Goler (Ss pure due to £-F transite, whitch Correspond to
nergy in visible reqlon of eletto maguthc spectrum.
Fue.
brit ~ 4F ® — Green
Tm = 4p l® ~ aren
Na ET KES rink
Er 38 - 4k ~ pinkLL
®)
Atomte aud tenic radi (Lanttraueld loutaten )
as we move aloug lauruadued Weve te qyadial dewreare’
22 Qhouvic & joule padi!) —> tra taauosd Coulda bier
Kee gus added tae nuchar charge Intrease, Asicleas
Charge lucvecucs dfomrie £ seule rAdiy ole crease.
the new @ ~ Wu adoteol Fo scume {nner AP Subs tell. Thus 4 >
| C"sluid eau ottr prom the nue ay hharge pooby ow
be Hur Aifpurec! notre,
Applicaton -
«|4s Heey are coloured, Used in grside surtace oF @ televRien Hlba
ex Compurer montterts Coated uty UNy parttles .
eq +- Mixed Oxide OF eeonpmicns 4 yttrrum reledsed Sa lense
red colour.
3. lhe opreeledrontes applitatirs nuke lautsarien fern as tthyve
fous i Luminestent material.
44
Nd: VAG laser _— "leedymium doped ytrtum aluminium gBrd
x
Erbium doped ber amplitrers are significant Aevktes in opt ca—
bre Lommunfratters.
hanthancids are Used UM hybrid crn, Wiper erltios
Apeomanat magnelActinotds
fa rock on earth.
| Achuerds ave (ess veacHve than lanteanolds .
wh ra) wid = Lawrensturn (22103)
eq are all radioactive. p man-made
Halt Uires of Hronum 4 Voanium are very loug + Hucy ext sh
Tt begins at thorium (2
elemenn have Ing Henstires, Uigh melt petup (2 100%
liigu bolifug potat. 7
They extiblt range oF oxidaticn No. to t2 tore
CaGetGRng Siecle CSee
Most stable 0-8 = +3.
forte radls decreases cls 0 Move across Serres _Aekinote
Con tachi arr
properttes of Alchinotds:
Appeay silver, White in tolour.
Are highly reattye Vaddioattire element.
| Axprelence decrease in atomic 4 lonle Yadti' Fron dlfinurn
4.| Usualiy exhibit +3 0-S
[because these oxtdes convert heat-energy Frcox but yy,
to Lawrenctur — 4ckueid contrackion .
Applications
| Th(VDoxtde, Thlg with 1% Ced2 used as prajor
Source of indoor lightning btlere incandes ten ¢ lamp
a
eto A
Gas to a0 mrense Vght -
. keeshal
Heat = ———> Ugh
aay eagy.
Do_biff" & Simbeio of layttienoics £ fetereorols