* The d- and f- block Elemert /ASN CHEMISTRY

TYansition mataly have high meting point,

OTYansition metals and many qy thei compQumds high Boilng poit omd high enthalpy o
show ponamagnetic behavio. Give eason, atomisation. TYomsition metaly ae
They have ynpaned elactyon s much hasder than akali metals, Gtve veason
cut is paiamagnetic . cut is diamagnetic. They have lange mumber unpaiyed electrng.
Give reason
So, They form styong metollie bond.
Cut has unpained electvons Zn, cd ond Hy have louw melting pot,
Cut does not have Unpained electrons low boilng pont ond low enthaley t Atomisatia
TYansition metals genehaly fovm colaed compoundg Zn, co and Hq ase Soft metals. hive Yeassn.
Gaive Yealm.
They do mot have unpained electyo().
They have unpaied electYons. Unpaned electyon So, They foim weak metallie bond.
absb coloui from visible region and undengoy TYonsition metaly ond thein many compoumds
d-d tyoansition So, the ynabs&bed light ig act as good catolysts. Give yeason
tyansmitted
3+
os complmetony colas. O0 They have albilty to show dibtrerent
9 Sc is colales in aqueous soltion shere a Ridatim stotey
T is colued. Give yeaSon. 2
They have abilty to form complestes.
T has unpained ele ctvem. So, d-d transttton
3t IASN CHEMI STRY/
possible. Se does not have unpaed electrons.
So, dod tyonsttin is not posst ble. youtube Telegyam Instagram
 TYansition metals foym complee compoundy. 2) TYan sition metaly eehibit vauabe
Give Yeason, ASN CHEMISTRY/ oidation states. Give veason .
They have empty d-vbitaly to accept Enevgy dibbenence between n-)d ond ms
eleetron pawy fyom ligandy. oY bi tals is very les. So, electyons
O They have Small size omd high change denty and ms avbitals Con paticipate in bndng.
O Zn, cd ond H9 ane not transition elements. Mn exhi bits angt um bes Oi datim stotyl
hive yeason 3d Seviy, Give yeason.
They have completely filled dor bi tal a) Mn C25) =
in it's groond state a uwell as it's oxidatim State Al electyons in 45 and 3d oY bitaly
(0) Sc is a tyansition elemet. Give veason. Can porti ce pote in bondung .(+2,+3,+9,+s,+6,+)
Se hasincompletey filled 3d abi tal (3a) cu ions ahe not stalble in aquecn souti.
in its iound Stote. (oR)
Siver (Ag) Is a tyansition elemert. Give veasm. copper () ion is not knon In aguey sotin.
Ag has in Completay flled 4d vbitals in Give Yeason
it's +2 oidatin state 4a) A 2 t (aa) cu Cag) + Cucs)
cult ion has higher negative hydhati
enthalpy than ct i0
iom,
ASN CHEMISTRY/
 5 what are inter stitial compounds? strongey Reduang aget than Fe.
Many tran sition elenet foYn intenstutial Give yeason
compoundg. Give veason ASN CHEMISTRY/ *3d1)
2+
3d) isis e a r tham
crystal lattice tyonsition element F+ ( 346)’ (345).
have itenstitial sites (voi d). So, Small otoms Because, in later, an electron s Yemoved
uke H,C,N occupy itenstitial sites fYom paiedor bita(dittiCult)
to form itenstitual compounds. Highet oidatin stote meta exhibited
24
and m* have Bd" conft gunotm in it's oide coY) Fluoride. Give veassn.
Bt, Cyt ats as a reducang aget. Oxy9en and fluorine have Small Size and
Mn ats a Ox diting aget. Grive veason high electvoneqativity so, Theg can o die
GA* Can lose an electron to fvm Cr. metal to ighet oxdatin state.
3
hay stable half filled tag electyonic cmkgnti 0 why is highe oxi datin state Mn with fluorime
M* Can accept an electron to form M. 4 4 CMnFy) while with oxygen is t (Mn0+).
Mit has stable halt fled 3d electrone Cmkgatin Give Yeason.
( Em foY Copper is positive. Give veaSoY OXYgen forms Pr-dT mutple bondy
Cu has high enthalpy otomis ati on and with metal.
Low hydvotin erthalpy ASN CHEMI STRY/
D Highet oxidatin state o metal eseibi ted The louet oxide , Tranitian metaly is Baic,
in OXO anions a metal. Give ve ason. the highet is amphoterie/aidic. Give veason
oxy gen has high electvonegat:vity Adc Strength o des increw
Oxy9e can foxm mut ple bondy with metal, with incree in oidatim state og, elemend.
2
Eg: Mno, , Cyo ASN CHEMISTRY/ 2 Cobat ()is stable in aquecw sotion bt
Mt is more Stable than Fe towa de in the presenca o complexin veaget
oKi dation to +3 stote. ive veaSo). it is eouty xi died. Give Yeasom,
My2t hay more stable 3A5 electyoic Co Cu) ion has gYeatey tendency to farm
conigunatim( Halt Hlled) complexes than CoC) ion, So,
(23) F is more stable than Fe.ive veason Co Ci) tion is oi died to Co Cr) am in pretene
F* has halt Hile d electrnic cmtigurastim Compleng veaget.
(349) 8 The d configuotion is very un stable in
2hd
24) Ienisotim enthalpy cu is voy high. ions. Give yeason.
A Cut has Stable electrorie conhguatm 34) Iors transition metaly with d' contighai
E value foy Mnm couple much moYe Lose one electron to get d configuatim
positive than that foy t Cor) F l * that mee stable nsnp)
/ASN CHEMISTRY
M e Mt
(sd) 3d5
Cmore stobla
M has a high tendency to get reduced to Myt )
2) Transition metal foYm loy,Give Yeason, 3) Atinoidy eehibit
ibit ieate wmb
A Because they have similar otomic Yadii. oXidatiom stoty. Give rea son
6 E/n valeey ae not regul foy 3d seg les eneng dittorence between Sf, 6d & s
elament, Give Yeason lASN CHEMISTRY/
bitals in astnoidg
in Inisotion ethalpiey 39) sepatetim of a mitae of lenthanoid
duffict. Give Yeason
and hydhation enthalpieg. element is
3 E2t/M Vaes of Mn and Zn ae They hoave Simlas atomic Yadius s
negative tham expeted Grive Yeason chemical propetieg.
Conkgoad
Mn2t (s&)- st abe halt fA(ed electhonic 39 chemistry a atinoidy is compli cated as
filled electroic lathanoidy, Give Yeason
Z2t (3d - stable completaly Cornposed to
confiquration ond study their
They areYadioactye
kaboratny is diktiut
yadii.
ZY ad Hf have simila otomic chemisty in the
lemen o heatar wmbey oxidatim statiy.
Due to larthamoid Comtactin the 2) They show
gi?. yd and sd serie have simila atomic Yadi. 3) ce1t is good onidiaing agent. Give veason
Atinoid antaction is greatar than cet has a stromg kendeny to gain electon to
t3 oedatin State
Lanthanoid
Contraction,Give Yeasorm attoin the m¡te stable
poovly shielded thon Give
Give reassn
electYy are more 38) E is a Strong redu cing agent.
tenden to lase ele ctron to
A) 5f
4f electyog. E has a strong
t3 oX dation stat.
attan the most stable
ASN CHE MISTRY/
* Sc (2) =A 3d' ys Fe (26) - aA 3d s * what u lanthanoid condyactin ? Giive reason.
Co C29 =TA3dt ys
Ti (2) = JA3d lgite two
CmsequeneS of lonthanoid contratian.
Ni (28) = JAJ3d s
v (23) = JA] 3d (A) The steady decveese mthe atomic and
ionic adii oe lathanoid element with
Mn (25) = JA 3dys
(ncrease in otomic wmb s called Lothanoid
magnetic moment,
* spincy u m n t ) BM m=Na. unpaired Es Contratim.
3+
Reason: poor shielding effet q Yf electrns
3dys
Cx C29= [Ar] Co(2¬) = JA] 3dt 45 cansequences:
3+
Co
TAJ36 Baic strength oxides & hy dioideg q
CHEMISTRy
ASN etomic rwnh.
lanthanoidy de cveaeg cuith mcreelng tn
u=/ n Cn+) BM
=/3C3+2) BM V24 Bry
BM
are similas.
= V15 4-9 BM
(Hf) have Simily atomic
Eg:- ZiYCmivo z) & Hafniom
3.84 BM
Tadi.
* pyepaati kmn Oy:
2 k2 MnOy t 2 Hs0 * wte simlarities & dibserences Blw
4 KoH t O,
O 2 Mno, t lothanot ds e actinoide.
Mno,t 2 Hao chemisty of
t ’ 2 Mnoy t
0 3 Mno Similaties:
O They are electiopoSitve in nate
y Fecr,o, +8 Na,cot t0,’8 Na,royt2 Fe,0 +8 co, ae eactive metay and
2 Na,COy t 2Ht Na,,o t 2nat + Hyo
> kz ayot 2 NacL
at a strorg yeduing ogety
3 Na,Cr,o, t 2 kel
 oidatim state of Lathanoidy ) +3 diffeences:
CommaY oe a-adioadive
OLarthanoids ex cept pYomet hivrg
coMmom sidtim stote, ceiUm +3,ty Yadioadive elenet
element. All atinotds oe
Commo oidation statyt Europium O+2,t3 Lonthanoidy show imited oidatin statey.
Lathanoide
show limited
Gieneal electroric Confquraticn state
Atnotds sho Lange no. q oxidatin
ley balic.
elenenty oides s hydroidey q lathanoid ae mYe balic
seidatin Stety ) Ma hydroxdes ot Atnoidg ae
O Maimon rwmbes of
Mn follomg equating
ding agent tn t3 O.s * Complete the
strong oxi +3 Gdatn stote
A Sc t 3s ++
3) Exhibity only CO + 3SHT+ IyHt>2 H,o
anet zeO m +2 0.S h,0,?- +6 I+ I4HT ’ 2Ct,
t 3 I t Hso
( spn only magnetic
unpaised electrony Y
S) Heve more wnmbr Cr,0 + 204
Have highet melting point 2.
2
Fe&t Fe2+ 8H’S festt Mt t qH0
5 Fe2t+ mnoy +
y 2 Mnoy + 5 S + I6H 2Mtt 5 S+ &Hyd
Tdentify the im cich
aget O Gt
Ostrong reducng Mnt 2 MnOy t s C,o t |6 HT> 2 Mtt+ lo co, t 8 Hyo
stog ding agt t H0’ 8 MnO2t 6 So, t 20H
unstabu n agulysot
Cut 8) 8 Mnoy t 3 S,0
heat KzMnot Mnot0,
colsilg A) Cut 2 kMnQy
Mn t s SO.
+ Ht
ASN CHEMISTRY 2 Mny tsSo,t 2Hz0>2
7 ASN CHENISTRy
youtube Telegram Instagram